FR2944226A1 - Fabricating a repositionable self-adhesive flexible tissue article, comprises applying silicone layer at the liquid state on a transfer paper, applying the article on the silicone layer to produce lamination, and heating the lamination - Google Patents
Fabricating a repositionable self-adhesive flexible tissue article, comprises applying silicone layer at the liquid state on a transfer paper, applying the article on the silicone layer to produce lamination, and heating the lamination Download PDFInfo
- Publication number
- FR2944226A1 FR2944226A1 FR0952447A FR0952447A FR2944226A1 FR 2944226 A1 FR2944226 A1 FR 2944226A1 FR 0952447 A FR0952447 A FR 0952447A FR 0952447 A FR0952447 A FR 0952447A FR 2944226 A1 FR2944226 A1 FR 2944226A1
- Authority
- FR
- France
- Prior art keywords
- article
- silicone layer
- lamination
- adhesive
- layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0086—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique
- D06N3/0095—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique by inversion technique; by transfer processes
- D06N3/0097—Release surface, e.g. separation sheets; Silicone papers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/20—Adhesives in the form of films or foils characterised by their carriers
- C09J7/21—Paper; Textile fabrics
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/20—Adhesives in the form of films or foils characterised by their carriers
- C09J7/22—Plastics; Metallised plastics
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
- C09J7/38—Pressure-sensitive adhesives [PSA]
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/12—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
- D06N3/128—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with silicon polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2483/00—Presence of polysiloxane
Abstract
Description
L'invention se rattache au secteur technique de la fabrication d'articles souples autocollants ayant la capacité d'être repositionnables. The invention relates to the technical sector of the manufacture of self-adhesive flexible articles having the ability to be repositionable.
Dans de nombreux domaines techniques, on a déjà proposé de réaliser des produits divers autocollants ayant la capacité d'être repositionnables à volonté. C'est le cas notamment des étiquettes autoadhésives. On connaît également les stickers muraux, généralement fabriqués en matière vinyle ayant un pouvoir autocollant et, le plus souvent, proposés avec un film transparent, afin de faciliter leur pose sur des surfaces lisses (murs, meubles, miroirs, ....).In many technical fields, it has already been proposed to produce various stickers with the ability to be repositionable at will. This is particularly the case with self-adhesive labels. Also known wall stickers, usually made of vinyl material having a self-adhesive power and, most often, with a transparent film, to facilitate their installation on smooth surfaces (walls, furniture, mirrors, ....).
On connaît également, par l'enseignement du brevet FR 2830027, un tissu enduit dont les deux faces reçoivent une couche d'imprégnation, notamment du polychlorure de vinyle. La première couche d'impression reçoit un vernis, tandis que l'autre reçoit un adhésif sensible à la pression. L'adhésif utilisé pour repositionner autant de fois que nécessaire le tissu, est à base de polymères acryliques ou méthacrylates ou dérivés.The teaching of patent FR 2830027 also discloses a coated fabric whose two faces receive an impregnation layer, in particular polyvinyl chloride. The first printing layer receives a varnish, while the other receives a pressure-sensitive adhesive. The adhesive used to reposition the fabric as many times as necessary is based on acrylic polymers or methacrylates or derivatives.
Le fait d'utiliser une matière adhésive du type acrylique, présente certains inconvénients.The fact of using an adhesive material of the acrylic type has certain disadvantages.
Si le support, sur lequel doit être appliqué le tissu enduit, n'est pas très propre, la poussière va adhérer sur la matière adhésive. Etant donné qu'un adhésif, à base de polymère acrylique, n'est pas lavable, il apparaît que les impuretés captées vont altérer, d'une manière significative, le pouvoir collant du tissu qui sera, par conséquent, difficilement repositionnable, ou à tout le moins, dans des conditions non satisfaisantes. On observe également qu'un adhésif, à base de polymère acrylique, a tendance à sécher dans le temps.If the support, to which the coated fabric is to be applied, is not very clean, the dust will adhere to the adhesive material. Since an adhesive based on acrylic polymer is not washable, it appears that the impurities captured will significantly alter the stickiness of the fabric which will therefore be difficult to repositionable, or at the very least, under unsatisfactory conditions. It is also observed that an adhesive, based on acrylic polymer, tends to dry in time.
L'invention s'est fixée pour but de remédier à ces inconvénients d'une manière simple, sûre, efficace et rationnelle.The object of the invention is to remedy these disadvantages in a simple, safe, effective and rational manner.
Le problème que se propose de résoudre l'invention est de proposer un article souple, autocollant et repositionnable à volonté sur tout type de support avec la possibilité de le laver si nécessaire, sans pour autant affecter ses qualités d'autoadhésivité dans le temps. Pour résoudre un tel problème, il a été conçu et mis au point un procédé de fabrication d'un article souple autocollant repositionnable selon lequel : on applique une couche de silicone, à l'état liquide, sur un papier transfert ; - on applique, sur la couche de silicone, l'article souple, de manière à réaliser un complexage ; on chauffe le complexage obtenu.The problem to be solved by the invention is to propose a flexible article, self-adhesive and repositionable at will on any type of support with the possibility of washing if necessary, without affecting its self-adhesive qualities over time. To solve such a problem, it has been conceived and developed a method of manufacturing a repositionable self-adhesive flexible article according to which: a layer of silicone, in the liquid state, is applied to a transfer paper; the flexible article is applied to the silicone layer so as to form a complexing; the complexing obtained is heated.
Il apparaît, d'une manière particulièrement avantageuse, que l'application du silicone en tant que matière adhésive permet de repositionner à volonté l'article considéré permettant, par conséquent, de conférer à l'article autocollant repositionnable ainsi obtenu, des avantages propres à l'utilisation du silicone, à savoir la possibilité de le laver, la tenue de ses caractéristiques dans le temps, la non migration de produits gras,It appears, in a particularly advantageous manner, that the application of silicone as an adhesive material makes it possible to reposition at will the article considered, thus making it possible to confer on the repositionable self-adhesive article thus obtained advantages particular to the use of silicone, namely the possibility of washing it, keeping its characteristics over time, non-migration of fatty products,
Les caractéristiques suivantes permettent d'obtenir des résultats avantageux : on chauffe le complexage par passage en continu dans un four porté à une température comprise entre 100°C et 160°C et à une vitesse comprise entre 10 et 30 m/mn ; - on applique la couche de silicone dans une proportion d'environ 150 g/m2.The following characteristics make it possible to obtain advantageous results: the complexing is heated by continuous passage in an oven heated to a temperature of between 100 ° C. and 160 ° C. and at a speed of between 10 and 30 m / min; the silicone layer is applied in a proportion of approximately 150 g / m 2.
Compte tenu des caractéristiques à la base du procédé selon l'invention, il est possible de découper, notamment par laser, le complexage en fonction de la forme souhaitée de l'article souple.Given the basic characteristics of the process according to the invention, it is possible to cut, in particular by laser, the complexing according to the desired shape of the flexible article.
L'invention trouve une application avantageuse dans le cas d'un article sous forme d'un tissu 100 % polyester ou autre, notamment du coton.The invention finds an advantageous application in the case of an article in the form of a 100% polyester or other fabric, especially cotton.
Une autre application du procédé est le cas où l'article est un film polyester faisant office de support d'écriture à un marqueur à encre effaçable.Another application of the method is the case where the article is a polyester film serving as a writing support for an erasable ink marker.
L'invention concerne également le complexage résultant du procédé, à savoir : un tissu autocollant repositionnable dont l'une des faces présente une couche d'adhésif sensible à la pression et résultant d'un transfert d'une couche de silicone ; un film polyester faisant office de support d'écriture à un marqueur à encre effaçable dont l'une des faces présente une couche d'adhésif sensible à la pression et résultant d'un transfert d'une couche de silicone.The invention also relates to the complexing resulting from the process, namely: a repositionable self-adhesive fabric, one of whose faces has a layer of pressure-sensitive adhesive resulting from a transfer of a silicone layer; a polyester film acting as a writing medium for an erasable ink marker, one of whose faces has a layer of pressure-sensitive adhesive resulting from a transfer of a silicone layer.
L'invention est exposée ci-après plus en détail à l'aide des figures des dessins annexés dans lesquels : la figure 1 est une vue en perspective d'un exemple de réalisation d'un tissu autocollant repositionnable, selon les caractéristiques de l'invention ; la figure 2 est, à grande échelle, une vue en coupe transversale, considérée selon la ligne 2-2 de la figure 1.The invention is explained below in more detail with the aid of the figures of the accompanying drawings in which: FIG. 1 is a perspective view of an exemplary embodiment of a repositionable self-adhesive fabric, according to the characteristics of the invention; Figure 2 is a large scale, a cross-sectional view, taken along the line 2-2 of Figure 1.
Selon une caractéristique à la base du procédé selon l'invention, on applique, à l'état liquide, une couche de silicone (1) sur un papier transfert (2). On applique ensuite, sur la couche de silicone (1), l'article souple (3) considéré, comme il sera indiqué dans la suite de la description, de manière à réaliser un complexage.According to a characteristic underlying the process according to the invention, a silicone layer (1) is applied in the liquid state to a transfer paper (2). The flexible article (3) in question is then applied to the silicone layer (1), as will be indicated in the following description, so as to form a complexing.
Le complexage résulte donc de la superposition du papier transfert (2), de la couche de silicone (1) et de l'article (3). Le complexage est ensuite chauffé, par passage en continu dans un four, porté à une température comprise entre 100 et 160°C et à une vitesse comprise entre 10 et 30 m/mn.The complexing therefore results from the superposition of the transfer paper (2), the silicone layer (1) and the article (3). The lamination is then heated, by continuous passage in an oven, brought to a temperature between 100 and 160 ° C and at a speed between 10 and 30 m / min.
La couche de silicone est appliquée dans une proportion d'environ 150 g/m2.The silicone layer is applied in a proportion of about 150 g / m2.
Des résultats avantageux ont été obtenus en utilisant un élastomère de silicone caractérisé par une viscosité comprise entre 100 et 20000 mPa.S à 23°C, une dureté Shore A comprise entre 3 et 30 suivant la norme DIN 53505 et un allongement compris entre 100 et 1200 % suivant la norme DIN 53504.Advantageous results have been obtained using a silicone elastomer characterized by a viscosity of between 100 and 20000 mPa · s at 23 ° C., a Shore A hardness of between 3 and 30 according to DIN 53505 and an elongation of between 100 and 1200% according to DIN 53504.
Le papier transfert (2) est un support lisse ou graine caractérisé par une force de démoulage comprise entre 1 et 200 N/m et composé de polyester et/ou de polypropylène et/ou de polyéthylène et/ou de papier traité notamment au stéarate de chrome.The transfer paper (2) is a smooth support or seed characterized by a demolding force of between 1 and 200 N / m and composed of polyester and / or polypropylene and / or polyethylene and / or paper treated in particular with chromium stearate.
Le complexage obtenu peut être découpé, notamment par laser, en fonction de la forme souhaitée de l'article souple autocollant repositionnable (3) que l'on veut obtenir.The complexing obtained may be cut off, in particular by laser, depending on the desired shape of the flexible repositionable flexible article (3) that is to be obtained.
L'article souple autocollant repositionnable (3) résultant de la mise en œuvre du procédé de fabrication, peut être un tissu, par exemple un tissu 100 % polyester, coton ou autre. Dans ce cas, après mise en œuvre du procédé, on obtient donc un tissu autocollant et repositionnable dont l'une des faces présente une couche d'adhésif sensible à la pression et résultant d'un transfert de la couche de silicone (figure 1).The repositionable self-adhesive flexible article (3) resulting from the implementation of the manufacturing method may be a fabric, for example a 100% polyester, cotton or other fabric. In this case, after implementation of the method, a self-adhesive and repositionable fabric is thus obtained, one of the faces of which has a layer of pressure-sensitive adhesive resulting from a transfer of the silicone layer (FIG. 1). .
L'article souple peut également être un film polyester du type de ceux parfaitement connus pour un homme du métier, et couramment utilisés pour faire office de support d'écriture à un marqueur à encre effaçable. Dans cette application, le film polyester obtenu est du type autocollant et repositionnable et dont l'une des faces présente une couche d'adhésif sensible à la pression et résultant d'un transfert de la couche de silicone (1).The flexible article may also be a polyester film of the type well known to those skilled in the art, and commonly used to serve as a writing support for an erasable ink marker. In this application, the polyester film obtained is of the self-adhesive and repositionable type and one of whose faces has a layer of pressure-sensitive adhesive resulting from a transfer of the silicone layer (1).
Les avantages ressortent bien de la description, en particulier on souligne et on rappelle : la possibilité de fixer l'article souple sur tout type de support avec la possibilité de le repositionner autant de fois que nécessaire avec toujours les mêmes qualités d'autoadhésivité ; - la possibilité de laver, si nécessaire, l'article souple, en considérant que la couche d'adhésif résultant du transfert de la couche silicone résiste au lavage à des températures de l'ordre de 90°C ; l'efficacité de la fixation obtenue, y compris après plusieurs repositionnements ; la durabilité de la qualité de la fixation ;The advantages are apparent from the description, in particular it emphasizes and recalls: the ability to fix the flexible article on any type of support with the ability to reposition as many times as necessary with always the same qualities of self-adhesive; the possibility of washing, if necessary, the flexible article, considering that the layer of adhesive resulting from the transfer of the silicone layer is resistant to washing at temperatures of the order of 90 ° C .; the effectiveness of the fixation obtained, including after several repositioning; the durability of the fixation quality;
Enfin, on observe, d'une manière classique, que le papier transfert (2) assure la protection de l'article, en évitant tout contact avec la couche d'adhésif constituée par la couche de silicone. Pour l'utilisation, il suffit de décoller l'article (3) du support de transfert (2) pour le fixer par collage sur le support souhaité (figure 1). Finally, it is observed, in a conventional manner, that the transfer paper (2) ensures the protection of the article, avoiding any contact with the adhesive layer constituted by the silicone layer. For use, simply take off the article (3) of the transfer medium (2) to fix it by gluing on the desired support (Figure 1).
Claims (9)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR0952447A FR2944226A1 (en) | 2009-04-14 | 2009-04-14 | Fabricating a repositionable self-adhesive flexible tissue article, comprises applying silicone layer at the liquid state on a transfer paper, applying the article on the silicone layer to produce lamination, and heating the lamination |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR0952447A FR2944226A1 (en) | 2009-04-14 | 2009-04-14 | Fabricating a repositionable self-adhesive flexible tissue article, comprises applying silicone layer at the liquid state on a transfer paper, applying the article on the silicone layer to produce lamination, and heating the lamination |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| FR2944226A1 true FR2944226A1 (en) | 2010-10-15 |
Family
ID=41319363
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FR0952447A Pending FR2944226A1 (en) | 2009-04-14 | 2009-04-14 | Fabricating a repositionable self-adhesive flexible tissue article, comprises applying silicone layer at the liquid state on a transfer paper, applying the article on the silicone layer to produce lamination, and heating the lamination |
Country Status (1)
| Country | Link |
|---|---|
| FR (1) | FR2944226A1 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR3072050A1 (en) * | 2017-10-05 | 2019-04-12 | Heraud Rubans | ADHESIVE TEXTILE LABEL AND METHOD FOR MANUFACTURING SUCH A LABEL |
| WO2019220339A1 (en) * | 2018-05-14 | 2019-11-21 | Lampe Textiles Nv | Method for producing a self-adhesive textile |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63301284A (en) * | 1987-05-30 | 1988-12-08 | Arisawa Seisakusho:Kk | Production of silicone adhesive glass tape |
| US5244701A (en) * | 1992-07-27 | 1993-09-14 | Sliontec Corporation | Fabric base pressure sensitive adhesive tape usable as ribbon |
| DE102004012442B3 (en) * | 2004-03-13 | 2005-09-01 | Lts Lohmann Therapie-Systeme Ag | Unidirectionally elastic bandage for supporting joints, e.g. during sporting activity, is in segment form and has pressure-sensitive adhesive on one side |
| EP1845144A1 (en) * | 1997-09-12 | 2007-10-17 | General Electric Company | Coated substrates having improved release characteristics |
| EP1990391A1 (en) * | 2006-02-28 | 2008-11-12 | Lintec Corporation | Protection sheet for coating film |
-
2009
- 2009-04-14 FR FR0952447A patent/FR2944226A1/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63301284A (en) * | 1987-05-30 | 1988-12-08 | Arisawa Seisakusho:Kk | Production of silicone adhesive glass tape |
| US5244701A (en) * | 1992-07-27 | 1993-09-14 | Sliontec Corporation | Fabric base pressure sensitive adhesive tape usable as ribbon |
| EP1845144A1 (en) * | 1997-09-12 | 2007-10-17 | General Electric Company | Coated substrates having improved release characteristics |
| DE102004012442B3 (en) * | 2004-03-13 | 2005-09-01 | Lts Lohmann Therapie-Systeme Ag | Unidirectionally elastic bandage for supporting joints, e.g. during sporting activity, is in segment form and has pressure-sensitive adhesive on one side |
| EP1990391A1 (en) * | 2006-02-28 | 2008-11-12 | Lintec Corporation | Protection sheet for coating film |
Non-Patent Citations (1)
| Title |
|---|
| DATABASE WPI Week 19894, Derwent World Patents Index; AN 1989-027858, XP002556579 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR3072050A1 (en) * | 2017-10-05 | 2019-04-12 | Heraud Rubans | ADHESIVE TEXTILE LABEL AND METHOD FOR MANUFACTURING SUCH A LABEL |
| WO2019220339A1 (en) * | 2018-05-14 | 2019-11-21 | Lampe Textiles Nv | Method for producing a self-adhesive textile |
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