FR2940803B1 - COPOLYMERS WITH SOFT MATRIX COMPOSITION GRADIENT SOLUBLE AND / OR DISPERSIBLE IN WATER AND ORGANIC SOLVENTS - Google Patents

COPOLYMERS WITH SOFT MATRIX COMPOSITION GRADIENT SOLUBLE AND / OR DISPERSIBLE IN WATER AND ORGANIC SOLVENTS

Info

Publication number
FR2940803B1
FR2940803B1 FR0950001A FR0950001A FR2940803B1 FR 2940803 B1 FR2940803 B1 FR 2940803B1 FR 0950001 A FR0950001 A FR 0950001A FR 0950001 A FR0950001 A FR 0950001A FR 2940803 B1 FR2940803 B1 FR 2940803B1
Authority
FR
France
Prior art keywords
repeating units
copolymers
dispersible
soluble
water
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
FR0950001A
Other languages
French (fr)
Other versions
FR2940803A1 (en
Inventor
Stephanie Magnet
Helene Hediger
Olivier Guerret
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Arkema France SA
Original Assignee
Arkema France SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Arkema France SA filed Critical Arkema France SA
Priority to FR0950001A priority Critical patent/FR2940803B1/en
Priority to PCT/FR2009/052494 priority patent/WO2010076461A1/en
Publication of FR2940803A1 publication Critical patent/FR2940803A1/en
Application granted granted Critical
Publication of FR2940803B1 publication Critical patent/FR2940803B1/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09D133/08—Homopolymers or copolymers of acrylic acid esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/02—Monomers containing only one unsaturated aliphatic radical
    • C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F212/06—Hydrocarbons
    • C08F212/08—Styrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/04—Acids; Metal salts or ammonium salts thereof
    • C08F220/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1802—C2-(meth)acrylate, e.g. ethyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04—Homopolymers or copolymers of esters
    • C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
    • C08L33/08—Homopolymers or copolymers of acrylic acid esters
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
    • C09J133/04—Homopolymers or copolymers of esters
    • C09J133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09J133/08—Homopolymers or copolymers of acrylic acid esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
    • C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
    • C08L2666/04—Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Cosmetics (AREA)

Abstract

L'invention a trait à des copolymères à gradient de composition comprenant . - des unités répétitives issues de la polymérisation d'au moins un premier monomère M dont l'homopolymère correspondant présente une température de transition vitreuse Tg inférieure à 20°C, lesdites unités répétitives représentant de 65% à 68% en masse par rapport à la masse totale du copolymère ; - des unités répétitives issues de la polymérisation d'au moins un second monomère M dont l'homopolymère correspondant présente une température de transition vitreuse Tg supérieure à 20°C, lesdites unités répétitives représentant de 19% à 22% en masse par rapport à la masse totale du copolymère ; - des unités répétitives hydrophiles issues de la polymérisation d'au moins un troisième monomère M , lesdites unités répétitives représentant de 12% à 14% en masse de la masse totale du copolymère.The invention relates to gradient copolymers of composition comprising. - repeating units resulting from the polymerization of at least a first monomer M whose corresponding homopolymer has a glass transition temperature Tg of less than 20 ° C, said repeating units representing from 65% to 68% by mass relative to the total mass of the copolymer; - repeating units resulting from the polymerization of at least one second monomer M whose corresponding homopolymer has a glass transition temperature Tg greater than 20 ° C, said repeating units representing from 19% to 22% by mass relative to the total mass of the copolymer; - hydrophilic repeating units resulting from the polymerization of at least a third monomer M, said repeating units representing from 12% to 14% by mass of the total mass of the copolymer.

FR0950001A 2009-01-02 2009-01-02 COPOLYMERS WITH SOFT MATRIX COMPOSITION GRADIENT SOLUBLE AND / OR DISPERSIBLE IN WATER AND ORGANIC SOLVENTS Expired - Fee Related FR2940803B1 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
FR0950001A FR2940803B1 (en) 2009-01-02 2009-01-02 COPOLYMERS WITH SOFT MATRIX COMPOSITION GRADIENT SOLUBLE AND / OR DISPERSIBLE IN WATER AND ORGANIC SOLVENTS
PCT/FR2009/052494 WO2010076461A1 (en) 2009-01-02 2009-12-11 Copolymers with a composition gradient and flexible matrix which are soluble and/or dispersible in water and in organic solvents

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR0950001A FR2940803B1 (en) 2009-01-02 2009-01-02 COPOLYMERS WITH SOFT MATRIX COMPOSITION GRADIENT SOLUBLE AND / OR DISPERSIBLE IN WATER AND ORGANIC SOLVENTS

Publications (2)

Publication Number Publication Date
FR2940803A1 FR2940803A1 (en) 2010-07-09
FR2940803B1 true FR2940803B1 (en) 2012-10-19

Family

ID=40756928

Family Applications (1)

Application Number Title Priority Date Filing Date
FR0950001A Expired - Fee Related FR2940803B1 (en) 2009-01-02 2009-01-02 COPOLYMERS WITH SOFT MATRIX COMPOSITION GRADIENT SOLUBLE AND / OR DISPERSIBLE IN WATER AND ORGANIC SOLVENTS

Country Status (2)

Country Link
FR (1) FR2940803B1 (en)
WO (1) WO2010076461A1 (en)

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2848429B1 (en) * 2002-12-13 2006-06-16 Oreal CAPILLARY COMPOSITION COMPRISING A GRADIENT FILMOGENE COPOLYMER, AEROSOL COMPOSITION COMPRISING THE SAME, AND PROCESSING METHODS
FR2848430B1 (en) * 2002-12-13 2006-06-23 CAPILLARY COMPOSITION COMPRISING A GRADIENT FILMOGENE COPOLYMER, AEROSOL COMPOSITION COMPRISING THE SAME, AND PROCESSING METHODS
FR2858933B1 (en) * 2003-08-22 2006-03-03 Oreal AEROSOL DEVICE CONTAINING SILICONE, GRADIENT COPOLYMER AND DIMETHYL ETHER

Also Published As

Publication number Publication date
WO2010076461A1 (en) 2010-07-08
FR2940803A1 (en) 2010-07-09

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Legal Events

Date Code Title Description
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Effective date: 20130930