FR2925310A1 - Kit, useful for coating keratin fibers, comprises a first composition comprising aqueous phase, emulsifier comprising triethanolamine and alginic acid based compound, and second composition comprising complexing agent of the compound - Google Patents

Abstract

Kit for coating of keratin fibers, comprises a first composition comprising an aqueous phase, an emulsifier comprising triethanolamine (less than 1%) and alginic acid based compound, and a second composition comprising a complexing agent of the compound. Independent claims are included for: (1) a cosmetic process for coating keratin fibers, comprising applying at least a layer of first composition and at least a layer of second composition, on the keratin fibers; (2) a process for make-up and/or cleansing of make-up coat formed by application of first and second compositions on the keratin fibers, comprising applying a make-up removing composition and/or cleansing composition comprising an aqueous phase and a sequestrant of the complexing agent in an acceptable medium, on the make-up coat; and (3) a cosmetic kit comprising first composition, second composition and make-up removing composition and/or cleansing composition.

Description

The present application relates to the field of make-up or care of eyelashes or mascaras. The eyelash coating compositions such as mascaras are generally makeup compositions, compositions for applying to a make-up (also called top-coat), or cosmetic eyelash care compositions.

Mascaras are especially prepared according to two types of formulation: the aqueous mascas called cream mascaras, in the form of dispersion solid particles, in particular waxes and pigments, in water using a surfactant system generally based on stearate triethanolamine. However, the makeup film obtained after the application of these compositions is not sufficiently resistant to water, for bathing or showers for example, with tears or sweat or sebum. The mascara then tends to crumble in time: grains are deposited and unsightly marks appear around the eyes.

Also known anhydrous mascaras or low water content, so-called waterproof mascaras, in the form of dispersions of waxes in organic solvents, which generally have good water resistance but require the use of a specific makeup remover, generally based on organic solvent, to eliminate the film formed on the eyelashes.

It is therefore sought to obtain a composition in which the solid particles, such as pigments and / or waxes, are dispersed in a homogeneous manner, which makes it possible to obtain a film on the eyelashes which exhibits good behavior and / or good resistance to water and easy to remove.

The inventors have discovered that the use of a composition comprising a surfactant system without triethanolamine and a compound based on alginic acid capable of crosslinking in the presence of a complexing agent makes it possible to obtain a good film on the keratin fibers. and the removal of makeup is easily done in the presence of a chelating agent of said complexing agent.

A first subject of the present application is a kit for coating keratin fibers, comprising: a first composition comprising an aqueous phase, an emulsifying system comprising less than 1% triethanolamine and at least one compound based on alginic acid, and a second composition comprising an agent for complexing said compound.

A second object of the present application is a cosmetic process for coating keratinous fibers, comprising applying to said keratinous fibers at least one layer of a mixture of a first composition and a second composition, the first composition comprising a phase aqueous solution, an emulsifying system comprising less than 1% of triethanolamine, at least one compound based on alginic acid, and the second composition comprising a complexing agent of said compound, said mixture being obtained either extemporaneously before application to the eyelashes , or simultaneously with its application on keratinous fibers. The terms first and second composition do not condition the order of application of said compositions on keratinous fibers.

Preferably, at least one layer of the first composition and then at least one layer of the second composition are applied to the keratinous fibers.

Furthermore, the coating or film formed after application of the first and second compositions described above can be easily removed using a composition comprising a chelating agent of the complexing agent.

This is why according to another aspect, the present invention also relates to a method of removing make-up and / or cleaning makeup films formed by the application, on keratinous fibers, of a first composition comprising an aqueous phase, an emulsifying system comprising less than 1% triethanolamine, at least one compound based on alginic acid, and a second composition comprising an agent for complexing said compound, the process comprising at least one step of applying to said films of makeup, makeup removal and / or cleaning composition comprising, in a physiologically acceptable medium, an aqueous phase and at least one sequestering agent of said complexing agent.

Finally, the subject of the invention is also a composition comprising an aqueous phase, an emulsifying system comprising less than 1% triethanolamine, at least one compound based on alginic acid and a complexing agent for said compound. In this embodiment, the alginic acid-based compound and / or the complexing agent may be present in an encapsulated form.

Other characteristics, properties and advantages of the present invention will emerge more clearly on reading the description and examples which follow.

Compound Based on Alginic Acid The term "alginic acid-based compound" means in particular alginic acid, alginic acid derivatives and alginic acid salts (alginates) or derivatives thereof. Preferably, the alginic acid-based compound is water soluble.

Alginic acid, a natural substance derived from brown algae or certain bacteria, is a polyuronic acid composed of 2 uronic acids linked by 1, 4 glycosidic linkages: RD-Manuronic acid (M) and α-glucuronic acid. (G).

The alginic acid is capable of forming water-soluble salts (alginates) with alkali metals such as sodium, potassium, lithium, lower amine and substituted ammonium cations such as methylamine, ethanolamine, diethaniolamine, triethanolamine. These alginates are water-soluble in aqueous medium at pH 4 but dissociate into alginic acid at a pH below 4.

These alginates are capable of crosslinking with each other in the presence of complexing agents, by formation of ionic bonds between said complexing agents and the negatively charged group of the residue G. The formation of multiple crosslinks between several alginate molecules results in the formation of a matrix forming a gel insoluble in water. Alginic acid-based compounds having a weight average molecular weight of from 10,000 to 1,000,000, preferably from 15,000 to 500,000 and most preferably from 20,000 to 250,000, are preferably used.

According to a preferred embodiment, the alginic acid-based compound is a sodium or potassium alginate. The compound based on alginic acid may be present in a content ranging from 0.1 to 30% by weight relative to the total weight of the composition comprising it, preferably from 0.5 to 20% by weight and preferably from 1 to at 10% by weight. Complexation agent

The complexing agent is capable of complexing with the alginic acid-based compound by ionic bond formation. This complexation is reversible. The complexing agent may be chosen in particular from polyelectrolytes, multivalent ions and their salts, in particular multivalent cation salts or polycations. It is preferably in water-soluble form in the second composition. The multivalent ions may in particular be cations such as polycations or multivalent cations, preferably having a valency ranging from 2 to 4 and more preferably divalent cations, in particular the cations of calcium, magnesium, aluminum, barium, zinc, nickel, copper (+ II), manganese and mixtures thereof. Mention may in particular be made of the chlorides or sulphates of the cations mentioned above and in particular the chorides such as calcium chloride. As polyelectrolyte, polyethylene amine may be mentioned

The complexing agent (s) may be present in a content ranging from 0.01% to 30% by weight relative to the total weight of the composition, preferably from 0.02% to 15% by weight and better still from 0.05% to 5% by weight.

The reaction rate between the polysaccharide and the complexing agent can be modulated by modifying the pH and / or temperature conditions of the composition, or else by adding a compound making it possible to accelerate or delay the reaction. between the polysaccharide and the complexing agent, such as, for example, sodium phosphate which makes it possible to retard the crosslinking of the alginic acid derivative. Emulsifying system The main emulsifying system, also called main surfactant system, of the first composition according to the invention comprises less than 1%, preferably less than 0.5% by weight of triethanolamine, and better still, is free of triethanolamine. According to a variant, the first composition comprises less than 1% by weight, preferably less than 0.5% by weight of triethanolamine stearate, and better still, is free of triethanolamine stearate.

According to the invention, an emulsifier suitably chosen for obtaining an oil-in-water emulsion is generally used. In particular, it is possible to use an emulsifier having at 25 ° C. an HLB balance (hydrophilic-lipophilic balance) in the Griffin sense, greater than or equal to 8. The HLB value according to Griffin is defined in J. Soc. Cosm. Chem. 1954 (volume 5), pages 249-256. These surfactants may be chosen from nonionic, anionic, cationic, amphoteric surfactants or surfactant emulsifiers. See Encyclopedia of Chemical Technology, KIRKOTHMER, Vol. 22, p. 333-432, 5th edition, 1979, WILEY, for the definition of the properties and functions (emulsifier) of surfactants, in particular p. 347-377 of this reference, for anionic, amphoteric and nonionic surfactants. The surfactants preferably used in the composition according to the invention are chosen from: a) nonionic surfactants with a HLB greater than or equal to 8 at 25 ° C., used alone or as a mixture; mention may be made in particular of: oxyethylenated and / or oxypropylenated ethers (which may contain from 1 to 150 oxyethylenated and / or oxypropylenated groups) of glycerol; oxyethylenated and / or oxypropylenated ethers (which can comprise from 1 to 150 oxyethylenated and / or oxypropylene groups) of fatty alcohols (in particular of C8-C24 and preferably of C12-C18 alcohols), such as oxyethylenated ether of oxyethylenated stearyl alcohol (CTFA name "Steareth-20") such as BRIJ 78 marketed by UNIQUEMA, oxyethylenated ether of cetyl alcohol with 30 oxyethylenated groups (CTFA name "Ceteareth-30") and the oxyethylenated ether of the mixture of C 12 -C 15 fatty alcohols containing 7 oxyethylenated groups (CTFA name "C12-15 Pareth-7" sold under the name NEODOL 25-7 by Shell Chemicals, fatty acid esters (in particular of C8-C24, and preferably C16-C22) acid and polyethylene glycol (which may comprise from 1 to 150 ethylene glycol units) such as PEG-50 stearate and PEG-40 monostearate sold under the MYRJ 52P by the company ICI UNIQUEMA, the ester s of fatty acid (especially C8-C24 acid, and preferably C16-C22) and oxyethylenated and / or oxypropylenated glycerol ethers (which can contain from 1 to 150 oxyethylene and / or oxypropylene groups), such as PEG-200 glyceryl monostearate sold under the name Simulsol 220 TM by the company SEPPIC; polyethoxylated glyceryl stearate with 30 ethylene oxide groups, such as the product TAGAT S sold by the company GOLDSCHMIDT, polyethoxylated glyceryl oleate with 30 ethylene oxide groups, such as the product TAGAT O sold by the company GOLDSCHMIDT glycerol cocoate polyethoxylated with 30 ethylene oxide groups, such as the product VARIONIC LI 13 sold by the company SHEREX, glyceryl isostearate polyethoxylated with 30 ethylene oxide groups, such as the product TAGAT L sold by the company GOLDSCHMIDT company and polyethoxylated glyceryl laurate with 30 ethylene oxide groups, such as the product TAGAT 1 from GOLDSCHMIDT, the fatty acid esters (in particular C 8 -C 24, and preferably C 16 -C 22, ) and oxyethylenated and / or oxypropylenated sorbitol ethers (which can contain from 1 to 150 oxyethylenated and / or oxypropylene groups), such as polysorbate 60 sold under the name Tween 60 by the company UNIQU EMA, dimethicone copolyol, such as that sold under the name Q2-25,520 by the company Dow Corning, dimethicone copolyol benzoate (FINSOLV SLB 101 and 201 from the company FINTEX), copolymers of propylene oxide and diene oxide. ethylene, also called EO / PO polycondensates, and mixtures thereof. The EO / PO polycondensates are more particularly copolymers consisting of polyethylene glycol and polypropylene glycol blocks, such as, for example, polyethylene glycol / polypropylene glycol / polyethylene glycol triblock polycondensates. These triblock polycondensates have, for example, the following chemical structure: H- (O-CH 2 -CH 2) (O-CH (CH 3) -CH 2) b- (O-CH 2 -CH 2) a-OH, in which formula from 2 to 120, and b ranges from 1 to 100. The EO / PO polycondensate preferably has a weight average molecular weight ranging from 1000 to 15000, and better from 2000 to 13000. Advantageously, said EO / PO polycondensate has a cloud temperature, at 10 g / l in distilled water, greater than or equal to 20 ° C, preferably greater than or equal to 60 ° C. The cloud temperature is measured according to the ISO 1065 standard. As polycondensate EO / PO that may be used according to the invention, mention may be made of the polyethylene glycol / polypropylene glycol / polyethylene glycol triblock polycondensates sold under the trade names SYNPERONIC such as SYNPERONIC PE / L44 and SYNPERONIC. PE / F127 by ICI. b) nonionic surfactants with a HLB of less than 8 at 25 ° C., optionally combined with one or more nonionic surfactants with a HLB of greater than 8 at 25 ° C., as mentioned above, such as: esters and ethers dies such as sucrose stearate, sucrose cocoate, sorbitan stearate and mixtures thereof such as Arlatone 2121 marketed by ICI or SPAN 65V from UNIQUEMA; esters of fatty acids (especially C8-C24, and preferably C16-C22) and of polyol, especially glycerol or sorbitol, such as glyceryl stearate, glyceryl stearate such as the product sold under the name TEGIN M by the company GOLDSCHMIDT, glyceryl laurate such as the product sold under the name IMWITOR 312 by the company HULS, polyglyceryl-2 stearate, sorbitan tristearate, glyceryl ricinoleate; oxyethylenated and / or oxypropylenated ethers such as the oxyethylenated ether of stearyl alcohol with 2 oxyethylenated groups (CTFA name "Steareth-2"), such as BRIJ 72 marketed by UNIQUEMA; the cyclomethicone / dimethicone copolyol mixture sold under the name Q2-3225C ° by the company Dow Corning; c) Anionic surfactants such as: salts of polyoxyethylenated fatty acids, in particular those derived from amines or alkaline salts, and mixtures thereof; phosphoric esters and their salts such as "DEA oleth-10 phosphate" (Crodafos N 10N from CRODA) or monocotyl monopotassium phosphate (Amphisol K from Givaudan or ARLATONE MAP 160K from UNIQUEMA); sulfosuccinates such as "Disodium PEG-5 citrate lauryl sulfosuccinate" and "Disodium ricinoleamido MEA sulfosuccinate"; alkyl ether sulfates such as sodium lauryl ether sulfate; isethionates; acylglutamates such as "Disodium hydrogenated tallow glutamate" (AMISOFT HS-21 R marketed by the company AJINOMOTO) and mixtures thereof. As representative of cationic surfactants, mention may be made in particular of: alkylimidazolidiniums such as isostearylmethylimidonium ethosulphate; ammonium salts such as N, N, N-trimethyl-1-10 chloride; docosanaminium (Behentrimonium chloride).

The compositions according to the invention may also contain one or more amphoteric surfactants such as N-acyl amino acids such as N-alkylaminoacetates and disodium cocoamphodiacetate and amine oxides such as stearamine oxide or silicone surfactants. as dimethicone copolyols phosphates such as that sold under the name PECOSIL PS 100 ° by the company PHOENIX CHEMICAL.

According to one embodiment, the emulsifier system of the first composition comprises at least one C 10 -C 30 alkyl phosphate. According to one embodiment, the emulsifier system of the composition comprises at least one C 10 -C 30 alkyl phosphate and at least one C 8 -C 24 fatty alcohol ether and polyethylene glycol, said ether comprising from 1 to 19 units ethylene glycol and having HLB <8 at 25 ° C. This emulsifier system may further comprise at least one C 8 -C 24 fatty alcohol ether and polyethylene glycol, said ether comprising from 20 to 1000 units of ethylene glycol and HLB> 8 at 25 ° C and at least one alcohol fatty acid comprising from 10 to 30 carbon atoms such as cetyl alcohol.

According to one embodiment, the emulsifying system of the first composition comprises at least one surfactant chosen from: glutamic acid derivatives and their salts, such as acyl glutamic acids (INCI name: acyl glutamic acid), and their salts ( glutamates) such as, for example, lauroyl glutamic acid, cocoyl glutamic acid, sodium stearoyl glutamate, potassium lauroyl glutamate, potassium cocoyl glutamate, sodium olivoyl glutamate, or disodium5 hydrogenated tallow glutamate and mixtures thereof; sarcosine derivatives of formula: CH 3 -N (R) -CH 2 -COOH wherein R is an O = CR 'acyl group, R' being a linear or branched, saturated or unsaturated hydrocarbon-based chain comprising from 10 to 30 carbon atoms, preferably from 12 to 22 carbon atoms, or one of its cosmetically acceptable salts, in particular the myristoyl sarcosine derivatives, the palmitoyl sarcosine derivatives, the oleoyl sarcosine derivatives, the ste aroyl sarcosine, preferably the stearoyl and palmitoyl sarcosine derivatives or their cosmetically acceptable salts (sarcosinates). Mention may in particular be made of sodium palmitoyl sarcosinate, magensium palmitoyl sarcosinate, myristoyl sarcosine, stearoyl sarcosine, and mixtures thereof. According to one embodiment, the composition further comprises a co-surfactant chosen from fatty alcohols, preferably comprising from 10 to 30 carbon atoms. By fatty alcohol comprising from 10 to 30 carbon atoms is meant any pure fatty alcohol, saturated or unsaturated, branched or unbranched, having from 10 to 30 carbon atoms. A fatty alcohol comprising from 10 to 26 carbon atoms, preferably from 10 to 24 carbon atoms and more preferably from 14 to 22 carbon atoms, is preferably used. Mention may in particular be made, as fatty alcohols that may be used in the composition, of lauryl, myristic, cetyl, stearyl, oleic, cetearyl (mixture of cetyl alcohol and stearyl alcohol), behenic alcohol, erucic alcohol and their mixtures. Cetyl alcohol is preferably used.

Such fatty alcohols are in particular marketed under the name NAFOL by the company SASOL. The fatty alcohol may be present in a content ranging from 0.2 to 20% by weight, preferably from 0.3 to 10% by weight relative to the total weight of the composition.

In the composition according to the invention, the total content of surfactants can range from 1 to 30% by weight relative to the total weight of the composition comprising them, preferably from 1 to 20% by weight and better still from 2 to 15% by weight. weight.

Aqueous Phase The first composition according to the invention comprises an aqueous phase, which can form the continuous phase of the composition. By aqueous continuous phase composition is meant that the composition has a conductivity, measured at 25 ° C., greater than or equal to 23 μS / cm (microSiemens / cm), the conductivity being measured, for example using a conductivity meter. MPC227 from Mettler Toledo and an Inlab730 conductivity cell. The measuring cell is immersed in the composition, so as to eliminate air bubbles that may form between the 2 electrodes of the cell. The reading of the conductivity is made as soon as the value of the conductivity meter is stabilized. An average is performed on at least 3 successive measurements.

The aqueous phase comprises water and / or at least one water-soluble solvent. By "water-soluble solvent" is meant in the present invention a liquid compound at room temperature and miscible with water (miscibility in water greater than 50% by weight at 25 ° C and atmospheric pressure). The water-soluble solvents that can be used in the compositions according to the invention can moreover be volatile. Among the water-soluble solvents that can be used in the compositions in accordance with the invention, there may be mentioned lower monoalcohols having from 1 to 5 carbon atoms such as ethanol and isopropanol, glycols having from 2 to 8 carbon atoms. carbon such as ethylene glycol, propylene glycol, 1,3-butylene glycol and dipropylene glycol, C3-C4 ketones and C2-C4 aldehydes.

The aqueous phase (water and optionally the solvent miscible with water) is generally present in the composition according to the present application in a content ranging from 1% to 95% by weight, relative to the total weight of the composition, preferably ranging from from 3% to 80% by weight, and preferably ranging from 5% to 60% by weight.

Wax (es)

The first and / or second composition according to the present application may comprise at least one wax. For the purposes of the present invention, the term "wax" means a lipophilic compound, solid at room temperature (25 ° C.), with a reversible solid / liquid state change, having a melting point of greater than or equal to 30 ° C. at 120 ° C. The melting point of the wax can be measured using a differential scanning calorimeter (D.S.C.), for example the calorimeter sold under the name DSC 30 by the company METLER. The waxes may be hydrocarbon-based, fluorinated and / or silicone-based and may be of vegetable, mineral, animal and / or synthetic origin. In particular, the waxes have a melting point greater than 25 ° C. and better still greater than 45 ° C.

The wax may be present in a content ranging from 0.1% to 50% by weight relative to the total weight of the composition, better still from 1% to 40% and even more preferably from 5% to 30% by weight. In particular, it is possible to use hydrocarbon-based waxes such as beeswax, lanolin wax, and Chinese insect waxes; rice wax, Carnauba wax, Candelilla wax, Ouricurry wax, Alfa wax, cork fiber wax, sugar cane wax, Japanese wax and sumac wax ; montan wax, microcrystalline waxes, paraffins and ozokerite; polyethylene waxes, waxes obtained by Fisher-Tropsch synthesis and waxy copolymers and their esters. Mention may also be made of waxes obtained by catalytic hydrogenation of animal or vegetable oils having linear or branched C8-C32 fatty chains. Among these, there may be mentioned hydrogenated jojoba oil, isomerized jojoba oil such as trans isomerized partially hydrogenated jojoba oil manufactured or marketed by Desert Whale under the trade reference ISO-JOJOBA-50 , hydrogenated sunflower oil, hydrogenated castor oil, hydrogenated coconut oil and hydrogenated lanolin oil, di- (1,1,1-trimethylolpropane) tetrastearate sold under the name "HEST 2T-4S "by the company HETERENE, di- (trimethylol-1,1,1 propane) tetraprenate sold under the name HEST 2T-4B by the company HETERENE. Mention may also be made of silicone waxes such as alkyl or alkoxy dimethicone containing from 16 to 45 carbon atoms and fluorinated waxes. It is also possible to use the wax obtained by hydrogenation of esterified olive oil with the stearyl alcohol sold under the name "PHYTOWAX Olive 18 L 57" or even the waxes obtained by hydrogenation of castor oil esterified with alcohol. cetyl sold under the name "PHYTOWAX ricin 16L64 and 22L73", by the company SOPHIM. Such waxes are described in application FR-A-2792190. According to one particular embodiment, the compositions in accordance with the invention may comprise at least one so-called sticking wax, that is to say having a tack greater than or equal to 0.7 Ns and a hardness of less than or equal to 3, 5 MPa.

The use of a sticky wax may in particular make it possible to obtain a cosmetic composition which is easily applied to the eyelashes, having good grip on the eyelashes and which leads to the formation of a smooth, homogeneous and thickening makeup . The tacky wax used may in particular have a tack ranging from 0.7 Ns to 30 Ns, in particular greater than or equal to 1 Ns, in particular ranging from 1 Ns to 20 Ns, in particular greater than or equal to 2 Ns, in particular ranging from 2 Ns at 10 Ns, and in particular ranging from 2 Ns to 5 Ns The stickiness of the wax is determined by measuring the evolution of the force (compressive force or stretching force) as a function of time, at 20 ° C. using the texturometer sold under the name "TA-TX2i" "by the company RHEO, equipped with a mobile in acrylic polymer cone forming an angle of 45 °. The measurement protocol is as follows: The wax is melted at a temperature equal to the melting point of the wax + 10 ° C. The melted wax is poured into a container 25 mm in diameter and 20 mm deep. The wax is recrystallized at room temperature (25 ° C) for 24 hours so that the surface of the wax is flat and smooth, then the wax is kept for at least 1 hour at 20 ° C before measuring. tights. The mobile of the texturometer is moved at a speed of 0.5 mm / s, then penetrates into the wax to a depth of penetration of 2 mm. When the mobile penetrated into the wax to the depth of 2 mm, the mobile is held stationary for 1 second (corresponding to the relaxation time) and then removed at a speed of 0.5 mm / s. During the relaxation time, the force (compression force) decreases sharply until it becomes zero and then, when the mobile is removed, the force (stretching force) becomes negative and then increases again to the value 0. The pantyhose corresponds to the integral of the force vs. time curve for the part of the curve corresponding to the negative values of the force (stretching force). The value of the sticky is expressed in N.s. The tacky wax that can be used generally has a hardness of less than or equal to 3.5 MPa, in particular ranging from 0.01 MPa to 3.5 MPa, in particular ranging from 0.05 MPa to 3 MPa, or even from 0 to 1 MPa at 2.5 MPa.

The hardness is measured according to the protocol described above. As sticky wax, a C20-C40 alkyl (hydroxystearyloxy) stearate (the alkyl group comprising 20 to 40 carbon atoms), alone or in a mixture, in particular a 12- (12'-hydroxystearyloxy) stearate, may be used. C20-C40 alkyl of formula (II): H3C (II) wherein m is an integer from 18 to 38, or a mixture of compounds of formula (II). Such a wax is especially sold under the names "Kester Wax K 82 P" and 5 "Kester Wax K 80 P" by the company Koster Keunen. The waxes mentioned above generally have an initial melting point below 45 ° C. It is also possible to use the microcrystalline wax sold under the reference SP18 by the company Strahl and Pitsch, which has a hardness of approximately 0.46 MPa and a tack value of approximately 1 N.sup.3. The wax (es) may be present in the form of an aqueous microdispersion of wax. By aqueous microdispersion of wax is meant an aqueous dispersion of wax particles in which the size of said wax particles is less than or equal to about 1 μm. Microdispersions of wax are stable dispersions of colloidal wax particles, and are especially described in "Microemulsions Theory and Practice", L. M. Prince Ed., Academic Press (1977) pages 21-32. In particular, these microdispersions of wax can be obtained by melting the wax in the presence of a surfactant, and possibly a portion of the water, and then gradually adding hot water with stirring. The intermediate formation of a water-in-oil emulsion is observed, followed by a phase inversion with final obtaining of an oil-in-water type microemulsion. On cooling, a stable microdispersion of solid colloidal particles of wax is obtained. The microdispersions of wax can also be obtained by stirring the mixture of wax, surfactant and water using stirring means such as ultrasound, the high-pressure homogenizer, the turbines. The particles of the microdispersion of wax preferably have average dimensions of less than 1 μm (in particular ranging from 0.02 μm to 0.99 μm), preferably less than 0.5 μm (in particular ranging from 0.06 μm to 0 μm). , 5 pm). These particles consist essentially of a wax or a mixture of waxes. However, they may comprise, in a minor proportion, oily fatty additives and / or pastes, a surfactant and / or a usual fat-soluble additive / active agent.

The compositions according to the present application may also contain at least one hydrophilic or lipophilic film-forming polymer.

In the present application, the term "film-forming polymer" means a polymer capable of forming on its own or in the presence of a film-forming auxiliary agent, a macroscopically continuous and adherent film on the eyelashes, and preferably a cohesive film, and more preferably a film whose cohesion and mechanical properties are such that said film can be isolatable and manipulable in isolation, for example when said film is produced by casting on a non-stick surface such as a Teflon or silicone surface. In general, the "film-forming polymer" content of the compositions according to the present application ranges from 0.1 to 40%, preferably from 0.5 to 30% and better still from 1 to 20% by weight, relative to the total weight. of the composition, The hydrophilic film-forming polymer may be a water-soluble polymer or may be dispersed in an aqueous medium. Among the film-forming polymers that can be used in the composition of the present invention, mention may be made of synthetic polymers, of free-radical type or of polycondensate type, polymers of natural origin, and mixtures thereof.

Examples of water-soluble film-forming polymers that may be mentioned include: proteins such as proteins of plant origin such as wheat and soy proteins; proteins of animal origin such as keratins, for example keratin hydrolysates and keratin sulfonates; cellulose polymers such as hydroxyethylcellulose, hydroxypropylcellulose, methylcellulose, ethylhydroxyethylcellulose and carboxymethylcellulose, as well as the quaternized derivatives of cellulose; acrylic polymers or copolymers, such as polyacrylates or polymethacrylates; vinyl polymers, such as polyvinylpyrrolidones, copolymers of methylvinyl ether and of malic anhydride, the copolymer of vinyl acetate and crotonic acid, copolymers of vinylpyrrolidone and of vinyl acetate; copolymers of vinylpyrrolidone and caprolactam; polyvinyl alcohol; anionic, cationic, amphoteric or nonionic chitin or chitosan polymers; gum arabic, guar gum, xanthan derivatives, karaya gum; alginates and carrageenans; glycosaminoglycans, hyaluronic acid and its derivatives; - shellac resin, sandaraque gum, dammars, elemis, copals; deoxyribonucleic acid; - Muccopolysaccharides such as chondroitin sulfate, and mixtures thereof.

The film-forming polymer may also be present in the composition in the form of particles in dispersion in an aqueous phase, generally known under the name of latex or pseudolatex. The techniques for preparing these dispersions are well known to those skilled in the art. As the aqueous dispersion of film-forming polymer, it is possible to use the acrylic dispersions sold under the names Neocryl XK-90, Neocryl A-1070, Neocryl A-1090, Neocryl BT-62, Neocryl A-1079 and Neocryl A-523 by the company Aveciane Sorresins. Dow Latex 432 by DOW CHEMICAL, Daitosol 5000 AD or Daitosol 5000 SJ by DAITO KASEY KOGYO; Syntran 5760 by the company Interpolymer Allianz Opt by Rohm and Haas or the aqueous polyurethane dispersions sold under the names Neorez R-981 and Neorez R-974 by the company Avecia-Neoresins, the Avalure UR-405, Avalure UR- 410, Avalure UR-425, Avalure UR-450, Sancure 875, Avalure UR-445 and Sancure 2060 by the company NOVEON, Impranil 85 by the company BAYER, Aquamere H-1511 by the company HYDROMER; sulfopolyesters sold under the trade name Eastman AQ by Eastman Chemical Products, vinyl dispersions such as Mexomer PAM, aqueous polyvinyl acetate dispersions such as "Vinybran" from Nisshin Chemical or those marketed by Union Carbide, aqueous dispersions of terpolymer vinyl pyrrolidone, dimethylaminopropyl methacrylamide and lauryldimethylpropylmethacrylamidoammonium chloride such as Styleze W-ISP, aqueous dispersions of polyurethane / polyacrylic hybrid polymers such as those sold under the references "Hybridur" by the company AIR PRODUCTS or " Duromer "of NATIONAL STARCH, the core / shell type dispersions: for example those marketed by ATOFINA under the reference Kynar (core: fluorinated shell: acrylic) or those described in US 5,188,899 (core; shell: silicone) and their mixtures. The lipophilic polymer may be in solution or in dispersion in a non-aqueous solvent phase The compositions according to the present application may also contain at least one hydrophilic gelling agent, they may be chosen from: homo or copolymers of acrylic or methacrylic acids or their salts and their esters and in particular the products sold under the names Versicolol F or Versicol K by the company Allied Colloid, UTRAHOLD 8 by the company CIBA-Geigy, polyacrylic acids of SYNTHALEN K type, - copolymers of acrylic acid and of acrylamide sold in the form of their sodium salt under the names Reten by the company Hercules, the sodium salts of polyhydroxycarboxylic acids sold under the name HYDAGEN F by the company HENKEL, - the polyacrylic acid / alkyl acrylate copolymers of the PEMULEN type, - AMPS (polyacrylamidomethyl propanesulfonic acid partially neutralized with ammonia and highly ticulé) sold by the company Clariant 20, - copolymers of AMPS / acrylamide Sepigel type or Simulgel marketed by Seppic, and - copolymers of AMPS / polyoxyethylenated alkyl methacrylate (crosslinked or not), and mixtures thereof. Associative polyurethanes, such as the C16-OE120-C16 polymer from the company Servo Delden (sold under the name SER AD FX1100, a urethane function molecule and a weight average molecular weight of 1300), EO being an oxyethylenated unit, the rheolate 205 with urea function sold by Rheox or else Rheolate 208 or 204 (these polymers being vensus in pure form) or DW 1206B 30 from RHOM & HAAS with C20 alkyl chain and urethane bond, sold at 20% by weight. active ingredient in water. It is also possible to use solutions or dispersions of these associative polyurethanes, especially in water or in a hydroalcoholic medium. By way of example, such polymers include SER AD fx1010, SER AD FX1035 and SER AD 1070 from SERVO DELDEN, Rheolate 255, Rheolate 278 and Rheolate 244 sold by RHEOX. . It is also possible to use the product DW 1206F and DW 1206J, as well as Acrysol RM 184 or Acrysol 44 from Rhom & Haas, or even Borchigel LW 44 from Borchers, and their mixtures. Certain water-soluble film-forming polymers mentioned above can also act as water-soluble gelling agent.

The hydrophilic gelling agents may be present in a content ranging from 0.05 to 40% by weight relative to the total weight of the composition comprising them, preferably from 0.1 to 20% and better still from 0.5 to 15% by weight. .

The compositions according to the present application may also contain at least one or more oils or organic solvent. By oil or organic solvent is meant a nonaqueous body liquid at room temperature and atmospheric pressure. The oil can be volatile or non-volatile.

For the purposes of the invention, the term "oil or volatile organic solvent" means any non-aqueous medium capable of evaporating on contact with keratin materials in less than one hour, at ambient temperature and atmospheric pressure. The volatile organic solvent (s) and the volatile oils of the invention are organic solvents and volatile cosmetic oils, liquid at ambient temperature, having a non-zero vapor pressure, at ambient temperature and atmospheric pressure, ranging from 0.13 Pa. at 40 000 Pa (10-3 at 300 mm Hg), in particular ranging from 1.3 Pa to 13 000 Pa (0.01 to 100 mm Hg), and more particularly ranging from 1.3 Pa to 1300 Pa (0.01 to 10 mmHg). By "non-volatile oil" is meant an oil remaining on the keratin materials at ambient temperature and atmospheric pressure for at least several hours and in particular having a vapor pressure of less than 10 -3 mm Hg (0.13 Pa). The oil may be present in the composition in a content ranging from 0.05 to 30%, preferably 0.1 to 15% by weight relative to the total weight of the composition. The composition according to the invention may comprise volatile oils and / or non-volatile oils, and mixtures thereof. The volatile oils (or organic solvents) may be hydrocarbon oils, silicone oils, fluorinated oils or their mixtures. The term "hydrocarbon-based oil" means an oil containing mainly hydrogen and carbon atoms and optionally oxygen, nitrogen, sulfur and phosphorus atoms. The volatile hydrocarbon oils may be chosen from hydrocarbon-based oils having 8 to 16 carbon atoms, and especially C8-C16 branched alkanes such as C8-C16 isoalkanes of petroleum origin (also known as isoparaffins), such as isododecane ( also called 2,2,4,4,6-pentamethylheptane), isodecane, isohexadecane, and for example the oils sold under the trade names "Isopars" or "permetyls", branched C8- C16, isohexyl neopentanoate, and mixtures thereof. Other volatile hydrocarbon oils such as petroleum distillates, especially those sold under the name "Shell Solt" by Shell, can also be used. As volatile oils, it is also possible to use volatile silicones, for example volatile linear or cyclic silicone oils, in particular those having a viscosity of 6 centistokes (6.10-6 m 2 / s), and having in particular 3 to 6 silicon atoms. these silicones optionally having one or more alkyl or alkoxy groups having 1 or 2 carbon atoms. As volatile silicone oil that can be used in the invention, there may be mentioned in particular octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane, heptamethylhexyltrisiloxane, heptamethyloctyltrisiloxane, hexamethylisiloxane, octamethyltrisiloxane and decamethyl tetrasiloxane, dodecamethylpentasiloxane and mixtures thereof. It is also possible to use volatile organic solvents, especially fluorinated solvents such as nonafluoromethoxy butane or perfluoromethylcyclopentane.

Each of the compositions in accordance with the invention may also comprise at least one nonvolatile organic oil or solvent, which may in particular be chosen from non-volatile hydrocarbon and / or silicone and / or fluorinated oils. Non-volatile hydrocarbon oils that may especially be mentioned include: hydrocarbon-based oils of vegetable origin, such as triglycerides consisting of esters of fatty acids and of glycerol, the fatty acids of which may have various chain lengths of C4 to C24, the latter may be linear or branched, saturated or unsaturated; these oils include wheat germ, sunflower, grape seed, sesame, maize, apricot, castor, shea, avocado, olive, soya, sweet almond, palm, rapeseed, cotton, hazelnut, macadamia, jojoba, alfalfa, poppy, pumpkin, sesame, pumpkin, rapeseed, blackcurrant, evening primrose, millet, barley, quinoa, rye, safflower, bancoulier, passiflora, muscat rose; or alternatively caprylic / capric acid triglycerides, such as those sold by Stéarineries Dubois or those sold under the names Miglyol 810, 812 and 818 by Dynamit Nobel, synthetic ethers having from 10 to 40 carbon atoms; linear or branched hydrocarbons of mineral or synthetic origin, such as petroleum jelly, polydecenes, hydrogenated polyisobutene such as Parleam, and squalane, and mixtures thereof; synthetic esters, such as the oils of formula R, 000 R 2 in which R represents the residue of a linear or branched fatty acid containing from 1 to 40 carbon atoms and R 2 represents a hydrocarbon chain, especially a branched hydrocarbon chain, containing from 1 to 40 atoms of carbon provided R, + R2 is 10, such as, for example, purcellin oil (cetostearyl octanoate), isopropyl myristate, isopropyl palmitate, C12-C15 alcohol benzoate, laurate hexyl, diisopropyl adipate, isononyl isononanoate, 2-ethylhexyl palmitate, isostearate isostearate, octanoates, decanoates or ricinoleates of alcohols or polyalcohols such as propylene glycol dioctanoate; hydroxylated esters such as isostearyl lactate, diisostearyl malate; and pentaerythritol esters; at room temperature liquids with a branched and / or unsaturated carbon chain having from 12 to 26 carbon atoms, such as octyl dodecanol, isostearyl alcohol, oleic alcohol, 2-hexyldecanol or 2-butyloctanol, 2-undecylpentadecanol; higher fatty acids such as oleic acid, linoleic acid, linolenic acid; and their mixtures. The non-volatile silicone oils that can be used in one or other of the compositions (i) or (ii) in accordance with the invention can be non-volatile polydimethylsiloxanes (PDMS), polydimethylsiloxanes comprising alkyl or alkoxy groups, during and / or at the end of the silicone chain, groups each having 2 to 24 carbon atoms, phenyl silicones such as phenyl trimethicones, phenyl dimethicones, phenyl trimethylsiloxy diphenylsiloxanes, diphenyl dimethicones, diphenyl methyldiphenyl trisiloxanes, 2-phenylethyl trimethylsiloxysilicates ; The fluorinated oils that can be used in the compositions in accordance with the invention are in particular fluorosilicone oils, fluorinated polyethers and fluorinated silicones as described in document EP-A-847752. The content of oil or non-volatile organic solvent in the compositions according to the invention ranges from 0.01 to 30% by weight, in particular from 0.1 to 25% by weight, and better still from 0.1 to 20% by weight. relative to the total weight of each composition.

The compositions in accordance with the invention may also comprise at least one dyestuff such as pulverulent materials, fat-soluble dyes and water-soluble dyes. The pulverulent dyestuffs may be chosen from pigments and nacres. The pigments may be white or colored, mineral and / or organic, coated or uncoated. Among the inorganic pigments, titanium dioxide, optionally surface-treated, oxides of zirconium, zinc or cerium, as well as oxides of iron or chromium, manganese violet, ultramarine blue, chromium hydrate and ferric blue. Among the organic pigments, mention may be made of carbon black, D & C type pigments, and lacquers based on cochineal carmine, barium, strontium, calcium, aluminum.

The nacres may be chosen from white pearlescent pigments such as mica coated with titanium or bismuth oxychloride, colored pearlescent pigments such as titanium mica with iron oxides, titanium mica with ferric blue or chromium oxide, titanium mica with an organic pigment of the aforementioned type as well as pearlescent pigments based on bismuth oxychloride.

Liposoluble dyes are for example Sudan Red, D & C Red 17, D & C Green 6, [3-carotene, soybean oil, Sudan Brown, D & C Yellow 11, D & C Violet 2, D & C Orange 5 , the yellow quinoline, the annatto. These dyestuffs may be present in a content ranging from 0.01 to 30% by weight relative to the total weight of the composition.

The compositions according to the invention may also comprise at least one filler. The fillers may be selected from those well known to those skilled in the art and commonly used in cosmetic compositions. The fillers can be mineral or organic, lamellar or spherical. Mention may be made of talc, mica, silica, kaolin, polyamide powders, such as the nylon sold under the name Orgasol by the company Atochem, poly-13-alanine and polyethylene, and tetrafluoroethylene polymer powders such as Teflon, lauroyl-lysine, starch, boron nitride, expanded polymeric hollow microspheres such as those of polyvinylidene chloride / acrylonitrile such as those sold under the name Expancel by Nobel Industrie, acrylic powders such as such as those marketed under the name Polytrap by Dow Corning, polymethyl methacrylate particles and silicone resin microspheres (Toshiba's Tospearls, for example), precipitated calcium carbonate, carbonate and hydro-carbonate. magnesium, hydroxyapatite, hollow silica microspheres (MAPRECOS Silica Beads), microcapsules of glass or ceramics e, metal soaps derived from organic carboxylic acids having from 8 to 22 carbon atoms, and in particular from 12 to 18 carbon atoms, for example zinc, magnesium or lithium stearate, zinc laurate, magnesium myristate.

It is also possible to use a compound capable of swelling with heat and in particular thermally expandable particles such as unexpanded microspheres of copolymer of vinylidene chloride / acrylonitrile / methyl methacrylate or copolymer of acrylonitrile homopolymer, for example those sold respectively under the references Expancel 820 DU 40 and Expancel 007WU by the company AKZO NOBEL. The fillers may represent from 0.1 to 25%, in particular from 0.2 to 20% by weight relative to the total weight of the composition comprising them. The compositions in accordance with the invention may also comprise at least one fiber which makes it possible to improve the lengthening effect.

By "fiber" it is necessary to understand an object of length L and of diameter D such that L is much greater than D, D being the diameter of the circle in which the section of the fiber is inscribed. In particular, the L / D ratio (or form factor) is chosen in the range from 3.5 to 2500, in particular from 5 to 500, and more particularly from 5 to 150. The fibers that can be used in the composition of the The invention may be fibers of synthetic or natural, mineral or organic origin. They can be short or long, unitary or organized, for example braided, hollow or full. Their shape can be any and in particular of circular or polygonal section (square, hexagonal or octagonal) depending on the specific application envisaged. In particular, their ends are blunt and / or polished to avoid injury.

In particular, the fibers have a length ranging from 1 μm to 10 mm, in particular from 0.1 mm to 5 mm and more particularly from 0.3 mm to 3.5 mm. Their section may be in a circle with a diameter ranging from 2 nm to 500 μm, in particular ranging from 100 nm to 100 μm and more particularly from 1 μm to 50 μm. The weight or titer of the fibers is often given in denier or decitex and represents the weight in gram for 9 km of yarn. The fibers according to the invention may in particular have a title chosen in the range from 0.15 to 30 denier and in particular from 0.18 to 18 denier. The fibers that can be used in the composition of the invention may be chosen from rigid or non-rigid fibers, they may be of synthetic or natural origin, mineral or organic.

Furthermore, the fibers may or may not be treated on the surface, coated or uncoated, colored or unstained. As fibers that can be used in the composition according to the invention, mention may be made of non-rigid fibers such as polyamide (nylon) fibers or rigid fibers such as polyimide-amide fibers such as those sold under the names KERMEL, KERMEL TECH by RHODIA or poly- (p-phenyleneterephthalamide) (or aramid) sold especially under the name Kevlar by the company DUPONT DE NEMOURS. The fibers may be present in the composition according to the invention in a content ranging from 0.01% to 10% by weight, relative to the total weight of the composition comprising them, in particular from 0.1% to 5% by weight. and more particularly from 0.3% to 3% by weight.

The compositions in accordance with the invention may also comprise at least one cosmetic active agent.

As cosmetic active agents that can be used in the compositions in accordance with the invention, mention may in particular be made of antioxidants, preservatives, perfumes, neutralizers, emollients, thickeners, coalescing agents, plasticizers, moisturizers and vitamins. and especially solar filters, and mixtures thereof.

Preferably, the first composition comprises particles of at least one wax and / or at least one dyestuff, in particular a pigment, as defined above.

The first and / or second composition may be in liquid, semiliquid, pasty or solid form. Preferably, the first composition and the second composition are packaged in separate packages.

Each composition can be packaged separately in the same packaging article. Each composition may also be packaged in a compartment within the same packaging article, the mixture of the two compositions being effected at the end or ends of the packaging article during the delivery of each composition.

Alternatively, each of the first and second compositions may be packaged in a different packaging article.

According to one embodiment, the second composition is packaged in the form of a spray, for example mineral water-based sprays, such as the Vichy and La Roche Posay waters, which are commercially available.

Of course, those skilled in the art will take care to choose the optional additional additives and / or their quantity in such a way that the advantageous properties of the composition according to the invention are not, or not substantially, impaired by the addition envisaged, and in particular so that they do not interfere with the complexing reaction between the alginic acid-based compound and the complexing agent.

The subject of the invention is also a cosmetic process for coating keratinous fibers comprising applying to said keratinous fibers: at least one layer of at least one first composition comprising an aqueous phase, an emulsifying system comprising less than 1% triethanolamine; at least one compound based on alginic acid, then - at least one layer of at least one second composition comprising a complexing agent of said compound.

The method of coating the eyelashes above may comprise a step of heating the first and / or second compositions, previously, simultaneously or after their application to the eyelashes.

According to one embodiment, the method of coating the eyelashes consists in applying to the eyelashes: at least one layer of at least one first composition comprising an aqueous phase, an emulsifying system comprising less than 1% triethanolamine, at least one compound based on alginic acid, then - at least one layer of at least one second composition comprising a complexing agent of said compound, then - to subject the film resulting from the application of the first and second compositions to a heat source .

The heat source may for example be a heating applicator.

Cleansing

The non-water-soluble film obtained by reaction between the alginic acid-based compound of the first composition described above and the complexing agent of the second composition described above can be easily removed with a sequestering agent ( also called chelating agent) of the complexing agent of the compound based on alginic acid.

This is why the invention also relates to a method for removing make-up and / or cleaning makeup films formed by the application, on keratinous fibers, of a first composition comprising an aqueous phase, an emulsifying system comprising less than 1% triethanolamine, at least one compound based on alginic acid, and a second composition comprising a complexing agent for said compound, the process comprising at least one step of applying to said makeup films, a composition removing makeup and / or cleaning comprising, in a physiologically acceptable medium, an aqueous phase and at least one sequestering agent of said complexing agent.

After application of the make-up removing and / or cleaning composition to the makeup film obtained after application of first and second compositions, the sequestering agent is bonded with the complexing agent (in particular the multivalent ions) present in the complex complexing agent-compound based on alginic acid, which causes the dissociation of said complex and the disintegration of the makeup film on the eyelashes.

The subject of the invention is also a cosmetic kit comprising: a first composition comprising an aqueous phase, an emulsifying system comprising less than 1% triethanolamine, at least one compound based on alginic acid, a second composition comprising an agent complexing said compound and - a makeup removal and / or cleaning composition comprising, in a physiologically acceptable medium, an aqueous phase and at least one sequestering agent of said complexing agent.

The first and second compositions are as described above.

The sequestering agent of the complexing agent is chosen in particular from carboxylic acids, preferably aminocarboxylic acids, phosphonic acids, preferably aminophosphonic acids, polyphosphoric acids, preferably linear polyphosphoric acids, their salts and derivatives. The salts include alkali metal, alkaline earth metal, ammonium and substituted ammonium salts.

The chelating agents may in particular be chosen from: amino carboxylic acids (that is to say acids comprising at least one carboxylic acid group), such as compounds having the following INCI name: phytic acid, diethylenetriamine pentaacetic acid (DTPA) ), ethylenediamine disuccinic acid (EDDS) and trisodium ethylenediamine disuccinate such as OCTEL Octaquest E30, ethylenediaminetetraacetic acid (EDTA), ethylenediamine-N, N'-diglutaric acid (EDDG) glycinamide-N, N'-disuccinic acid (GADS) ), glycinamide-N, N'-disuccinic acid (GADS), 2-hydroxypropylenediamine-N, N'-disuccinic acid (HPDDS), ethylenediamine-N-N'-bis (ortho-hydroxyphenyl acetic acid) (EDDHA), N, N'-bis (2-hydroxybenzyl) ethylenediamine-N, N'-diacetic acid (HBED), nitrilotriacetic acid (NTA), methylglycine diacetic acid (MGDA) N-2-hydroxyethyl N, N diacetic acid and glyceryl imino diacetic acid (as described in EP-A-317,542 and EP-A-399,133, iminodiacetic acid-N-2-hyd roxypropyl sulfonic acid and aspartic acid N-carboxymethyl N-2-hydroxypropyl-3-sulfonic acid (as described in EP-A-516,102), beta-alanine-N, N'-diacetic acid, aspartic acid-N , N'-diacetic acid, aspartic acid-N-monoacetic acid (described in EP-A-509,382), chelating agents based on iminodisuccinic acid (IDSA) (as described in EP-A-509,382), and etoldiglycine acid - phophonobutane tricarboxylic acid such as the compound marketed by Bayer under the reference Bayhibit AM, - tetrasodium glutamate diacetate (GLDA) such as Dissolvine GL38 or Dissolvine GL-45S from Akzo Nobel - chelating agents based on mono or polyphosphonic acid such as the compounds having the INCI name: diethylenetriamine-penta (methylene phosphonic acid) (DTPMP), ethane-1-hydroxy-1,1,2-triphosphonic acid (El HTP), ethane-2- hydroxy-1,1,2-triphosphonic acid (E2HTP), ethane-1-hydroxy-1,1-triphosphonic acid (EHDP), ethan-1,1,2-triphosphonic acid (ETP), ethylenediaminetetr amethylene phosphonic acid (EDTMP), 1,1-hydroxyethane diphosphonic acid (HEDP), polyphosphoric acid-based chelants such as compounds having the following INCI name: sodium tripolyphosphate (STP), tetrasodium diphosphate, hexametaphophoric acid, sodium metaphosphate, their salts and derivatives, and their mixtures.

Mention may also be made of carboxylated derivatives of fructan inulin (as for example those described in US6280628.

Among the chelating agents mentioned, ethylene diaminetetraacetic acid (EDTA), diethylene triamine pentaacetic acid (DTPA), S, S-ethylenediamine disuccinic acid (EDDS), ethylene diamine tetramethylene phosphonic acid are preferably used ( EDTMP), phophonobutane tricarboxylic acid, tetrasodium glutamate diacetate (GLDA) and mixtures thereof.

The sequestering agent may be present in a content ranging from 0.01% to 30% by weight relative to the total weight of the makeup removal and / or cleaning composition, preferably from 0.05% to 15% by weight and more preferably from 0.05% to 15% by weight. 0.1 to 10% by weight.

Preferably, the sequestering agent is present in the form of an aqueous solution, that is to say that the cleansing and / or cleaning composition comprises an aqueous phase as defined above. The compositions according to the invention may each be packaged in a container defining at least one compartment which comprises said composition, said container being closed by a closure element.

The container is preferably associated with an applicator, particularly in the form of a brush having an arrangement of bristles held by a twisted wire. Such a twisted brush is described in particular in US Pat. No. 4,887,622. It may also be in the form of a comb comprising a plurality of application elements, obtained in particular from molding. Such combs are described, for example, in patent FR 2 796 529. The applicator may be integral with the container, as described for example in patent FR 2 761 959. Advantageously, the applicator is secured to a rod which, it itself is integral with the closure element.

The closure member may be coupled to the container by screwing. Alternatively, the coupling between the closure element and the container is other than by screwing, in particular via a bayonet mechanism, snap-fastening or clamping. By "snapping" is meant in particular any system involving the crossing of a bead or a bead of material by elastic deformation of a portion, in particular of the closure element, then by return to the position not elastically constrained by 30 said portion after crossing the bead or cord.

The container may be at least partly made of thermoplastic material. Examples of thermoplastic materials include polypropylene or polyethylene. Alternatively, the container is made of non-thermoplastic material, in particular glass or metal (or alloy).

The container is preferably equipped with a wiper arranged in the vicinity of the opening of the container. Such a wiper makes it possible to wipe the applicator and, optionally, the rod which can be secured to it. Such a wiper is described, for example, in patent FR 2 792 618.

The following examples are illustrative of the present invention and can not limit its scope. Examples The following compositions were made. The amounts indicated are expressed as a percentage by weight relative to the total weight of the composition. Composition 1 Beeswax 10% Sodium Alginate (ISP Kelcosol) 4% 20 Cetyl Phosphate (Rock Amphisol K) 4% Antifoam (Simethicone) 0.13% Black Iron Oxide 7% Preservatives qs Water qs 100 25 Compositions 2 2A 2B Hydroxyethylcellulose 3.21% 3.31% Calcium Chloride 2H20 3% - (Merck) Preservatives 0.15% 0.15% Water qs 100 qs 100 28 30 1) Evaluation of the resistance properties and resistance to The following tests were conducted: Test 1 (comparative) Test 2 (Invention) Test 3 (Comparative) Application of composition 1 on a false-eyelash test specimen (straight Caucasian hair 30 knots (60 cilia 1 cm long) length of the fringe 2 cm), making 3 x 10 passages spaced 2 minutes with product recovery between each set of 10. allowed to dry 1 min Application of the composition Application of composition 2A (3 x 10 spaced passages 2B (3 x 10 passages spaced 2 minutes apart with 2 minute resumption with product recovery between each series of product t between each set of 10). 10). The test specimen is allowed to dry at room temperature for a drying time of one hour.

The resistance and water resistance properties of the film formed on each test piece were evaluated according to the protocols described below. a) The masked test tube was passed under running water at 25 ° C for 1 min and wiped on a blotter by going back and forth on the blotter.

The amount of mascara is visually assessed on the blotter. b) It is then immersed in a container containing water for 1 hour. The test piece is then run back and forth on a blotter, and then the test piece is then pinched in a dry cotton pad for ten seconds and then the cotton is pulled for makeup removal.

The amount of mascara on the blotter and cotton is visually evaluated. Held Trial 1 Trial 2 Trial 3 Step a) Swelling of the film No trace of Swelling of the mascara water under mascara blotter under Traces black on Traces gray on blotter 29 Step b) Traces gray on No trace on Traces gray on blotting blotter No blotting Total make-up remover Makeup on total cleansing of mascara cotton mascara on cotton The makeup film formed by complexation of alginate with calcium ions (Test 2) according to the invention has a very good performance at the same time. water, much greater than that of the film formed by application of composition 1 alone (Test 1) or that of the film formed by application of compositions 1 and 2B (Test 3) according to the invention has good strength and is resistant to the water. 2) Evaluation of the Makeup Removal Composition 1 was applied to 4 test pieces of false eyelashes by making 3 × 10 passes spaced for 2 minutes with product recovery between each set of 10, then the specimens were allowed to dry for 1 min at 25 ° C. . Each composition is then applied to Composition 2A (3 x 10 passages spaced 2 minutes apart with product recovery between each set of 10).

The specimens are allowed to dry at room temperature for a drying time of one hour. Specimens Nos. 1 and 2 are immersed in a container containing a 10% EDTA solution for 30 minutes and 1 hour, respectively. Then one roundtrip of each test piece is made on a blotter.

Specimens Nos. 3 and 4 are immersed in a container containing water for 30 minutes and 1 hour, respectively. Then one roundtrip of each test piece is made on a blotter.

The effectiveness of cleansing is noted by visually evaluating the amount of mascara on the blotter. Make-up removal after: Test tube Test tube Test tube No.1 No.2 No.3 No.4 Immersion 30min in Black marks - - 10% EDTA solution on the blotter 1 hour immersion in - Black traces - - EDTA solution to 10% on the blotter Immersion 30min in - -Very light - water gray traces on the blotter Immersion 1 hour in - - Very light water gray traces on the blotter The makeup film formed by complexation of the alginate with the calcium ions according to the invention is easily cleansed in the presence of a chelating ion solution and removes very easily with water (good resistance to water), contrary to Tests 1 and 3.

Claims (22)

A kit for coating keratinous fibers comprising a first composition comprising an aqueous phase, an emulsifying system comprising less than 1% triethanolamine, at least one compound based on alginic acid, and a second composition comprising a complexing agent. said compound. 2. Kit according to claim 1, characterized in that the compound based on alginic acid has a weight average molecular weight ranging from 10,000 to 1,000,000, preferably from 15,000 to 500,000 and preferably from 20,000 to 250,000. 3. Kit according to claim 1 or 2, characterized in that the compound based on alginic acid is a sodium or potassium alginate. 4. Kit according to one of the preceding claims, characterized in that the compound based on alginic acid is present in a content ranging from 0.1 to 30% by weight relative to the total weight of the first composition comprising it, preferably from 0.5 to 20% by weight and better still from 1 to 10% by weight. 5. Kit according to one of the preceding claims characterized in that the first composition comprises less than 1%, preferably less than 0.5% by weight of triethanolamine. 6. Kit according to one of the preceding claims characterized in that the first composition is free of triethanolamine. 7. Kit according to one of the preceding claims characterized in that the first composition comprises less than 1%, preferably less than 0.5% by weight of triethanolamine stearate. 8. Kit according to one of the preceding claims characterized in that the first composition is free of triethanolamine stearate25 9. Kit according to one of the preceding claims characterized in that the aqueous phase is present in a content ranging from 1% to 95% by weight, relative to the total weight of the composition, preferably ranging from 3% to 80% by weight. % by weight, and preferably ranging from 5% to 60% by weight. 10. Kit according to one of the preceding claims characterized in that the complexing agent of the compound based on alginic acid is selected from polyeléctrolytes, multivalent ions and their salts. 10 11. Kit according to one of the preceding claims characterized in that the complexing agent of the compound based on alginic acid is selected from multivalent cation salts or polycations. 12. Kit according to the preceding claim, characterized in that the cations are divalent cations, in particular cations of calcium, magnesium, aluminum, barium, zinc, nickel, copper (+ II), manganese and mixtures thereof. 13. Kit according to one of the preceding claims characterized in that the complexing agent of the compound based on alginic acid is calcium chloride. 14. Kit according to one of the preceding claims characterized in that the complexing agent is present in a content ranging from 0.01 to 30% by weight relative to the total weight of the composition, preferably 0.02 at 15% by weight and more preferably from 0.05 to 5% by weight. 15. A cosmetic process for coating keratinous fibers comprising applying to said keratinous fibers: at least one layer of at least one first composition comprising an aqueous phase, an emulsifying system comprising less than 1% triethanolamine, at least one compound containing alginic acid base, then - at least one layer of at least one second composition comprising a complexing agent of said compound. 20 25 30 16. A method for removing makeup and / or cleaning make-up films formed by the application, on the keratinous fibers, of a first composition comprising an aqueous phase, an emulsifying system comprising less than 1% of triethanolamine, at least one compound based on alginic acid, and a second composition comprising a complexing agent of said compound, the process comprising at least one step of applying to said makeup films, a make-up removing and / or cleaning composition comprising in a physiologically acceptable medium, an aqueous phase and at least one sequestering agent of said complexing agent. 17. The method of claim 16, characterized in that the sequestering agent of the complexing agent is selected from carboxylic acids, preferably aminocarboxylic acids, phosphonic acids, preferably amino phosphonic acids, polyphosphoric acids, preferably linear polyphosphoric acids, their salts and derivatives. 18. The method of claim 16 or 17, characterized in that the sequestering agent of the complexing agent is selected from: - aminocarboxylic acids such as: diethylenetriamine pentaacetic acid (DTPA), ethylenediamine disuccinic acid (EDDS) and trisodium ethylenediamine disuccinate, ethylenediaminetetraacetic acid (EDTA), ethylenediamine-N, N'-diglutaric acid (EDDG) glycinamide-N, N'-disuccinic acid (GADS), glycinamide-N, N'-disuccinic acid (GADS), 2-hydroxypropylenediamine- N, N'-disuccinic acid (HPDDS), ethylenediamine-N-N'-bis (ortho-hydroxyphenyl acetic acid) (EDDHA), N, N'-bis (2-hydroxybenzyl) ethylenediamine-N, N'-diacetic acid (HBED), nitrilotriacetic acid (NTA), methylglycine diacetic acid (MGDA) the N-2-hydroxyethyl N, N diacetic acid and the glyceryl imino diacetic acid, the iminodiacetic acid-N-2-hydroxypropyl sulfonic acid and the aspartic acid N-carboxymethyl N-2-hydroxypropyl-3-sulfonic acid, beta-alanine-N, N'-diacetic acid, aspartic acid-N, N'-diacetic acid , aspartic acid-N-monoacetic acid, - chelants based on iminodisuccinic acid (IDSA), - ethanoldiglycine acid - phophonobutane tricarboxylic acid, - tetrasodium glutamate diacetate (GLDA), - acid-based chelating agents mono or polyphosphonic such as: diethylenetriamine-penta (methylene phosphonic acid) (DTPMP), ethane-1-hydroxy-1,1,2-triphosphonic acid (El HTP), ethane-2-hydroxy-1,1,2- triphosphonic acid (E2HTP), ethane-1-hydroxy-1,1-triphosphonic acid (EHDP), ethan-1,1,2-triphosphonic acid (ETP), ethylenediaminetetramethylene phosphonic acid (EDTMP), hydroxyethane-1,1 diphosphonic acid (HEDP), - polyphosphoric acid-based chelants such as: sodium tripolyphosphate (STP), tetrasodium diphosphate, hexametaphophoric acid, sodium metaphosphate, phytic acid, their salts and derivatives, and mixtures thereof. 19. Method according to one of claims 16 to 18, characterized in that the sequestering agent is selected from ethylene diaminetetraacetic acid (EDTA), diethylene triamine pentaacetic acid (DTPA), S, S-ethylenediamine disuccinic acid (EDDS), ethylene diamine tetramethylene phosphonic acid (EDTMP), phophonobutane tricarboxylic acid, tetrasodium glutamate diacetate (GLDA), their salts and derivatives, phytic acid, and mixtures thereof. 20. Method according to one of claims 16 to 19, characterized in that the sequestering agent is ethylene diamine tetra acetic acid. 21. Method according to one of claims 16 to 20, characterized in that the sequestering agent is present in a content ranging from 0.01 to 30% by weight relative to the total weight of the makeup removal composition and / or cleaning, preferably from 0.05 to 15% by weight and better still from 0.1 to 10% by weight. 22. A cosmetic kit comprising: a first composition comprising an aqueous phase, an emulsifying system comprising less than 1% triethanolamine, at least one compound based on alginic acid, a second composition comprising a complexing agent of said compound and a make-up removing and / or cleaning composition comprising, in a physiologically acceptable medium, an aqueous phase and at least one sequestering agent of said complexing agent.