FR2924341A1 - Reshapable hair styling composition comprises (meth)acrylic copolymers comprising butyl (meth)acrylate monomer units, hydroxyalkyl (meth)acrylate monomer units and other copolymerizable monomer units, and fillers - Google Patents

Abstract

Reshapable hair styling composition comprises: one or more (meth)acrylic copolymers comprising (a) units obtained from one or more monomers containing butyl (meth)acrylate monomers, (b) units obtained from one or more monomers comprising hydroxyalkyl (meth)acrylate monomers, and (c) optional units obtained from one or more other copolymerizable monomers other than the monomers (a) and (b); and one or more fillers, in an excipient. Independent claims are included for a cosmetic treatment of hair comprising applying the composition on the hair and then styling the hair without any additional composition or heat.

Description

B07 / 2736FR FB / GBO OA07458 Anonymous company known as L'OREAL Styling composition comprising (meth) acrylic copolymers and at least one filler Invention of: Sandrine DECOSTER Jean Mary PROUST Styling composition comprising (meth) acrylic copolymers and at least one a charge

The present invention relates to a repositionable styling composition which is preferably a rinsed composition. The fixation of the hairstyle is an important element of styling, and involves the creation of a shape or the maintenance of a shape that has already been achieved. According to the invention, the term styling composition relates to any type of hair composition that can be used for styling. The most common hair styling compositions on the market for cosmetic products for shaping and / or maintaining the hairstyle are spray compositions comprising a solution, usually based on alcohol or water, and one or more compounds, generally polymeric resins. One of the functions of polymer resins is to form bonds between the hair. These materials, also known as fixatives, are often mixed with different cosmetic adjuvants. This solution is generally packaged either in a suitable aerosol container, which is pressurized with a propellant, or in a pump bottle. Many styling compositions existing to date have the same drawback: they are not intended to allow the hairstyle to be subsequently modified into a desired shape, which is other than that initially formed, without restarting the hairstyling operations again. and fixation. Moreover, under different types of stress, the hairstyle tends to take an unwanted permanent form that can not be easily changed. In addition, during the styling process, the beneficial effects of hair conditioning, such as ease of combing and softness to the touch of the hair, can be investigated. There are also rinsed compositions allowing a repositionable effect. The term "repositionable styling composition" is intended to mean a styling composition giving a styling that can be restored or modified without reapplying a substance or heat. For example, to restore or change the hairstyle in the case of weighting or loss of setting (dishing), there is no need for any new material such as water or any form of fixing agent nor additional heat. The effectiveness of the composition can be sustainable leading to a lasting styling effect. However, these repositionable styling compositions generally do not provide such a pronounced recoating effect as that of a non-rinsed composition. In particular, the effect obtained with a rinsed composition generally results in a lack of holding the same day of application and over time. Such compositions are described for example in the patent application EP-A-1 321 130. The object of the present invention is to obtain a repositionable styling composition, preferably rinsed, imparting a reinforced styling effect, a ease of styling improved upon application and improved texture.

This object is achieved by the present invention, which relates to a repositionable capping composition, preferably rinsed, comprising, in a cosmetically acceptable vehicle, (i) one or more (meth) acrylic copolymers comprising: (a) patterns derived from one or more monomers chosen from butyl (meth) acrylate monomers, (b) units derived from one or more monomers selected from the hydroxyalkyl (meth) acrylate monomers and optionally (c) one or more copolymerizable monomers other than said monomers (a) and (b), and (ii) one or more fillers.

Another subject of the invention is a method for the cosmetic treatment of the hair, comprising the application to the hair, prior to the shaping of said hair, of a composition comprising one or more fillers and one or more (meth) acrylic copolymers as described above. Another object of the invention is a hair treatment method, comprising: (1) applying to the hair, prior to the initial shaping of the hairstyle, a composition comprising one or more fillers and one or more (meth) acrylic copolymers as described above, said composition providing a repositionable effect and preferably being a rinsed composition such as a shampoo or a conditioner, and then (2) shaping the hairstyle at least one time, without the need for additional composition or additional heat. The invention also relates to the use of the composition according to the invention as a shampoo or conditioner. The (meth) acrylic copolymer used according to the invention is described in EP-A-1 321 130. The term (meth) acrylate includes both the term acrylate and the term methacrylate. Similarly, the term (meth) acrylic acid includes both acrylic acid and methacrylic acid. By rinsed composition is meant any composition which is formulated to be rinsed immediately or after a laying time generally less than 30 minutes, preferably less than 10 minutes, after application to the hair. The monomers (a) usable for the preparation of the (meth) acrylic copolymer (i) used in the composition according to the invention are the monomers of butyl (meth) acrylates such as, for example, n-butyl (meth) acrylates, t-butyl (meth) acrylates, isobutyl (meth) acrylates, 2-decylbutyl (meth) acrylates and 2-methylbutyl (meth) acrylates. Preferably, the monomers (a) are chosen from n-butyl acrylate.

The monomers (a) are generally from 10 to 90% by weight, preferably from 15 to 50% by weight, more preferably from 30 to 40% by weight, based on the total amount of monomers used. According to another distinct embodiment, the monomers (a) constitute from 50 to 90% by weight and preferably from 70 to 90% by weight, relative to the total amount of monomers used. The monomers (b) that can be used for the preparation of the (meth) acrylic copolymer (i) used in the composition according to the invention are chosen from the monomers of (meth) acrylate of hydroxy (C1-C4) alkyl, such as, for example 2-hydroxyethyl (meth) acrylates, hydroxypropyl (meth) acrylates, 2,3-dihydroxypropyl (meth) acrylates, 4-hydroxybutyl (meth) acrylates, and (meth) acrylates of 2-hydroxyethyl hydroxypropyl. Preferably, the monomers (b) are chosen from monomers of 2-hydroxyethyl acrylate, 2-hydroxyethyl methacrylate and hydroxypropyl acrylate and more particularly 2-hydroxyethyl methacrylate. The monomers (b) are generally from 2 to 50% by weight, preferably from 2 to 25% by weight, more preferably from 2 to 10% by weight, based on the total amount of monomers used. According to another embodiment of a separate embodiment, the monomers (b) constitute from 10 to 50% by weight, preferably from 10 to 30% by weight, relative to the total amount of monomers used.

The monomers (c) which may optionally be used for the preparation of the (meth) acrylic copolymer (i) used in the composition according to the invention may be chosen from (i ') the (meth) acrylate monomers, preferably ( C1-C24 alkyl (meth) acrylates; (ii ') polar monomers; and (iii') ethylenically unsaturated monomers free radically polymerizable. The alkyl (meth) acrylate monomers (i ') may include, for example, methyl (meth) acrylates, isobornyl (meth) acrylates, ethyl (meth) acrylates, (meth) acrylates, and the like. isooctyl, 2-ethylhexyl (meth) acrylates, lauryl (meth) acrylates, octa-decyl (meth) acrylates, and mixtures thereof. In another embodiment, the units derived from the monomers of 2-ethylhexyl (meth) acrylate constitute from 30 to 80% by weight of the total amount of monomers used. Useful polar monomers (ii ') include (meth) acrylic acid, itaconic acid, N-vinylpyrrolidone, N-vinylcaprolactam, substituted (meth) acrylamides (such as N, N-dimethyl (meth) acrylamides and N-octyl (meth) acrylamide), dimethylaminoethyl (meth) acrylate, (meth) acrylonitrile, 2-carboxyethyl (meth) acrylate, maleic anhydride, and mixtures thereof. Another example of useful polar monomers (ii ') is methoxypolyethylene glycol 550acrylate available from Sartomer Co. under the trade name CD553.

Free radical polymerizable (III ') polymerizable ethylenically unsaturated monomers include styrene and C 1 -C 4 vinyl esters such as vinyl acetate, vinyl propionate, and mixtures thereof. In yet another embodiment, the units derived from copolymerizable free radical polymerizable ethylenically unsaturated monomers (iii ') are present in a concentration of up to 30% by weight relative to the total weight of all the monomers. Preferably, the monomers (c) which may be used for the preparation of the (meth) acrylic copolymer (i) used in the composition according to the invention is 2-ethylhexyl (meth) acrylate. The monomers (c) which may optionally be used for the preparation of the (meth) acrylic copolymer (i) used in the composition according to the invention constitute, for example, up to 80% by weight, preferably from 30% to 80% by weight, and more preferably from 50 to 70% by weight, based on the total amount of monomers used. According to another embodiment, the monomers (c) may constitute up to 50% by weight, preferably up to 30% by weight, relative to the total amount of monomers used.

The (meth) acrylic copolymer (s) (i) used in the composition according to the invention are prepared from a monomer mixture which may contain one or more polyfunctional crosslinking agents.

For the purposes of the present invention, the term "polyfunctional crosslinking agent" means a crosslinking agent having an average functionality greater than 1, for example greater than 1.8 and preferably greater than 2.0. However, the average functionality is less than 6, for example less than 4, and preferably equal to or less than 3. Examples of crosslinking agents include, but are not limited to, those selected from divinylbenzene, diacrylates, and the like. alkyl (such as those selected from 1,2-ethylene glycol diacrylate, 1,4-butanediol diacrylate, 1,6-hexanediol diacrylate, 1,8-octanediol diacrylate and 1,12-diacrylate). -dodecanediol), alkyl triacrylates and alkyl tetra acrylates (such as trimethylolpropane triacrylate and pentaerythritol tetra acrylate), monoethylenically unsaturated aromatic ketones (such as 4-acryloxybenzophenone), aziridine multifunctional amides (such as 1,1 '- (1,3-phenylenedicarbonyl) bis [2-methylaziridine], 2,2,4-trimethyladipoylbis [2-ethylaziridine], 1,1'-azelaoylbis [2- methylaziridine] and 2,4,6-tris (2-ethyl-1-aziridinyl) -1,3,5-triazine), the reticulated metal ionizers (such as copper, zinc, zirconium and chromium) and mixtures thereof. In one embodiment, the metal ionic crosslinking agents are chosen from the chelated esters of ortho-titanic acid sold under the trade name TYZOR and available on the market from EI of the Pont de Nemours Co. In another mode of implemented, the TYZOR is TYZOR AA, which is titanium acetylacetonate. Preferably, the crosslinking agent is 1,6-hexanediol diacrylate. The crosslinking agents, when used, can be up to 10 parts by weight, typically from 0.1 to 2 parts by weight of the total copolymerizable mixture based on 100 parts by weight of the monomers mentioned in (a) , (b) and (c), when present. The (meth) acrylic copolymer (s) (i) used in the composition according to the invention may be optionally obtained with one or more water-soluble and / or oleo-soluble initiators, which are used to obtain (meth) acrylic copolymers in the form of emulsions. Such initiators, upon exposure to heat, generate free radicals which initiate the (co) polymerization of butyl (meth) acrylate monomers, hydroxyalkyl (meth) acrylate monomers, and optional comonomer and extender components. crosslinking agent. According to one embodiment, one or more water-soluble initiators are used. For the purposes of the present invention, the term "water-soluble initiator" means initiators having a solubility in water measured at 25 ° C. of at least 0.1 gram / liter (g / L) (obtaining a macroscopically isotropic solution). and transparent, colored or not). This solubility is preferably greater than or equal to 1 g / L. Suitable water-soluble initiators include, but are not limited to, those selected from potassium persulfate, ammonium persulfate, sodium persulfate, and mixtures thereof; oxidation-reducing initiators such as the reaction product of the persulfates mentioned above and reducing agents such as those selected from sodium metabisulfite and sodium bisulfite; and 4,4'-azobis (4-cyanopentanoic acid) and its soluble salts (eg, sodium, potassium). In another embodiment, the water-soluble initiator is potassium persulfate.

Alternatively, suitable oleo-soluble initiators include, but are not limited to, those selected from azo compounds such as VAZO 64 (2,2'-azobis (isobutyronitrile) and VAZO 52 (2,2'-azobis). azobis (2,4-dimethylpentanenitrile)), both available from EI Pont de Numours Co., and peroxides such as benzoyl peroxide, lauroyl peroxide and mixtures thereof. in use, the oleo-soluble thermal initiator is 2,2'-azobis (isobutyronitrile). When they are (are) used, the initiator (s) can from 0.05 to 1 part by weight, also from 0.1 to 0.5 parts by weight based on 100 parts by weight of the total copolymerizable mixture. Meth) acrylics (i) used in the composition according to the invention may optionally be obtained with one or more chain transfer agents. Useful chain salts include, but are not limited to, those selected from carbon tetrabromide, alcohols, mercaptans, and mixtures thereof.

In a particularly preferred manner, the chain transfer agent is chosen from iso-octylthioglycolate and carbon tetrabromide. The copolymerizable mixture may further comprise up to 0.5 parts by weight of one or more chain transfer agents, typically from 0.01% by weight to 0.5 parts by weight, if used, also from 0.05 parts by weight to 0.2 parts by weight, based on 100 parts by weight of the total copolymerizable mixture. According to a preferred embodiment, the (meth) acrylic copolymer (s) used in the composition according to the invention comprise: (a) from 10 to 90% by weight of units derived from one or more monomers chosen from monomers of butyl (meth) acrylate, - (b) from 2 to 50% by weight of units derived from one or more monomers chosen from hydroxyalkyl (meth) acrylate monomers, preferably (meth) acrylate monomers. hydroxy-C1-C4-alkyl, and - (c) from 0 to 80% by weight of the possible units derived from one or more copolymerizable monomers other than said monomers (a) and (b) More preferably, the copolymer (s) (Meth) acrylics (i) used in the composition according to the invention comprise: - (a) from 30 to 40% by weight of units derived from one or more monomers chosen from n-butyl acrylate monomers, (b) from 2 to 10% by weight of units derived from one or more monomers selected from methacrylate monomers 2-hydroxyethyl ester, and - (c) from 50 to 70% by weight of units derived from one or more monomers selected from 2-ethylhexyl acrylate monomers.

Even more preferably, the (meth) acrylic copolymer (i) used in the composition according to the invention comprises: - (a) 35% by weight of units derived from a butyl acrylate monomer, - (b) 5% by weight of units derived from a monomer of 2-hydroxyethyl methacrylate, and (c) 60% by weight of units derived from a monomer of 2-ethylhexyl acrylate. Such a product is proposed by the company 3M under the name CPC-00960 ACP 45 Acrylates Copolymer. The percentages by weight of units (a), (b) and (c) are based on the total weight of each type of monomer used relative to the total weight of all the monomers used. The (meth) acrylic copolymer or copolymers (i) may be present in an amount ranging from 0.01 to 40% by weight, preferably ranging from 0.1 to 15% by weight, and more preferably ranging from 0.1 to 2% by weight, of the total weight of the composition to give a repositionable effect. The (meth) acrylic copolymer (s) (i) may be in the form of an emulsion or dispersion. All emulsions comprise a continuous phase and at least one dispersed phase. By dispersion is generally meant a multiphase system in which at least one phase contains discrete particles distributed in a liquid, solid or gaseous external phase. Part of the polymer may exist as discrete particles in an aqueous phase. Dispersions are possible through the use of certain components that are insoluble in the aqueous system. In a dispersion, it is not necessarily the entire polymer that must be insoluble in water; a portion of the polymer may be soluble in the aqueous mixture. It may be desirable for a dispersion to remain stable under ambient conditions. In one embodiment, the dispersions are stable at room temperature for more than about 30 days, for example for more than about 90 days, preferably for more than about 180 days, and more preferably for more than about 360 days. A dispersion is considered stable since the discrete particles of the internal phase remain distributed throughout the mass substance (external phase).

In one embodiment, such dispersions can be mixed with other dispersions or other known additives such as plasticizers, pigments (such as carbon black), silica sols and other agents. leveling agents, wetting agents, anti-foaming agents, and known stabilizers.

The (meth) acrylic copolymer (s) (i) used in the composition according to the invention can be prepared by conventional polymerization techniques, such as emulsion polymerization, as is well known in the polymer field. Polymerization via emulsion techniques may require the presence of one or more emulsifiers to facilitate emulsification of the monomer mixture (which may also be called emulsifiers or surfactants). Emulsifiers useful for the present invention include those selected from anionic surfactants, nonionic surfactants, and mixtures thereof. Anionic surfactants useful as emulsifiers include, but are not limited to, those whose molecular structure includes at least one hydrophobic moiety selected from C6 to C18 alkyls, C6 to C12 alkylaryls, and C6 to C16 alkenyls and at least one anionic group chosen from sulphates, sulphonates, phosphates, polyoxyethylenesulphates, polyoxyethylenesulphonates, polyoxyethylenephosphates, etc., and the salts of such groups. In one embodiment, said salts are chosen from alkali metal salts, ammonium salts, tertiary amino salts, and the like. Representative commercial examples of the anionic surfactants useful as emulsifiers include sodium lauryl sulphates, available from Stepan Chemical Co. as POLYSTEP B-3; sodium lauryl ether sulphates, available from Stepan Chemical Co. as POLYSTEP B-12; sodium dodecylbenzenesulphonates, available from Rhodia Chimie in the form of SIPONATE DS-10; and alkylene polyalkoxyammonium sulfates, available from PPG Industries as MAZON SAM-211.

Nonionic surfactants useful as emulsifiers include, but are not limited to, those whose molecular structure comprises a condensation product of an organic aliphatic moiety and / or aromatic alkyl moiety with a hydrophilic alkylene oxide such as The HLB coefficient (lipophilic-hydrophilic balance) of nonionic surfactants useful as emulsifiers is about 10 or greater, for example about 10 to about 20. The HLB coefficient of a surfactant is an expression of the balance of the size and resistance of the hydrophilic groups (hydro-attractors or polar) and lipophilic groups (oleo-attractors or non-polar) of the surfactant. Commercial examples of nonionic surfactants useful in the present invention include, but are not limited to, nonylphenoxy or octylphenoxy poly (ethyleneoxy) ethanols available from Rhodia Chimie in the form of the IGEPAL CA or CO series, respectively; C11-C15 secondary alcohol ethoxylates available from Union Carbide in the form of the TERGITOL 15-S series; and the oxyethylenated sorbitan fatty acid esters available from ICI Chemicals in the form of the TWEEN surfactant series.

In one embodiment, an emulsion polymerization according to the invention is carried out in the presence of one or more anionic surfactants as emulsifiers. A useful range of emulsifier concentration is 0.5 to 8% by weight, for example 1 to 5% by weight, based on the total weight of all monomers. According to one embodiment of the invention, the (meth) acrylic copolymers (i) are emulsions or dispersions of (meth) acrylic copolymers. Emulsions and dispersions of (meth) acrylic copolymers (i) can be prepared by a semicontinuous emulsion polymerization process. In the process, a vial is charged with a primer monomer mixture comprising deionized water (DI), surfactant, butyl (meth) acrylate monomers (a), (meth) acrylate monomers, hydroxyalkyl (b), and optional components such as copolymerizable monomers (c), polyfunctional crosslinking agents, chain transfer agents, pH modifiers and other additives. The mixture is stirred and heated under an inert atmosphere such as a blanket of nitrogen. When the mixture has reached the induction temperature, typically from about 50 ° C to about 70 ° C, the first initiator is added to initiate polymerization and the reaction is allowed to proceed exothermically. When the priming reaction is complete, the batch temperature is then increased to the feed reaction temperature of from about 70 ° C to about 85 ° C. At the feed reaction temperature, the monomer pre-emulsion comprising DI water, surfactant, butyl (meth) acrylate monomers (a), hydroxyalkyl (meth) acrylate monomers (b) ), and optional components such as copolymerizable monomers (c), polyfunctional crosslinking agents, chain transfer agents, and other additives are added to the stirred flask over a period of time, typically from 2 to 4 hours. hours, while the temperature is maintained. At the end of the feed reaction, the second initiator feed, if used, is added to the reaction to further reduce the residual monomers in the emulsion / dispersion. After another hour of heating, the mixture is cooled to room temperature (about 23 ° C) and the emulsion / dispersion is recovered for evaluation.

In one embodiment, the pH of the emulsion / dispersion is from about 2 to about 3. The acidity of the emulsion / dispersion can be varied depending on the formation of the emulsion / dispersion. using one or more pH modifiers such as basic solutions (eg sodium hydroxide solutions, ammonium hydroxide solutions, etc.) or buffer solutions (eg sodium bicarbonate) , etc.) at lower acid levels. In another embodiment, the pH is 7 or lower. In yet another embodiment, the pH is in the range of 2 to 6. In one embodiment of the invention, the (meth) acrylic copolymers (i) can be neutralized in the emulsion. the dispersion and / or in the composition with one or more neutralizing agents. Suitable neutralizing agents may be chosen from organic, inorganic or organo-mineral bases, such as aminomethylpropanols, sodium and potassium hydroxides, primary, secondary and tertiary amines, ammonia, derivatives thereof, and associations of these. According to one embodiment, the (meth) acrylic emulsions of the invention may also contain one or more conventional additives, such as plasticizers, dyes, antioxidants, and UV stabilizers. Such additives may be used if desired. they do not alter the repositionable properties of the composition. According to one embodiment of the invention, the (meth) acrylic copolymer (i) has a glass transition temperature (Tg) of from about 100 ° C to about 15 ° C. According to the present invention, the Tg of the (meth) acrylic copolymer is obtained following the application of the (meth) acrylic copolymer (i) in an aqueous or aqueous-alcoholic medium on a matrix, then drying to constant weight. The glass transition temperature is determined by the differential thermal analysis (DSC) method.

In one embodiment of the invention, the (meth) acrylic copolymer (i) is chosen from nonionic and slightly anionic (meth) acrylic copolymers. Slightly anionic means that the proportion of units derived from anionic monomers in the copolymer is less than 5% by weight. The composition according to the invention comprises one or more fillers. For the purposes of the present invention, the term "filler" means insoluble solid particles in the composition.

Preferably, the fillers of the composition according to the invention have a solubility in water at 25 ° C. and at atmospheric pressure (760 mmHg) of less than 0.5%, and even more preferentially less than 0.1%. Preferably, the fillers of the invention are mineral fillers. Preferably, these fillers are not pearlescent compounds. The fillers may be selected from those well known to those skilled in the art and commonly used in cosmetic compositions.

The fillers can be mineral or organic, lamellar or spherical. Mention may be made of talc, silica, kaolin, polyamide powders, such as the nylon sold under the name Orgasol by Atochem, poly- (3-alanine and polyethylene), tetrafluoroethylene polymer powders such as Teflon, lauroyl-lysine, starch, boron nitride, expanded polymeric hollow microspheres such as those of polyvinylidene chloride / acrylonitrile such as those sold under the name Expancel by Nobel Industrie, acrylic powders such as those sold under the name Polytrap by the company Dow Corning, polymethyl methacrylate particles and silicone resin microbeads (Toshiba Tospearls, for example), calcium carbonate, magnesium carbonate and magnesium carbonate, hydroxyapatite, hollow silica microspheres (MAPRECOS Silica Beads), glass or ceramic microcapsules, metallic soaps derivatives derived from organic carboxylic acids having from 8 to 22 carbon atoms, and in particular from 12 to 18 carbon atoms, for example zinc, magnesium or lithium stearate, zinc laurate, magnesium myristate. Preferably, the filler is calcium carbonate. It is also possible to use a compound capable of swelling with heat and in particular thermally expandable particles such as unexpanded microspheres of copolymer of vinylidene chloride / acrylonitrile / methyl methacrylate or copolymer of acrylonitrile homopolymer, for example those sold respectively under the references Expancel 820 DU 40 and Expancel 007WU by the company AKZO NOBEL. The charge or fillers are present in the composition in a content ranging from 0.1 to 20%, preferably from 0.5 to 10% by weight relative to the total weight of the composition. The composition provides a repositionable effect and is preferably a rinsed composition, for example, a conditioner or shampoo, the latter may or may not have a conditioning effect. According to a first preferred embodiment of the invention, the composition of the invention comprises in a cosmetically acceptable vehicle, (1) one or more fillers and (2) one or more (meth) acrylic copolymers comprising: (a) units derived from one or more monomers selected from butyl (meth) acrylate monomers, (b) units derived from one or more monomers selected from hydroxyalkyl (meth) acrylate monomers and optionally (c) units derived from one or more copolymerizable monomers other than said monomers (a) and (b), and (3) one or more surfactants.

According to a second embodiment of the invention, the composition of the invention comprises in a cosmetically acceptable vehicle, (1) one or more fillers and (2) one or more (meth) acrylic copolymers comprising: (a) patterns derived from one or more monomers chosen from butyl (meth) acrylate monomers, (b) units derived from one or more monomers chosen from hydroxyalkyl (meth) acrylate monomers and optionally (c) from one or more copolymerizable monomers other than said monomers (a) and (b), and (3) one or more conditioning agents. The composition comprising one or more fillers and one or more (meth) acrylic copolymers, as described above, may be in the form of sprays, aerosols, foams, gels, lotions, creams, dispersions or emulsions. The rinsed composition may be in any of the conventional forms of rinsed cosmetic compositions including, but not limited to, shampoos, conditioners, hair rinse lotions, perming compositions, hair dyeing compositions, hair conditioners, and the like. use before or after a hair dyeing treatment, products to be used before or after a permanent treatment, hair straightening compositions, products to be used before or after straightening treatment, and combinations thereof. A shampoo has a cleansing effect on the hair and can also have a conditioning effect. A conditioner has a conditioning effect on the hair without significant cleaning effect. According to one embodiment of the invention, the (meth) acrylic copolymer may be present in an amount ranging from 0.01 to 40, preferably from 0.1 to 15% by weight, and more preferably from 0, 1 to 2% by weight, of the total weight of the composition to give a repositionable effect. The composition may further comprise any cosmetically acceptable vehicle which does not substantially interfere with the adhesive properties of the composition according to the invention. The choice of vehicle is adapted to the chosen application method. In one embodiment, the cosmetically acceptable vehicle may be selected from water, water-miscible solvents such as lower alcohols, e.g. C1-C4 branched and straight chain aliphatic alcohols, and combinations thereof. In one embodiment, the (meth) acrylic copolymer is insoluble in the cosmetically acceptable vehicle. The vehicle may also include one or more additional solvents. For example, other rapidly evaporating solvents may be used, such as hexamethyldisiloxane (HMDS); cyclic silicones (D4 and D5); C 4 -C 10 alkanes including isoparaffins such as Permethyl 97A and Isopar C; acetone; hydrofluoroethers (HFE), etc. The composition according to the invention may further comprise one or more constituents known in cosmetics which do not substantially interfere with the repositionable properties of the composition. Such constituents may be selected from, but are not limited to: reducing agents (such as thiols); oxidizing agents anionic polymers; silanes (such as aminopropyltriethoxysilane); fat; plasticizing thickeners; moisturizing agents; sunscreens (such as UV filters) active hair care agents; perfumes; conservatives; protein polyols; provitamines; vitamins; colorants; and pH modifiers.

According to the second embodiment of the invention, the composition may also comprise one or more conditioning agents. The term "conditioning agent" as used herein means any agent whose function is to improve the cosmetic properties of the hair, for example the softness, the ease of disentangling, the touch, and the absence of static electricity. In one variant, the conditioning agent is chosen from cationic, amphoteric and nonionic non-silicone polymers and silicones. According to a particular embodiment, the conditioning agent is chosen from non-silicone polymers such as cationic, amphoteric (as zwitterionic) and nonionic polymers, preferably cationic polymers and combinations thereof. . The term "polymer" as used herein refers to homopolymers and copolymers, the copolymers being derived from more than one type of monomer, for example from two, three or four different types of monomer or more. The cationic polymers comprise cationic groups or groups that can be converted into cationic groups. Suitable examples of cationic polymers which may be used according to the present invention are those which may be chosen from polymers comprising at least one group chosen from primary amine groups, secondary amine groups, tertiary amine groups, and amine groups. wherein said at least one moiety is part of the polymer chain or is directly attached thereto, having a weight average molecular weight of from about 500 to about 5,000,000, e.g. from about 1,000 to about 3,000,000. Among these polymers, mention may be made more particularly of the following cationic conditioning polymers: (1) homopolymers and copolymers derived from monomers chosen from (meth) acrylic esters and (meth) acrylic amides comprising at least one of the following formulas: embedded image in which each R 3 is independently selected from hydrogen ene and CH3 groups; each A is independently selected from linear and branched alkyl groups having 1 to 6 carbon atoms and hydroxyalkyl groups having 1 to 4 carbon atoms; each R4, R5 and R6 is independently selected from alkyl groups of 1 to 18 carbon atoms and benzyl groups; each R1 and R2 is independently selected from hydrogen and alkyl groups having from 1 to 6 carbon atoms; and each X- is independently selected from methyl sulfate anions and halide anions, such as chloride or bromide anions. In one embodiment, the copolymers of the family (1) further comprise at least one unit derived from monomers chosen from (meth) acrylamides, diacetones (meth) acrylamides, (meth) acrylamides substituted on the nitrogen by a group selected from lower alkyl, (meth) acrylic acids, (meth) acrylic acid esters, vinyllactams such as vinylpyrrolidone and vinylcaprolactam, and vinyl esters.

Thus, among these cationic conditioning copolymers of the family (1), mention may be made of: copolymers of acrylamide and of dimethylaminoethyl methacrylate quaternized with dimethyl sulphate or with a dimethyl halide, such as Hercofloc available from the company Hercules; copolymers of acrylamide and of methacryloyloxyethyltrimethylammonium chloride which are disclosed, for example, in document EP-A-080 976 and sold, for example, under the name Bina Quat P 100 by the company Ciba-Geigy; copolymers of acrylamide and methacryloyloxyethyltrimethylammonium methosulphate, such as Reten available from Hercules; optionally vinylpyrrolidone / dialkylaminoalkyl (meth) acrylate copolymers, which are disclosed, for example, in French Patents 2,077,143 and 2,393,573 and sold, for example, under the name Gafquat by the company ISP, such as for example, Gafquat 734 or Gafquat 755, or the products referred to as Copolymer 845, 958 and 937; dimethylaminoethyl methacrylate / vinylcaprolactam / vinylpyrrolidone terpolymers, such as the product sold under the name Gaffix VC 713 by the company ISP; the vinylpyrrolidone / methacrylamidopropyldimethylamine copolymers sold in particular under the name Styleze CC 10 by ISP, and the quaternized vinylpyrrolidone / dimethylaminopropylmethacrylamide copolymer, such as the product sold under the name Gafquat HS 100 by the company ISP. (2) cellulose ether derivatives containing quaternary ammonium groups described in French Patent 1,492,597. Examples include the polymers sold under the names JR (JR 400, JR 125 and JR 30M) or LR (LR 400 and LR 30M) by the company Amerchol. These polymers are also defined in the CTFA dictionary as quaternary ammoniums of hydroxyethylcellulose reacted with an epoxide substituted with a trimethylammonium group. (3) cationic cellulose derivatives such as cellulose copolymers and cellulose derivatives grafted with a water-soluble quaternary ammonium monomer, and disclosed in particular in US Pat. No. 4 131 576. Examples include hydroxyalkylcelluloses, for example hydroxymethyl -, hydroxyethyl-, and hydroxypropyl-celluloses grafted in particular with a salt of methacryloylethyltrimethylammonium, methacrylamidopropyltrimethylammonium, or diallyldimethylammonium. The marketed products corresponding to this definition are more particularly the products sold under the name Celquat L 200 and Celquat H 100 by the company National Starch. (4) chitosans or their salts. Salts that may be used include chitosan acetate, lactase, glutamate, gluconate or pyrrolidone carboxylate. Among these compounds, mention may be made of chitosan having a degree of deacetylation of 90.5% by weight, sold under the name Kytan Crude Standard by Aber Technologies, and the pyrrolidone carboxylate of chitosan sold under the name Kytamer PC by the Amerchol company. (5) quaternized polysaccharides, disclosed more particularly in U.S. Patent Nos. 3,589,578 and 4,031,307, such as guar gums comprising cationic trialkylammonium groups. Examples include guar gums modified with a salt (eg, chloride) of 2,3-epoxypropyltrimethylammonium. Such products are sold in particular under the trade names Jaguar C13 S, Jaguar C 15, Jaguar C 17, and Jaguar C162 by Rhodia Chimie. (6) copolymers comprising piperazinyl units of divalent alkylene or straight and branched chain hydroxyalkylene groups, optionally interrupted by one or more oxygen atoms, sulfur atoms, nitrogen atoms, or by aromatic rings, and rings; heterocyclic. Examples include oxidation and quaternization products of these copolymers. Such polymers are described in particular in French Patents 2 162 025 and 2 280 361. (7) water-soluble polyaminoamides, which can be prepared by polycondensation of an acidic compound with a polyamine. These polyaminoamides may be crosslinked by at least one compound chosen from epihalohydrins, diepoxides, dianhydrides, unsaturated dianhydrides, bis-unsaturated derivatives, bis-halohydrins, bis-azetidiniums, bis-haloacyl diamines and bis-halides. alkyl, and oligomers resulting from the reaction of a difunctional compound, reactive with a compound selected from bis-halohydrins, bis-azetidiniums, bishaloacyldiamines, alkyl bis-halides, epihalohydrins, diepoxides, and bis-unsaturated derivatives. The crosslinking agent may be used in amounts ranging from about 0.025 to about 0.35 moles per amine group of the polyamino amide. In one embodiment, these polyaminoamides are alkylated and / or, if they contain one or more tertiary amine functions, quaternized.

Such polymers are described in particular in French patents 2 252 840 and 2 368 508. (8) polyamino amide derivatives resulting from the condensation of polyalkylene-polyamines with polycarboxylic acids, followed by alkylation with difunctional agents. Examples include adipic acid / dialkylaminohydroxyalkyldialkylenetriamine polymers in which the alkyl groups are alkyl groups are C1-C4 alkyl groups (such as methyl, ethyl, and propyl), such as the adipic acid / dimethylaminohydroxypropyldiethylenetriamine polymers sold under the name Cartaretine F, F4 and F8 by the company Sandoz. Such polymers are described in particular in French Patent 1,583,363. (9) polymers obtained by reaction of a polyalkylene polyamine containing two primary amine groups and at least one secondary amine group with a dicarboxylic acid chosen from diglycolic acids and saturated aliphatic dicarboxylic acids having from 3 to 8 carbon atoms. The molar ratio of the polyalkylene polyamine to the dicarboxylic acid is from about 0.8: 1 to about 1.4: 1. The resultant polyaminoamide is reacted with epichlorohydrin in a molar ratio of epichlorohydrin to the secondary amine moiety of the polymaminoamide of from about 0.5: 1 to about 1.8: 1. Such polymers are described in particular in US Pat. Nos. 3,227,615 and 2,961,347. Polymers of this type are sold in particular under the name Hercosett 57 by the company Hercules Inc., or else under the name PD 170 or Delsette 101. by the company Hercules in the case of the adipic acid / epoxypropyl / diethylenetriamine copolymer. (10) alkyldiallylamine and / or dialkyldiallylammonium cyclopolymers, such as homopolymers or copolymers containing, as a main constituent of the following formulas (I) and / or (II): - chain, - (CH 2) 1 - units - (I) (CH 2) k CR, z C (R, z) -CH 2 -CH 2 CH 2 N 2 N + y. R, / (CH,) k (CH2) t CRt2 C (R, 2) -CH2- i H2C CHZ N R10 in which k and t are either 0 or 1 and the sum k + t is 1; each R12 is independently selected from hydrogen and methyl groups; R10 and R11 are independently selected from alkyl groups having from 1 to 8 carbon atoms (such as from 1 to 4 carbon atoms), C1-4 hydroxyalkyl groups and C1-C4 amidoalkyl, or R10 and R11 groups; taken together with the nitrogen atom to which they are attached may form a heterocyclic group such as piperidyl and morpholinyl; Y- is independently selected from anions such as anions bromide, chloride, acetate, borate, citrate, tartrate, bisulfate, bisulfite, sulfate, and phosphate. These polymers are described in particular in French Patent 2,080,759 and in its certificate of addition 2,190,406. Among the polymers defined above, mention may be made more particularly of the homopolymer of dimethyldiallylammonium chloride sold under the name Merquat 100 by Nalco (its low weight average molecular weight homologs) and copolymers of diallyldimethylammonium chloride and acrylamide, sold under the name Merquat 550. (11) quaternary diammonium polymers containing repeating units corresponding to formula (III): wherein R 13, R 14, R 15 and R 16 are independently selected from C 1 -C 20 aliphatic groups, C1-C20 alicyclic or C1-C20 arylaliphatic, and lower aliphatic hydroxyalkyl groups; or R13, R14, R15 and R16, together or separately, together with the nitrogen atoms to which they are attached, form heterocycles optionally containing a second heteroatom other than nitrogen; or else R13, R14, R15 and R16 are independently selected from linear and branched C1-C6 alkyl groups, substituted by at least one group selected from nitrile, ester, acyl, amide groups, -CO-O-R17-D and -CO-NH-R17-D groups, where R17 is alkylene and D is a quaternary ammonium group; Al and B1 are independently chosen from linear and branched, saturated and unsaturated polymethylene groups containing from 2 to 20 carbon atoms and capable of containing, bound to or intercalated in the main chain, at least one group chosen from aromatic rings, oxygen, sulfur, sulfoxides, sulfones, disulfides, amino, alkylamino, hydroxy, quaternary ammonium, ureido, amides and esters; X- is independently selected from anions derived from mineral or organic acids. In one embodiment, X- is an anion such as chloride and bromide. A1, R13, and R15 can form, with the two nitrogen atoms to which they are attached, a piperazine ring.

Alternatively, Al is selected from linear and branched, saturated and unsaturated alkylene or hydroxyalkylene groups, and B 1 is selected from (CH 2) n -CO-E-OC- (CH 2) n-groups in which n is 1 at 6 and E is chosen from: a) glycol residues of formula: -OZO-, where Z is chosen from linear and branched hydrocarbon groups and groups corresponding to one of the following formulas: - (CH2-CH2- O) x-CH 2 -CH 2 - and - [CH 2 -CH (CH 3) -O] y -CH 2 -CH (CH 3) - where x and y are integers ranging independently from 1 to 4 and representing a defined degree of polymerization and single or any number from 1 to 4 and representing an average degree of polymerization b) bis-secondary diamine residues, such as a piperazine derivative; c) bis-primary diamine residues, of formula: -NH-YNH-, where Y is selected from linear and branched hydrocarbon groups and CH2-CH2-S-S-CH2-CH2-; and d) ureylene groups of formula: -NH-CO-NH-. These polymers generally have a number average molecular weight of from about 1000 to about 100,000. Examples of such polymers of this type are described in US Pat. Nos. 2,273,780, 2,375,853, 2,388,614, and 2,454. 547, 3,206,462, 2,261,002, 2,271,378, 3,874,870, 4,001,432, 3,929,990, 3,966,904, 4,005,193, 4,025,617, 4,025,627, 4,025,653, 4,026,945, and 4,027,020. In one embodiment, the cationic conditioning polymers of the family (11) consist of repeating units corresponding to the formula: R R3.

Wherein R1, R2, R3, and R4 are independently selected from C1-C4 alkyl and C1-C4 hydroxyalkyl, n and p are integers ranging independently from about 2 to about 20 and X- is an anion selected from inorganic and organic acids. In one embodiment, R1, R2, R3, and R4 are selected from methyl groups; n = 3; p = 6; and X = Cl, referred to as hexadimethrin chloride according to the INCI nomenclature (CTFA). (12) quaternary polyammonium polymers consisting of units of formula (V): ## STR2 ## in which: R18, R19, R20, and R21 are independently selected from hydrogen, methyl, ethyl, propyl, -3-hydroxyethyl, -3-hydroxypropyl, and -CH2CH2 (OCH2CH2) pOH, where p is an integer from 0 to 6; with the proviso that R18, R19, R20, and R21 are not simultaneously hydrogen; r and s are integers independently of 1 to 6; q is an integer from 0 to 34; X- is selected from anions, such as halides; A is selected from dihalide groups such as - CH2-CH2-O-CH2-CH2-. Such compounds are described in particular in patent application EP-A-122 324. Among these products, mention may be made, for example, of Mirapol A 15, Mirapol AD1, Mirapol AZ1 and Mirapol 175 sold by Miranol. (13) Quaternary polymers of vinylpyrrolidone and vinylimidazole such as, for example, the products sold under the names Luviquat TFC, FC 905, FC 550 and FC 370 by BASF. (14) polyamines such as Polyquart H sold by Henkel referred to as Polyethylene glycol (15) tallow polyamine in the CTFA dictionary. (15) crosslinked or non-crosslinked polymers of methacryloyloxyalkyl (C1-C4) trialkyl (C1-C4) ammonium salts such as polymers obtained by homopolymerization of dimethylaminoethyl methacrylate quaternized with methyl chloride or by copolymerization of acrylamide with dimethylaminoethyl methacrylate quaternized by a methyl halide (such as chloride), the homopolymerization or copolymerization being followed by crosslinking with an olefinically unsaturated compound, especially methylenebisacrylamide. In one embodiment, a crosslinked acrylamide / methacryloyloxyethyltrimethylammonium chloride copolymer (20/80 by weight) is used in the form of a dispersion containing 50% by weight of said copolymer in mineral oil. This dispersion is sold under the name Salcare SC 92 by the company Allied Colloids. In another embodiment, it is also possible to use a crosslinked homopolymer of methacryloyloxyethyltrimethylammonium chloride containing about 50% by weight of the homopolymer in mineral oil or in a liquid ester. These dispersions are sold under the names Salcare SC 95 and Salcare SC 96 by the company Allied Colloids. Other cationic conditioning polymers that can be used in the context of the invention are cationic proteins or hydrolysates of cationic proteins, polyalkyleneimines, in particular polyethyleneimines, polymers containing vinylpyridine or vinylpyridinium units, condensates of polyamines and epichlorohydrin. , quaternary polyureylenes and chitin derivatives. In one embodiment, the cationic conditioning polymers are chosen from quaternary cellulose ether derivatives such as the products sold under the name JR 400 by the company Amerchol; quaternized guar gum such as the products sold under the name Jaguar C 13 S by Rhodia; cationic cyclopolymers, especially homopolymers or copolymers of dimethyldiallylammonium chloride, sold under the names Merquat 100, Merquat 550 and Merquat S by Nalco, quaternary vinylpyrrolidone and vinylimidazole polymers; uncrosslinked and crosslinked polymers of methacryloyloxyalkyl (C1-C4) trialkyl (C1-C4) ammonium salts, such as the products sold under the name Salcare SC 96 by the company Nalco; and mixtures thereof. According to a particularly preferred embodiment, the compositions according to the invention comprise at least one cationic polymer chosen from homopolymers or copolymers of dimethyldiallylammonium chloride. According to the invention, the cationic polymer (s) may (may) represent from 0.001% to 20% by weight, for example from 0.01% to 10% by weight, for example from 0, 1% to 3% by weight, relative to the total weight of the composition. The amphoteric polymers that may be used in accordance with the invention may be chosen from polymers comprising X and Y units, statistically distributed in the polymer chain, where the X unit is chosen from units derived from at least one monomer comprising at least one function. basic, in particular a basic nitrogen atom, and wherein the unit Y is chosen from units derived from at least one acid monomer comprising at least one group chosen from carboxy groups and sulpho groups, or where each unit X and Y is independently selected from the groups derived from zwitterionic monomers of carboxybetaine and sulfobetaine. In another embodiment, the amphoteric polymers that may be used in accordance with the invention may be chosen from polymers comprising X and Y units, each X and Y unit is chosen independently from at least one cationic polymer chain comprising at least one at least one group chosen from primary amine groups, secondary amine groups, tertiary amine groups, and quaternary amine groups, in which at least one of the amine groups comprises a group chosen from the carboxy and sulpho groups connected by the intermediate of a hydrocarbon group, or the X and Y units, which are identical or different, are part of a chain of at least one polymer comprising an α, β-dicarboxy-ethylene unit, where at least one of the groups carboxy has been reacted with a polyamine comprising at least one group selected from primary and secondary amine groups. ode implementation, the amphoteric polymers as defined above are selected from the following polymers: (1) the polymers resulting from the copolymerization of a monomer derived from a vinyl compound carrying a carboxy group such as the (meth) acrylic acids, maleic acids, and α-chloroacrylic acids and a basic monomer derived from a substituted vinyl compound comprising at least one basic atom such as dialkylaminoalkyl- (meth) acrylate and dialkylaminoalkyl- (meth) ) acrylamide. Such compounds are disclosed in US Pat. No. 3,836,537. (2) Polymers comprising units derived from a) at least one monomer selected from the group consisting of alkyl-substituted (meth) acrylamides ) at least one acidic comonomer comprising at least one reactive carboxy group and c) at least one basic comonomer such as esters comprising at least one substituent chosen from primary, secondary, tertiary and quaternary amine substituents of the acids (meth) ), and the quaternization product of dimethylaminoethyl methacrylate with dimethyl or diethyl sulfate. The N-substituted (meth) acrylamide monomer mentioned in (a) is chosen more particularly from the N-substituted (meth) acrylamides in which the alkyl groups comprise from 2 to 12 carbon atoms, such as N-ethylacrylamide, N-ethylacrylamide and tert-butylacrylamide, N-tert-octylacrylamide, N-octylacrylamide, N-decylacrylamide, N-dodecylacrylamide, and the corresponding methacrylamides. The acidic comonomer mentioned in (b) is chosen more particularly from (meth) acrylic acids, crotonic acids, itaconic acids, maleic acids, fumaric acids, C1-C4 alkyl monoesters of maleic acid, C 1 -C 4 alkyl monoesters of fumaric acid, C 1 -C 4 alkyl monoesters of maleic anhydride, and C 1 -C 4 alkyl monoesters of fumaric anhydride. The basic comonomer mentioned in (c) is chosen more particularly from aminoethyl, butylaminoethyl, N, N'-dimethylaminoethyl, and N-tert-butylaminoethyl methacrylates.

In one embodiment, the amphoteric polymer is chosen from the copolymers whose CTFA name (4th ed., 1991) is octylacrylamide / acrylates / butylaminoethyl methacrylate copolymer, such as the products sold under the name Amphomer or Lovocryl 47 by the National Starch company. (3) the cross-linked and partially or completely alkylated polyaminoamides derived from polyaminoamides of general formula: ## STR2 ##

wherein R 10 represents a divalent group derived from a saturated dicarboxylic acid, a mono- or dicarboxylic aliphatic acid comprising an ethylenic double bond, an ester of a lower alkanol (having from 1 to 6 carbon atoms) of these acids, or a group resulting from the addition of any of said acids with a bisprimary or bis-secondary amine; and Z denotes a bis-primary, mono- or bis-secondary polyalkylene-polyamine group and represents, for example: a) in the proportions of about 60 mol% to 100 mol%, the group: --NH-4 (CH2) x Where X = 2 and p = 2 or 3, or x = 3 and p = 2 and wherein this group is derived from diethylenetriamine, triethylenetetraamine, or dipropylenetriamine; b) in the proportions of 0 mol% to about 40 mol%, the group (VIII) above, in which x = 2 and p = 1 and which is derived from ethylenediamine, or the group derived from piperazine ; C) in the proportions of from 0 mol% to about 20 mol%, the NH- (CH 2) 6 -NH- group derived from hexamethylenediamine, said polyaminoamines being crosslinked by adding a bifunctional crosslinking agent chosen from epihalohydrins; , diepoxides, dianhydrides and bisunsaturated derivatives, with the aid of from about 0.025 moles to about 0.35 moles of crosslinking agent per amine group of the polyaminoamide and alkylated by the action of acrylic acid, d. chloroacetic acid or an alkanesultone, or their salts. In one embodiment, the saturated carboxylic acids are selected from acids having from 6 to 10 carbon atoms, such as adipic acid, 2,2,4-trimethyladipic acid, acid 2, 4,4-trimethyladipic acid, terephthalic acid, and ethylenically double bonded acids such as acrylic acid, methacrylic acid and itaconic acid. In one embodiment, the alkanesultones used in the alkylation are chosen from propanesultone and butanesultone and the salts of the alkylating agents are chosen from sodium and potassium salts. (4) polymers comprising zwitterionic units of formula: ## STR2 ## in which R 11 is chosen from unsaturated groups

polymerizable compounds such as (meth) acrylate and (meth) acrylamide groups; y and z are independently selected from integers from 1 to 3; R12 and R13 are independently selected from hydrogen, methyl groups, ethyl groups and propyl groups; R14 and R15 are independently selected from hydrogen and

the alkyl groups, where the sum of the carbon atoms in R14 and R15 is less than or equal to 10. The polymers comprising such units may also comprise units derived from non-zwitterionic monomers, such as dimethylaminoethyl (meth) acrylate, (meth) acrylate

diethylaminoethyl, alkyl (meth) acrylates, (meth) acrylamides, and vinyl acetates. By way of example, mention may be made of the methyl methacrylate / dimethylcarboxymethylammonioethyl methacrylate copolymer such as the product sold under the name Diaformer Z301 by the

Sandoz company. (5) polymers derived from chitosan comprising monomeric units corresponding to the following formulas: ## STR1 ## where (E) the unit D being present in proportions ranging from 0% to about 30%, the E unit in proportions ranging from about 5% to about 50% and the F unit in proportions ranging from about 30% to about 90%, with the proviso that in this unit F , R16 represents a group of formula: ## STR2 ## in which, if q = 0, R 17, R 18 and R 19, which are identical or different, are chosen from hydrogen, methyl groups, hydroxy groups, acetoxy groups, amino residues, monoalkylamine residues, and dialkylamine residues, optionally interrupted by one or more nitrogen atoms and / or optionally substituted with one or more amine, hydroxy, carboxy, alkylthio, or sulfo groups; , and alkylthio residues in which the alkyl group carries a residue a mino, at least one of R17, R18 and R19 being, in this case, hydrogen; or if q = 1, R17, R18 and R19 each represents hydrogen, and the salts formed by these compounds with bases or acids. (6) polymers derived from the N-carboxyalkylation of chitosan, such as N- (carboxymethyl) chitosan or N- (carboxybutyl) chitosan sold under the name Evalsan by the company Jan Dekker. (7) The polymers corresponding to the general formula (X), for example disclosed in the French patent 1,400,366: (CH 2 CH 2) n -CH 2 COOH CO 0 III-R 21 F124 r -R 23 R 22 (X) in which R20 is selected from hydrogen, CH3O, CH3CH2O and phenyl; R21 is selected from hydrogen and lower alkyl groups such as methyl or ethyl; R22 is selected from hydrogen and lower alkyl groups such as methyl or ethyl; and R 23 is chosen from lower alkyl groups such as methyl or ethyl and the groups corresponding to the formula: -R 24 -N (R 22) 2, where R 24 is chosen from the groups -CH 2 -CH 2 -, -CH 2 -CH 2 -CH 2 - and ûCH 2 -CH (CH 3) - and R 22 have the same meanings as above, and the higher homologs of these groups comprising up to 6 carbon atoms. (8) Amphoteric polymers of the type ûD-XDX- chosen from: polymers obtained by the reaction of chloroacetic acid or sodium chloroacetate with compounds comprising at least one unit of formula -DXDXD- (XI) in which D denotes a group: and X denotes the symbol E or E '. E and E ', which may be identical or different, denote a divalent group chosen from straight and branched chain alkylene groups comprising up to 7 carbon atoms in the main chain, which is unsubstituted or substituted by hydroxyl groups and may comprise in addition to oxygen, nitrogen or sulfur atoms, or 1 to 3 aromatic and / or heterocyclic rings; the oxygen, nitrogen and sulfur atoms being present in the form of ether, thioether, sulfoxide, sulfone, sulphonium, alkylamine or alkenylamine groups, of benzylamine, amine oxide, quaternary ammonium, amide, imide, alcohol groups, ester, and / or urethane. b) polymers of formula: -DXDX- (XII) in which D denotes a group: ## EQU1 ## and X denotes the symbol E or E ', where X denotes E' at least once, E has the meaning indicated above; and E 'is a divalent group selected from straight and branched chain alkylene groups having up to 7 carbon atoms in the main chain, which is unsubstituted or substituted by one or more hydroxy groups and comprising one or more atoms of nitrogen, the nitrogen atom being substituted by an alkyl chain optionally interrupted by an oxygen atom and comprising obligatorily one or more carboxy functional groups and one or more hydroxyl functional groups and wherein the polymer of formula (XII) is betainized by reaction with chloroacetic acid or sodium chloroacetate. (9) (C1-C5) alkyl vinyl ether / maleic anhydride copolymers which are partially modified by semiamidation with an N, N-dialkylaminoalkylamine such as N, N-dimethylaminopropylamine, or by semi-esterification with N, N-dialkanolamine. These copolymers may also comprise other vinyl comonomers such as vinylcaprolactam.

In one embodiment, the amphoteric polymers according to the invention are chosen from family (3), such as the copolymers whose CTFA name (4th edition, 1991) is a copolymer of octylacrylamide methacrylate / acrylate / butylamino ethyl, such as the products sold under the names Amphomer, Amphomer LV 71 or Lovocryl 47 by the company National Starch and the family (4), such as the methyl methacrylate / dimethylcarboxymethylammonioethyl methyl methacrylate copolymer sold for example under the name Diaformer Z301 by the company Sandoz. The nonionic polymers that can be used according to the present invention are chosen for example from: homopolymers of vinylpyrrolidone; copolymers of vinylpyrrolidone and of vinyl acetate; polyalkyloxazolines such as the polyethyloxazolines sold by Dow Chemical under the names PEOX 50 000, PEOX 200 000 and PEOX 500 000; homopolymers of vinyl acetate, such as the product sold under the name Appretan EM by the company Hoechst or the product sold under the name Rhodopas A 012 by the company Rhodia Chimie; copolymers of vinyl acetate and of acrylic ester, such as the product sold under the name Rhodopas AD 310 by Rhodia Chimie; copolymers of vinyl acetate and ethylene, such as the product sold under the name Appretan TV by Hoechst; copolymers of vinyl acetate and of maleic ester, for example of dibutyl maleate, such as the product sold under the name Appretan MB Extra by the company Hoechst; copolymers of polyethylene and maleic anhydride; homopolymers of alkyl acrylate and homopolymers of alkyl methacrylate, such as the product sold under the name Micropearl RQ 750 by Matsumoto or the product sold under the name Luhydran A 848 S by the company BASF; copolymers of acrylic esters such as, for example, copolymers of alkyl (meth) acrylates, such as the products sold by Rohm & Haas under the names Primal AC-261 K and Eudragit NE 30 D, by the company BASF under the names Acronal 601, Luhydran LR 8833 or 8845, and by Hoechst under the names Appretan N 9213 or N 9212; copolymers of acrylonitrile and of a nonionic monomer chosen, for example, from butadiene and alkyl (meth) acrylates; mention may be made of the products sold under the names Nipol LX 531 B by the company Nippon Zeon or those sold under the name CJ0601 B by the company Rohm &Haas; polyurethanes, such as the products sold under the names Acrysol RM 1020 or Acrysol RM 2020 by the company Rohm & Haas, and the Uraflex XP 401 UZ and Uraflex XP 402 UZ products by the company DSM Resins; copolymers of alkyl acrylate and urethane such as the product 8538-33 by the company National Starch; polyamides, such as the product Estapor LO 11 sold by the company Rhodia Chimie; chemically modified or unmodified nonionic guar gums. The unmodified nonionic guar gums are, for example, the products sold under the name Vidogum GH 175 by the company Unipectine and under the name Jaguar C by the company Rhodia Chimie.

The modified nonionic guar gums that can be used according to the invention are, for example, modified with hydroxy-C 1 -C 6 groups. Examples that may be mentioned include hydroxymethyl, hydroxyethyl, hydroxypropyl and hydroxybutyl groups. These guar gums are well known in the prior art and can be prepared for example by reacting corresponding alkene oxides such as, for example, propylene oxides, with guar gum so as to obtain a modified guar gum. hydroxypropyl groups. Such nonionic guar gums possibly modified with hydroxyalkyl groups are for example sold under the trade names Jaguar HP8, Jaguar HP60, Jaguar HP120, Jaguar DC 293, and Jaguar HP 105 by Rhodia Chimie and under the name Galactosol 4H4FD2 by the Aqualon company. The alkyl groups of the nonionic polymers comprise from 1 to 6 carbon atoms, unless otherwise indicated. According to another embodiment of the invention, the conditioning agent is a silicone.

In what follows, silicone is meant, in accordance with the general acceptance, any organosilicon polymers or oligomers with a linear or cyclic, branched or crosslinked structure, of variable molecular weight, obtained by polymerization and / or by polycondensation of silanes. suitably functionalized, and essentially constituted by a repetition of main units in which the silicon atoms are connected to each other by oxygen atoms (siloxane bond -Si-O-Si-), optionally substituted hydrocarbon radicals, being directly linked via a carbon atom to said silicon atoms. The most common hydrocarbon radicals are alkyl radicals, especially C 1 -C 10 radicals, and in particular methyl radicals, fluoroalkyl radicals whose alkyl part is C 1 -C 10, aryl radicals and in particular phenyl radicals.

The silicones that can be used in the composition according to the invention can be volatile or nonvolatile, soluble or insoluble in the composition. They may in particular be polyorganosiloxanes insoluble in the composition of the invention and may be in the form of oils, waxes, resins or gums. The insoluble silicones are in particular dispersed in compositions in the form of particles generally having a number-average size of between 2 nanometers and 100 microns, preferably between 20 nanometers and 20 microns (measured with a particle size analyzer). Polyorganosiloxanes are further defined in Walter Noll's "Chemistry and Technology of Silicones" (1968) Academic Press. They can be volatile or nonvolatile. When they are volatile, the silicones are more particularly chosen from those having a boiling point of between 60 ° C. and 260 ° C., and even more particularly from: (i) cyclic silicones containing from 3 to 7 silicon atoms and, preferably, 4 to 5. It is, for example, octamethylcyclotetrasiloxane sold in particular under the name "VOLATILE SILICONE 7207" by UNION CARBIDE or "SILBIONE 70045 V 2" by Rhodia, decamethylcyclopentasiloxane marketed under the name "VOLATILE SILICONE 7158" by UNION CARBIDE, "SILBIONE 70045 V 5" by RHODIA, and mixtures thereof.

Mention may also be made of cyclocopolymers of the dimethylsiloxane / methylalkylsiloxane type, such as the "VOLATILE SILICONE FZ 3109" marketed by UNION CARBIDE, of chemical structure CH3 CH3 with D: SiO2 + with SiO5 CH3 C31-i17. mention the cyclic silicone mixtures with organic compounds derived from silicon, such as the mixture of octamethylcyclotetrasiloxane and tetramethylsilylpentaerythritol (50/50) and the mixture of octamethylcyclotetrasiloxane and oxy-1,1 '- (hexa-2), 2,2 ', 2', 3,3'-trimethylsilyloxy) bis-neopentane; (ii) linear volatile silicones having 2 to 9 silicon atoms and having a viscosity of less than or equal to 5.10.6 m 2 / s at 25 ° C. This is, for example, decamethyltetrasiloxane marketed in particular under the name "SH 200" by Toray Silicone. Silicones included in this class are also described in the article published in Cosmetics and toiletries, Vol. 91, Jan. 76, p. 27-32 - TODD & BYERS "Volatile Silicone fluids for cosmetics". By non-volatile silicone is meant in the sense of the present invention, any silicone whose number of silicon atoms is greater than 7. Of the non-volatile silicones, there may be mentioned polyalkylsiloxanes, polyarylsiloxanes, polyalkylarylsiloxanes, gums and silicone resins, polyorganosiloxanes modified with organofunctional groups, linear polysiloxane (A) -polyoxyalkylene (B) linear block copolymers of type (AB) with n> 3; the grafted silicone polymers having a non-silicone organic skeleton, consisting of an organic main chain formed from organic monomers containing no silicone, on which is grafted, inside said chain as well as optionally to the at least one of its ends, at least one polysiloxane macromonomer; the grafted silicone polymers having a polysiloxane backbone grafted with non-silicone organic monomers, comprising a polysiloxane main chain on which is grafted, inside said chain as well as possibly at at least one of its ends, with at least one organic macromonomer not comprising silicone; as well as their mixtures. As examples of polyalkylsiloxanes, there may be mentioned polydimethylsiloxanes trimethylsilyl end groups having a viscosity of 5.10-6 to 2.5 m2 / s at 25 ° C and preferably 1.10-5 to 1 m2 / s. The viscosity of the silicones is, for example, measured at 25 ° C. according to the ASTM 445 Appendix C standard. Among these polyalkylsiloxanes, mention may be made, without limitation, of the following commercial products: SILBIONE oils of the 47 and 70 047 series or MIRASIL oils marketed by RHONE POULENC such as, for example, 70 047 V 500 000; oils of the MIRASIL series marketed by Rhodia; the oils of the 200 series of Dow Corning, such as, more particularly, the DC200 with a viscosity of 60,000 cSt; - VISCASIL oils from GENERAL ELECTRIC and some oils from SF series (SF 96, SF 18) from GENERAL ELECTRIC.

Mention may also be made of polydimethylsiloxanes containing dimethylsilanol end groups (Dimethiconol according to the CTFA name), such as the oils of the 48 series from Rhodia. In this class of polyalkylsiloxanes, mention may also be made of the products sold under the names "ABIL WAX 9800 and 9801" by GOLDSCHMIDT, which are poly (C1-C20) alkylsiloxanes. The polyalkylarylsiloxanes may in particular be chosen from polydimethylmethylphenylsiloxanes and linear and / or branched polydimethyl-diphenylsiloxanes with a viscosity of from 1 × 10 -5 to 5 × 10 -2 m 2 / s at 25 ° C. Among these polyalkylarylsiloxanes, mention may be made, by way of example, of the products sold under the following names - the SILBIONE oils of the 70 641 series from RHODIA, the oils of RHODORSIL 70 633 and 763 series from RHODIA

- DOW CORNING 556 COSMETIC GRAD FLUID oil from Dow Corning; the silicones of the PK series of BAYER, such as the product PK20; the silicones of the PN, PH series of BAYER, such as the PN1000 and PH1000 products; certain oils of the series SF of GENERAL ELECTRIC such as SF 1023, SF 1154, SF 1250, SF 1265. The silicone gums that can be used in the composition according to the invention are, in particular, polydiorganosiloxanes having high average molecular weights of between 200,000. and 1,000,000, used alone or as a mixture in a solvent. This solvent may be chosen from volatile silicones, polydimethylsiloxane (PDMS) oils, polyphenylmethylsiloxane (PPMS) oils, isoparaffins, polyisobutylenes, methylene chloride, pentane, dodecane, tridecanes or their mixtures. Mention may be made more particularly of the following products: polydimethylsiloxane gums, polydimethylsiloxane / methylvinylsiloxane gums, polydimethylsiloxane / diphenylsiloxane gums, polydimethylsiloxane / phenylmethylsiloxane gums, polydimethylsiloxane / diphenylsiloxane / methylvinylsiloxane gums. Can also be used mixtures of silicones such as: - mixtures formed from a hydroxylated polydimethylsiloxane gum at the end of the chain (called dimethiconol according to the CTFA dictionary nomenclature) and a cyclic polydimethylsiloxane (called cyclomethicone according to the nomenclature of the CTFA dictionary) such as the product Q2 1401 sold by the company Dow Corning; the mixtures formed from a polydimethylsiloxane gum with a cyclic silicone such as the product SF 1214 Silicone Fluid from the company General Electric, this product is an SF 30 gum corresponding to a dimethicone, having a number average molecular weight of 500 000 solubilized in oil SF 1202 Silicone Fluid corresponding to decamethylcyclopentasiloxane; Mixtures of two PDMSs of different viscosities, and more particularly of a PDMS gum and a PDMS oil, such as the product SF 1236 from the company General Electric. The product SF 1236 is the mixture of an SE 30 gum defined above having a viscosity of 20 m 2 / s and an SF 96 oil with a viscosity of 5 × 10 -6 m 2 / s. This product preferably comprises 15% of SE gum and 85% of an SF 96 oil. The polyorganosiloxane resins that can be used in the composition according to the invention are crosslinked siloxane systems containing the units: R2SiOz12, R3SiO112, RSiO312 and SiO412 in which R represents a hydrocarbon group having 1 to 16 carbon atoms or a phenyl group. Among these products, those particularly preferred are those in which R denotes a lower alkyl radical C1-C4, more particularly methyl, or a phenyl radical. Among these resins may be mentioned the product marketed under the name "Dow Corning 593" or those sold under the names "Silicone Fluid SS 4230 and SS 4267" by the company General Electric and which are silicones of dimethyl / trimethyl siloxane structure. Mention may also be made of the trimethylsiloxysilicate type resins sold in particular under the names X22-4914, X21-5034 and X21-5037 by the company Shinetsu.

The organomodified silicones that can be used in the composition according to the invention are silicones as defined above and comprising in their structure one or more organofunctional groups attached via a hydrocarbon-based group. Among the organomodified silicones, mention may be made of polyorganosiloxanes comprising: polyethyleneoxy and / or polypropyleneoxy groups optionally comprising C6-C24 alkyl groups such as the products known as dimethicone-copolyol sold by the company Dow Corning under the name DC 1248 or SILWET oils L 722, L 7500, L 77, L 711 from UNION CARBIDE and the (C 12) -methicone-copolyol alkyl sold by the company Dow Corning under the name Q 5200; thiol groups, such as the products sold under the names "GP 72 A" and "GP 71" from GENESEE; alkoxylated groups, such as the product sold under the name "Silicone Copolymer F-755" by SWS Silicones and Abil Wax 2428, 2434 and 2440 by the company GOLDSCHMIDT; hydroxyl groups, such as the hydroxyalkyl-functional polyorganosiloxanes described in the French patent application FRA-85 16334; acyloxyalkyl groups such as, for example, the polyorganosiloxanes described in US-A-4957732. anionic groups of the carboxylic acid type, for example in the products described in patent EP 186 507 of the company Chisso Corporation, or of the alkylcarboxylic type, such as those present in the product X-22-3701E from the company Shin-Etsu 2-hydroxyalkylsulfonate; 2-hydroxyalkylthiosulphate such as the products marketed by GOLDSCHMIDT under the names "ABIL 5201" and "ABIL S255". hydroxyacylamino groups, such as the polyorganosiloxanes described in application EP 342 834. There may be mentioned, for example, the product Q2- 8413 from the company Dow Corning. Preferably, the silicone is an amino silicone. For the purposes of the present invention, the term "aminated silicone" means any silicone comprising at least one primary, secondary, tertiary amine function or a quaternary ammonium group.

The amino silicones that can be used in the composition according to the present invention are chosen from: (a) the compounds corresponding to the following formula (XIII): (R 1) a (T) 3-a-Si [OSi (T) 2 ] n- [OSi (T) b (R1) 2-b] m-OSi (T) 3-a- (R1) a (XIII) in which, T is a hydrogen atom, or a phenyl radical, hydroxyl (-OH), or C1-C8 alkyl, and preferably methyl or C1-C8 alkoxy, preferably methoxy, a denotes the number 0 or an integer of 1 to 3, and preferably 0, b is 0 or 1, and in particular 1, m and n are numbers such that the sum (n + m) may vary in particular from 1 to 2,000 and in particular from 50 to 150, n being able to designate a number from 0 to 1,999 and in particular from 49 to 149 and m being able to designate a number from 1 to 2,000, and in particular from 1 to 10; R1 is a monovalent radical of the formula -CqH2qL wherein q is a number from 2 to 8 and L is an optionally quaternized amino group selected from the groups: -N (R2) -CH2-CH2-N (R2) 2; N (R 2) 2 N + (R 2) 3 Q- - N + (R 2) (H) 2 Q- -N + (R 2) 2HQ- -N (R 2) -CH 2 -CH 2 -N + (R 2) (H) 2 Q in which R 2 can denote a hydrogen atom, a phenyl, a benzyl, or a monovalent saturated hydrocarbon radical, for example a C 1 -C 20 alkyl radical, and Q represents a halide ion such as, for example, fluoride, chloride, , bromide or iodide. In particular, the aminosilicones corresponding to the definition of the formula (XIII) are chosen from the compounds corresponding to the following formula (XIV): ## STR1 ## where SiO 2 SiO 2 SiCH 3 CH 3 CH 3 CH 3

NH 1 (H2) 2 m NH 2 (XIV)

in which R, R ', R ", identical or different, denote a C 1 -C 4 alkyl radical, preferably CH 3, a C 1 -C 4 alkoxy radical, preferably methoxy, or OH; A represents a linear or branched, C3-C8, preferably C3-C6; m and n are integers dependent on molecular weight and whose sum is between 1 and 2000.

According to a first possibility, R, R ', R ", identical or different, represent a C1-C4 alkyl or hydroxyl radical, A represents a C3 alkylene radical and m and n are such that the weight average molecular weight of the compound The compounds of this type are referred to in the CTFA dictionary as "amodimethicone".

According to a second possibility, R, R ', R ", which may be identical or different, represent a C1-C4 alkoxy or hydroxyl radical, at least one of the radicals R or R" is an alkoxy radical and A represents a radical alkylene radical. C3. The hydroxyl / alkoxy molar ratio is preferably between 0.2 / 1 and 0.4 / 1 and advantageously equal to 0.3 / 1. Moreover, m and n are such that the weight average molecular weight of the compound is between 2000 and 106. More particularly, n is between 0 and 999 and m is between 1 and 1000, the sum of n and m being between 1 and 1000.

In this category of compounds, mention may be made inter alia of the product Belsil ADM 652, marketed by Wacker.

According to a third possibility, R, R ", different, represent a C1-C4 alkoxy or hydroxyl radical, at least one of the radicals R, R" is an alkoxy radical, R 'represents a methyl radical and A represents a radical. C3 alkylene. The molar ratio of hydroxy / alkoxy is preferably between 1 / 0.8 and 1 / 1.1, and advantageously is equal to 1 / 0.95. Furthermore, m and n are such that the weight average molecular weight of the compound is between 2000 and 200000. More particularly, n is between 0 and 999 and m is between 1 and 1000, the sum of n and m being between 1 and 1000. More particularly, there may be mentioned F1uidWR 1300 product, marketed by Wacker. The molecular mass of these silicones is determined by gel permeation chromatography (ambient temperature, polystyrene standard, styragem columns, THF eluent, flow rate of 1 mm / m, 200 l of a 0.5% solution by weight of silicone in THF and the detection is carried out by refractometry and UV-metry). A product corresponding to the definition of the formula (XIII) is in particular the polymer referred to in the CTFA dictionary "trimethylsilylamodimethicone", corresponding to the following formula (XV): (CH 3) 3 SiO CH 3 SiO 1 CH 3 CH 3 SiO CH 2 CHCH 3 CH 2 NH (1H 2) 2 NH 2 Si (CH 3) 3 m (XV) wherein n and m have the meanings given above according to formula (XIV). Such compounds are described for example in EP 95238; a compound of formula (XIII) is for example sold under the name Q2-8220 by the company OSI.

(b) compounds having the following formula (XVI): R 4 CH 2 CHOH 1 CH 2 or N + (R 3) 3 Q R 3 Si O

Wherein R3 represents a monovalent C1-C18 hydrocarbon radical, and in particular a C1-C18 alkyl radical, or a C2-C18 alkenyl radical, R3 R3 R3 R3 R3 R3 for example methyl; R4 represents a divalent hydrocarbon radical, especially a C1-C18 alkylene radical or a C1-C18, for example C1-C8, divalent alkyleneoxy radical; Q- is a halide ion, especially chloride; r represents an average statistical value of 2 to 20 and in particular 2 to 8; s represents an average statistical value of 20 to 200 and in particular 20 to 50. Such compounds are described more particularly in US Patent 4185087. A compound in this class is that sold by Union Carbide under the name " Ucar Silicone ALE 56 ". C) the quaternary ammonium silicones of formula (XVII): wherein R 7, which may be identical or different, represent a monovalent hydrocarbon radical having from 1 to 18 carbon atoms, and in particular a C1-C18 alkyl radical, a C2-C18 alkenyl radical or a ring comprising 5 or 6 carbon atoms, for example methyl; R 6 represents a divalent hydrocarbon radical, in particular a C 1 -C 18 alkylene radical or a divalent C 1 -C 18, for example C 1 -C 8, alkyleneoxy radical connected to Si by an SiC bond; R8, which may be identical or different, represent a hydrogen atom, a monovalent hydrocarbon radical having from 1 to 18 carbon atoms, and in particular a C1-C18 alkyl radical, a C2-C18 alkenyl radical or a radical -R6- NHCOR7; X - is an anion such as a halide ion, especially chloride or an organic acid salt (acetate, etc.); r represents an average statistical value of 2 to 200 and in particular 5 to 100; These silicones are for example described in application EP-A-0530974. According to the invention, it is also possible to use grafted silicone type polymers comprising a polysiloxane portion and a portion comprising a non-silicone organic chain, one of the two portions constituting the main chain of the polymer and the other being grafted onto the main chain. These polymers are disclosed, for example, in the documents EP A 0 412 704, EP-AO 412 707, EP-A-0 640 105, WO 95/00578, EP-A-0 582 152 and WO 93/23009 and the US patents. Nos. 4,693,935, 4,728,571 and 4,972,037. These polymers are, for example, anionic or nonionic. Examples of such polymers are, for example, copolymers obtainable by radical polymerization from the monomer mixture comprising: a) about 50% to about 90% % by weight of tert-butyl acrylate; b) 0% to about 40% by weight of acrylic acid; c) from about 5% to about 40% by weight of silicone macromer of the formula: ## STR5 ## where ## STR2 ##

Wherein v is a number from 5 to 700; the percentages by weight being calculated with respect to the total weight of the monomers. Other examples of grafted silicone polymers are, in particular, polydimethylsiloxanes (PDMS) on which are grafted, by means of a thiopropylene type connecting chain, mixed polymer units of the poly (meth) acrylic acid type and of the type alkyl poly (meth) acrylate and polydimethylsiloxanes (PDMS) on which are grafted, via a thiopropylene type connecting chain, polymeric units of the isobutyl poly (meth) acrylate type. It is also possible to use, as polymers, functionalized polyurethanes or not and silicone or not. Examples of useful polyurethanes include those disclosed in EP 0 751 162, EP 0 637 600, FR 2 743 297, EP 0 648 25 485, EP 0 656 021, WO 94/03510 and EP 0 619 111.

The silicone or non-silicone conditioning polymers may be used in solubilized form or may be in the form of dispersions of solid or liquid particles (latex or pseudolatex). According to the first embodiment, the composition may also comprise one or more surfactants chosen from anionic, amphoteric, nonionic and cationic surfactants, and mixtures thereof. The surfactant or surfactants are present in an amount ranging from 0.1% to 60% by weight, for example from 1% to 40%, and in addition from 5% to 30%, relative to the total weight of the composition.

In a variant, the composition is a shampoo in which the surfactant or surfactants are present in an amount ranging from 5% to 30% relative to the total weight of the composition. In another variant, the composition is a particular after-shampoo, in which one or more cationic surfactants are present in an amount ranging from 0.1% to 15% relative to the total weight of the composition and preferably 0.5 at 5% by weight. Representative surfactants suitable for carrying out the present invention are for example the following: (i) Anionic surfactant (s): Examples of anionic surfactants which can be used alone or in admixture include salts (such as alkali metal salts, especially sodium salts, ammonium salts, amine salts, aminoalcohol salts and magnesium salts) of compounds (such as alkyl sulphates, alkyl ether sulphates, alkylamido ether sulphates, alkylaryl polyether sulphates, monoglyceride sulfates, alkylsulfonates, alkylphosphates, alkylamidesulfonates, alkylarylsulfonates, α-olefin-sulfonates, paraffin-sulfonates, alkylsulfosuccinates, alkylethersulfosuccinates, alkylamidesulfosuccinates, alkylsulfosuccinamates, alkylsulfoacetates, alkyletherphosphates, acylsarcosinates, acylisethionates and N-acyltaurates). In one embodiment, the alkyl and acyl groups contain from about 8 to about 24 carbon atoms and the aryl groups are selected from phenyl and benzyl groups.

Among the anionic surfactants that may also be used, mention may also be made of fatty acid salts (such as the salts of oleic, ricinoleic, palmitic and stearic acids, coconut oil and hydrogenated coconut oil acids); and acyllactylates whose acyl group contains from 8 to 20 carbon atoms. It is also possible to use weakly anionic surfactants, such as alkyl-D-galactosiduronic acids and their salts, as well as polyoxyalkylenated (C6-C24) alkyl ether carboxylic acids, polyoxyalkylenated (C6-C24) aryl ether carboxylic acids, and alkyl (C6-C6) alkyl acids. C24) polyoxyalkylenated amidoether carboxylic acids and their salts, such as those containing from 2 to 50 ethylene oxide groups, and mixtures thereof. In one embodiment, the anionic surfactant (s) may be chosen from alkyl sulphate salts, alkyl ether sulphate salts, and mixtures thereof. In another embodiment, the anionic surfactant is chosen from lauryl ether sulphates of sodium, ammonium or magnesium. (ii) Nonionic surfactant (s): Nonionic surfactants are described, for example, in Handbook of Surfactants by M. R. Porter, published by Blackie & Son (Glasgow and London, 1991, pp. 116 - 178). Examples of nonionic surfactants that may be used alone or in admixture include alkylphenols, α-diols and alcohols; which all have a fatty chain containing, for example, from 8 to 18 carbon atoms and which have been polyethoxylated, polypropoxylated, and / or polyglycerolated, in which the number of ethylene oxide or propylene oxide groups varies from 2 to 50 and the number of glycerol groups ranges from 2 to 30. Mention may also be made of copolymers of ethylene oxide and propylene oxide, the ethylene oxide and propylene oxide condensates on fatty alcohols. ; polyethoxylated fatty amides (such as those having from 2 to 30 moles of ethylene oxide); polyglycerolated fatty amides containing on average 1 to 5, for example from 1.5 to 4 glycerol groups; polyethoxylated fatty amines (such as those having from 2 to 30 moles of ethylene oxide); oxyethylenated sorbitan fatty acid esters having from 2 to 30 moles of ethylene oxide; fatty acid esters of sucrose; polyethylene glycol fatty acid esters; alkylpolyglycosides; N-alkylglucamine derivatives; and amine oxides such as (Cio-C14) alkyl oxides and N-acylaminopropylmorpholine oxides. In one embodiment, the nonionic surfactants are chosen from alkylpolyglycosides. (iii) Amphoteric Surfactant (s): The amphoteric surfactants may be chosen, for example, from aliphatic secondary or tertiary amine derivatives in which the aliphatic radical is chosen from linear and branched chains containing 8 to 22 carbon atoms. and containing at least one water-soluble anionic group (for example carboxylate, sulphonate, sulfate, phosphate and phosphonate groups). Suitable examples include (C8-C20) alkyl betaines, sulfobetaines, (C8-C20) alkylamido (C1-C6) alkyl betaines and (C8-C20) alkylamido (C1-C6) alkyl sulfobetaines. Among the amine derivatives, mention may be made of the products of formulas (A) and (B): R2-CONHCH2CH2-N + (R3) (R4) (CH2COO-) (A) in which R2 is chosen from alkyl groups derived from an R2-COOH acid present in the hydrolysed coconut oil, heptyl, nonyl and undecyl groups, R3 is selected from β-hydroxyethyl groups, and R4 is selected from carboxymethyl groups; and R5-CONHCH2CH2-N (B) (C) (B) wherein B is selected from ùCH2CH2OX ', C is selected from ù (CH2) zuY', with z = 1 or 2; X 'is selected from the groups -CH 2 CH 2 -COOH and hydrogen; Y 'is selected from COOH and ùCH2-CHOH-SO3H; R5 is selected from alkyl radicals of an R9-COOH acid present in coconut oil and hydrolyzed linseed oil, alkyl radicals (such as C7, C9, C11 and C13 alkyl radicals), and C17 alkyl radicals (such as the iso form and unsaturated C17 radicals). These compounds are classified in the CTFA dictionary, 5th edition, 1993, under the names disodium cocoamphodiacetate, disodium lauroamphodiacetate, disodium caprylamphodiacetate, disodium capryloamphodiacetate, disodium cocoamphodipropionate, disodium lauroamphodipropionate, disodium caprylamphodipropionate, disodium capryloamphodipropionate, lauroamphodipropionic acid, and cocoamphodipropionic acid. A useful example may be cocoamphodiacetate sold under the trade name Miranol C2M concentrated by Rhodia Chimie. (iv) Cationic surfactant (s) The cationic surfactants may be chosen from: A) the quaternary ammonium salts of formula (XVIII) below: R 3 R 3 LR 2 4 (XVIII) in which X - is a anion selected from halides (such as chloride, bromide and iodide) and (C2-C6) alkyl sulphates (such as methyl sulphates), phosphates, alkyl and alkyl aryl sulphonates, anions derived from organic acids (such as acetate and lactate), and either: (i) R1, R2 and R3 are independently selected from linear and branched aliphatic groups containing from 1 to 4 carbon atoms and aromatic groups (such as aryl and alkylaryl). The aliphatic groups may include heteroatoms such as, for example, oxygen, nitrogen and sulfur, and halogens. The aliphatic groups may be chosen for example from alkyl, alkoxy and alkylamide groups. R4 may be selected from linear and branched alkyl groups containing from 12 to 30 carbon atoms. In one embodiment, the cationic surfactant is chosen from behenyltrimethylammonium salts (for example chloride); or (ii) R1 and R2 are independently selected from linear and branched aliphatic groups containing from 1 to 4 carbon atoms and aromatic groups including aryls and alkylaryls. The aliphatic groups may comprise one or more halogens and heteroatoms such as, for example, oxygen, nitrogen and sulfur. The aliphatic groups may be chosen for example from alkyl, alkoxy, cetyl, stearyl, alkylamide and hydroxyalkyl groups containing from about 1 to 4 carbon atoms. R3 and R4 are independently selected from linear and branched alkyl groups containing from 12 to 30 carbon atoms, said groups may comprise at least one function derived from ester and amide functions. In one embodiment, R3 and R4 can be chosen from (C1-C22) alkylamido (C2-C6) alkyl and (C1-C22) alkyl (acetate) groups. In one embodiment, the cationic surfactant is chosen from stearamidopropyldimethyl (myristylacetate) ammonium salts (for example chloride). In another embodiment, the cationic surfactant is chosen from palmitamidopropyltrimonium chloride, which is sold under the name Varisoft PTC by Degussa Goldschmidt; B) the quaternary ammonium salts of imidazolinium, such as, for example, that of formula (XIX): X- (XIX) CH 2 -CH 2 N (R 8) -CO-R 5 in which R 5 is chosen from alkenyl groups and alkyl containing from 8 to 30 carbon atoms, such as, for example, tallow fatty acid derivatives; R6 is selected from hydrogen, and alkenyl and alkyl groups containing from 8 to 30 carbon atoms; R7 is selected from C1-C4 alkyl groups; R8 is selected from hydrogen and C1-C4 alkyl groups; and X is an anion selected from halides, phosphates, acetates, lactates, alkylsulfates, alkylsulfonates and alkylarylsulfonates. In one embodiment, R5 and R6 are independently selected from alkenyl and alkyl groups containing from 12 to 21 carbon atoms, such as, for example, tallow fatty acid derivatives; R7 is a methyl group; and R8 is hydrogen. Examples include Quaternium-27 (CTFA 1997) and Quaternium-83 (CTFA 1997), which are sold under the names Rewoquat W75, W90, W75PG and W75HPG by Witco; C) the quaternary diammonium salts of formula (XX): wherein R 9 is selected from aliphatic groups containing from about 16 to about 30 carbon atoms; R10, R11, R12, R13 and R14 are independently selected from hydrogen and alkyl groups containing from 1 to 4 carbon atoms; and X- is an anion selected from halides, acetates, phosphates, nitrates and methylsulfates. Such quaternary diammonium salts include propane dichloride dichloride; and D) quaternary ammonium salts containing at least one ester function of formula (XXI) below: ++ 2X (XX) (R 2, R 18, n - (Co, H2aO), Rie (XXI)

R15 0 R1` where (0Cn); wherein R15 is selected from C1-C6 alkyl, C1-C6 hydroxyalkyl and dihydroxyalkyl; R16 is selected from R19-CO- groups, linear and branched, saturated and unsaturated C1-C22 hydrocarbon R20 groups, and hydrogen; R18 is selected from R21-CO-, linear and branched, saturated and unsaturated C1-C6 hydrocarbon R22 groups, and hydrogen; R17, R19 and R21 are independently selected from linear and branched, saturated and unsaturated C7-C21 hydrocarbon groups; n, p and r are integers independently of 2 to 6; y is an integer ranging from 1 to 10; x and z are integers independently of 0 to 10; X- is selected from simple and complex anions, organic and inorganic; with the proviso that the sum x + y + z is from 1 to 15, that when x is 0, then R16 is R20, and that when z is 0, then R18 is R22. In one embodiment, R15 is selected from methyl and ethyl groups; x and y are equal to 1; z is 0 or 1; n, p and r are 2; R16 is selected from R19-CO-, methyl, ethyl, and C14-C22 hydrocarbon groups, and hydrogen; R17, R19 and R21 are independently selected from linear and branched, saturated and unsaturated C7-C21 hydrocarbon groups; R18 is selected from R21-CO- and hydrogen.

Examples include compounds sold under the names Dehyquart by Henkel, Stepanquat by Stepan, Noxamium by Ceca, and Rewoquat WE 18 by Rewo-Witco.

In one embodiment, the cationic surfactants are chosen from behenyltrimethylammonium chloride and stearamidopropylmethyl (myristylacetate) ammonium chloride, sold under the name Ceraphyl 70 by Van Dyk, and Quaternium-27 or Quaternium-83 sold by the company. Witco company.

In the compositions according to the invention, mixtures of surfactants can be used. For example, mixtures of anionic surfactants and mixtures of anionic surfactants with amphoteric and / or nonionic surfactants are possible. In one embodiment, a mixture comprising at least one anionic surfactant and at least one amphoteric surfactant is chosen. The anionic surfactant may be chosen, for example, from sodium alkyl (C12-C14) sulphates, triethanolamine alkyl (C12-C14) sulphates, ammonium (C12-C14) alkyl sulphates and (C12-C14) alkyls. oxyethylenated sodium ethersulfates with 2.2 moles of ethylene oxide, triethanolamine alkyl (C12-C14) ethersulfates oxyethylenated with 2.2 moles of ethylene oxide, alkyl (C12-C14) ammonium ethersulfates oxyethylenated with 2.2 moles of ethylene oxide, sodium cocoylisethionates and sodium (C14-C16) -olefins. The amphoteric surfactant may be chosen, for example, from the amine derivatives known as cocoamphodipropionates disodium and cocoamphopropionates sodium, such as those sold by Rhodia Chimie under the trade name Miranol C2M Conc. in the form of an aqueous solution containing 38% of active ingredient, or under the name Miranol C32, and amphoteric surfactants of the zwitterionic type, of which the alkylbetaines, such as cocoylbetaine sold under the name Dehyton AB 30 in the form of a 32% aqueous solution. from MA by Henkel or cocoylamidopropylbetaine. In a preferred embodiment, the mixture comprises cocoylbetaine and sodium lauryl ether sulfate. According to a preferred embodiment of the invention, the composition according to the invention comprises one or more cationic polymers, and / or one or more silicones, and one or more surfactants. The composition according to the invention may be vaporizable, for example by a pump, or may be a pressurized aerosol composition. It can be vaporized by a dispensing valve controlled by a dispensing head, which in turn comprises a nozzle, which vaporizes the aerosol composition. A vaporizable composition according to the invention comprises a suitable solvent. Advantageously, the appropriate solvent comprises at least one solvent selected from water and lower alcohols. According to the invention, lower alcohol is understood to mean a C 1 to C 4 aliphatic alcohol, such as ethanol. When the vaporizable composition according to the invention is an aerosol composition, it further comprises an appropriate amount of propellant. The propellant comprises compressed or liquefied gases, which are normally used for the preparation of aerosol compositions. Suitable gases include compressed air, carbon dioxide, nitrogen, and gases capable of being soluble in the composition, such as dimethyl ether, fluorinated or nonfluorinated hydrocarbons, and mixtures thereof. The present invention further provides a method of treating keratinous fibers, in particular the hair, in which the repositionable styling composition according to the invention, as described above, is applied to the hair before, during or after the setting shape of the hairstyle. The present invention further provides the use of a composition as described above in a repositionable styling cosmetic formulation or for its preparation. The determination of the ability of a composition containing a (meth) acrylic copolymer according to the invention to give a repositionable effect can be determined by an in vivo test. When the composition is in the form of a lotion, for example, the in vivo test proceeds as follows. The model's hair is washed, then divided into two symmetrical portions, the right and left sides. The composition is applied to one side of the model head and rinsed while a reference composition is applied to the other side of the head. The reference composition may be selected, for example, from water, an existing commercial product, or another composition under study. The hairdresser dries and combs both sides of the head. Both sides of the head are evaluated separately for styling effect, cosmetic properties, and repositionable effect. For example, once dried, the hair is brushed in different directions to remove the original hairstyle. The hair is then brushed to restore the original hairstyle. The method for removing the hairstyle, restoring the hairstyle, and evaluating the success of restoring the hairstyle is repeated at least one more time to determine if the composition is a repositionable hairstyle composition. A repositionable styling composition allows (1) the restoration of the original hairstyle after brushing and (2) the creation of a new hairstyle after brushing, which can also be restored after brushing. If the composition to be evaluated is in another form, such as a shampoo or conditioner, the in vivo test may be suitably modified by those skilled in the art. It is understood that one skilled in the art could recognize that not all formulations would provide a repositionable effect for all types of hair during the in vivo test and will know how to formulate and evaluate repositionable styling compositions. in view of the various capillary parameters, such as the length (short against long), the diameter (fine against thick), the structure (curly versus straightened), the state (fat, dry or normal); and if the hair is colored, discolored, permed or relaxed. Thus, the in vivo test may require testing on 10-20 different individuals. EXAMPLES: 1) Preparation of a (meth) acrylic copolymer emulsion: A mixture of 300 grams of 2-ethylhexyl acrylate (2- EHA), 175 grams of n-butyl acrylate (BA), and grams of 2-hydroxyethyl methacrylate (HEMA) was prepared, giving 500 grams of a monomer solution containing 60/35/5 parts of 2-EHA / BA / HEMA. Fifty grams of the entire monomer solution were charged to a two-liter divided resin vial together with 380 grams of deionized water and 0.5 grams of RHODACAL DS-10 (sodium dodecylbenzenesulfonate surfactant available in US Pat. trade with Rhodia Chimie). The head was placed on the flask and a thermocouple, a nitrogen inlet and a mechanical stirrer were attached. The contents were heated by infrared lamps to about 60 ° C while stirring at 350 rpm. A solution of 1 gram of potassium persulfate initiator was charged into 2015 grams of deionized water, the flask was sealed, and the flask was evacuated four times, breaking each time with nitrogen. The flask was kept at 60 ° C for 20 minutes and then heated at 80 ° C for 10 minutes to give a seed polymer. A preemulsion was prepared from the remaining 450 grams of the monomer solution by charging a solution of 4.5 grams of sodium dodecylbenzenesulfonate in 211 grams of deionized water and stirring under nitrogen. This pre-emulsion was added dropwise to the two-liter divided resin vial containing the primer polymer at a rate of 6 grams per minute. The addition lasted almost 2 hours. After the addition, the stirring speed was reduced to 200 rpm and the reaction was maintained at 80 ° C for two hours, and the resulting latex was filtered through a doubled cheese-making fabric. Low levels of coagulum were noted around the thermocouple and the stirring blade. 2) Preparation of a styling composition: A styling composition according to the invention in the form of a shampoo was prepared using the following components, the amounts of which are expressed in% by weight as is. Formulation: 2-Ethylhexyl acrylate copolymer (EMA) / 0% ~ n-butyl acrylate (BA) / 2-hydroxyethyl methacrylate (HEMA) 60/35/5 to 44.5% in water (CPC- 00960-ACP 45 Acrylates Copolymer of 3M) Poly-dimethyldiallylammonium chloride in 0.25% water at 40% unstabilized (MERQUAT 100 from Nalco) Acrylic polymer at 30% emulsion (AQUA SF1 3% Noveon) Carbonate ground natural calcium (36% of the 5% particles have an average size of less than 2 m) Pure sodium hydroxide 0.31% Sodium chloride 2% Sodium lauryl ether sulfate 70% in solution 14.11% aqueous (2.2 0E) 90% lauryl ether carboxylic acid in 2% aqueous solution (4.5%) (sold under the name AKYPORLM45 from Kao) Cocoyl betaine 30% in aqueous solution 5.2% N-cocoyl amidoethyl, N-ethoxycarboxymethyl 1% glycinate 31% sodium in water (MIRANOL C2M Rhodia conc.) Ethylene glycol distearate 1% Hexylene glycol (2 methyl-2,4-pentanediol) 1% Perfume, advisable qsp 100% deionized water microbiologically clean water The above formulation used in the form of shampoo, that is to say applied on the hair, then washed and rinsed, gives the hair a good ease of styling, a good styling effect , and a repositionable effect with good performance.

Claims (35)

1. A repositionable styling composition characterized in that it comprises, in a cosmetically acceptable vehicle, one or more (meth) acrylic copolymers comprising (a) units derived from one or more monomers chosen from the monomers of (meth) butyl acrylate, (b) units derived from one or more monomers selected from hydroxyalkyl (meth) acrylate monomers, and (c) optional units derived from one or more copolymerizable monomers other than the monomers (a). ) and (b), and one or more charges. 2. Composition according to claim 1, characterized in that it is rinsed. 3. Composition according to claim 1 or 2, characterized in that the filler is selected from inorganic or organic fillers, preferably mineral. 4. Composition according to one of claims 1 to 3 characterized in that the filler is selected from talc, silica, kaolin, powders of polyamide, poly- (3-alanine and polyethylene, polymer powders tetrafluoroethylene, lauroyl-lysine, starch, boron nitride, expanded polyvinylidene chloride / acrylonitrile hollow spheres, acrylic powders, polymethyl methacrylate particles and silicone resin microbeads, calcium, magnesium carbonate and hydrocarbonate, hydroxyapatite, hollow silica microspheres, glass or ceramic microcapsules, metal soaps derived from organic carboxylic acids having from 8 to 22 carbon atoms, and preferably from 12 to 18 carbon atoms, unexpanded microspheres of vinylidene chloride / acrylonitrile / methyl methacrylate copolymer or acrylonitrile homopolymer copolymer. 5. Composition according to claim 4, characterized in that the filler is calcium carbonate. 6. Composition according to one of claims 1 to 5, characterized in that the charge or fillers are present in an amount of 0.1 to 20% by weight, preferably 0.5 to 10% by weight, relative to to the total weight of the composition. 7. Composition according to one of claims 1 to 6, characterized in that the monomer mentioned in (a) is chosen from n-butyl (meth) acrylates, isobutyl (meth) acrylates, (meth) t-butyl acrylates and 2-methylbutyl (meth) acrylates, preferably n-butyl acrylate. 8. Composition according to any one of claims 1 to 7, characterized in that the monomer mentioned in (b) is chosen from 2-hydroxyethyl (meth) acrylates and hydroxypropyl (meth) acrylates, and preferably 2-hydroxyethyl methacrylate. 9. Composition according to any one of claims 1 to 8, characterized in that the copolymerizable monomer mentioned in (c) is selected from (i ') the monomers of (meth) acrylate, (ii') the monomers polar, and (iii ') free radical polymerizable monomers with ethylenic unsaturation. 10. Composition according to claim 9, characterized in that the (meth) acrylate monomers (i ') are chosen from methyl (meth) acrylates, isobornyl (meth) acrylates, (meth) acrylates. ethyl, isooctyl (meth) acrylates and 2-ethylhexyl (meth) acrylates, and preferably 2-ethylhexyl acrylate. 11. Composition according to Claim 9, characterized in that the polar monomers (ii ') are chosen from (meth) acrylic acids, itaconic acids, N-vinylpyrrolidones, N-vinylcaprolactams, (meth) acrylamides, dimethylaminoethyl (meth) acrylates, acrylonitriles, 2-carboxyethyl (meth) acrylates, maleic anhydrides, and methoxypolyethylene glycol 550 monoacrylates. 12. Composition according to claim 9, characterized in that the free radical polymerizable monomers ethylenically unsaturated (iii ') are selected from styrene and vinyl esters C1-C4. 13. Composition according to any one of claims 1 to 12, characterized in that the (meth) acrylic copolymer is crosslinked with at least one polyfunctional crosslinking agent. 14. Composition according to Claim 13, characterized in that the polyfunctional crosslinking agent is chosen from divinylbenzene, alkyl diacrylates, alkyl triacrylates, alkyl tetra-acrylates and monoethylenically unsaturated aromatic ketones. multifunctional aziridine amides and metal ion crosslinking agents. 15. Composition according to any one of claims 1 to 14, characterized in that the (meth) acrylic copolymer comprises: (a) from 10 to 90% by weight of units derived from one or more monomers chosen from the monomers of butyl (meth) acrylate, (b) from 2 to 50% by weight of units derived from one or more monomers selected from hydroxyalkyl (meth) acrylate monomers, and (c) from 0 to 80% by weight units derived from one or more copolymerizable monomers other than monomers (a) and (b). 16. Composition according to any one of claims 1 to 15, characterized in that the units derived from said monomer mentioned in (a) are present in an amount ranging from 15 to 50% by weight, preferably from 30 to 40% by weight. weight. 17. Composition according to any one of claims 1 to 16, characterized in that the units derived from said monomer mentioned in (b) are present in an amount ranging from 2 to 25% by weight, preferably from 2 to 10% by weight. weight. 18. Composition according to any one of claims 1 to 17, characterized in that the units derived from said copolymerizable monomer mentioned in (c) are present in an amount ranging from 30 to 80% by weight, preferably from 50 to 70% by weight. in weight. 19. Composition according to any one of claims 1 to 18, characterized in that the (meth) acrylic copolymer comprises: (a) from 30 to 40% by weight of units derived from one or more monomers chosen from the monomers d n-butyl acrylate, (b) from 2 to 10% by weight of units derived from one or more monomers selected from 2-hydroxyethyl (meth) acrylate monomers, and (c) from 50 to 70% by weight. weight of units derived from one or more monomers selected from 2-ethylhexyl acrylate monomers. 20. Composition according to claim 1 to 19, characterized in that the (meth) acrylic copolymer has a Tg ranging from -100 ° C to 15 ° C. 21. Composition according to any one of claims 1 to 20, characterized in that the (meth) acrylic copolymer or copolymers are present in an amount ranging from 0.01 to 40%, preferably from 0.1 to 15%, and more preferably from 0.1 to 2% by weight, of the total weight of the composition. 22. Composition according to any one of claims 1 to 21, further comprising one or more constituents chosen from reducing agents; oxidizing agents; anionic polymers; silanes; Fatty substances ; thickeners; plasticizers; moisturizing agents; solar filters; active agents for hair care; the perfumes ; conservatives ; polyols; the proteins ; provitamines; vitamins; dyes; and pH modifiers. 23. Composition according to any one of claims 1 to 22, characterized in that it further comprises one or more surfactants selected from anionic, cationic, amphoteric, nonionic surfactants and mixtures thereof. 24. A composition according to claim 23, characterized in that the surfactant or surfactants are present in an amount ranging from 0.1 to 60%, preferably from 1 to 40%, and more preferably from 5 to 30% by weight, relative to the total weight of the composition. 25. Composition according to any one of claims 1 to 24, characterized in that it further comprises one or more conditioning agents selected from non-silicone cationic, nonionic, amphoteric polymers or silicones. 26. Composition according to any one of claims 1 to 25, characterized in that it comprises one or more conditioning agents and one or more surfactants. 27. Composition according to any one of claims 1 to 26, characterized in that it comprises one or more cationic polymers and one or more surfactants. 28. Composition according to any one of claims 25 to 27, characterized in that the cationic polymer is chosen from quaternary cellulose ether derivatives; quaternized guar gum; cationic cyclopolymers, especially homopolymers or copolymers of dimethyldiallylammonium chloride, quaternary polymers of vinylpyrrolidone and vinylimidazole; non-crosslinked and crosslinked polymers of methacryloyloxyalkyl (C1-C4) trialkyl (C1-C4) ammonium salts; and mixtures thereof. 29. Composition according to claim 28, characterized in that the cationic polymer is chosen from homopolymers or copolymers of dimethyldiallylammonium chloride. 30. Composition according to any one of claims 27 to 29, characterized in that the cationic polymer or polymers represent from 0.001% to 20% by weight, preferably from 0.01% to 10% by weight, and still more preferably from 0.1% to 3% by weight, of the total weight of the composition. 31. Composition according to any one of claims 1 to 30, characterized in that the composition is a shampoo. 32. Composition according to any one of claims 1 to 30, characterized in that the composition is a conditioner. 33. Composition according to any one of claims 1 to 32, characterized in that it is in a form selected from sprays, aerosols, foams, gels, lotions, creams, dispersions and emulsions. 34. A method of cosmetic hair treatment, comprising applying to the hair, before shaping, a composition according to any one of claims 1 to 33. A method of treating the hair, comprising: (1) applying to the hair, prior to the initial shaping of the hairstyle, a composition according to any one of claims 1 to 33, and then (2) the shaping the hairstyle at least once, characterized in that an additional composition or additional heat is not necessary.