FR2921065B1 - METHOD FOR MANUFACTURING (CO) POLYMERS WITH MOLECULAR FOOT (S) BY PHOTOPOLYMERIZATION UNDER EVANESCENT WAVES, (CO) POLYMERS OBTAINED AND THEIR APPLICATIONS - Google Patents

METHOD FOR MANUFACTURING (CO) POLYMERS WITH MOLECULAR FOOT (S) BY PHOTOPOLYMERIZATION UNDER EVANESCENT WAVES, (CO) POLYMERS OBTAINED AND THEIR APPLICATIONS

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Publication number
FR2921065B1
FR2921065B1 FR0706522A FR0706522A FR2921065B1 FR 2921065 B1 FR2921065 B1 FR 2921065B1 FR 0706522 A FR0706522 A FR 0706522A FR 0706522 A FR0706522 A FR 0706522A FR 2921065 B1 FR2921065 B1 FR 2921065B1
Authority
FR
France
Prior art keywords
polymers
foot
molecular
evanescent waves
applications
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
FR0706522A
Other languages
French (fr)
Other versions
FR2921065A1 (en
Inventor
Olivier Andre Soppera
Karsten Olaf Haupt
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Centre National de la Recherche Scientifique CNRS
Universite de Technologie de Compiegne
Universite de Technologie de Compiegne UTC
Universite de Haute Alsace
Original Assignee
Centre National de la Recherche Scientifique CNRS
Universite de Technologie de Compiegne
Universite de Technologie de Compiegne UTC
Universite de Haute Alsace
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Centre National de la Recherche Scientifique CNRS, Universite de Technologie de Compiegne, Universite de Technologie de Compiegne UTC, Universite de Haute Alsace filed Critical Centre National de la Recherche Scientifique CNRS
Priority to FR0706522A priority Critical patent/FR2921065B1/en
Priority to PCT/FR2008/001300 priority patent/WO2009090326A1/en
Publication of FR2921065A1 publication Critical patent/FR2921065A1/en
Application granted granted Critical
Publication of FR2921065B1 publication Critical patent/FR2921065B1/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/46—Polymerisation initiated by wave energy or particle radiation
    • C08F2/48—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
    • B01J20/26—Synthetic macromolecular compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
    • B01J20/26—Synthetic macromolecular compounds
    • B01J20/268—Polymers created by use of a template, e.g. molecularly imprinted polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/44—Polymerisation in the presence of compounding ingredients, e.g. plasticisers, dyestuffs, fillers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F226/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen
    • C08F226/06—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen by a heterocyclic ring containing nitrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D15/00—Separating processes involving the treatment of liquids with solid sorbents; Apparatus therefor
    • B01D15/08—Selective adsorption, e.g. chromatography
    • B01D15/26—Selective adsorption, e.g. chromatography characterised by the separation mechanism
    • B01D15/38—Selective adsorption, e.g. chromatography characterised by the separation mechanism involving specific interaction not covered by one or more of groups B01D15/265 - B01D15/36
    • B01D15/3852—Selective adsorption, e.g. chromatography characterised by the separation mechanism involving specific interaction not covered by one or more of groups B01D15/265 - B01D15/36 using imprinted phases or molecular recognition; using imprinted phases
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2220/00—Aspects relating to sorbent materials
    • B01J2220/50—Aspects relating to the use of sorbent or filter aid materials
    • B01J2220/54—Sorbents specially adapted for analytical or investigative chromatography
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
    • C08F222/10—Esters
    • C08F222/1006—Esters of polyhydric alcohols or polyhydric phenols
    • C08F222/103—Esters of polyhydric alcohols or polyhydric phenols of trialcohols, e.g. trimethylolpropane tri(meth)acrylate

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Analytical Chemistry (AREA)
  • Treatments Of Macromolecular Shaped Articles (AREA)
  • Polymerisation Methods In General (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

La présente invention concerne le domaine de la synthèse de (co)polymères à empreinte(s) moléculaire(s) et a pour objet un procédé pour leur fabrication. Elle concerne également l'application des substances obtenues grâce audit procédé pour diverses applications et les dispositifs qui en découlent.Ledit procédé est caractérisé par une photopolymérisation où l'on irradie une face d'un substrat portant les substances à faire réagir par des radiations ou rayons lumineux d'une longueur d'onde comprise entre 150 nm et 1200 nm de sorte à former des ondes évanescentes pour former ledit (co)polymère à empreinte(s) moléculaire(s) et qu'on le rince ensuite avec au moins un solvant approprié pour éliminer tout ou partie du ou des monomères n'ayant pas polymérisé et tout ou partie de la ou des entités ou molécules cibles, le cas échéant, en détachant le produit final obtenu dudit substrat.The present invention relates to the field of the synthesis of molecularly imprinted (co) polymers and relates to a process for their manufacture. It also relates to the application of the substances obtained by said process for various applications and the devices resulting therefrom. light rays with a wavelength between 150 nm and 1200 nm so as to form evanescent waves to form said molecularly imprinted (co) polymer (s) and that it is then rinsed with at least one suitable solvent for removing all or part of the monomer (s) which have not polymerized and all or part of the target entity (s) or molecules, where appropriate, by detaching the final product obtained from said substrate.

FR0706522A 2007-09-17 2007-09-17 METHOD FOR MANUFACTURING (CO) POLYMERS WITH MOLECULAR FOOT (S) BY PHOTOPOLYMERIZATION UNDER EVANESCENT WAVES, (CO) POLYMERS OBTAINED AND THEIR APPLICATIONS Expired - Fee Related FR2921065B1 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
FR0706522A FR2921065B1 (en) 2007-09-17 2007-09-17 METHOD FOR MANUFACTURING (CO) POLYMERS WITH MOLECULAR FOOT (S) BY PHOTOPOLYMERIZATION UNDER EVANESCENT WAVES, (CO) POLYMERS OBTAINED AND THEIR APPLICATIONS
PCT/FR2008/001300 WO2009090326A1 (en) 2007-09-17 2008-09-17 Method for producing molecularly imprinted (co)polymers by photopolymerization under evanescent waves, (co)polymers obtained and uses thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR0706522A FR2921065B1 (en) 2007-09-17 2007-09-17 METHOD FOR MANUFACTURING (CO) POLYMERS WITH MOLECULAR FOOT (S) BY PHOTOPOLYMERIZATION UNDER EVANESCENT WAVES, (CO) POLYMERS OBTAINED AND THEIR APPLICATIONS

Publications (2)

Publication Number Publication Date
FR2921065A1 FR2921065A1 (en) 2009-03-20
FR2921065B1 true FR2921065B1 (en) 2009-11-27

Family

ID=38800757

Family Applications (1)

Application Number Title Priority Date Filing Date
FR0706522A Expired - Fee Related FR2921065B1 (en) 2007-09-17 2007-09-17 METHOD FOR MANUFACTURING (CO) POLYMERS WITH MOLECULAR FOOT (S) BY PHOTOPOLYMERIZATION UNDER EVANESCENT WAVES, (CO) POLYMERS OBTAINED AND THEIR APPLICATIONS

Country Status (2)

Country Link
FR (1) FR2921065B1 (en)
WO (1) WO2009090326A1 (en)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2964104B1 (en) 2010-09-01 2013-11-29 Univ Paris Diderot Paris 7 ULTRAMINAL LAYERS OF POLYMERS WITH CONFINED MOLECULAR IMPRESSIONS IN SURFACE OF A SUPPORT
CN103599759B (en) * 2013-10-29 2016-01-20 江苏大学 A kind of preparation method of adsorbent of Selective Separation ciprofloxacin in water environment
CN105482025B (en) * 2016-01-01 2019-01-25 兰州交通大学 Reverse microemulsion polymerization preparation absorption methylene blue molecularly imprinted polymer
CN111693586B (en) * 2020-06-02 2022-09-09 上海海洋大学 Bacterial molecularly imprinted polymer, preparation method thereof and bacterial detection method
CN114768885A (en) * 2022-05-18 2022-07-22 常州瑞华化工工程技术股份有限公司 Extrusion molding method and application of copper acetophenone hydrogenation catalyst

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2738831B1 (en) * 1995-09-19 1997-10-17 Thomson Csf PROCESS FOR PRODUCING POLYMER-BASED MATERIAL FILM
US7049049B2 (en) * 2001-06-27 2006-05-23 University Of South Florida Maskless photolithography for using photoreactive agents
US6890486B2 (en) * 2001-07-26 2005-05-10 University Of Massachusetts MIP/QCM sensors for high sensitivity-fast sensing of small molecules in solution
US20070286546A1 (en) * 2003-03-11 2007-12-13 Jean-Francois Masson Surface Initiated Thin Polymeric Films for Chemical Sensors

Also Published As

Publication number Publication date
FR2921065A1 (en) 2009-03-20
WO2009090326A1 (en) 2009-07-23

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Effective date: 20130531