FR2897609B1 - COMPOSITION BASED ON ZIRCONIUM, CERIUM, YTTRIUM, LANTHAN AND OTHER RARE EARTH OXIDES, METHOD OF PREPARATION AND USE IN CATALYSIS - Google Patents

COMPOSITION BASED ON ZIRCONIUM, CERIUM, YTTRIUM, LANTHAN AND OTHER RARE EARTH OXIDES, METHOD OF PREPARATION AND USE IN CATALYSIS

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Publication number
FR2897609B1
FR2897609B1 FR0601407A FR0601407A FR2897609B1 FR 2897609 B1 FR2897609 B1 FR 2897609B1 FR 0601407 A FR0601407 A FR 0601407A FR 0601407 A FR0601407 A FR 0601407A FR 2897609 B1 FR2897609 B1 FR 2897609B1
Authority
FR
France
Prior art keywords
lanthan
yttrium
cerium
catalysis
zirconium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
FR0601407A
Other languages
French (fr)
Other versions
FR2897609A1 (en
Inventor
Aimin Huang
Olivier Larcher
Emmanuel Rohart
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Rhodia Recherche et Technologies SAS
Original Assignee
Rhodia Recherche et Technologies SAS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to FR0601407A priority Critical patent/FR2897609B1/en
Application filed by Rhodia Recherche et Technologies SAS filed Critical Rhodia Recherche et Technologies SAS
Priority to RU2008137138/04A priority patent/RU2398629C2/en
Priority to DK07704559.9T priority patent/DK1991354T3/en
Priority to EP07704559.9A priority patent/EP1991354B1/en
Priority to PCT/EP2007/051387 priority patent/WO2007093593A1/en
Priority to CN2007800055799A priority patent/CN101511479B/en
Priority to PL07704559T priority patent/PL1991354T3/en
Priority to KR1020117004510A priority patent/KR101076945B1/en
Priority to KR1020117020245A priority patent/KR101142669B1/en
Priority to CA2642237A priority patent/CA2642237C/en
Priority to KR1020087019994A priority patent/KR101030623B1/en
Priority to US12/279,382 priority patent/US7964527B2/en
Priority to JP2008554760A priority patent/JP5498023B2/en
Publication of FR2897609A1 publication Critical patent/FR2897609A1/en
Application granted granted Critical
Publication of FR2897609B1 publication Critical patent/FR2897609B1/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/9445—Simultaneously removing carbon monoxide, hydrocarbons or nitrogen oxides making use of three-way catalysts [TWC] or four-way-catalysts [FWC]
    • B01D53/945—Simultaneously removing carbon monoxide, hydrocarbons or nitrogen oxides making use of three-way catalysts [TWC] or four-way-catalysts [FWC] characterised by a specific catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/066—Zirconium or hafnium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/10—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of rare earths
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/613—10-100 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0018—Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G25/00—Compounds of zirconium
    • C01G25/006—Compounds containing, besides zirconium, two or more other elements, with the exception of oxygen or hydrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/206—Rare earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/20715—Zirconium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/63—Platinum group metals with rare earths or actinides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/06—Washing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B01J37/10—Heat treatment in the presence of water, e.g. steam
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
    • C01P2002/72—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/12—Surface area
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/12—Surface area
    • C01P2006/13—Surface area thermal stability thereof at high temperatures
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00—Road transport of goods or passengers
    • Y02T10/10—Internal combustion engine [ICE] based vehicles
    • Y02T10/12—Improving ICE efficiencies

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Environmental & Geological Engineering (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Catalysts (AREA)
FR0601407A 2006-02-17 2006-02-17 COMPOSITION BASED ON ZIRCONIUM, CERIUM, YTTRIUM, LANTHAN AND OTHER RARE EARTH OXIDES, METHOD OF PREPARATION AND USE IN CATALYSIS Active FR2897609B1 (en)

Priority Applications (13)

Application Number Priority Date Filing Date Title
FR0601407A FR2897609B1 (en) 2006-02-17 2006-02-17 COMPOSITION BASED ON ZIRCONIUM, CERIUM, YTTRIUM, LANTHAN AND OTHER RARE EARTH OXIDES, METHOD OF PREPARATION AND USE IN CATALYSIS
KR1020087019994A KR101030623B1 (en) 2006-02-17 2007-02-13 Composition based on oxides of zirconium, cerium, yttrium, lanthanum and of another rare earth, method for preparing same and catalytic use
EP07704559.9A EP1991354B1 (en) 2006-02-17 2007-02-13 Composition based on oxides of zirconium, cerium, yttrium, lanthanum and of another rare earth, method for preparing same and catalytic use
PCT/EP2007/051387 WO2007093593A1 (en) 2006-02-17 2007-02-13 Composition based on oxides of zirconium, cerium, yttrium, lanthanum and of another rare earth, method for preparing same and catalytic use
CN2007800055799A CN101511479B (en) 2006-02-17 2007-02-13 Composition based on oxides of zirconium, cerium, yttrium, lanthanum anh of another rare earth, method for preparing same and catalytic use
PL07704559T PL1991354T3 (en) 2006-02-17 2007-02-13 Composition based on oxides of zirconium, cerium, yttrium, lanthanum and of another rare earth, method for preparing same and catalytic use
RU2008137138/04A RU2398629C2 (en) 2006-02-17 2007-02-13 Composition base on oxides of zirconium, cerium, yttrium, lanthanum and other rare-earth metals, method of its production and use in catalysis
KR1020117020245A KR101142669B1 (en) 2006-02-17 2007-02-13 Composition based on oxides of zirconium, cerium, yttrium, lanthanum and of another rare earth, method for preparing same and catalytic use
CA2642237A CA2642237C (en) 2006-02-17 2007-02-13 Composition based on oxides of zirconium, cerium, yttrium, lanthanum anh of another rare earth, method for preparing same and catalytic use
DK07704559.9T DK1991354T3 (en) 2006-02-17 2007-02-13 COMPOSITION BASED ON ZIRCONIUM, CERIUM, YTTRIUM AND LANTHANOXIDE AND ANOTHER RARE EARTH METAL OXIDE, METHOD FOR PRODUCING IT AND CATALYTIC USE THEREOF
US12/279,382 US7964527B2 (en) 2006-02-17 2007-02-13 Catalytic compositions comprising the oxides of zirconium, cerium, yttrium, lanthanum and other rare earths
JP2008554760A JP5498023B2 (en) 2006-02-17 2007-02-13 Compositions based on oxides of zirconium, oxides of cerium, oxides of yttrium, oxides of lanthanum and other rare earths, methods for preparing the same and use as catalysts
KR1020117004510A KR101076945B1 (en) 2006-02-17 2007-02-13 Composition based on oxides of zirconium, cerium, yttrium, lanthanum and of another rare earth, method for preparing same and catalytic use

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR0601407A FR2897609B1 (en) 2006-02-17 2006-02-17 COMPOSITION BASED ON ZIRCONIUM, CERIUM, YTTRIUM, LANTHAN AND OTHER RARE EARTH OXIDES, METHOD OF PREPARATION AND USE IN CATALYSIS

Publications (2)

Publication Number Publication Date
FR2897609A1 FR2897609A1 (en) 2007-08-24
FR2897609B1 true FR2897609B1 (en) 2009-01-16

Family

ID=37009599

Family Applications (1)

Application Number Title Priority Date Filing Date
FR0601407A Active FR2897609B1 (en) 2006-02-17 2006-02-17 COMPOSITION BASED ON ZIRCONIUM, CERIUM, YTTRIUM, LANTHAN AND OTHER RARE EARTH OXIDES, METHOD OF PREPARATION AND USE IN CATALYSIS

Country Status (2)

Country Link
CN (1) CN101511479B (en)
FR (1) FR2897609B1 (en)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2898887B1 (en) 2006-03-21 2008-05-02 Rhodia Recherches & Tech COMPOSITION BASED ON ZIRCONIUM OXIDE AND CERIUM OXIDE WITH HIGH REDUCIBILITY AND STABLE SPECIFIC SURFACE PROCESS FOR THE PREPARATION AND USE IN THE TREATMENT OF EXHAUST GASES
FR2976574B1 (en) * 2011-06-17 2013-05-31 Rhodia Operations COMPOSITION BASED ON OXIDES OF CERIUM, ZIRCONIUM AND ANOTHER RARE EARTH WITH HIGH REDUCIBILITY, PROCESS FOR PREPARATION AND USE IN THE CATALYSIS FIELD.
DE102011107702A1 (en) 2011-07-14 2013-01-17 Sasol Germany Gmbh Process for the preparation of composites of alumina and cerium / zirconium mixed oxides
EP2731709B1 (en) 2011-07-14 2020-01-22 Treibacher Industrie AG Ceria zirconia alumina composition with enhanced thermal stability
RU2698674C2 (en) * 2013-12-23 2019-08-28 Родиа Операсьон Inorganic composite oxides and methods for production thereof
BR112017004418B1 (en) * 2014-09-05 2022-04-19 Neo Performance Materials (Singapore), Pte. Ltd Composition comprising oxide containing zirconium and high porosity cerium
FR3050450A1 (en) * 2016-04-26 2017-10-27 Rhodia Operations MIXED OXIDE BASED ON CERIUM AND ZIRCONIUM
EP3448557A4 (en) * 2016-04-26 2020-01-01 Rhodia Operations Cerium-and zirconium-based mixed oxides
JP7114595B2 (en) * 2016-12-23 2022-08-08 ローディア オペレーションズ Aging-resistant mixed oxide for automotive catalytic converters made from cerium, zirconium, aluminum and lanthanum
US10322409B1 (en) 2018-03-05 2019-06-18 King Fahd University Of Petroleum And Minerals Low temperature hydrothermal method for the preparation of LaCO3OH nanoparticles
WO2020061723A1 (en) * 2018-09-24 2020-04-02 Rhodia Operations Mixed oxide with improved reducibility

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2736343B1 (en) * 1995-07-03 1997-09-19 Rhone Poulenc Chimie COMPOSITION BASED ON ZIRCONIUM OXIDE AND CERIUM OXIDE, METHOD OF PREPARATION AND USE
US5958827A (en) * 1995-12-07 1999-09-28 Toyota Jidosha Kabushiki Kaisha Solid solution particle of oxides, a process for producing the same and a catalyst for purifying exhaust gases
JP4094689B2 (en) * 1996-04-05 2008-06-04 阿南化成株式会社 Method for producing composite oxide having oxygen absorption / release capability
FR2793161B1 (en) * 1999-05-07 2001-10-12 Renault EXHAUST PURIFICATION DEVICE FOR AN INTERNAL COMBUSTION ENGINE
US6387338B1 (en) * 2000-03-15 2002-05-14 Delphi Technologies, Inc. Preparation of multi-component Ce, Zr, Mox high oxygen-ion-conduct/oxygen-storage-capacity materials
FR2852592B1 (en) * 2003-03-18 2007-02-23 Rhodia Elect & Catalysis COMPOSITIONS BASED ON A CERIUM OXIDE, A ZIRCONIUM OXIDE AND, POSSIBLY, AN OXIDE OF ANOTHER RARE EARTH, WITH A HIGH SPECIFIC SURFACE AT 1100 C, PROCESS FOR THEIR PREPARATION AND THEIR USE AS A CATALYST

Also Published As

Publication number Publication date
FR2897609A1 (en) 2007-08-24
CN101511479A (en) 2009-08-19
CN101511479B (en) 2012-07-18

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