FR2872048A1 - Disinfecting composition, useful e.g. for natural or synthetic resins of device for softening and refining water by the process of electro chlorination, comprises an alkaline chloride comprising one or more sterilizing agents - Google Patents
Disinfecting composition, useful e.g. for natural or synthetic resins of device for softening and refining water by the process of electro chlorination, comprises an alkaline chloride comprising one or more sterilizing agents Download PDFInfo
- Publication number
- FR2872048A1 FR2872048A1 FR0407123A FR0407123A FR2872048A1 FR 2872048 A1 FR2872048 A1 FR 2872048A1 FR 0407123 A FR0407123 A FR 0407123A FR 0407123 A FR0407123 A FR 0407123A FR 2872048 A1 FR2872048 A1 FR 2872048A1
- Authority
- FR
- France
- Prior art keywords
- composition
- water
- composition according
- natural
- sterilizing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L2/00—Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor
- A61L2/16—Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor using chemical substances
- A61L2/18—Liquid substances or solutions comprising solids or dissolved gases
- A61L2/186—Peroxide solutions
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L2/00—Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor
- A61L2/16—Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor using chemical substances
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L2/00—Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor
- A61L2/16—Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor using chemical substances
- A61L2/23—Solid substances, e.g. granules, powders, blocks, tablets
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J49/00—Regeneration or reactivation of ion-exchangers; Apparatus therefor
- B01J49/60—Cleaning or rinsing ion-exchange beds
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/72—Treatment of water, waste water, or sewage by oxidation
- C02F1/722—Oxidation by peroxides
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F5/00—Softening water; Preventing scale; Adding scale preventatives or scale removers to water, e.g. adding sequestering agents
- C02F5/08—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents
- C02F5/083—Mineral agents
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/42—Treatment of water, waste water, or sewage by ion-exchange
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/50—Treatment of water, waste water, or sewage by addition or application of a germicide or by oligodynamic treatment
- C02F1/505—Treatment of water, waste water, or sewage by addition or application of a germicide or by oligodynamic treatment by oligodynamic treatment
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/42—Nature of the water, waste water, sewage or sludge to be treated from bathing facilities, e.g. swimming pools
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2303/00—Specific treatment goals
- C02F2303/04—Disinfection
Abstract
Description
L'invention concerne une composition pour la désinfection des résinesThe invention relates to a composition for the disinfection of resins
utilisées pour éliminer le calcaire et pour la désinfection de l'eau par le procédé d'électrochloration. used to remove limescale and to disinfect water by the electrochlorination process.
Cette composition contient en combinaison au moins un chlorure alcalin, un agent désinfectant et un chlorure d'argent. This composition contains in combination at least one alkaline chloride, a disinfecting agent and a silver chloride.
L'invention concerne une nouvelle composition pour la désinfection des résines utilisées tout particulièrement pour adoucir l'eau. The invention relates to a new composition for the disinfection of resins used especially for softening water.
L'invention concerne également l'utilisation de cette composition pour la désinfection des résines utilisées pour adoucir l'eau et pour la désinfection de 10 l'eau par procédé d'électrochloration. The invention also relates to the use of this composition for the disinfection of resins used to soften water and for the disinfection of water by electrochlorination process.
On sait que, pour désinfecter des résines on utilise des produits stérilisants que l'on verse dans le bac à saumure des adoucisseurs pour ensuite que cette solution soit envoyer dans la bouteille contenant les résines pour ainsi les désinfecter. It is known that, in order to disinfect resins, sterilizing products are used which are poured into the brine tank of the softeners and then that this solution is sent to the bottle containing the resins in order to disinfect them.
On sait que, pour la désinfection des eaux, et tout particulièrement les eaux de piscines, on utilise un procédé permettant de produire, in situ, par électrochioration d'une solution saline de chlorure, du chlore naissant se transformant immédiatement en hypochlorite. It is known that, for the disinfection of water, and especially swimming-pool water, a method is used for producing, in situ, by electrochlorination of a chloride saline solution, nascent chlorine which is immediately converted into hypochlorite.
A titre d'exemples non limitatifs, on peut citer les applications suivantes: ^ Adoucisseurs ^ affineurs ^ eaux de piscines ^ eaux de refroidissement industriel ^ solutions désinfectantes pour le traitement des plages ^ traitement d'eaux urbaines Dans la pratique, pour un adoucisseur, par exemple, la solution désinfectante est pré-préparée est conditionnée en bouteille de un litre environ. Elle set composé souvent d'eau associée à un désinfectant, telle que le peroxyde d'hydrogène. By way of nonlimiting examples, mention may be made of the following applications: Softeners, refiners, swimming-pool waters, industrial cooling water, disinfecting solutions for the treatment of beaches, urban water treatment In practice, for a softener, for example, the disinfectant solution is pre-prepared and packaged in a bottle of about one liter. It is often composed of water associated with a disinfectant, such as hydrogen peroxide.
Cette opération de désinfection des résines n'est pas toujours bien comprise par l'utilisateur de l'adoucisseur et souvent oubliée. Alors qu'elle est indispensable minimum une fois par an. This disinfection of resins operation is not always well understood by the user of the softener and often forgotten. While it is essential minimum once a year.
Pour une piscine équipée d'un système d'électrochloration, lors de la première mise en service, il est indispensable de traiter au moins pendant huit jours l'eau de remplissage de la piscine. Pour ce faire, on réalise des traitements de chocs avec différents produits chimiques, dont le chlore, tous les matins et ce pendant huit jours, minimum. For a swimming pool equipped with an electrochlorination system, during the first commissioning, it is essential to treat at least eight days the water filling the pool. To do this, shock treatments are carried out with different chemicals, including chlorine, every morning for a minimum of eight days.
Pour les deux cas on utilise un sel (chlorure de sodium) répondant à des impératifs précis: - Une teneur minimale en composés alcalino-terreux Une très faible teneur en matières insolubles dans l'eau. For both cases a salt (sodium chloride) is used which meets specific requirements: - A minimum content of alkaline earth compounds A very low content of insoluble matter in water.
- Une très faible teneur en matières organiques oxydables. - A very low content of oxidizable organic materials.
- Une très faible teneur en fer, manganèse et cuivre, de façon à optimiser le rendement électrolytique ainsi qu'une qualité de saumure pour nettoyer les résines d'adoucisseur. - Very low content of iron, manganese and copper, so as to optimize the electrolytic efficiency and brine quality to clean the softener resins.
Dans le cas des adoucisseurs les utilisateurs oublient de stériliser régulièrement les résines. In the case of softeners, users forget to sterilize the resins regularly.
La présente invention permet de remédier à ce problème. The present invention overcomes this problem.
Dans le cas des piscines, traiter pendant plusieurs jours la piscine devient un travail astreignant. In the case of swimming pools, treating the pool for several days becomes a demanding job.
La présente invention permet de remédier à ce problème. The present invention overcomes this problem.
A cet effet, l'invention à pour objet une composition pour la désinfection des résines d'adoucisseurs ainsi que pour la désinfection d'une eau de piscine en complément d'un système d'électrochloration. For this purpose, the invention relates to a composition for the disinfection of softener resins and for the disinfection of a pool water in addition to an electrochlorination system.
Cette composition comprenant au moins un chlorure alcalin et étant caractérisée en ce qu'elle contient un agent stérilisant (tel que le peroxyde 55 d'hydrogène) ainsi qu'un sel d'argent. This composition comprising at least one alkaline chloride and being characterized in that it contains a sterilizing agent (such as hydrogen peroxide) and a silver salt.
Ainsi, au cours de la dissolution, le sel libère l'agent stérilisant et le sel d'argent. Thus, during the dissolution, the salt releases the sterilizing agent and the silver salt.
Dans le cas de l'adoucisseur lors de la régénération des résines par l'aspiration de la saumure les agents stérilisants libérés vont traiter automatiquement les résines. In the case of the softener during the regeneration of the resins by the suction of the brine, the sterilizing agents released will automatically treat the resins.
Dans le cas des piscines le sel libère l'agent stérilisant et les sels d'argent 5 pour traiter l'eau neuve de la piscine. In the case of swimming pools salt releases the sterilizing agent and the silver salts to treat the new water of the pool.
Dans les deux cas cette composition peut-être utilisée en complément. In both cases this composition can be used in addition.
Pour les piscines lorsque la concentration de chlorure alcalin devient inférieure à celle préconisée par le fabriquant d'appareils d'électrochloration. Pour les adoucisseurs lorsque la concentration de la saumure est elle aussi inférieure à celle préconisée par le fabriquant d'adoucisseurs ou d'affineurs. For swimming pools when the concentration of alkaline chloride becomes lower than that recommended by the manufacturer of electrochlorination devices. For softeners when the concentration of brine is also lower than that recommended by the manufacturer of softeners or refiners.
L'invention à donc également pour but l'utilisation de cette composition pour la désinfection de l'eau par le procédé d'électrochloration et l'utilisation de cette composition pour la désinfection des résines naturelles ou synthétiques des adoucisseurs ou des affineurs d'eau. The invention therefore also aims the use of this composition for the disinfection of water by the electrochlorination process and the use of this composition for the disinfection of natural or synthetic resins water softeners or refiners .
La quantité d'agent stérilisant libéré par la dissolution du sel permet de stériliser correctement soit l'eau, soit les résines naturelles ou synthétiques des adoucisseurs ou des affineurs d'eau. The amount of sterilizing agent released by the dissolution of the salt makes it possible to correctly sterilize either the water or the natural or synthetic resins of softeners or water refiners.
Les agents stérilisants sont choisis parmi les produits agréés pour cet usage par les règlements en vigueur, par exemple le peroxyde d'hydrogène. The sterilizing agents are chosen from the products approved for this use by the regulations in force, for example hydrogen peroxide.
L'avantage de cet agent stérilisant est qu'il n'a pas d'incompatibilité, ni d'action corrosive sur les résines échangeuses d'ions, naturelles ou synthétiques. Ce qui n'est pas le cas par exemple des produits chlorés. L'autre avantage, pour l'eau des piscines est qu'il est compatible avec l'hypochlorite de sodium fabriqué lors de l'électrochloration. The advantage of this sterilizing agent is that it has no incompatibility or corrosive action on ion exchange resins, natural or synthetic. This is not the case, for example, with chlorinated products. The other advantage for swimming pool water is that it is compatible with sodium hypochlorite manufactured during electrochlorination.
Le pourcentage d'agent stérilisant peut-être modifié en fonction du traitement souhaité. Le pourcentage utilisé pour la piscine peut-être différent de celui utilisé pur la stérilisation des résines échangeuses d'ions naturelles ou synthétiques des adoucisseurs ou des affineurs d'eau. The percentage of sterilizing agent can be modified according to the desired treatment. The percentage used for the pool may be different from that used for the sterilization of natural or synthetic ion exchange resins softeners or refiners water.
La composition selon l'invention pourra être préparée de façon adaptée à son 30 usage en réalisant un mélange intime du sel et des agents stérilisants et elle pourra être commercialisée en l'état ou présentée sous forme de pastilles, comprimés, blocs, piules, compacts, agglomérés ou granulés, fabriqués par compression à sec dudit mélange. The composition according to the invention may be prepared in a manner suitable for its use by making an intimate mixture of salt and sterilizing agents and it may be marketed in the state or presented in the form of tablets, tablets, blocks, pills, compact , agglomerates or granules, made by dry compression of said mixture.
Pour une utilisation plus pratique l'invention selon la composition pourra être 35 commercialisée dans des conditionnements de 5,10,25 kg ou plus ou moindre si nécessaire. For more practical use the invention according to the composition may be marketed in packages of 5, 10, 25 kg or more or less if necessary.
II est établi que, sous ces présentations ou sous ces différentes formes, le présente ente autre les avantages suivants (par rapport aux techniques et produits actuels: - solubilité totale - absence de résidus, homogénéité de la composition, - régularité du dosage des composants dans la solution à traiter( suppression des erreurs de dosage,- adaptation du produit à tous les types d'électrochlorinateurs, 45 d'adoucisseurs ou d'affineurs d'eau. It is established that, under these presentations or in these different forms, it presents the following additional advantages (compared to the current techniques and products: - total solubility - absence of residues, homogeneity of the composition, - regularity of the dosage of the components in the solution to be treated (elimination of dosing errors, - adaptation of the product to all types of electrochlorinators, 45 water softeners or refiners.
- Suppression de produits chimiques dangereux et de leur stockage. - Removal of dangerous chemicals and their storage.
Claims (11)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR0407123A FR2872048B1 (en) | 2004-06-29 | 2004-06-29 | SALT COMPOSITION FOR WATER DISINFECTION AND SOFTENER RESINS AND SWIMMING POOLS AND USE OF SAID COMPOSITION CONTAINING IN COMBINATION AT LEAST ONE ALKALINE CHLORIDE, A DISINFECTANT AND A SILVER SALT |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR0407123A FR2872048B1 (en) | 2004-06-29 | 2004-06-29 | SALT COMPOSITION FOR WATER DISINFECTION AND SOFTENER RESINS AND SWIMMING POOLS AND USE OF SAID COMPOSITION CONTAINING IN COMBINATION AT LEAST ONE ALKALINE CHLORIDE, A DISINFECTANT AND A SILVER SALT |
Publications (2)
Publication Number | Publication Date |
---|---|
FR2872048A1 true FR2872048A1 (en) | 2005-12-30 |
FR2872048B1 FR2872048B1 (en) | 2010-02-26 |
Family
ID=35507740
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR0407123A Active FR2872048B1 (en) | 2004-06-29 | 2004-06-29 | SALT COMPOSITION FOR WATER DISINFECTION AND SOFTENER RESINS AND SWIMMING POOLS AND USE OF SAID COMPOSITION CONTAINING IN COMBINATION AT LEAST ONE ALKALINE CHLORIDE, A DISINFECTANT AND A SILVER SALT |
Country Status (1)
Country | Link |
---|---|
FR (1) | FR2872048B1 (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2905954A1 (en) * | 2006-09-18 | 2008-03-21 | Roman Gerusz | PREVENTIVE AND / OR CURATIVE CLEANING AGENT FOR MATERIALS IN CONTACT WITH WATER |
US10029928B2 (en) | 2011-06-16 | 2018-07-24 | Mp Technic | Device for manufacturing sodium hypochlorite or hypochlorous acid and water treatment system in general |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4596648A (en) * | 1984-07-25 | 1986-06-24 | Sweeney Charles T | Continuous electrolytic gas generator |
GB2189394A (en) * | 1986-04-22 | 1987-10-28 | Sanosil Ag | Process for preparing a storage-stable concentrate |
WO1997046102A1 (en) * | 1996-05-30 | 1997-12-11 | Bgp Industries Pty Ltd. | Herbicidal formulation and method of controlling plants |
EP0876762A1 (en) * | 1997-05-05 | 1998-11-11 | Tevan B.V. | Composition having disinfecting action |
WO2001087068A1 (en) * | 2000-05-18 | 2001-11-22 | Nontox Environmental Solutions Pty Ltd. | Herbicidal formulations and methods of use thereof |
US20020193453A1 (en) * | 2001-06-04 | 2002-12-19 | Bohling James Charles | Preparation of weak acid cation exchange resins |
-
2004
- 2004-06-29 FR FR0407123A patent/FR2872048B1/en active Active
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4596648A (en) * | 1984-07-25 | 1986-06-24 | Sweeney Charles T | Continuous electrolytic gas generator |
GB2189394A (en) * | 1986-04-22 | 1987-10-28 | Sanosil Ag | Process for preparing a storage-stable concentrate |
WO1997046102A1 (en) * | 1996-05-30 | 1997-12-11 | Bgp Industries Pty Ltd. | Herbicidal formulation and method of controlling plants |
EP0876762A1 (en) * | 1997-05-05 | 1998-11-11 | Tevan B.V. | Composition having disinfecting action |
WO2001087068A1 (en) * | 2000-05-18 | 2001-11-22 | Nontox Environmental Solutions Pty Ltd. | Herbicidal formulations and methods of use thereof |
US20020193453A1 (en) * | 2001-06-04 | 2002-12-19 | Bohling James Charles | Preparation of weak acid cation exchange resins |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2905954A1 (en) * | 2006-09-18 | 2008-03-21 | Roman Gerusz | PREVENTIVE AND / OR CURATIVE CLEANING AGENT FOR MATERIALS IN CONTACT WITH WATER |
WO2008034995A1 (en) * | 2006-09-18 | 2008-03-27 | Roman Gerusz | Agent for the preventive and/or curative cleaning of materials in contact with water |
US8211842B2 (en) | 2006-09-18 | 2012-07-03 | Roman Gerusz | Preventive and/or curative agent for cleaning materials that are brought into contact with water |
US10029928B2 (en) | 2011-06-16 | 2018-07-24 | Mp Technic | Device for manufacturing sodium hypochlorite or hypochlorous acid and water treatment system in general |
Also Published As
Publication number | Publication date |
---|---|
FR2872048B1 (en) | 2010-02-26 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US7534368B2 (en) | Oxidizing composition including a gel layer | |
US7695631B2 (en) | Composition and method for reducing chemical oxygen demand in water | |
US7927509B2 (en) | Cyclic process for the efficient generation of chlorine dioxide in dilute solutions | |
US7927508B2 (en) | Composition and process for enhanced sanitation and oxidation of aqueous systems | |
US7572390B2 (en) | Composition and method for reducing chemical oxygen demand in water | |
CA2536200A1 (en) | Dual layer tablet, method of making and use thereof | |
US7255797B2 (en) | Composition including potassium monopersulfate and a halogen | |
CN1227346C (en) | Cleaning & disinfecting agent | |
US7008543B2 (en) | Use of chlorine dioxide and ozone for control of disinfection by-products in water supplies | |
AU2010317776B2 (en) | Adsorption of contaminants from liquid and electrochemical regeneration of adsorbent | |
EP0912448A1 (en) | Methods for sanitizing water | |
WO1998000368A9 (en) | Methods for sanitizing water | |
CN1503763A (en) | Stabilised hypobromous acid solutions | |
EP2079666B1 (en) | Solid composition for treating water | |
FR2872048A1 (en) | Disinfecting composition, useful e.g. for natural or synthetic resins of device for softening and refining water by the process of electro chlorination, comprises an alkaline chloride comprising one or more sterilizing agents | |
Xie et al. | A review on bromate occurrence and removal strategies in water supply | |
EP1934145A2 (en) | Method for chlorite removal | |
CN105236691A (en) | Production process for controlling generation of ozonized bromate | |
EP0555598B1 (en) | Composition for disinfecting water by means of electrochlorination and use of this composition | |
Juretić et al. | Degradation of natural organic matter in water by using UV-C/H2O2 process | |
EP1412288B1 (en) | Disinfecting peroxosilicated compound with scale preventive effect, preparation method and use thereof | |
US20110024367A1 (en) | Cyclic process for in-situ generation of chlorine dioxide in biguanide treated aquatic facilities | |
US20090208547A1 (en) | Oxidizing composition including a gel layer | |
US20060049118A1 (en) | Method of disinfection in water treatment | |
WO2005019111A2 (en) | A composition including potassium monopersulfate and a halogen |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PLFP | Fee payment |
Year of fee payment: 13 |
|
PLFP | Fee payment |
Year of fee payment: 14 |