FR2869613A1 - Procede de transesterification d'huiles vegetales ou animales au moyen de catalyseurs heterogenes a base de bismuth, de titane et d'aluminium - Google Patents

Procede de transesterification d'huiles vegetales ou animales au moyen de catalyseurs heterogenes a base de bismuth, de titane et d'aluminium

Info

Publication number
FR2869613A1
FR2869613A1 FR0404731A FR0404731A FR2869613A1 FR 2869613 A1 FR2869613 A1 FR 2869613A1 FR 0404731 A FR0404731 A FR 0404731A FR 0404731 A FR0404731 A FR 0404731A FR 2869613 A1 FR2869613 A1 FR 2869613A1
Authority
FR
France
Prior art keywords
titanium oxide
glycerin
vegetable
catalyst
preparation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR0404731A
Other languages
English (en)
Other versions
FR2869613B1 (fr
Inventor
Bruno Delfort
Gerard Hillion
Pennec Dominique Le
Christophe Lendresse
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IFP Energies Nouvelles IFPEN
Original Assignee
IFP Energies Nouvelles IFPEN
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IFP Energies Nouvelles IFPEN filed Critical IFP Energies Nouvelles IFPEN
Priority to FR0404731A priority Critical patent/FR2869613B1/fr
Priority to EP05290798A priority patent/EP1593732A1/fr
Priority to US11/118,776 priority patent/US7151187B2/en
Priority to BRPI0501601-0A priority patent/BRPI0501601B1/pt
Publication of FR2869613A1 publication Critical patent/FR2869613A1/fr
Application granted granted Critical
Publication of FR2869613B1 publication Critical patent/FR2869613B1/fr
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/03—Preparation of carboxylic acid esters by reacting an ester group with a hydroxy group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Un nouveau procédé de fabrication d'esters d'acides monocarboxyliques linéaires de 6 à 26 atomes de carbone, par réaction d'huiles végétales ou animales, neutres ou non, avec des monoalcools de 1 à 18 atomes de carbone, en présence d'un catalyseur choisi parmi les mélanges d'oxydes de bismuth et de titane et les mélanges d'oxyde de bismuth, d'oxyde de titane et d'alumine répondant à la formule :[(Bi2O3)a - (TiO2)b]y [Al2O3]1-y(a ayant une valeur comprise entre 0.5 et 5, b ayant une valeur comprise entre 0.5 et 5 et y ayant une valeur de 0,005 à 1) permet de fabriquer directement, en une ou plusieurs étapes, un ester utilisable comme carburant ou combustible et une glycérine pure.
FR0404731A 2004-05-03 2004-05-03 Procede de transesterification d'huiles vegetales ou animales au moyen de catalyseurs heterogenes a base de bismuth, de titane et d'aluminium Expired - Fee Related FR2869613B1 (fr)

Priority Applications (4)

Application Number Priority Date Filing Date Title
FR0404731A FR2869613B1 (fr) 2004-05-03 2004-05-03 Procede de transesterification d'huiles vegetales ou animales au moyen de catalyseurs heterogenes a base de bismuth, de titane et d'aluminium
EP05290798A EP1593732A1 (fr) 2004-05-03 2005-04-11 Procede de transesterification d'huiles vegezales ou animales au moyen de catalyseurs heterogenes a base de zinc ou de bismuth de titane et d'aluminium
US11/118,776 US7151187B2 (en) 2004-05-03 2005-05-02 Process for transesterification of vegetable oils or animal oils by means of heterogeneous catalysts based on zinc or bismuth, titanium and aluminium
BRPI0501601-0A BRPI0501601B1 (pt) 2004-05-03 2005-05-03 Processo de transesterificação de óleos vegetais ou animais em um meio de catalisadores heterogêneos a base de zinco ou bismuto, titânio e alumínio

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR0404731A FR2869613B1 (fr) 2004-05-03 2004-05-03 Procede de transesterification d'huiles vegetales ou animales au moyen de catalyseurs heterogenes a base de bismuth, de titane et d'aluminium

Publications (2)

Publication Number Publication Date
FR2869613A1 true FR2869613A1 (fr) 2005-11-04
FR2869613B1 FR2869613B1 (fr) 2008-08-29

Family

ID=34949290

Family Applications (1)

Application Number Title Priority Date Filing Date
FR0404731A Expired - Fee Related FR2869613B1 (fr) 2004-05-03 2004-05-03 Procede de transesterification d'huiles vegetales ou animales au moyen de catalyseurs heterogenes a base de bismuth, de titane et d'aluminium

Country Status (1)

Country Link
FR (1) FR2869613B1 (fr)

Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7557253B2 (en) 2005-05-20 2009-07-07 Solvay (Societe Anonyme) Method for converting polyhydroxylated aliphatic hydrocarbons into chlorohydrins
EP2336279A1 (fr) 2009-12-16 2011-06-22 IFP Energies nouvelles Procédé de production d'esters alkyliques à partir d'huile végétale ou animale et d'un monoalcool aliphatique avec purification à chaud en lit fixe
WO2011149754A1 (fr) 2010-05-26 2011-12-01 Dow Global Technologies Llc Procédé d'hydro-chloration pour hydrocarbures aliphatiques multi-hydroxylés
US8124814B2 (en) 2006-06-14 2012-02-28 Solvay (Societe Anonyme) Crude glycerol-based product, process for its purification and its use in the manufacture of dichloropropanol
US8197665B2 (en) 2007-06-12 2012-06-12 Solvay (Societe Anonyme) Aqueous composition containing a salt, manufacturing process and use
US8258350B2 (en) 2007-03-07 2012-09-04 Solvay (Societe Anonyme) Process for the manufacture of dichloropropanol
US8273923B2 (en) 2007-06-01 2012-09-25 Solvay (Societe Anonyme) Process for manufacturing a chlorohydrin
US8314205B2 (en) 2007-12-17 2012-11-20 Solvay (Societe Anonyme) Glycerol-based product, process for obtaining same and use thereof in the manufacturing of dichloropropanol
US8378130B2 (en) 2007-06-12 2013-02-19 Solvay (Societe Anonyme) Product containing epichlorohydrin, its preparation and its use in various applications
US8471074B2 (en) 2007-03-14 2013-06-25 Solvay (Societe Anonyme) Process for the manufacture of dichloropropanol
US8507643B2 (en) 2008-04-03 2013-08-13 Solvay S.A. Composition comprising glycerol, process for obtaining same and use thereof in the manufacture of dichloropropanol
US8536381B2 (en) 2008-09-12 2013-09-17 Solvay Sa Process for purifying hydrogen chloride
US8715568B2 (en) 2007-10-02 2014-05-06 Solvay Sa Use of compositions containing silicon for improving the corrosion resistance of vessels
US8795536B2 (en) 2008-01-31 2014-08-05 Solvay (Societe Anonyme) Process for degrading organic substances in an aqueous composition
US9309209B2 (en) 2010-09-30 2016-04-12 Solvay Sa Derivative of epichlorohydrin of natural origin
US9663427B2 (en) 2003-11-20 2017-05-30 Solvay (Société Anonyme) Process for producing epichlorohydrin

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20080036555A (ko) 2005-05-20 2008-04-28 솔베이(소시에떼아노님) 클로로히드린으로부터 출발하여 에폭시드를 제조하는 방법
EP1948583A2 (fr) 2005-11-08 2008-07-30 Solvay S.A. Procede de fabrication de dichloropropanol par chloration de glycerol

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5908946A (en) * 1996-08-08 1999-06-01 Institut Francais Du Petrole Process for the production of esters from vegetable oils or animal oils alcohols
EP0924185A1 (fr) * 1997-12-18 1999-06-23 Institut Français du Pétrole Procédé de fabrication d'esters de corps gras et les esters de haute pureté obtenus

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5908946A (en) * 1996-08-08 1999-06-01 Institut Francais Du Petrole Process for the production of esters from vegetable oils or animal oils alcohols
EP0924185A1 (fr) * 1997-12-18 1999-06-23 Institut Français du Pétrole Procédé de fabrication d'esters de corps gras et les esters de haute pureté obtenus

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
PETERSON G R ET AL: "Rapeseed oil transesterification by heterogenous catalysis", JOURNAL OF THE AMERICAN OIL CHEMISTS' SOCIETY, AMERICAN OIL CHEMISTS' SOCIETY. CHAMPAIGN, US, vol. 61, no. 10, October 1984 (1984-10-01), pages 1593 - 1597, XP002170978, ISSN: 0003-021X *

Cited By (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9663427B2 (en) 2003-11-20 2017-05-30 Solvay (Société Anonyme) Process for producing epichlorohydrin
US7615670B2 (en) 2005-05-20 2009-11-10 Solvay (Société Anonyme) Method for making chlorohydrin in liquid phase in the presence of heavy compounds
EP2275417A2 (fr) 2005-05-20 2011-01-19 SOLVAY (Société Anonyme) Procédé de fabrication de dichloropropanol
EP2284163A2 (fr) 2005-05-20 2011-02-16 SOLVAY (Société Anonyme) Procédé de fabrication de dichloropropanol
EP2284162A2 (fr) 2005-05-20 2011-02-16 SOLVAY (Société Anonyme) Procédé de fabrication de dichloropropanol
US7557253B2 (en) 2005-05-20 2009-07-07 Solvay (Societe Anonyme) Method for converting polyhydroxylated aliphatic hydrocarbons into chlorohydrins
US8124814B2 (en) 2006-06-14 2012-02-28 Solvay (Societe Anonyme) Crude glycerol-based product, process for its purification and its use in the manufacture of dichloropropanol
US8258350B2 (en) 2007-03-07 2012-09-04 Solvay (Societe Anonyme) Process for the manufacture of dichloropropanol
US8471074B2 (en) 2007-03-14 2013-06-25 Solvay (Societe Anonyme) Process for the manufacture of dichloropropanol
US8273923B2 (en) 2007-06-01 2012-09-25 Solvay (Societe Anonyme) Process for manufacturing a chlorohydrin
US8197665B2 (en) 2007-06-12 2012-06-12 Solvay (Societe Anonyme) Aqueous composition containing a salt, manufacturing process and use
US8378130B2 (en) 2007-06-12 2013-02-19 Solvay (Societe Anonyme) Product containing epichlorohydrin, its preparation and its use in various applications
US8399692B2 (en) 2007-06-12 2013-03-19 Solvay (Societe Anonyme) Epichlorohydrin, manufacturing process and use
US8715568B2 (en) 2007-10-02 2014-05-06 Solvay Sa Use of compositions containing silicon for improving the corrosion resistance of vessels
US8314205B2 (en) 2007-12-17 2012-11-20 Solvay (Societe Anonyme) Glycerol-based product, process for obtaining same and use thereof in the manufacturing of dichloropropanol
US8795536B2 (en) 2008-01-31 2014-08-05 Solvay (Societe Anonyme) Process for degrading organic substances in an aqueous composition
US8507643B2 (en) 2008-04-03 2013-08-13 Solvay S.A. Composition comprising glycerol, process for obtaining same and use thereof in the manufacture of dichloropropanol
US8536381B2 (en) 2008-09-12 2013-09-17 Solvay Sa Process for purifying hydrogen chloride
EP2336279A1 (fr) 2009-12-16 2011-06-22 IFP Energies nouvelles Procédé de production d'esters alkyliques à partir d'huile végétale ou animale et d'un monoalcool aliphatique avec purification à chaud en lit fixe
WO2011149754A1 (fr) 2010-05-26 2011-12-01 Dow Global Technologies Llc Procédé d'hydro-chloration pour hydrocarbures aliphatiques multi-hydroxylés
US9067845B2 (en) 2010-05-26 2015-06-30 Dow Global Technologies Llc Process for hydrochlorination of multihydroxylated aliphatic hydrocarbons
US9309209B2 (en) 2010-09-30 2016-04-12 Solvay Sa Derivative of epichlorohydrin of natural origin

Also Published As

Publication number Publication date
FR2869613B1 (fr) 2008-08-29

Similar Documents

Publication Publication Date Title
FR2869612A1 (fr) Procede de transesterification d'huiles vegetales ou animales au moyen de catalyseurs heterogenes a base de zinc, de titane et d'aluminium
FR2869613A1 (fr) Procede de transesterification d'huiles vegetales ou animales au moyen de catalyseurs heterogenes a base de bismuth, de titane et d'aluminium
TW200631597A (en) External use preparation and adhesive preparation thereof
WO2006050925A8 (fr) Procede permettant de produire desespere a partir d'huiles vegetales ou de graisses animales au moyen de catalyseurs heterogenes
WO2005117984A3 (fr) Composes liant l'albumine
NZ591261A (en) Improvements in the absorption of therapeutic agents across mucosal membranes or the skin
EP2194119A3 (fr) Production d'acides gras et dérivés associés
PL1791532T3 (pl) Kompozycja w mikropeletkach o kontrolowanym uwalnianiu substancji fizjologicznie czynnych, sposób jej wytwarzania i jej zastosowanie w dziedzinie zootechniki
EP2840131A3 (fr) Production d'acides gras et dérivés associés
EP2455459A3 (fr) Variantes de lipase pour utilisation pharmaceutique
ECSP034430A (es) Esteres oxigenados de acidos 4-yodo fenilamino benzhidroxamcios
BR0300931A (pt) Processo de produção de ésteres alquìlicos a partir de um óleo vegetal ou animal e de um monoálcool alifático
WO2011123188A9 (fr) Connecteur de ligne de sécurité destiné à être utilisé avec une ligne de sécurité se rétractant automatiquement et une ligne de sécurité détachable
WO2003074043A1 (fr) Agents destines a elever la temperature corporelle
TW200503790A (en) Adhesive preparations
MX2007006908A (es) Estabilizacion de esteres de glucocorticoides con acidos.
MX2007006775A (es) Composiciones estables de fenofibrato con esteres de acido graso.
WO2008104271A3 (fr) Sondes d'imagerie
WO2011156807A3 (fr) Extrudat de dioxyde de titane-alumine-dioxyde de tungstène et ses applications
WO2005052152A8 (fr) Adn intervenant dans l'hydroxylation d'un compose macrolide
IL174691A0 (en) Infusion preparation containing (2r)-2-propyloctanoic acid as the active ingredient
WO2009038090A1 (fr) Composition contenant un composant de sésamine et un composant d'acide arachidonique
AU2003295147A1 (en) Adhesive derived from dimeric fatty acid or dimeric fatty diol
EP0955375A3 (fr) Procédé de préparation de l'ester optiquement actif de l'acide 4-halo-3 hydroybutyrique
EP2327398A3 (fr) Composition pharmaceutique comprenant un composé de 11-déoxy-prostaglandine et procédé de stabilisation du composé

Legal Events

Date Code Title Description
CD Change of name or company name
ST Notification of lapse

Effective date: 20120131