FR2860920A1 - Multiple short local electrical connections for selective linkage of integrated circuit elements comprise masked selective humid attack of deposited metal - Google Patents

Multiple short local electrical connections for selective linkage of integrated circuit elements comprise masked selective humid attack of deposited metal Download PDF

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FR2860920A1
FR2860920A1 FR0311987A FR0311987A FR2860920A1 FR 2860920 A1 FR2860920 A1 FR 2860920A1 FR 0311987 A FR0311987 A FR 0311987A FR 0311987 A FR0311987 A FR 0311987A FR 2860920 A1 FR2860920 A1 FR 2860920A1
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substrate
connection
integrated circuit
conductive
selective
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Stephan Niel
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STMicroelectronics SA
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STMicroelectronics SA
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/70Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
    • H01L21/71Manufacture of specific parts of devices defined in group H01L21/70
    • H01L21/768Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics
    • H01L21/76838Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the conductors
    • H01L21/76895Local interconnects; Local pads, as exemplified by patent document EP0896365
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/04Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
    • H01L21/18Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
    • H01L21/28Manufacture of electrodes on semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/268
    • H01L21/283Deposition of conductive or insulating materials for electrodes conducting electric current
    • H01L21/285Deposition of conductive or insulating materials for electrodes conducting electric current from a gas or vapour, e.g. condensation
    • H01L21/28506Deposition of conductive or insulating materials for electrodes conducting electric current from a gas or vapour, e.g. condensation of conductive layers
    • H01L21/28512Deposition of conductive or insulating materials for electrodes conducting electric current from a gas or vapour, e.g. condensation of conductive layers on semiconductor bodies comprising elements of Group IV of the Periodic Table
    • H01L21/28518Deposition of conductive or insulating materials for electrodes conducting electric current from a gas or vapour, e.g. condensation of conductive layers on semiconductor bodies comprising elements of Group IV of the Periodic Table the conductive layers comprising silicides

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  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Manufacturing & Machinery (AREA)
  • Computer Hardware Design (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Internal Circuitry In Semiconductor Integrated Circuit Devices (AREA)

Abstract

An electric connection selectively linking elements (10, 12) on an integrated circuit substrate (28) comprises: (a) realizing the elements on a substrate of which a part of the surface is made of a first material, depositing, on the substrate and the elements, a second conducting material (44, 46) that is able to create a reaction with the first material to form a conducting material on the substrate surface; (b) treating the substrate to produce the reaction; and (c) realizing a selective withdrawal of the second material that has not reacted with the first material, in order to leave some of the second material according to a pattern that corresponds with at least a part of the connection. An independent claim is also included for an integrated circuit incorporating the above electrical connections.

Description

PROCEDE DE REALISATION DE CONNEXIONS CONDUCTRICES DEMETHOD FOR MAKING CONDUCTIVE CONNECTIONS OF

CIRCUITS INTEGRES, ET CIRCUIT INTEGRE METTANT EN UVRE DES TELLES CONNEXIONS.  INTEGRATED CIRCUITS, AND INTEGRATED CIRCUIT USING SUCH CONNECTIONS.

L'invention concerne la réalisation de circuits intégrés, et plus particulièrement une technique de connexion électrique sélective entre des éléments du circuit intégré, notamment lorsque ces derniers sont relativement proches l'un de l'autre. A ce titre, l'invention permet de réaliser des interconnexions dites locales sur de courtes distances à l'échelle du circuit intégré.  The invention relates to the production of integrated circuits, and more particularly to a technique of selective electrical connection between elements of the integrated circuit, especially when the latter are relatively close to one another. As such, the invention makes it possible to achieve so-called local interconnections over short distances on the scale of the integrated circuit.

Dans l'état de l'art, on réalise ces connexions locales par des techniques dites de niveau d'interconnexion local (connues par l'acronyme anglais de LIL, pour "Local Interconnect Level"). De manière générale, ces interconnexions sont réalisées avec des niveaux de métallisation sur le silicium dans une structure diélectrique pré- métallique. De telles interconnexions sont typiquement réalisées par dépôt de tungstène directement sur le silicium.  In the state of the art, these local connections are made by techniques called local interconnection level (known by the acronym LIL for "Local Interconnect Level"). In general, these interconnections are made with metallization levels on the silicon in a pre-metallic dielectric structure. Such interconnections are typically made by depositing tungsten directly on the silicon.

La figure 1 illustre un exemple, vu de dessus, d'une topographie d'interconnexion de niveau local (abrévié dans ce qui suit à "interconnexion locale"), dans lequel sont représentées deux zones actives 2 et 4, chacune formant un îlot dans un substrat en silicium 6 du circuit intégré 8. L'isolation des deux zones actives est obtenue par formation d'un oxyde de champ du type dit tranchée d'isolation à faible profondeur 3 (connu par l'acronyme anglais STI, pour "Shallow Trench Isolation").  FIG. 1 illustrates an example, seen from above, of a local level interconnection topography (hereinafter abbreviated to "local interconnection"), in which two active zones 2 and 4 are represented, each forming an island in a silicon substrate 6 of the integrated circuit 8. The insulation of the two active zones is obtained by forming a field oxide of the type said trench isolation of shallow depth 3 (known by the acronym STI, for "Shallow Trench Isolation ").

Une première zone active 2 représentée comporte deux transistors MOS, dont les grilles respectives 10 et 12 sont reliées électriquement par une première interconnexion locale 14.  A first active zone 2 shown comprises two MOS transistors, whose respective gates 10 and 12 are electrically connected by a first local interconnection 14.

Par ailleurs, les deux zones actives 2 et 4 sont reliées électriquement entre elles de part et d'autre de la tranchée 3 par une deuxième interconnexion locale 16.  Moreover, the two active zones 2 and 4 are electrically connected to each other on either side of the trench 3 by a second local interconnection 16.

Enfin, la seconde zone active 4 comporte une troisième interconnexion locale 18, qui est verticale afin de relier deux niveaux conducteurs superposés, en l'occurrence au voisinage de la grille de contrôle 20 d'un transistor MOS.  Finally, the second active zone 4 comprises a third local interconnection 18, which is vertical in order to connect two superimposed conductive levels, in this case in the vicinity of the control gate 20 of a MOS transistor.

Les interconnexions locales sont réalisées au niveau du silicium dans le but de connecter entre elles des lignes de silicium polycristallin et des lignes de zones actives.  The local interconnections are made at the silicon level for the purpose of interconnecting polycrystalline silicon lines and active zone lines.

Selon les techniques classiques de réalisation, les interconnexions locales 14, 16, 18 sont en métal, typiquement du tungstène (W). Les interconnexions locales qui sont latérales relativement au plan du circuit intégré, comme les première et deuxième interconnexions 14, 16, sont chacune sous forme de tranchée. Les interconnexions verticales, par exemple la troisième interconnexion 18, sont sous forme d'un trou rempli d'un matériau conducteur formant un contact connu par le terme anglais de "plug".  According to conventional manufacturing techniques, the local interconnections 14, 16, 18 are made of metal, typically tungsten (W). Local interconnections that are lateral relative to the plane of the integrated circuit, such as the first and second interconnections 14, 16, are each in trench form. The vertical interconnections, for example the third interconnection 18, are in the form of a hole filled with a conductive material forming a contact known by the English term "plug".

Plus généralement, les interconnexions locales se répartissent en deux types tranchées et trous, comblés de matériau conducteur.  More generally, local interconnections are divided into two types of trenches and holes, filled with conductive material.

Les tranchées servent à connecter notamment deux zones du circuit, par exemple deux zones actives, deux ligne de polysilicium, ou une zone active et une ligne de polysilicium. Les trous servent à connecter juste un point particulier à un autre.  The trenches serve to connect in particular two zones of the circuit, for example two active zones, two polysilicon lines, or an active zone and a polysilicon line. The holes are used to connect just one particular point to another.

La réalisation des interconnexions locales fait intervenir un niveau supplémentaire de photolithographie et gravure.  The realization of local interconnections involves an additional level of photolithography and etching.

Pour mémoire, les figures 2a à 2d représentent schématiquement les étapes principales dans la formation d'un motif en relief sur une plaquette de silicium par une technique de photolithographie et gravure.  For the record, Figures 2a to 2d show schematically the main steps in the formation of a pattern in relief on a silicon wafer by a photolithography and etching technique.

A un stade initial (figure 2a), un masque 22 comportant sous forme de découpes 24 un motif de matériau à supprimer est apposé sur une couche de résine photosensible 26 déposée uniformément sur la surface de la plaquette de silicium 28. Un rayonnement 30 apte à provoquer une réaction sur la résine est appliqué à travers le masque.  At an initial stage (FIG. 2a), a mask 22 comprising, in the form of blanks 24, a pattern of material to be removed is affixed to a layer of photosensitive resin 26 uniformly deposited on the surface of the silicon wafer 28. A radiation 30 suitable for cause a reaction on the resin is applied through the mask.

L'ensemble comprenant le substrat 28 et la résine 26 est développé dans un bain chimique de sorte à retirer les parties exposée de la résine, rendues non résistantes au bain. On obtient alors le motif du masque 22 reproduit en relief sur la résine, permettant d'exposer la surface supérieure 28a du substrat 28 aux endroits où la résine est retirée (figure 2b).  The assembly comprising the substrate 28 and the resin 26 is developed in a chemical bath so as to remove the exposed portions of the resin, made non-resistant to the bath. The pattern of the mask 22 reproduced in relief on the resin is then obtained, making it possible to expose the upper surface 28a of the substrate 28 at the places where the resin is removed (FIG. 2b).

L'ensemble précité est ensuite soumis à une gravure, par exemple du type par contact, durant laquelle la surface exposée 28a du silicium est usinée chimiquement pour former des tranchées 32, dont la surface du fond 32a est sensiblement en retrait de la surface supérieure 28a du substrat (figure 2c).  The aforementioned assembly is then subjected to etching, for example of the contact type, during which the exposed surface 28a of the silicon is machined chemically to form trenches 32, whose bottom surface 32a is substantially set back from the upper surface 28a. of the substrate (Figure 2c).

Enfin, la résine est complètement retirée du substrat silicium 28 (figure 2d).  Finally, the resin is completely removed from the silicon substrate 28 (Figure 2d).

La figure 3 illustre, par une vue selon la ligne III-III' de la figure 1, la réalisation concrète des interconnexions locales de la figure 1 selon un état de la technique.  FIG. 3 illustrates, by a view along the line III-III 'of FIG. 1, the concrete embodiment of the local interconnections of FIG. 1 according to a state of the art.

Pour définir les tranchées et les trous ("plugs") devant former les interconnexions locales du circuit, on prévoit le dépôt, sur la surface du substrat 28, de deux niveaux de diélectrique dits pré-métalliques (plus connue par l'acronyme anglais PMD, pour "Pre-Metal Dielectric"), chacun comportant les éléments conducteurs 14, 16 qui constituent les interconnexions locales. (Le terme "pré-métallique provient du fait que ces niveaux sont situés entre le substrat 28 et un premier niveau de métallisation 34, dit "métal 1" du circuit intégré.) Dans la figure, les premier et second niveaux de la structure, comptés à partir du substrat 28, sont respectivement désignés PMD1 et PMD2.  To define the trenches and holes ("plugs") to form the local interconnections of the circuit, it is expected the deposition, on the surface of the substrate 28, of two so-called pre-metallic dielectric levels (better known by the acronym PMD) , for "Pre-Metal Dielectric"), each comprising the conductive elements 14, 16 which constitute the local interconnections. (The term "pre-metal comes from the fact that these levels are located between the substrate 28 and a first level of metallization 34, called" metal 1 "of the integrated circuit.) In the figure, the first and second levels of the structure, counted from the substrate 28 are respectively designated PMD1 and PMD2.

On observe que les éléments sur lesquels doivent être formés les interconnexions locales, à savoir les contacts de grilles de contrôle 10, 12, ainsi que les zones de contact pour les deuxième et troisième interconnexions locales 16, 20 précitées, sont recouvertes de CoSi2 (ces parties sont repérées par des hachures). Le CoSi2 recouvre également d'autres éléments, notamment la grille de contrôle 20.  It is observed that the elements on which the local interconnections, ie the control grid contacts 10, 12, and the contact zones for the second and third local interconnections 16, 20 mentioned above, must be formed are covered with CoSi 2 (these parts are marked with hatching). CoSi2 also covers other elements, in particular the control grid 20.

Les reliefs verticaux sur la surface du substrat 28, constitués ici par les grilles de contrôle 10, 12, 20, sont bordés sur leur flancs par des éléments dits "espaceur" (plus connus par le terme anglais de "spacer") 38, dont les faces extérieures présentent des pentes. Les espaceurs sont ici formés par un bicouche oxyde-nitrure gravé de manière anisotropique.  The vertical reliefs on the surface of the substrate 28, constituted here by the control grids 10, 12, 20, are bordered on their flanks by so-called "spacer" elements (better known by the term "spacer") 38, of which the outer faces have slopes. The spacers are here formed by an oxide-nitride bilayer etched anisotropically.

Initialement, le premier niveau PMD1 est formé selon les étapes suivantes: Al. Formation préalable d'une couche de siliciure de cobalt (CoSi2), comprenant: A1.1. le dépôt d'une couche de cobalt, ou autre conducteur équivalent, sur l'ensemble de la partie exposée du substrat semiconducteur 6, après nettoyage de celle-ci; A1.2. un recuit rapide de cette couche enrobée, (connu par l'acronyme anglais de RTP, pour "Rapid Thermal Processing") ; A1.3. le retrait sélectif par voie humide d'une partie de la couche, soit du cobalt non réagi et du TiN.  Initially, the first level PMD1 is formed according to the following steps: A1. Prior formation of a cobalt silicide layer (CoSi2), comprising: A1.1. depositing a layer of cobalt, or other equivalent conductor, over the entire exposed portion of the semiconductor substrate 6, after cleaning thereof; A1.2. rapid annealing of this coated layer, (known by the acronym RTP, for "Rapid Thermal Processing"); A1.3. selective wet removal of part of the layer, either unreacted cobalt and TiN.

A2. Dépôt de la couche PMD1, comprenant: A2.1. le dépôt d'une couche en nitrure, du type connu par le terme anglais de "borderless nitride" (traduction littérale: "nitrure sans bordure") ; A2.2. le dépôt d'oxyde de silicium SiO2 en utilisant par exemple une technique de dépôt chimique sub-atmosphérique en phase vapeur (connu par l'acronyme anglais SACVD, pour "Sub-Atmospheric Chemical Vapour Deposition"), ou de dépôt chimique en phase vapeur renforcé par plasma (connu par l'acronyme anglais PECVD, pour "Plasma-Enhanced Chemical Vapour Deposition), ou de dépôt en plasma à haute densité (connu par l'acronyme anglais HOP, pour "High density plasma), etc. Selon l'application, ce dépôt peut être soit non dopé, soit dopé. Dans ce dernier cas, le matériau de dopage peut être, à titre d'exemple, du bore et du phosphore formant un dépôt connu par l'acronyme anglais BPSG, pour "Boron/Phosphorous-Doped Silicon Glass") ; et A2.3. une étape de densification de la couche PMD1 ainsi formée, avec transformation du matériau CoSi en CoSi2.  A2. Deposition of the PMD1 layer, comprising: A2.1. the deposition of a nitride layer, of the type known by the term "borderless nitride" (literal translation: "nitride without border"); A2.2. the deposition of silicon oxide SiO 2 using, for example, a sub-atmospheric chemical vapor deposition technique (known by the acronym SACVD, for "Sub-Atmospheric Chemical Vapor Deposition"), or chemical vapor deposition plasma enhanced (known by the acronym PECVD, for "Plasma-Enhanced Chemical Vapor Deposition), or deposition in high density plasma (known by the acronym HOP, for" High density plasma), etc. Depending on the application, this deposit may be either undoped or doped. In the latter case, the doping material may be, for example, boron and phosphorus forming a deposit known by the acronym BPSG, for "Boron / Phosphorous-Doped Silicon Glass"); and A2.3. a densification step of the PMD1 layer thus formed, with conversion of CoSi material to CoSi2.

A.2.4. un polissage ou de planarisation mécano- chimique (connu par l'acronyme anglais CMP, pour "Chemical-Mechanical Polising/Planarisation")de l'oxyde. Cette étape permet d'obtenir une couche PMD plane.  A.2.4. polishing or mechano-chemical planarization (known by the acronym CMP, for "Chemical-Mechanical Polishing / Planarization") of the oxide. This step makes it possible to obtain a flat PMD layer.

A3. Photolithographie et gravure du motif des interconnexions locales avec remplissage du motif par du tungstène. Cette phase permet de définir, par un masque approprié, les "plugs" et les tranchées de la l'interconnexion locale. Elle comprend les étapes suivantes.  A3. Photolithography and etching of the pattern of local interconnections with filling of the pattern with tungsten. This phase makes it possible to define, by an appropriate mask, the "plugs" and the trenches of the local interconnection. It includes the following steps.

A3.1. une photolithographie pour la formation du motif de résine photosensible 26 (cf. figures 2a et 2b) ; A3.2. une gravure sèche (par plasma) des interconnexions locales (cf. figures 2c et 2d), avec arrêt critique sur le CoSi2 et/ou sur la tranchée d'isolation STI 3 servant à isoler les zones actives entre elles A3.3. le retrait de la résine; A3.4. la réalisation d'un dépôt barrière (couche conductrice) sur toute la plaquette, réalisée en bicouche, par exemple avec du Ti/TiN, entrant dans les contacts (tranchées ou "plugs"). Plus particulièrement, cette couche très fine, typiquement de 200 Angstrom au total, se dépose au fond des contacts et surtout sur les flancs de ces derniers; A3.5. le dépôt de tungstène formant les éléments conducteurs 14 et 20, ainsi que la partie du "plug" 18 sur l'étendu de la section verticale du diélectrique pré-métallique PMD1; et A3.6. le polissage/la planarisation mécanochimique utilisant une technique CMP comme pour l'étape A.2.4 supra. Cette étape a pour but d'enlever par usinage le tungstène qui se trouve au- dessus de l'oxyde afin de ne le laisser que dans les "plugs" et dans les tranchées.  A3.1. photolithography for the formation of the photoresist pattern 26 (see Figures 2a and 2b); A3.2. dry etching (by plasma) of the local interconnections (see FIGS. 2c and 2d), with critical shutdown on the CoSi2 and / or on the insulation trench STI 3 serving to isolate the active zones from each other A3.3. removal of the resin; A3.4. the production of a barrier deposit (conductive layer) on the entire wafer, made bilayer, for example with Ti / TiN, entering the contacts (sliced or "plugs"). More particularly, this very thin layer, typically 200 Angstrom in total, is deposited at the bottom of the contacts and especially on the flanks of the latter; A3.5. the deposition of tungsten forming the conductive elements 14 and 20, as well as the portion of the "plug" 18 over the extent of the vertical section of the pre-metallic dielectric PMD1; and A3.6. mechanochemical polishing / planarization using a CMP technique as for step A.2.4 above. The purpose of this step is to mechanically remove the tungsten above the oxide to leave it only in plugs and trenches.

A l'issu de ces étapes, il ne subsiste du tungstène que dans les tranchées 14 et dans les "plugs" 18 de l'interconnexion locale. A partir de cette préparation, on réalise le second niveau diélectrique PMD2, constitué d'un ensemble de "plugs" destiné à la connexion sélective des parties du tungstène du premier diélectrique avec la première métallisation 34, désigné métal 1.  At the end of these steps, only tungsten remains in the trenches 14 and in the "plugs" 18 of the local interconnection. From this preparation, the second dielectric level PMD2 is formed, consisting of a set of "plugs" intended for the selective connection of the tungsten parts of the first dielectric with the first metallization 34, designated metal 1.

Pour ce faire, on dépose à nouveau une couche pré-métallique (soit diélectrique) servant à définir les connexions. Cette seconde couche prémétallique ne définit que des "plugs". Ces derniers sont destinés à relier le métal 1 avec soit les "plugs" du niveau PMD1, soit les lignes réalisées par le premier dépôt de tungstène.  To do this, is deposited again a pre-metallic layer (or dielectric) used to define the connections. This second pre-metallic layer only defines "plugs". These are intended to connect the metal 1 with either the "plugs" of the PMD1 level, or the lines made by the first deposit of tungsten.

Le second niveau PMD2 est réalisé par les étapes suivantes, consistant à former les "plugs" : 4.1. un dépôt d'oxyde de silicium SiO2 qui, comme pour le premier niveau PMD1, peut être non dopé ou dopé, le dopage dans ce dernier cas pouvant être avec du bore et du phosphore pour former la composition BPSG précitée; 4.2. si le dépôt est dopé, une densification de ce dépôt, par exemple de BPSG; 4.3. une photolithographie afin de définir les trous pour les "plugs"; 4.4. une gravure des "plugs" ; et 4.5. le retrait de la résine utilisée lors de la gravure.  The second level PMD2 is achieved by the following steps, consisting of forming the "plugs": 4.1. a silicon oxide SiO2 deposit which, as for the first level PMD1, may be undoped or doped, the doping in the latter case possibly being with boron and phosphorus to form the aforementioned BPSG composition; 4.2. if the deposit is doped, a densification of this deposit, for example BPSG; 4.3. a photolithography to define the holes for the "plugs"; 4.4. an engraving of "plugs"; and 4.5. the removal of the resin used during the etching.

Concernant l'ensemble de ce processus classique de fabrication des connexions locales, on remarque que l'étape de photolithographie est très critique et nécessite un masque coûteux, s'agissant d'un masque à décalage de phase, spécialement conçu pour définir des motifs très fins.  As regards the whole of this conventional process of manufacturing local connections, it should be noted that the photolithography step is very critical and requires an expensive mask, being a phase-shifted mask, specially designed to define very complex patterns. purposes.

Au niveau de la gravure, un point de criticité très élevé dans l'exemple de la figure 3 est indiqué par le repère A, situé au bord de la tranchée 3 et du substrat 28, soit à l'arrêt de la gravure. En effet, ce masque doit définir simultanément, pour un même niveau et avec un même masque, des ouvertures à la fois en forme de tranchée et en forme de trou, pour les "plugs".  In the etching, a very high criticality point in the example of Figure 3 is indicated by the mark A, located at the edge of the trench 3 and the substrate 28, or at the end of the etching. Indeed, this mask must simultaneously define, for the same level and with the same mask, openings both trench-shaped and hole-shaped, for "plugs".

L'étape de photolithogravure est également très critique, car elle nécessite d'être hautement sélective, à la fois: - par rapport au siliciure de cobalt (CoSi2), celui-ci se présentant sous forme d'une couche métallique formée sélectivement sur les zones actives et sur les lignes de polysilicium, afin de réduire les résistances de ligne de contact, et - par rapport à l'oxyde de la tranchée d'isolation STI 3, s'agissant d'un oxyde de champ servant à isoler entre elles les zones actives 2, 4 (cf. repère A de la figure 3).  The photolithography step is also very critical because it requires being highly selective, both: with respect to cobalt silicide (CoSi 2), this latter being in the form of a metal layer formed selectively on the active zones and on the polysilicon lines, in order to reduce the contact line resistances, and - with respect to the oxide of the insulation trench STI 3, being a field oxide used to isolate them the active zones 2, 4 (see reference A of FIG.

En effet, une sur-gravure du cobalt ou de l'oxyde en bord du tranché d'isolation précité peut provoquer des courants de fuite, par fuite de jonction, destructeurs pour le circuit.  In fact, an over-etching of cobalt or oxide at the edge of the aforementioned insulation slice can cause leakage currents, by junction leakage, which are destructive for the circuit.

De plus, il est pénalisant d'avoir recours à un second dépôt de diélectrique pré-métallique (cf. phase 4 supra) afin de permettre d'établir un contact entre le tungstène de l'interconnexion avec l'aluminium du métal 1.  In addition, it is disadvantageous to use a second deposit of pre-metallic dielectric (see phase 4 above) in order to make it possible to establish a contact between the tungsten of the interconnection with the aluminum of the metal 1.

Au vu de ce qui précède, l'invention propose une nouvelle approche permettant de réaliser notamment des connexions conductrices avec une simplification par rapport à l'état de la technique, entre autres au niveau des masques.  In view of the foregoing, the invention proposes a new approach making it possible in particular to make conductive connections with a simplification compared to the state of the art, among other things at the level of the masks.

Dans le mode de réalisation qui sera décrit, l'invention permet la suppression d'une gravure critique à sec au niveau des lignes locales d'interconnexion, en la remplaçant par une attaque humide sélective masquée du métal déposé, en l'occurrence du cobalt dans l'exemple décrit.  In the embodiment to be described, the invention makes it possible to eliminate dry critical etching at the local interconnection lines, replacing it with a selective wet etching of the deposited metal, in this case cobalt in the example described.

Plus particulièrement, l'invention prévoit, selon un premier aspect, un procédé de réalisation d'au moins une connexion électriquement conductrice reliant sélectivement des éléments sur un substrat de circuit intégré, caractérisé en ce qu'il comprend les étapes de: - réaliser lesdits éléments sur un substrat dont au moins une portion de la surface est constituée d'un premier matériau, - déposer, sur le substrat et lesdits éléments, au moins un deuxième matériau, qui est conducteur et susceptible de créer une réaction avec le premier matériau pour former un matériau conducteur à la surface du substrat, - traiter le substrat pour réaliser ladite réaction, - réaliser un retrait sélectif du deuxième matériau n'ayant pas réagi avec ledit premier matériau, pour laisser du deuxième matériau selon un motif qui correspond à au moins une partie de la connexion.  More particularly, according to a first aspect, the invention provides a method for producing at least one electrically conductive connection selectively connecting elements to an integrated circuit substrate, characterized in that it comprises the steps of: elements on a substrate of which at least a portion of the surface consists of a first material, - depositing, on the substrate and said elements, at least a second material, which is conductive and capable of creating a reaction with the first material for forming a conductive material on the surface of the substrate, - treating the substrate to carry out said reaction, - selectively removing the second material unreacted with said first material, to leave the second material in a pattern which corresponds to at least part of the connection.

Avantageusement, le retrait sélectif du deuxième matériau n'ayant pas réagi est réalisé par au moins un masque définissant ledit motif, par exemple en utilisant une technique de gravure par voie humide. Dans ce cas, le retrait sélectif peut être réalisé par immersion du substrat et de son masque dans un bain.  Advantageously, the selective removal of the unreacted second material is carried out by at least one mask defining said pattern, for example by using a wet etching technique. In this case, the selective shrinkage can be achieved by immersing the substrate and its mask in a bath.

Dans le mode de réalisation, au moins une connexion relie un desdits éléments à une aire du substrat rendue conductrice par ladite réaction entre le premier et le deuxième matériau.  In the embodiment, at least one connection connects one of said elements to an area of the substrate made conductive by said reaction between the first and second material.

Au moins une aire du substrat rendue conductrice par ladite réaction entre le premier et le deuxième matériau peut être utilisée comme point de base pour un contact par trou, connu par le terme anglais de "plug", permettant une connexion vers un point de contact superposé.  At least one area of the substrate rendered conductive by said reaction between the first and the second material can be used as a base point for a hole contact, known as plug, allowing connection to a superimposed contact point. .

De préférence, le retrait sélectif réalise de multiples connexions.  Preferably, the selective removal performs multiple connections.

Avantageusement, la connexion est réalisée sous forme de ligne/les connexions sont réalisées uniquement sous forme de lignes.  Advantageously, the connection is made as a line / connections are made only in the form of lines.

Le masque peut alors comporter un motif uniquement de ligne(s) pour définir la ou chaque connexion.  The mask can then comprise a pattern of only line (s) to define the or each connection.

Le masque peut être formé par une technique de photolithographie.  The mask can be formed by a photolithography technique.

Ladite étape de traitement peut comprendre un traitement thermique rapide, connu par l'acronyme anglais RTP, pour "Rapid Thermal Processing".  Said processing step may comprise a rapid thermal treatment, known by the acronym RTP, for "Rapid Thermal Processing".

Le deuxième matériau déposé, ou l'un au moins des matériaux déposés, peut être un métal, par exemple un métal réfractaire. Dans ce dernier cas, le métal réfractaire peut être au moins l'un parmi du cobalt, du titane, du nickel.  The second deposited material, or at least one of the deposited materials, may be a metal, for example a refractory metal. In the latter case, the refractory metal may be at least one of cobalt, titanium, nickel.

L'étape de dépôt d'au moins un deuxième matériau peut, selon une option avantageuse, consister à déposer un bicouche formé d'une première composante qui est recouverte, ou encapsulée, par une deuxième composante, différente le la première.  The deposition step of at least one second material may, according to an advantageous option, consist in depositing a bilayer formed of a first component which is covered, or encapsulated, by a second component, different from the first one.

Si cette option est utilisée, la première composante du bicouche peut comprendre, entre autres, du cobalt, et la seconde composante, qui la recouvre ou la l'encapsule, peut comprendre, entre autres, du titane (Ti), la première composante étant en contact avec le premier matériau.  If this option is used, the first component of the bilayer may comprise, inter alia, cobalt, and the second component, which covers or encapsulates it, may comprise, inter alia, titanium (Ti), the first component being in contact with the first material.

Ledit premier matériau formant au moins une portion de ladite surface exposée du substrat peut être du silicium. Dans ce cas, le matériau conducteur formé par ladite réaction peut être un siliciure. Dans ce dernier cas, le siliciure peut être au moins l'un parmi: un siliciure de cobalt (CoSi), un siliciure de titane, un siliciure de nickel.  Said first material forming at least a portion of said exposed surface of the substrate may be silicon. In this case, the conductive material formed by said reaction may be a silicide. In the latter case, the silicide may be at least one of: cobalt silicide (CoSi), titanium silicide, nickel silicide.

Le procédé peut comprendre en outre la réalisation d'une structure dite diélectrique pré-métallique (PMD) unique comprenant au moins un contact par trou, connu par le terme anglais de "plug", permettant une connexion vers un point de contact superposé destiné à relier des points de ladite connexion électrique avec un niveau de métallisation.  The method may furthermore comprise the production of a single pre-metallic dielectric (PMD) structure comprising at least one hole contact, known by the English term "plug", allowing a connection to a superimposed contact point for connecting points of said electrical connection with a metallization level.

La ou chaque connexion électrique ainsi réalisée peut former une connexion locale s'étendant sur de courtes distances à l'échelle du circuit intégré.  The or each electrical connection thus formed may form a local connection extending over short distances on the scale of the integrated circuit.

Selon un second aspect, l'invention concerne en outre un circuit intégré comprenant au moins une connexion électriquement conductrice reliant sélectivement des éléments sur son substrat, dont au moins une portion de la surface est constitué d'un premier matériau, caractérisé en ce que la connexion est réalisée par un motif formé par au moins un deuxième matériau qui est conducteur, ce deuxième matériau formant en outre au moins une région conductrice sur la substrat par réaction avec le premier matériau de ce dernier. Le second matériau peut être du nitrure de titane.  According to a second aspect, the invention furthermore relates to an integrated circuit comprising at least one electrically conductive connection selectively connecting elements to its substrate, at least a portion of the surface of which consists of a first material, characterized in that the connection is made by a pattern formed by at least a second material which is conductive, this second material further forming at least one conductive region on the substrate by reaction with the first material thereof. The second material may be titanium nitride.

Les aspects optionnels présentés dans la cadre du procédé selon le premier objet, peuvent s'appliquer mutatis mutandis à ce circuit intégré selon le second objet, et ne seront pas repris ici par souci de concision.  The optional aspects presented in the context of the method according to the first object, may apply mutatis mutandis to this integrated circuit according to the second object, and will not be repeated here for the sake of brevity.

L'invention et les avantages qui en découlent apparaîtront plus clairement à la lecture des modes de réalisation préférés, donnés purement à titre d'exemples non-limitatifs, par référence aux dessins annexés, dans lesquelles: - la figure 1, déjà décrite, est une vue de plan d'un exemple d'interconnexions à un niveau local d'une zone d'un circuit intégré, les figures 2a à 2d, déjà décrites, sont des vues en coupe simplifiées montrant les étapes 0 successives intervenant lors d'une opération de photolithographie et de gravure sur un substrat en silicium, utilisée notamment lors de la réalisation d'interconnexions à un niveau local, la figure 3, déjà décrite, est une vue en coupe selon la ligne III-III' de la zone du circuit de la figure 1, pour le cas d'une structure d'interconnexions à un niveau local réalisée selon une technique classique à deux niveaux de diélectrique pre-métal, et - les figures 4a à 4g sont des vues en coupe d'une portion de plaquette silicium sur laquelle sont formées des interconnexions locales conformément au mode de réalisation préféré de l'invention, montrant l'évolution de la fabrication à travers des étapes successives.  The invention and the advantages resulting therefrom will emerge more clearly on reading the preferred embodiments, given purely by way of non-limiting examples, with reference to the appended drawings, in which: FIG. 1, already described, is a plan view of an example of interconnections at a local level of a zone of an integrated circuit, FIGS. 2a to 2d, already described, are simplified sectional views showing the successive steps 0 occurring during a photolithography and etching operation on a silicon substrate, used in particular when making interconnections at a local level, Figure 3, already described, is a sectional view along line III-III 'of the circuit zone of FIG. 1, for the case of a structure of interconnections at a local level made according to a conventional two-level pre-metal dielectric technique, and FIGS. 4a to 4g are sectional views of a portion of plat silicon on which are formed local interconnections according to the preferred embodiment of the invention, showing the evolution of manufacture through successive steps.

Le mode de réalisation préféré de l'invention est décrit dans le cadre de connexions locales sur un substrat en silicium, en reprenant l'exemple de la topographie de la figure 1.  The preferred embodiment of the invention is described in the context of local connections on a silicon substrate, using the example of the topography of FIG. 1.

Dans ce contexte, l'invention permet d'éliminer le niveau critique que constitue l'utilisation d'un type particulier de masque utilisé classiquement pour réaliser l'interconnexion au niveau local LIL, celuici devant, dans l'état de la technique, définir à la fois des trous et des tranchés.  In this context, the invention makes it possible to eliminate the critical level that constitutes the use of a particular type of mask conventionally used to achieve interconnection at the local level LIL, which before this, in the state of the art, defines both holes and trenches.

Dans l'exemple, cette élimination est obtenue, inter alla, par une exploitation judicieuse d'un matériau, ici sous forme d'un bicouche, pour réaliser les chemins conducteurs des interconnexions de niveau local. (Par contraste, dans l'état de la technique, lorsqu'un bicouche est utilisé, celui-ci ne sert qu'à former les points de contact, lesquels sont recouverts par des tranchées de tungstène formant les chemins conducteurs de l'interconnexion). Ainsi, on utilise la propriété conductrice d'un bicouche, en l'occurrence le couple cobalt/TiN, pour supprimer le niveau local d'interconnexion LIL.  In the example, this elimination is obtained, inter alla, by a judicious use of a material, here in the form of a bilayer, to make the conductive paths of the interconnections of local level. (By contrast, in the state of the art, when a bilayer is used, it only serves to form the contact points, which are covered by tungsten trenches forming the conductive paths of the interconnection) . Thus, the conductive property of a bilayer, in this case the cobalt / TiN couple, is used to suppress the local level of LIL interconnection.

Le bicouche ainsi utilisé conformément au mode de réalisation sert à réduire la résistance des contacts et la résistance des lignes, s'agissant d'une couche équipotentielle.  The bilayer thus used according to the embodiment serves to reduce the resistance of the contacts and the resistance of the lines, being an equipotential layer.

L'ensemble des étapes du présent mode de réalisation de l'invention est représentée par les figures 4a à 4g, qui reprennent comme élément de base la structure d'interconnexion locale représenté à la figure 1. Les parties structurelles de ces figures déjà décrites dans le cadre des figures précédentes ne seront pas répétées, et portent les mêmes références que ces dernières. Pour les mêmes raisons, toute étape de fabrication utilisée également dans le mode de réalisation de l'état de la technique et déjà décrite (cf. figures 2a-2d, 3) ne sera pas décrite à nouveau.  The set of steps of the present embodiment of the invention is represented by FIGS. 4a to 4g, which take as a basic element the local interconnection structure shown in FIG. 1. The structural parts of these figures already described in FIG. the frame of the previous figures will not be repeated, and have the same references as the latter. For the same reasons, any manufacturing step also used in the embodiment of the state of the art and already described (see Figures 2a-2d, 3) will not be described again.

La figure 4a reprend la configuration décrite dans le cadre de la figure 3, en ce qui concerne le substrat de silicium 28 constituant la plaquette, la tranchée d'isolation STI 3 constituant l'oxyde de champ, les grilles de contrôle 10, 12, 20 des transistors MOS, et les espaceurs de nitrure 38.  FIG. 4a shows the configuration described in the context of FIG. 3, with regard to the silicon substrate 28 constituting the wafer, the STI 3 insulation trench constituting the field oxide, the control gates 10, 12, MOS transistors, and nitride spacers 38.

Cette configuration initiale est obtenue selon des techniques classiques.  This initial configuration is obtained according to conventional techniques.

A partir de cette base, on procède à un nettoyage approprié de la surface de la plaquette 28.  From this base, an appropriate cleaning of the surface of the wafer 28 is carried out.

Ensuite, comme le montre la figure 4b, on dépose un bicouche 42 sur l'ensemble de la surface de la plaquette (ou du moins sur au moins une zone de sa surface destinée à recevoir des interconnexions locales si possible). Dans l'exemple, ce bicouche 42 est réalisé par dépôt d'une fine couche de cobalt 44 avec une couche de nitrure de titane (TiN) 46. Cette dernière constitue une couche d'enrobage, ou d'encapsulation, de la couche de cobalt 44.  Then, as shown in Figure 4b, a bilayer 42 is deposited on the entire surface of the wafer (or at least on at least one area of its surface to receive local interconnections if possible). In the example, this bilayer 42 is made by depositing a thin layer of cobalt 44 with a layer of titanium nitride (TiN) 46. The latter constitutes a coating layer, or encapsulation, of the layer of cobalt 44.

Une transformation par recuit rapide (connu par l'acronyme anglais RTP, pour "Rapid Thermal Processing") est ensuite effectuée pour faire réagir le cobalt avec le silicium en contact de la plaquette 28, pour y former du siliciure de cobalt (CoSi).  Rapid annealing (RTP) is then performed to react cobalt with silicon in contact with wafer 28 to form cobalt silicide (CoSi).

Comme le montre la figure 4c, le CoSi n'est donc formé qu'aux endroits où le cobalt 44 a été en contact avec le silicium. Ainsi, il ne se forme pas sur les surfaces comprenant de l'oxyde ou du nitrure, notamment sur les portions constituées par les espaceurs 38 et sur l'oxyde de champ 3 constitué par la tranchée d'isolation (STI). Dans ces portions, le cobalt non réagi reste à l'état métallique pur.  As shown in FIG. 4c, the CoSi is therefore formed only at the places where the cobalt 44 has been in contact with the silicon. Thus, it does not form on the surfaces comprising oxide or nitride, in particular on the portions constituted by the spacers 38 and on the field oxide 3 constituted by the isolation trench (STI). In these portions, the unreacted cobalt remains in the pure metal state.

On obtient ainsi deux zones de formation de CoSi - une première zone 48 sur les éléments de silicium en relief, en l'occurrence le sommet des grilles de contrôle 10, 12, 20, et - une seconde zone 50 au niveau du silicium du substrat.  Thus two CoSi formation zones are obtained - a first zone 48 on the raised silicon elements, in this case the top of the control gates 10, 12, 20, and a second zone 50 at the silicon level of the substrate. .

Ces zones 48, 50 laissent exposées en surface la couche conductrice de TiN.  These zones 48, 50 leave the TiN conductive layer exposed on the surface.

Globalement, le bicouche 42, ayant réagi ou pas, reste conducteur.  Overall, the bilayer 42, having reacted or not, remains conductive.

De la sorte, on peut former la topographie de l'ensemble des lignes d'interconnexion locale en utilisant le bicouche, par retrait sélectif des portions de celui-ci non affectées aux lignes conductrices.  In this way, it is possible to form the topography of all the local interconnection lines by using the bilayer, by selective removal of the portions thereof that are not assigned to the conductive lines.

Conformément au mode de réalisation, ce retrait sélectif est réalisé non pas en pleine plaque, mais en plaque masquée. De manière remarquable, il suffit alors de masquer les zones que l'on souhaite relier électriquement, puis de plonger la plaquette dans le bain de retrait sélectif. Le cobalt et le TiN ne seront retirés qu'aux endroits où la résine est ouverte (exposée).  According to the embodiment, this selective removal is performed not in full plate, but in masked plate. Remarkably, it is then enough to hide the areas that are to be electrically connected, then plunge the wafer in the selective removal bath. Cobalt and TiN will only be removed where the resin is open (exposed).

On garde ainsi le bicouche cobalt/TiN 42 dans les zones protégées par la résine, et obtient alors une interconnexion électrique basse impédance qui correspond fonctionnellement au niveau local d'interconnexion obtenu selon les techniques classiques.  The cobalt / TiN 42 bilayer is thus kept in the areas protected by the resin, and then obtains a low impedance electrical interconnection which corresponds functionally to the local level of interconnection obtained according to conventional techniques.

Pour ce faire, le mode de réalisation met en oeuvre une photolitographie selon le principe présenté par référence à la figure 2. Dans le cas d'espèce, le retrait sélectif s'opère par voie humide.  To do this, the embodiment implements photolithography according to the principle presented with reference to FIG. 2. In the case in point, the selective shrinkage is carried out wet.

Comme le montre la figure 4d, on dépose sur la structure de la figure 4c une couche de résine photo résiste 26, sur laquelle on appose un masque de photolithographie 22, dont les parties masquées 22a se situent à l'aplomb des emplacements du circuit des lignes conductrices d'interconnexion à réaliser. On note que cette étape de photolithographie correspond à l'inverse de celle utilisée classiquement pour la réalisation d'interconnexions locales, en ce sens que les ouvertures 24 définissent des lignes à la surface du substrat (et sur les éléments de faible relief, tels que les grilles, qui sont sensiblement dans le même plan focal), et non pas des tranchées et des trous.  As shown in FIG. 4d, a layer of resist photoresist 26 is deposited on the structure of FIG. 4c, on which a photolithography mask 22 is affixed, the masked portions 22a of which are in line with the locations of the circuit of FIG. conductive lines of interconnection to achieve. Note that this photolithography step corresponds to the inverse of that conventionally used for the realization of local interconnections, in that the openings 24 define lines on the surface of the substrate (and on the elements of low relief, such as the grids, which are substantially in the same focal plane), and not trenches and holes.

Comme le montre la figure 4e, à l'issu de l'exposition au rayonnement 30 à travers le masque de photolithographie 22, et du retrait sélectif de la résine 26, la résine restante définit un masque de gravure qui masque les emplacements destinés uniquement aux lignes d'interconnexion. On note que cette approche contraste avec le procédé conventionnel qui nécessite la réalisation de tranchées.  As shown in FIG. 4e, at the end of the exposure to radiation 30 through the photolithography mask 22, and the selective removal of the resin 26, the remaining resin defines an etching mask that masks the locations intended solely for interconnection lines. It is noted that this approach contrasts with the conventional method which requires the realization of trenches.

Ensuite, on effectue un retrait chimique au moyen d'un bain humide qui est sélectif au CoSi, permettant de retirer, aux parties exposées par le masque de résine 26, le TiN et le cobalt n'ayant pas réagis lors du traitement thermique (i.e. se situant, dans le cas illustré, sur les espaceurs de nitrure 38 et sur les tranchées d'isolation STI 2).  Then, a chemical shrinkage is carried out by means of a wet bath which is selective with CoSi, making it possible to remove, at the parts exposed by the resin mask 26, unreacted TiN and cobalt during the heat treatment (ie lying, in the illustrated case, on the nitride spacers 38 and on the insulation trenches STI 2).

Comme le montre la figure 4f, ce retrait sélectif laisse ainsi des zones dites "siliciurées" 48, 50, dépourvues de TiN conducteur.  As shown in FIG. 4f, this selective shrinkage thus leaves so-called "silicide" zones 48, 50 devoid of conducting TiN.

Ensuite, on retire la résine du masque et on 35 effectue les opérations de déposition de diélectrique pré-métallique PMD et de formation des contacts sous forme de trous de contact 52 (plus connus par le terme anglais "plug") de la structure PMD, donnant le résultat illustré à la figure 4g. On note qu'un seul niveau de diélectrique pré-métallique PMD est nécessaire.  Subsequently, the resin is removed from the mask and PMD pre-metal dielectric deposition and contact formation operations in the form of contact holes 52 (better known by the English term "plug") of the PMD structure are performed. giving the result illustrated in Figure 4g. It is noted that only one level of pre-metallic dielectric PMD is necessary.

Plus particulièrement, ces opérations comprennent Il. Le dépôt de la couche unique de diélectrique pré-métallique PMD, comprenant: I1.1. la réalisation de plages de contact en nitrure, du type sans bordure (connu par le terme anglais de "borderless nitride"; I1.2. le dépôt d'oxyde de silicium SiO2, soit sans dopage, soit avec dopage. Dans ce dernier cas, on peut utiliser, entre autres, un dopage de bore et de phosphore pour obtenir du dioxyde de silicium dopé bore/phosphore, (connu par l'acronyme anglais BPSG, pour "Boron/Phosphorous-Doped Silicon Oxide"). Cela peut être obtenu en utilisant une technique de dépôt chimique subatmosphérique en phase vapeur (connu par l'acronyme anglais SACVD, pour "Sub-Atmospheric Chemical Vapour Deposition") ou par tout autre moyen adapté, comme le dépôt chimique en phase vapeur renforcé par plasma (connu par l'acronyme anglais PECVD, pour "Plasma-Enhanced Chemical Vapour Deposition), ou de dépôt en plasma à haute densité (connu par l'acronyme anglais HDP, pour "High-Density Plasma), etc. I1.3. une étape de densification de la couche unique de diélectrique pré-métallique ainsi formée, avec transformation du matériau CoSi en CoSi2.  More particularly, these operations include II. The deposition of the single layer of pre-metallic PMD dielectric, comprising: I1.1. the realization of nitride contact pads, of the type without border (known by the term "borderless nitride"), the deposit of silicon oxide SiO 2, either without doping or with doping, in the latter case it is possible, among other things, to use boron and phosphorus doping to obtain boron / phosphorus doped silicon dioxide (known by the acronym BPSG for "Boron / Phosphorous-Doped Silicon Oxide"). obtained using a subatmospheric chemical vapor deposition technique (known by the acronym SACVD, for "Sub-Atmospheric Chemical Vapor Deposition") or by any other suitable means, such as plasma-enhanced chemical vapor deposition (known by the acronym PECVD, for "Plasma-Enhanced Chemical Vapor Deposition", or deposition in high-density plasma (known by the acronym HDP, for "High-Density Plasma"), etc. I1.3. of densification of the single layer of pre-metallic dielectric thus formed, with conversion of CoSi material to CoSi2.

I2. Photolithographie et gravure contact, comprenant: I2.1. une photolithographie de type contact, I2.2. une gravure de type contact, et I2.3. le retrait de la résine.  I2. Photolithography and contact etching, comprising: I2.1. contact type photolithography, I2.2. an etching of the contact type, and I2.3. the removal of the resin.

De ce qui précède, on remarque que l'une des originalités du procédé réside dans le fait que l'on effectue un retrait sélectif du TiN et du cobalt, qui n'ont pas réagis lors du traitement thermique, en utilisant un retrait sélectif masqué, en l'occurrence par une étape de photolithographie.  From the foregoing, it is noted that one of the original features of the process is that selective removal of TiN and cobalt, which have not reacted during the heat treatment, is carried out using masked selective shrinkage. , in this case by a photolithography step.

Bien que le masque utilisé pour cette opération soit spécifique, il est moins critique que le masque utilisé classiquement pour obtenir les lignes locales d'interconnexion avec le tungstène.  Although the mask used for this operation is specific, it is less critical than the mask conventionally used to obtain the local interconnection lines with tungsten.

En effet, le masque pour le retrait sélectif utilisé conformément à l'invention n'a pas à définir à la fois des trous et des tranchés. Ce masque ne définit que des lignes. Il n'y donc pas le problème lié à une profondeur de champ conséquente qui apparaît avec les reliefs constitués notamment par les trous.  Indeed, the mask for selective removal used in accordance with the invention does not have to define both holes and trenches. This mask only defines lines. There is therefore no problem associated with a substantial depth of field which appears with the reliefs formed in particular by the holes.

L'invention peut être utilisée avec tout matériau pouvant former dusilicide. Le métal utilisé peut être, par exemple, du titane, du nickel, etc. soit tout métal réfractaire qui entre la définition du siliciure.  The invention can be used with any material that can form a killing agent. The metal used may be, for example, titanium, nickel, etc. any refractory metal that enters the definition of silicide.

Par ailleurs, le siliciure peut être remplacé par d'autres compositions selon l'application envisagée, en apportant les adaptations qui s'imposent aux enseignements donnés dans le contexte de présente description donnée dans le cadre du siliciure.  Furthermore, the silicide can be replaced by other compositions depending on the intended application, making the necessary adaptations to the teachings given in the context of this description given in the context of silicide.

Plus généralement, la technique venant d'être décrite peut être appliquée à tous les métaux réfractaires encapsulés (Ti, Ni, ....).  More generally, the technique just described can be applied to all encapsulated refractory metals (Ti, Ni, ....).

Une application avantageuse de la technique conforme à l'invention est la fabrication de composant électroniques de faible consommation électrique, notamment pour véhiculer du signal.  An advantageous application of the technique according to the invention is the manufacture of electronic components of low power consumption, in particular for conveying the signal.

Le procédé conforme à l'invention est remarquable en ce qu'il permet: - de passer d'un masque critique à décalage de phase à un masque critique standard (passage d'un masque où l'on défini des tranchées et des trous à un masque où l'on défini uniquement des lignes; - de supprimer la gravure du niveau local d'interconnexion, très critique au niveau des bords de zone d'oxyde de champ; - de réaliser le diélectrique pré-métallique en une seule fois, grâce à la suppression d'un niveau de diélectrique pré-métallique avec le dépôt de BPSG, dépôt espaceur, dépôt de tungstène et de tungstène avec polissage/planarisation chimico-mécanique.  The process according to the invention is remarkable in that it makes it possible: to change from a phase shift critical mask to a standard critical mask (passage of a mask where trenches and holes are defined); a mask in which only lines are defined, - to eliminate the etching of the local interconnection level, which is very critical at the level of the field oxide zone edges, - to make the pre-metallic dielectric at once, thanks to the removal of a pre-metallic dielectric level with BPSG deposition, spacer deposit, tungsten and tungsten deposition with polishing / chemical mechanical planarization.

Claims (27)

Revendicationsclaims 1. Procédé de réalisation d'au moins une connexion électriquement conductrice reliant sélectivement des éléments (2, 4, 10, 12) sur un substrat (28) de circuit intégré (8), caractérisé en ce qu'il comprend les étapes de: - réaliser lesdits éléments (2, 4, 10, 12) sur un substrat dont au moins une portion de la surface est constituée d'un premier matériau, déposer, sur le substrat et lesdits éléments, au moins un deuxième matériau, qui est conducteur (42, 44, 46) et susceptible de créer une réaction avec le premier matériau pour former un matériau conducteur à la surface du substrat, - traiter le substrat pour réaliser ladite réaction, - réaliser un retrait sélectif du deuxième matériau n'ayant pas réagi avec ledit premier matériau, pour laisser du deuxième matériau selon un motif qui correspond à au moins une partie de la connexion.  A method of producing at least one electrically conductive connection selectively connecting elements (2, 4, 10, 12) to an integrated circuit substrate (28), characterized in that it comprises the steps of: - Making said elements (2, 4, 10, 12) on a substrate of which at least a portion of the surface consists of a first material, depositing, on the substrate and said elements, at least a second material, which is conductive (42, 44, 46) and capable of creating a reaction with the first material to form a conductive material on the surface of the substrate, - treating the substrate to carry out said reaction, - selectively removing the second unreacted material with said first material, to leave second material in a pattern that corresponds to at least a portion of the connection. 2. Procédé selon la revendication 1, caractérisé en ce que le retrait sélectif du deuxième matériau n'ayant pas réagi est réalisé par au moins un masque (46) définissant ledit motif.  2. Method according to claim 1, characterized in that the selective removal of the unreacted second material is performed by at least one mask (46) defining said pattern. 3. Procédé selon la revendication 1 ou 2, caractérisé en ce que le retrait sélectif du deuxième matériau n'ayant pas réagi est réalisé selon une technique de gravure par voie humide.  3. Method according to claim 1 or 2, characterized in that the selective removal of the unreacted second material is carried out according to a wet etching technique. 4. Procédé selon la revendication 3, caractérisé en ce que le retrait sélectif du deuxième matériau n'ayant pas réagi est réalisé par immersion du substrat (28) et de son masque (46) dans un bain.  4. Method according to claim 3, characterized in that the selective removal of the unreacted second material is made by immersing the substrate (28) and its mask (46) in a bath. 5. Procédé selon l'une quelconque des revendications 1 à 4, caractérisé en ce que au moins une connexion relie un desdits éléments (2, 4, 10, 12) à une aire du substrat rendue conductrice par ladite réaction entre le premier et le deuxième matériau.  5. Method according to any one of claims 1 to 4, characterized in that at least one connection connects one of said elements (2, 4, 10, 12) to an area of the substrate made conductive by said reaction between the first and the second material. 6. Procédé selon l'une quelconque des revendications 1 à 5, caractérisé en ce qu'au moins une aire du substrat rendue conductrice par ladite réaction entre le premier et le deuxième matériau est utilisée comme point de base pour un contact par trou, connu par le terme anglais de "plug", permettant une connexion vers un point de contact superposé.  6. Method according to any one of claims 1 to 5, characterized in that at least one area of the substrate made conductive by said reaction between the first and second material is used as a base point for a contact hole, known by the English word "plug", allowing a connection to a superimposed point of contact. 7. Procédé selon l'une quelconque des revendications 1 à 6, caractérisé en ce que le retrait sélectif réalise de multiples connexions.  7. Method according to any one of claims 1 to 6, characterized in that selective removal carries out multiple connections. 8. Procédé selon l'une quelconque des revendication 1 à 7, caractérisé en ce que la connexion est réalisée sous forme de ligne/les connexions sont réalisées uniquement sous forme de lignes.  8. Method according to any one of claims 1 to 7, characterized in that the connection is made in the form of line / connections are made only in the form of lines. 9. Procédé selon l'une quelconque des revendications 2 à 8, caractérisé en ce que le masque (46) comporte un motif uniquement de ligne(s) pour 35 définir la ou chaque connexion.  9. Method according to any one of claims 2 to 8, characterized in that the mask (46) comprises a pattern of only line (s) to define the or each connection. 10. Procédé selon l'une quelconque des revendications 2 à 9, caractérisé en ce que le masque (46) est formé par une technique de photolithographie.  10. Method according to any one of claims 2 to 9, characterized in that the mask (46) is formed by a photolithography technique. 11. Procédé selon l'une quelconque des revendications 1 à 10, caractérisé en ce que ladite étape de traitement comprend un traitement thermique rapide, connu par l'acronyme anglais RTP, pour "Rapid Thermal Processing".  11. Method according to any one of claims 1 to 10, characterized in that said processing step comprises a rapid thermal treatment, known by the acronym RTP, for "Rapid Thermal Processing". 12. Procédé selon l'une quelconque des revendications 1 à 11, caractérisé en ce que le deuxième matériau déposé (42, 44, 46), ou l'un au moins des matériaux déposés, est un métal.  12. Method according to any one of claims 1 to 11, characterized in that the second deposited material (42, 44, 46), or at least one of the deposited materials, is a metal. 13. Procédé selon l'une quelconque des  13. Process according to any one of revendications 1 à 12, caractérisé en ce que le  Claims 1 to 12, characterized in that the deuxième matériau déposé (46) comprend un métal réfractaire.  second deposited material (46) comprises a refractory metal. 14. Procédé selon l'une quelconque des  14. Process according to any one of revendications 1 à 13, caractérisé en ce que le  Claims 1 to 13, characterized in that the deuxième matériau déposé (44) comprend au moins l'un parmi.  second deposited material (44) comprises at least one of. - du cobalt, - du titane, - du nickel.  - cobalt, - titanium, - nickel. 15. Procédé selon l'une quelconque des revendications 1 à 14, caractérisé en ce que l'étape de dépôt d'au moins un deuxième matériau consiste à déposer un bicouche (42) formé d'une première composante (44) qui est recouverte, ou encapsulée, par une deuxième composante (46), différente le la première.  15. Method according to any one of claims 1 to 14, characterized in that the deposition step of at least a second material consists of depositing a bilayer (42) formed of a first component (44) which is covered , or encapsulated, by a second component (46), different from the first one. 16. Procédé selon la revendication 15, caractérisé en ce que la première composante (44) du bicouche comprend du cobalt, et en ce que la seconde composante, qui la recouvre ou l'encapsule, comprend du nitrure de titane (TiN), ladite première composante étant en contact avec le premier matériau.  16. The method of claim 15, characterized in that the first component (44) of the bilayer comprises cobalt, and in that the second component, which covers or encapsulates, comprises titanium nitride (TiN), said first component being in contact with the first material. 17. Procédé selon l'une quelconque de revendications 1 à 16, caractérisé en ce que ledit premier matériau formant au moins une portion de ladite surface exposée du substrat (28) est du silicium.  17. Method according to any one of claims 1 to 16, characterized in that said first material forming at least a portion of said exposed surface of the substrate (28) is silicon. 18. Procédé selon 1a revendication 17, caractérisé en ce que le matériau conducteur formé par ladite réaction est un siliciure.  18. The method of claim 17, characterized in that the conductive material formed by said reaction is a silicide. 19. Procédé selon la revendication 18, caractérisé en ce que ledit siliciure est au moins l'un parmi: - un siliciure de cobalt (CoSi), - un siliciure de titane, - un siliciure de nickel.  19. The method of claim 18, characterized in that said silicide is at least one of: - a cobalt silicide (CoSi), a titanium silicide, a nickel silicide. 20. Procédé selon l'une quelconque des  20. Process according to any one of revendications 1 à 19, caractérisé en ce qu'il  claims 1 to 19, characterized in that comprend en outre la réalisation d'une structure dite diélectrique prémétallique (PMD) unique comprenant au moins un contact par trou, connu par le terme anglais de "plug", permettant une connexion vers un point de contact superposé (52) destiné à relier des points de ladite connexion électrique avec un niveau de métallisation (34).  further comprises producing a single pre-metal dielectric (PMD) structure comprising at least one hole contact, known by the English term "plug", allowing a connection to a superimposed contact point (52) for connecting points of said electrical connection with a metallization level (34). 21. Procédé selon l'une quelconque des revendications 1 à 20, caractérisé en ce que la ou chaque connexion électrique ainsi réalisée est une connexion locale s'étendant sur de courtes distances à l'échelle du circuit intégré.  21. Method according to any one of claims 1 to 20, characterized in that the or each electrical connection thus made is a local connection extending over short distances on the scale of the integrated circuit. 22. Circuit intégré (8) comprenant au moins une connexion électriquement conductrice reliant sélectivement des éléments (2, 4, 10, 12) sur son substrat (28), dont au moins une portion de la surface est constitué d'un premier matériau, caractérisé en ce que la connexion est réalisée par un motif formé par au moins un deuxième matériau qui est conducteur, ce deuxième matériau formant en outre au moins une région conductrice sur la substrat par réaction avec le premier matériau (28) de ce dernier.  An integrated circuit (8) comprising at least one electrically conductive connection selectively connecting elements (2, 4, 10, 12) to its substrate (28), at least a portion of the surface of which is made of a first material, characterized in that the connection is made by a pattern formed by at least a second material which is conductive, this second material further forming at least one conductive region on the substrate by reaction with the first material (28) thereof. 23. Circuit intégré selon la revendication 22, caractérisé en ce que le deuxième matériau (44) comprend du cobalt.  23. Integrated circuit according to claim 22, characterized in that the second material (44) comprises cobalt. 24. Circuit intégré selon l'une quelconque des revendications 22 ou 23, caractérisé en ce que le deuxième matériau (46) comprend un métal réfractaire.  24. Integrated circuit according to any one of claims 22 or 23, characterized in that the second material (46) comprises a refractory metal. 25. Circuit intégré selon la revendication 24, caractérisé en ce que le deuxième matériau est du nitrure de titane (TiN).  25. Integrated circuit according to claim 24, characterized in that the second material is titanium nitride (TiN). 26. Circuit intégré selon l'une quelconque des  26. Integrated circuit according to any of revendications 22 à 25, caractérisé en ce qu'il  claims 22 to 25, characterized in that comprend en outre une structure dite diélectrique pré-métallique (PMD) unique comprenant au moins un contact par trou, connu par le terme anglais de "plug", permettant une connexion vers un point de contact superposé (52) et destiné à relier des points de ladite connexion conductrice avec un niveau de métallisation (34).  further comprises a single pre-metal dielectric (PMD) structure comprising at least one hole contact, known by the English term "plug", allowing a connection to a superimposed contact point (52) and for connecting points said conductive connection with a metallization level (34). 27. Circuit intégré selon l'une quelconque des revendications 22 à 26, caractérisé en ce que ladite connexion électrique est une connexion locales s'étendant sur de courtes distances à l'échelle du circuit intégré.  27. Integrated circuit according to any one of claims 22 to 26, characterized in that said electrical connection is a local connection extending over short distances on the scale of the integrated circuit.
FR0311987A 2003-10-14 2003-10-14 Multiple short local electrical connections for selective linkage of integrated circuit elements comprise masked selective humid attack of deposited metal Pending FR2860920A1 (en)

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