FR2843695A1 - Cosmetic cleansing or make-up remover composition includes a make-up removing oil and an amphiphilic polymer derived from an ethylenically unsaturated sulfonate monomer - Google Patents

Abstract

Cosmetic cleansing or make-up remover composition comprising an oil phase dispersed in an aqueous phase includes a make-up removing oil and an amphiphilic polymer derived from an ethylenically unsaturated sulfonate monomer. An Independent claim is also included for a cosmetic make-up removing or cleansing method comprising applying the above composition to the skin, lips and/or eyes.

Description

<Desc / Clms Page number 1>

The invention relates to a cosmetic makeup remover and / or cleaning composition in the form of an oil-in-water emulsion comprising a particular amphiphilic polymer and at least 40% cleansing oil. This composition is used in particular for removing makeup and / or cleaning the skin, lips and / or eyes.

Cleansers and facial cleansers in the form of oil-in-water (O / W) emulsions have the advantage of providing freshness due to the presence of water in the external aqueous phase, but However, these products have the disadvantage of being relatively ineffective because the oily phase being the internal phase, it is not directly available to dissolve the fats and, as a result, removing make-up is less effective. However, for the cleansing of the face and more especially for the make-up removal which consists in removing all the make-up products, the women seek to obtain a make-up removal the most effective possible.

In these O / W emulsions, the oil content is generally around 20% of the total weight of the composition, in order to reconcile cleansing efficiency and cosmetic comfort, since the cleansing oils have the advantage of having a very good cleansing power but, when they are at a high rate, they usually give on the skin, a heavy touch and form a greasy film, not penetrating the skin.

Moreover, the increase in the amount of oily phase (or fat phase) can compromise the stability of the composition, and it is then necessary to add an emulsifying agent, which, present in a sufficient amount, will stabilize the emulsion . However, for reasons of safety, especially when the composition is used for removing makeup from the eyes, it is important to use emulsions which have no or few emulsifiers. To ensure the stability of the emulsions without an emulsifying agent, it is known to gel the external aqueous phase with an aqueous gelling agent. However, when a large quantity of oils is introduced into a gelled aqueous phase with a conventional aqueous gelling agent, the stability of the composition is compromised beyond a certain amount of oil if it is not added in addition. an emulsifying surfactant. And it is all the more difficult to make emulsions without an emulsifying agent with a high oil content that the medium is fluid.

Thus, make-up removing compositions are subject to 3 criteria: a good make-up removal efficiency; - a good cosmetic comfort; - and a good tolerance.

Also, there remains the need for a cosmetic cleansing and / or make-up remover in the form of an oil-in-water emulsion, which is effective in particular for removing make-up from waterproof or transfer-free make-ups, and therefore which contain a large amount of oil (at least 40%), while being stable and having good cosmetic properties.

<Desc / Clms Page number 2>

The Applicant has now found an uncrosslinked amphiphilic polymer to achieve these objectives, regardless of the viscosity of the composition, that is to say that it is fluid or thick.

The subject of the present invention is a cosmetic cleaning and / or makeup removal composition, comprising an oily phase dispersed in an aqueous phase, characterized in that it comprises at least one non-crosslinked amphiphilic polymer comprising at least two hydrophobic side members, and that the oily phase comprises at least one makeup removal oil and constitutes at least 40% by weight relative to the total weight of the composition.

Amphiphilic polymer is understood to mean any polymer comprising both a hydrophilic part and a hydrophobic part.

The polymer used in the composition of the invention is a hydrophilic polymer. The term "hydrophilic polymer" means any polymer that is soluble or dispersible in water, either as such or in neutralized form.

The term "non-crosslinked polymer" means a polymer that has not reacted with crosslinking agents and therefore does not contain crosslinking groups. It can be a linear or connected polymer. The polymer used in the composition of the invention is preferably linear.

The composition being a cosmetic composition, it comprises a physiologically acceptable medium. In the present application, the term "physiologically acceptable medium" means a medium that is compatible with all keratin materials such as the skin, including the scalp, the nails, the mucous membranes, the eyes and the hair, or any other cutaneous zone of the body.

The composition of the invention, even free of any emulsifying agent, has excellent stability, regardless of its viscosity and regardless of the oil content, and, moreover, it has a very good removal efficiency. Moreover, the cosmetic feel of the composition according to the invention is very pleasant: there is no sticky effect or formation of fatty film, and the composition is fresh when applied to the skin.

The composition according to the invention preferably has a viscosity ranging from 0.1 Pa.s (1 poise) to 23 Pa.s (230 poise), preferably from 0.1 Pa.s (1 poise) to 15 Pa. s. (150 poises), this viscosity being measured at room temperature (25 ° C.) with the RM180 Rheomat apparatus from METTLER.

The composition according to the invention generally has a pH ranging from 4 to 9, more preferably from 6 to 8 and more preferably from 6.5 to 8.

Amphiphilic Polymers The non-crosslinked amphiphilic polymers used according to the invention are polymers that can be obtained from at least one monomer

<Desc / Clms Page number 3>

 hydrophilic A with ethylenic unsaturation and at least one hydrophobic monomer B. They are soluble or dispersible in water, in neutralized form.

The monomer A comprises at least one heteroatom which may be an oxygen atom, a nitrogen atom, a sulfur atom, a phosphorus atom, a chlorine atom, a fluorine atom or their mixtures. Preferably, the monomer A has a strong acid function, in particular a sulphonic acid or phosphonic acid function.

The hydrophobic monomer B comprises at least one hydrophobic radical chosen from: linear or saturated C 6 -C 50 alkyl radicals (for example n-hexyl, n-octyl, n-decyl, n-dodecyl, n-hexadecyl, n octadecyl, n-behenyl, oleyl), branched (for example isostearic) or cyclic (for example cyclododecane or adamantane); fluorinated or alkylfluorinated C6-C30 radicals (for example the group of formula - (CH2) 2- (CF2) 9-CF3); the cholesteryl radical or the radicals derived from cholesterol (for example, cholesteryl hexanoate); polycyclic aromatic groups such as naphthalene or pyrene; the silicone or alkylsilicone or alkylfluorosilicone radicals.

Among these radicals, alkyl, linear and branched radicals are more particularly preferred. Preferably, the hydrophobic monomer is an alkyl chain comprising from 6 to 30 carbon atoms, more preferably from 6 to 22 carbon atoms and even more preferably from 6 to 18 atoms and more particularly from 12 to 18 carbon atoms.

Preferably, the polymers in accordance with the invention are partially or completely neutralized with a mineral base (sodium hydroxide, potassium hydroxide, aqueous ammonia) or an organic base such as mono-, di- or tri-ethanolamine, aminomethylpropanediol, N- methylglucamine, basic amino acids such as arginine and lysine, and mixtures of these compounds.

The amphiphilic polymers in accordance with the invention generally have a number-average molecular weight ranging from 1000 to 20,000,000 g / mole, preferably ranging from 20,000 to 5,000,000 and still more preferably from 100,000 to 1,500,000 g / mole. mole.

In particular, the polymers used according to the invention are preferably amphiphilic polymers capable of being obtained from at least one ethylenically unsaturated monomer containing a sulphonic group, in free form or partially or completely neutralized, and from minus one hydrophobic monomer.

The monomers with ethylenic unsaturation containing sulphonic groups may be chosen in particular from vinylsulfonic acid, styrenesulphonic acid, (meth) acrylamido (C1-C22) alkylsulphonic acids, N- (C, -C22) alkyl-

<Desc / Clms Page number 4>

 (meth) acrylamido (C1-C22) alkylsulfonic acids such as undecyl-acrylamidomethanesulfonic acid, as well as their partially or completely neutralized forms, and mixtures thereof.

According to a preferred embodiment of the invention, the (meth) acrylamido (C1-C22) alkylsulfonic acids, such as, for example, acrylamidomethanesulfonic acid, acrylamido acid, are used as ethylenically unsaturated monomers containing a sulfonic group. ethanesulfonic acid, acrylamidopropanesulfonic acid, 2-acrylamido-2-methylpropanesulfonic acid, 2-methacrylamido-2-methylpropanesulfonic acid, 2-acrylamido-n-butanesulfonic acid, 2-acid 2,4,4-trimethylpentanesulfonic acid, 2-methacrylamido-dodecyl-sulfonic acid, 2-acrylamido-2,6-dimethyl-3-heptanesulfonic acid, and their partially or completely neutralized forms, and their mixtures.

More particularly, 2-acrylamido-2-methylpropanesulfonic acid (AMPS) and its partially or completely neutralized forms are used.

The amphiphilic polymers in accordance with the invention may especially be chosen from AMPS random amphiphilic polymers modified by reaction with a n-monoalkylamine or a C6-C22 di-n-alkylamine, such as those described in document WO-A -00/31154 (forming part of the content of the description). They may also be chosen from the polymers described in documents EP-A-1,069,142 and EP-A-1,138,703 (forming an integral part of the content of the description).

In addition to the monomers indicated above, these polymers may also contain other hydrophilic ethylenically unsaturated monomers (not comprising a hydrophobic fatty chain) chosen, for example, from (meth) acrylic acids, their p-substituted alkyl derivatives or their esters. obtained with monoalcohols or mono- or polyalkylene glycols, (meth) acrylamides, vinylpyrrolidone, maleic anhydride, itaconic acid, maleic acid, cationic monomers such as diallyl dimethylammonium chloride, or mixtures of these compounds.

The preferred polymers used of the invention are chosen from AMPS amphiphilic copolymers and at least one hydrophobic monomer containing ethylenic unsaturation, comprising at least one hydrophobic part having from 6 to 30 carbon atoms, more preferably from 6 to 22. carbon atoms, more preferably 6 to 18 carbon atoms and more particularly 12 to 18 carbon atoms.

As indicated above, these AMPS copolymers may also contain one or more ethylenically unsaturated monomers having no fatty chain, such as (meth) acrylic acids, their p-substituted alkyl derivatives or their esters obtained with monoalcohols. or mono- or polyalkylene glycols, (meth) acrylamides, vinylpyrrolidone, maleic anhydride,

<Desc / Clms Page number 5>

 itaconic acid, maleic acid, cationic monomers or mixtures of these compounds.

Such AMPS copolymers are described in particular in patent application EP-A-750899, US-A-5,089,578 and in the following Yotaro Morishima publications: Self-assembly amphiphilic polyelectrolytes and their nanostructures Chinese Journal of Polymer Science Flight. 18, N 40, (2000), 323-336; - Miscellanous formation of random copolymers of sodium 2- (acrylamido) -2-methylpropanesulfonate and a non-ionic surfactant macromonomer in water as studied by fluorescence and dynamic light scattering - Macromolecules 2000, Vol.

33, No. 10-3694-3704; - Solution properties de miscelle les formation une non ionic moieties covalently bound à une polyelectrolyte: Langmuir, 2000, Vo1.16, N 12, 5324-5332; Stimuli responsive amphiphilic copolymers of sodium 2- (acrylamido) -2-methylpropanesulfonate and associative macromonomers - Polym. Preprint, Div.

Polym. Chem. 1999, 40 (2), 220-221.

dans laquelle R, et R3, identiques ou différents, désignent un atome d'hydrogène ou un radical alkyle linéaire ou ramifié en (C1-C6) (de préférence méthyle) ; Y désigne 0 ou NH ; R2 désigne un radical hydrocarboné hydrophobe comportant au moins de 6 à 30 atomes de carbone, plus préférentiellement de 6 à 22 atomes de carbone, encore plus préférentiellement de 6 à 18 atomes de carbone et plus particulièrement de 12 à 18 atomes de carbone ; x désigne un nombre de moles d'oxyde d'alkylène et varie de 0 à 100. The hydrophobic monomers with ethylenic unsaturation of these particular copolymers are preferably chosen from acrylates, alkyl acrylates, acrylamides or alkyl acrylamides of formula (I) below:

in which R and R3, which may be identical or different, denote a hydrogen atom or a linear or branched (C1-C6) alkyl radical (preferably methyl); Y is 0 or NH; R2 denotes a hydrophobic hydrocarbon radical containing at least 6 to 30 carbon atoms, more preferably 6 to 22 carbon atoms, even more preferably 6 to 18 carbon atoms and more particularly 12 to 18 carbon atoms; x denotes a number of moles of alkylene oxide and ranges from 0 to 100.

The radical R 2 is preferably chosen from linear C 6 -C 18 (for example n-hexyl, n-octyl, n-decyl, n-hexadecyl, n-dodecyl), branched or cyclic (for example cyclododecane (C 12)) alkyl radicals. or adamantane (C10)); perfluorinated C6-C18 alkyl radicals (for example the group of formula - (CH2) 2- (CF2) g-CF3); the cholesteryl radical (C27) or a cholesteryl ester residue such as the cholesteryl oxyhexanoate group; polycyclic aromatic groups such as naphthalene or pyrene. Among these radicals, we prefer

<Desc / Clms Page number 6>

 particularly the linear alkyl radicals and more particularly the n-dodecyl, n-hexadecyl, n-octadecyl radicals or their mixtures.

According to a particularly preferred form of the invention, the monomer of formula (I) comprises at least one alkylene oxide unit (x # 1), and preferably several alkylene oxide units constituting a polyoxyalkylene chain. The polyoxyalkylene chain is preferably composed of ethylene oxide units and / or propylene oxide units. Preferably, the monomer of formula (I) comprises only units of ethylene oxide units. The number of oxyalkylenated units (or number of moles of alkylene oxide) generally varies from 3 to 100, more preferably from 3 to 50 and even more preferably from 7 to 25.

(C,-Cl6)alkyl(méth)acrylamide ou de motifs (C$ C,6)alkyl(méth)acrylate par rapport au polymère, tels que ceux décrits dans le document EP-A-750 899 ; - les terpolymères comportant de 10 à 90% en mole de motifs acrylamide, de 0,1 à 10% en mole de motifs AMPS et de 5 à 80% en mole de motifs n-(C6-C18)alkylacrylamide, tels que ceux décrits dans le document US-A- 5,089,578. Among these polymers, mention may be made of: non-crosslinked copolymers, neutralized or not, comprising from 15 to 60% by weight of AMPS units and from 40 to 85% by weight of units

(C 1 -C 6) alkyl (meth) acrylamide or (C 6 -C 6) alkyl (meth) acrylate units relative to the polymer, such as those described in EP-A-750 899; terpolymers comprising from 10 to 90 mol% of acrylamide units, from 0.1 to 10 mol% of AMPS units and from 5 to 80 mol% of n- (C6-C18) alkylacrylamide units, such as those described in US-A-5,089,578.

Mention may also be made of copolymers of completely neutralized AMPS and of dodecyl methacrylate, n-hexadecyl and / or n-octadecyl, as well as copolymers of AMPS and n-dodecylmethacrylamide, non-crosslinked, such as those described above. in the articles of Morishima quoted above.

dans laquelle X+ est un proton, un cation de métal alcalin, un cation alcalinoterreux ou l'ion ammonium, et de motifs de formule (III) suivante : There may be mentioned more particularly the copolymers consisting of 2acrylamido-2-methylpropanesulfonic acid (AMPS) units of formula (II) below:

in which X + is a proton, an alkali metal cation, an alkaline earth cation or the ammonium ion, and units of the following formula (III):

<Desc / Clms Page number 7>

dans laquelle x désigne un nombre entier variant de 3 à 100, de préférence de 5 à 80 et plus préférentiellement de 7 à 25 ; R, a la même signification que celle indiquée ci-dessus dans la formule (1) et R4 désigne un alkyle linéaire ou ramifié en C6-C22 et plus préférentiellement en C10-C22.

in which x denotes an integer ranging from 3 to 100, preferably from 5 to 80 and more preferably from 7 to 25; R, has the same meaning as that indicated above in formula (1) and R4 denotes a linear or branched C6-C22 and more preferably C10-C22 alkyl.

Particularly preferred polymers are obtained from AMPS units of formula (II) and units of formula (III) where x = 8, R denotes the methyl radical (CH3) and R4 = C16-18.

The polymers for which X + denotes sodium or ammonium are more particularly preferred.

The preferred amphiphilic polymers used according to the invention can be obtained according to the conventional methods of radical polymerization in the presence of one or more initiators such as, for example, azobisisobutyronitrile (AIBN), azobisdimethylvaleronitrile, hydrochloride of 2,2- azobis- [2-amidinopropane] (ABAH = 2,2-AzoBis- [2-Amidinopropane] Hydrochloride), organic peroxides such as dilauryl peroxide, benzoyl peroxide, tert-butyl hydroperoxide, etc. inorganic peroxidized compounds such as potassium or ammonium persulfate, or H 2 O 2 optionally in the presence of reducing agents.

The polymers may in particular be obtained by radical polymerization in tert-butanol medium in which they precipitate. By using precipitation polymerization in tert-butanol, it is possible to obtain a particle size distribution of the polymer which is particularly favorable for its uses.

The polymerization reaction may be conducted at a temperature between 0 and 150 C, preferably between 10 and 100 C, either at atmospheric pressure or under reduced pressure. It can also be carried out under an inert atmosphere, and preferably under nitrogen.

According to this process, 2-acrylamido-2-methylpropanesulfonic acid (AMPS) or one of its sodium or ammonium salts, with a (meth) acrylic acid ester, has been polymerized in particular. a C10-C18 alcohol oxyethylenated with 8 moles of ethylene oxide (GENAPOL C-080 from the company HOECHST / CLARIANT), - a C11 oxo alcohol oxyethylenated with 8 moles of ethylene oxide (GENAPOL UD -080 from HOECHST / CLARIANT),

<Desc / Clms Page number 8>

 a C 10 oxo alcohol oxyethylenated with 7 moles of ethylene oxide (GENAPOL # UD-070 from the company HOECHST / CLARIANT), a C 12 -C 14 alcohol oxyethylenated with 7 moles of oxide of ethylene (GENAPOL LA-070 from the company HOECHST / CLARIANT), - a C12-C14 alcohol oxyethylenated with 9 moles of ethylene oxide (GENAPOL LA-090 from the company HOECHST / CLARIANT), - a C12-C14 alcohol oxyethylenated with 11 moles of ethylene oxide (GENAPOL LA-110 from HOECHST / CLARIANT), - of a C16-C18 alcohol oxyethylenated with 8 moles of ethylene oxide (GENAPOL T -080 from HOECHST / CLARIANT), - a C16-C18 alcohol oxyethylenated with 15 moles of ethylene oxide (GENAPOL T-150 from the company HOECHST / CLARIANT), - a C16- alcohol. C18 oxyethylenated with 11 moles of ethylene oxide (GENAPOL T-110 from the company HOECHST / CLARIANT), - a C16-C18 alcohol oxyethylenated with 20 moles of ethylene oxide (GENAPOL # T-200 HOECHST / CLARIANT), - from a C16-C18 alcohol oxyethylenated with 25 moles of ethylene oxide (GENAPOL T-250 from the company HOECHST / CLARIANT), - a C18-C22 alcohol oxyethylenated with 25 moles of ethylene oxide and / or an iso-C16-C18 alcohol oxyethylenated with 25 moles of ethylene oxide.

The molar concentration in% of the units of formula (II) and of units of formula (III) in the polymers according to the invention varies according to the desired cosmetic application and the rheological properties of the desired formulation. It can vary between 0.1 and 99.9 mol%.

Preferably for the most hydrophobic polymers, the molar proportion of units of formula (1) or (III) ranges from 40 to 99.9%, more particularly from 50 to 90% and even more particularly from 60 to 80%.

Preferably for the low hydrophobic polymers, the molar proportion of units of formula (1) or (III) ranges from 0.1 to 50%, more particularly from 1 to 25% and even more particularly from 2 to 20%.

The distribution of the monomers in the polymers of the invention may be, for example, alternating, block (including multiblock) or any.

According to a preferred embodiment of the invention, the amphiphilic polymer used is a copolymer of AMPS and C16-C18 alcohol methacrylate containing 8 oxyethylenated groups, obtained from AMPS or an AMPS salt. and Genapol T-080 or Genapol C-080.

The amphiphilic polymers used according to the invention are preferably present in the composition of the invention in an amount equal to or less than 1% by weight relative to the total weight of the composition. They may be present for example in amounts ranging from 0.01 to 1% by weight of active ingredient, more preferably from 0.05 to 0.7% of active ingredient,

<Desc / Clms Page number 9>

 more preferably from 0.1 to 0.6% by weight of active material relative to the total weight of the emulsion.

Aqueous Phase The composition according to the invention comprises an amount of aqueous phase ranging from 20 to 60% by weight, preferably from 25 to 55% by weight and better still from 30 to 50% by weight relative to the total weight of the composition. The aqueous phase comprises water. It may furthermore comprise any other water-soluble compound that may be present, such as in particular water-soluble solvents and additives (for example surfactants and active ones).

As water-soluble solvents, mention may be made in particular of lower alcohols and polyols. By "lower alcohol" is meant alcohols having 1 to 8 carbon atoms and more preferably 1 to 6 carbon atoms, such as ethanol. Examples of polyols that may be mentioned include glycerin, propylene glycol, butylene glycol and polyethylene glycols (for example PEG-8). These solvents and in particular the alcohols and / or polyols may be present in the composition in an amount ranging preferably from 0.1 to 25% and from 1 to 15% of the total weight of the composition.

Oily phase The oily phase is present in the composition according to the invention in an amount of at least 40% by weight relative to the total weight of the composition.

This amount may range, for example, from 40 to 80% by weight, preferably from 45 to 75% by weight and better still from 50 to 70% by weight relative to the total weight of the composition. The oily phase includes oils and other fatty substances as well as fat-soluble additives (for example surfactants and active ones).

The oily phase of the composition according to the invention contains at least one makeup-removing oil preferably chosen from hydrocarbon-based oils, fatty acid esters comprising at least 8 carbon atoms and mixtures thereof.

By hydrocarbon oil is meant here any oil predominantly comprising carbon and hydrogen atoms. As hydrocarbon-based oils, mention may be made, for example, of paraffin oils, volatile or not, and their derivatives, liquid petrolatum, polydecenes, hydrogenated polyisobutene such as Parleam oil, hydrogenated isoparaffin and isohexadecane. , isododecane, and mixtures thereof.

The fatty acid esters comprise at least 8 carbon atoms, preferably 9 to 26 carbon atoms and better still 12 to 22 carbon atoms. They may be chosen in particular from: (1) esters obtained from straight or branched chain fatty acids comprising at least 9 carbon atoms and straight or branched chain alcohols containing from 1 to 17 carbon atoms; (2) esters obtained from straight or branched chain acid having 1 to 17 carbon atoms and straight or branched chain fatty alcohol having at least 9 carbon atoms;

<Desc / Clms Page number 10>

 (3) esters obtained from benzoic acid and straight or branched chain fatty alcohol having at least 9 carbon atoms, and (4) mixtures thereof.

 The esters are preferably mono- or di-esters. In a preferred manner, the esters contain no unsaturation and / or no ether or hydroxyl group. Even more advantageously, it is a saturated ester which contains no ether or hydroxyl group.

Thus, the ester used as makeup-removing oil of the composition in accordance with the invention may be chosen especially from the group comprising 2-ethylhexyl palmitate (or octyl palmitate), isononyl isononanoate and lactate. isostearyl, 2-ethyl hexyl myristate (or octyl myristate), isopropyl palmitate, isopropyl myristate, di-isopropyl adipate, dioctyl adipate, hexanoate 2-ethyl hexyl, ethyl laurate, methyl myristate, octyldodecyl octanoate, isodecyl neopentanoate, ethyl myristate, myristyl propionate, ethyl 2-ethyl hexanoate 2-hexyl, 2-ethylhexyl octanoate, 2-ethylhexyl caprate / caprylate, methyl palmitate, butyl myristate, isobutyl myristate, ethyl palmitate, laurate isohexyl, hexyl laurate, isopropyl isostearate, benzoic acid ester and C12-C15 alcohols (CTFA name: C12-15 Alkyl Benzoate), and mixtures thereof es.

The amount of cleansing oil (s) may constitute all or part of the oily phase, for example from 1 to 100%, preferably from 5 to 80% and better still from 10 to 70% of the total weight of the oil phase. the oily phase.

The oily phase may additionally contain all the fatty substances and in particular the oils other than those indicated above, conventionally used in the cosmetic field. Other oils that may be present in the oily phase include, for example, vegetable oils such as apricot kernel oil; synthetic oils; volatile or non-volatile silicone oils and fluorinated oils. The other fatty substances that may be present in the oily phase may be, for example, fatty acids, fatty alcohols and waxes.

As silicone oils, mention may be made, for example, of volatile or non-volatile polymethylsiloxanes (PDMS) with a linear or cyclic silicone chain, which are liquid or pasty at room temperature, in particular cyclopolydimethylsiloxanes (cyclomethicones) such as cyclohexasiloxane and cyclopentasiloxane; polydimethylsiloxanes comprising alkyl, alkoxy or phenyl groups, during or at the end of the silicone chain, groups having from 2 to 24 carbon atoms; phenyl silicones such as phenyltrimethicones, phenyldimethicones, phenyltrimethylsiloxydiphenylsiloxanes, diphenyldimethicones, diphenylmethyldiphenyltrisiloxanes, 2-phenylethyltrimethylsiloxysilicates, and polymethylphenylsiloxanes, and mixtures thereof.

According to one particular embodiment of the invention, the composition comprises at least one silicone oil, and in particular at least one silicone oil

<Desc / Clms Page number 11>

 volatile such as cyclopolydimethylsiloxanes (cyclomethicones) such as cyclohexasiloxane and cyclopentasiloxane.

Adjuvants In a known manner, the composition of the invention may also contain one or more adjuvants, chosen from the usual adjuvants in the cosmetic field, such as hydrophilic or lipophilic active agents, preservatives, antioxidants, perfumes, solvents, fillers, fibers, sunscreens, dyestuffs (especially pigments, nacres), polymers other than those mentioned above, basic or acidic agents, lipid vesicles, and mixtures thereof. These adjuvants are used in the usual proportions in the cosmetic or dermatological field, and for example from 0.01 to 30% of the total weight of the composition, and they are, according to their nature, introduced into the aqueous phase or into the oily phase. emulsion, or in vesicles. These adjuvants and their concentrations must be such that they do not modify the desired property for the composition.

Thus, one or more polymers may be incorporated in the composition of the invention, in concentrations ranging preferably from 0.05 to 2% by weight relative to the total weight of the composition. Examples of polymers that can be used in the composition of the invention are: polysaccharide biopolymers such as xanthan gum, guar gum, alginates, modified celluloses; synthetic polymers such as polyacrylics such as CARBOPOL 980 sold by the company Goodrich, acrylate / acrylonitrile copolymers such as HYPAN SS201 marketed by the company KINGSTON; inorganic compounds such as smectites, modified or non-modified hectorites such as BENTONE products marketed by RHEOX, LAPONITE products marketed by SOUTHERN CLAY 30 PRODUCTS, VEEGUM HS product marketed by R.T.

VANDERBILT; - and their mixtures.

As active agents that may be used in the composition of the invention, mention may be made in particular of antiseborrhoeic and antimicrobial active agents; allowing in particular to treat oily skin. This active agent may especially be chosen from beta-lactam derivatives, quinolone derivatives, ciprofloxacin, norfloxacin, tetracycline and its salts, erythromycin and its salts, amikacin and its salts, 2,4, 4'-trichloro-2'-hydroxy diphenyl ether (or triclosan), 3,4,4'trichlorobanilide (or triclocarban), phenoxyethanol, phenoxypropanol, phenoxyisopropanol, doxycycline and its salts, capreomycin and its salts, chlorhexidine and its salts, chlortetracycline and its salts, oxytetracycline and its salts, clindamycin and its salts, ethambutol and its salts, hexamidine isethionate, metronidazole and its salts, pentamidine and its salts, gentamicin and its salts, kanamycin and its salts, linomycin and its salts, methacycline and its salts, methenamine and its salts, minocycline and its salts, neomycin and its salts, netilmicin and its salts, paromomycin and its salts,

<Desc / Clms Page number 12>

 streptomycin and its salts, tobramycin and its salts, miconazole and its salts, amanfadine salts, para-chloro-metaxylenol, nystatin, tolnaftate, salicylic acid and its salts, acid 5-N-octanoylsalicylic acid and its salts, benzoyl peroxide, 3-hydroxy benzoic acid, 4-hydroxy benzoic acid, acetylsalicylic acid, 2-hydroxybutanoic acid, 2-hydroxypentanoic acid, 2-hydroxyhexanoic acid, phytic acid, N-acetyl-Lysteine acid, lipoic acid, azelaic acid, arachidonic acid, ibuprofen, naproxen, hydrocortisone, acetaminophen, resorcinol, octopirox, lidocaine hydrochloride, clotrimazole, octoxyglycerine, octanoylglycine, caprylylglycol, 10-hydroxy-2-decanoic acid, zinc salts such as zinc gluconate, niacinamide or vitamin B3 (or vitamin PP), and mixtures thereof.

As active agents, there may also be mentioned α-hydroxy acids such as lactic acid, glycolic acid, citric acid and their derivatives; essential oils ; vitamins and in particular retinol (vitamin A), ascorbic acid (vitamin C), tocopherol (vitamin E), panthenol (vitamin B5) and their derivatives (esters for example); co-enzymes and in particular coenzyme Q10 or ubiquinone; enzymes such as, for example, lipases, proteases, phospholipases, cellulases, peroxidases, especially lactoperoxidases, catalases, superoxide dimutases and plant extracts containing the abovementioned enzymes; yeasts such as Saccharomyces cerevisiae; steroids; anti-oxidants and anti-free radicals; moisturizers such as polyols (glycerin, sorbitol, sugars), protein hydrolysates, urea and mixtures thereof; slimming as caffeine; anti-elastase and anticollagenase agents; oily skin treatment agents; plant extracts and in particular plankton extracts; tensors; mattifying agents; antiperspirants such as aluminum salts; and their mixtures.

As examples of steroids, mention may be made of dehydroepiandrosterone (or DHEA), as well as (1) its precursors and biological derivatives, in particular salts and esters of DHEA, such as DHEA sulfate and salicylate, 7-hydroxy-DHEA. , 7-keto DHEA, 7-hydroxy and 7-keto DHEA esters, in particular 3beta-acetoxy-7-oxo DHEA, and (2) its precursors and chemical derivatives, in particular sapogenins such as diosgenin or hecogenin, and / or their derivatives such as hecogenin acetate, and / or natural extracts containing it and in particular extracts of Dioscoreas, such as wild yam (Wild Yam).

The fibers that may be used in the composition of the invention may be hydrophilic or hydrophobic fibers, of synthetic or natural, mineral or organic origin. The fibers may be, for example, those used in the manufacture of textiles, and in particular silk, cotton, wool, flax, cellulose fibers extracted especially from wood, vegetables or algae, polyamide (Nylon®), modified cellulose (rayon, viscose, acetate especially rayon acetate), poly-p-phenylene terephthalamide including Kevlar #, acrylic especially polymethyl methacrylate or poly 2-hydroxyethyl methacrylate, polyolefin and especially polyethylene or polypropylene, glass, silica, aramid, carbon in particular in graphite form,

<Desc / Clms Page number 13>

 Teflon, insoluble collagen, polyesters, polyvinyl chloride or vinylidene, polyvinyl alcohol, polyacrylonitrile, chitosan, polyurethane, polyethylene phthalate, fibers formed from a mixture of polymers such as those mentioned above above, such as polyamide / polyester fibers, and mixtures thereof. Synthetic resorbable fibers used in surgery may also be used, such as fibers prepared from glycolic acid and caprolactone (Monocryl from Johnson &Johnson); resorbable synthetic fibers of the copolymer type of lactic acid and glycolic acid (Vicryl from Johnson &Johnson); polyester terephthalic fibers (Ethibond from Johnson & Johnson), and stainless steel wire (Steel from Johnson & Johnson). It is also possible to use a mixture of these different fibers. These fibers may be present in amounts ranging from 0 to 20% by weight and preferably from 0.5 to 10% by weight relative to the total weight of the composition.

The composition of the invention may further contain fillers for modifying the texture of the composition. As fillers which can be used in the composition of the invention, mention may be made, for example, besides the pigments, the silica powder; talcum; polyamide particles and in particular those sold under the name ORGASOL by the company Atochem; polyethylene powders; microspheres based on acrylic copolymers, such as those made of ethylene glycol dimethacrylate / lauryl methacrylate copolymer sold by Dow Corning under the name Polytrap; expanded powders such as hollow microspheres and in particular the microspheres sold under the name Expancel by the company Kemanord Plast or under the name Micropearl F 80 ED by the company Matsumoto; powders of natural organic materials such as corn starch, wheat or rice, crosslinked or not, such as starch powders crosslinked with octenylsuccinic anhydride, sold under the name DRY-FLO by the company National Starch; silicone resin microbeads such as those sold under the name Tospearl by the company Toshiba Silicone; and their mixtures. These fillers may be present in amounts ranging from 0 to 40% by weight and preferably from 1 to 10% by weight relative to the total weight of the composition.

The sunscreens (or U.V. filters) optionally present in the composition may be chosen from organic screening agents, physical screening agents such as titanium or zinc oxides and mixtures thereof.

The more particularly preferred organic UV filters are chosen from the following compounds: Salicylic derivatives, and especially ethylhexyl salicylate (or ethyl hexyl salicylate) sold under the trade name NEO HELIOPAN OS by
HAARMANN and REIMER; Derivatives of dibenzoylmethane and in particular butyl methoxydibenzoylmethane sold in particular under the trade name
PARSOL 1789 by HOFFMANN LA ROCHE;

<Desc / Clms Page number 14>

Cinnamic derivatives and especially ethylhexyl methoxycinnamate sold in particular under the trade name PARSOL MCX by HOFFMANN LA
ROCK; Derivatives of ss, ss'-diphenylacrylate and in particular octocrylene (α-cyano-p, p-diphenylacrylate of 2-ethylhexyl) sold in particular under the trade name
UVINUL N539 by BASF; Phenylbenzimidazole sulfonic acid; Benzylidenecamphor derivatives, and in particular terephthalylidene dicamphosulphonic acid (Terephthalylidene Dicamphor Sulfonic) manufactured under the name Mexoryl SX by Chimex, and 4-methylbenzylidene camphor sold under the trade name Eusolex 6300 by Merck; Benzophenone derivatives, and in particular Benzophenone-3 or
Oxybenzone, sold under the trade name UVINUL M40 by BASF; the
Benzophenone-4 sold under the trade name UVINUL MS40 by BASF; Benzophenone-5; Phenyl benzimidazole derivatives, and in particular benzimidazilate sold under the trade name NEO HELIOPAN AP by HAARMANN and
REIMER; Derivatives of triazine, and in particular anisotriazine sold under the trade name Tinosorb S by CIBA GEIGY; ethylhexyl triazone sold in particular under the trade name UVINUL T150 by BASF; anddiethylhexylbutamido triazone sold under the trade name UVASORB
HEB by SIGMA 3V; Methylene bis-benzotriazolyl tetramethylbutylphenol; Derivatives of phenyl benzotriazole, and in particular Drometrizole Trisiloxane sold under the trade name Silatriazole by Rhodia Chimie; - and their mixtures.

As physical filters which may be added in the composition of the invention, mention may be made, for example, of pigments and nano-pigments of metal oxides, coated or uncoated, in particular the oxides of titanium, iron, zirconium, zinc or cerium, and mixtures thereof, these oxides possibly being in the form of micro- or nanoparticles (nanopigments), optionally coated.

Of course, those skilled in the art will take care to choose the optional compounds to be added to the composition according to the invention in such a way that the advantageous properties intrinsically attached to the composition according to the invention are not or substantially not , altered by the envisaged addition.

The compositions according to the invention may be more or less fluid and may therefore be in the form of milk or in the form of cream more or less thick. They may constitute in particular skin cleansing products and / or cleaning the skin, lips and / or hair.

The present invention also relates to a cosmetic process for removing makeup and / or cleaning the skin, lips and / or eyes, characterized in that it is applied to the skin, lips and / or eyes, a composition as defined above.

<Desc / Clms Page number 15>

The invention also relates to the cosmetic use of the composition as defined above for removing makeup and / or cleaning the skin, lips and / or eyes.

The following examples of compositions according to the invention are given by way of illustration and without limitation. Quantities are given in% by weight unless otherwise stated.

The process for preparing the exemplified compositions is as follows: A1 is dispersed in water with stirring, followed by addition of the other constituents of phase A; B is emulsified in A at 25 ° C. with mechanical stirring until a white, smooth and glossy emulsion is formed.

<Desc / Clms Page number 16>

<Tb>
<Tb>

Examples <SEP> Emulsion <SEP> HIE <SEP> n <SEP> 1 <SEP> n <SEP> 2 <SEP> n <SEP> 3 <SEP> n <SEP> 4
<tb> 60 <SEP>% <SEP> of <SEP> phase <SEP> B <SEP> 40 <SEP>% <SEP> of <SEP> phase <SEP> B
<tb> - <SEP> A1 <SEP> - <SEP> Copolymer
<tb> AMPS <SEP> / <SEP> methacrylate <SEP> 0. <SEP> 4 <SEP> 0.4 <SEP> 0.4 <SEP> 0.6
<tb> alcohol <SEP> C16-18
<tb> Phase <SEP> A <SEP> (8 <SEP> OE)
<tb> aqueous <SEP> A2 <SEP> - <SEP> water <SEP> qsp <SEP> 100 <SEP> qsp <SEP> 100 <SEP> qsp <SEP> 100 <SEP> qsp <SEP> 100
<tb> - <SEP> A3 <SEP> - <SEP> glycerin <SEP> 3 <SEP> 3 <SEP> 3 <SEP> 3
<tb> - <SEP> A4 <SEP> - <SEP> basis <SEP> (soda) <SEP> 0. <SEP> 07 <SEP> 0. <SEP> 07 <SEP> 0. <SEP> 07 <SEP> 0.0105
<tb> - <SEP> A5 <SEP> - <SEP> conservative <SEP> 0. <SEP> 1 <SEP> 0.1 <SEP> 0.1 <SEP> 0. <SEP> 1
<tb> - <SEP> Cyclopentasiloxane <SEP> 12 <SEP> 36 <SEP> - <SEP> Phase <SEP> B <SEP> - <SEP> Oil <SEP> of <SEP> Vaseline <SEP> 31.8
<Tb>

huileuse Palmitate 16.2 24 24 huileuse Palmitate 16.2

Oily Palmitate 16.2 24 24 Oily Palmitate 16.2

<Tb>
<tb> oily <SEP> isopropyl
<tb> -Isohexadecane <SEP> - <SEP> 24
<tb> -Isododecane <SEP> - <SEP> 36 <SEP> 36
<tb> pH <SEP> = <SEP> 7.23 <SEP> pH <SEP> = <SEP> 6.91 <SEP> pH <SEP> = <SEP> 7.43 <SEP> pH <SEP> = <SEP> 7
<tb> viscosity <SEP> = <SEP> viscosity <SEP> = <SEP> viscosity
<tb> viscosity <SEP> 464 <SEP> 15 <SEP> poises <SEP> 4,6 <SEP> poises
<tb> 19 <SEP> poises <SEP> cPoise <SEP> (= <SEP> 1.5 <SEP> (= <SEP> 0.46
<tb> (= 1.9 <SEP> Pa.s) <SEP> (= <SEP> 0.464 <SEP> (= <SEP> 1.5 <SEP> Pa.s)
<tb> Pa.s) <SEP> Pa.s) <SEP> Pa.s)
<tb> size <SEP> of <SEP> size <SEP> of <SEP> size <SEP> of
<tb> Controls <SEP> to <SEP> 24 <SEP> hours <SEP> globules <SEP> globules <SEP> globules
<tb> oily <SEP> = <SEP> oily <SEP> = <SEP> oily <SEP> =
<tb> 7 m <SEP> $ 20 m <SEP> $ 28 m
<tb> Emulsion <SEP> Emulsion <SEP> Emulsion <SEP> Emulsion
<tb> fine, <SEP> plus <SEP> fluid, <SEP> fine <SEP> and <SEP> of appearance
<tb> homoge- <SEP> homoge- <SEP> homoge- <SEP> white,
<tb> ne, <SEP> ne, <SEP> ne. <SEP> homogenous <SEP> and <SEP> white <SEP> homog
<tb> brilliant <SEP> does not
<tb> Stability <SEP> after <SEP> 2 <SEP> months <SEP> of <SEP> recoil <SEP> to <SEP> Stable <SEP> Stable <SEP> Stable <SEP> Stable
<tb> 4 C, <SEP> 25 C <SEP> and <SEP> 45 C <SEP> Stable
<Tb>
These emulsions have the following advantages:> They are therefore stable after a retreat of 2 months at different temperatures (4 C, 25 C, 45 C).

> They can have a fairly high viscosity (about 15 poises)
1.5 Pa. At Rheomat 180 at 25 ° C - 200 sec-1). In this case, the composition is not a milk but a flexible cream, and it has the advantage of not sinking when applied to the skin (examples 1 and 3).

<Desc / Clms Page number 17>

 > Several types of oils are compatible, both silicones and alkanes or esters or other> These emulsions are stable without the addition of other surfactants (emulsifying surfactant, co-surfactant such as fatty alcohols) Cleansing power : The cleansing power of the examples indicated above was tested, using a foundation without transfer to verify the effectiveness of makeup removal.

The test is carried out as follows: 1) L'Oréal Paris Air Transfer Foundation is applied in an amount of 50 mg over a defined area of 4x4 cm-2 of the forearm. .

2) In parallel, the make-up removing formulas are weighed (100 mg) and deposited on a cotton.

3) After drying the makeup (about 15 minutes) is applied by 5 movements (from top to bottom) cotton soaked in makeup remover on the defined makeup area.

4) Next, we compare the make-up removal obtained with the bare skin.

In this test, the formulas n 1, 2,3 showed an excellent make-up removal, the formula n 4 a proper make-up removal.

The effectiveness of the make-up remover, the comfort and the sensory evaluation of the formula n 3 were also tested on a panel of 27 women who used it during 10 days. It emerged from this test that the product had a cleansing power considered good, very good cosmetic aspects, easy rinsing, and good comfort.

Claims (37)

 1. Cosmetic cleaning and / or makeup removal composition, comprising an oily phase dispersed in an aqueous phase, characterized in that it comprises at least one non-crosslinked amphiphilic polymer comprising at least two hydrophobic side members. and that the oily phase comprises at least one makeup removal oil and constitutes at least 40% by weight relative to the total weight of the composition. 2. Composition according to Claim 1, characterized in that the polymer is capable of being obtained from at least one hydrophilic monomer A with ethylenic unsaturation and at least one hydrophobic monomer B. 3. Composition according to the preceding claim, characterized in that the monomer A comprises at least one oxygen atom, a nitrogen atom, a sulfur atom, a phosphorus atom, a chlorine atom, a fluorine atom. or their mixtures. 4. Composition according to the preceding claim, characterized in that the monomer A comprises a sulfonic acid or phosphonic acid function. 5. Composition according to any one of claims 2 to 4, characterized in that the hydrophobic monomer B comprises at least one hydrophobic radical selected from: - C6-C50 alkyl radicals, saturated or unsaturated, linear, branched or cyclic ; fluorinated or alkylfluorinated C 6 -C 30 radicals; the cholesteryl radical or the radicals derived from cholesterol; - polycyclic aromatic groups; silicone or alkylsilicone or alkylfluorosilicone radicals. 6. Composition according to the preceding claim, characterized in that the hydrophobic monomer B comprises at least one hydrophobic radical selected from linear or branched alkyl radicals. 7. Composition according to the preceding claim, characterized in that the hydrophobic monomer is an alkyl chain having from 6 to 30 carbon atoms. 8. Composition according to any one of the preceding claims, characterized in that the polymer is neutralized partially or totally by a mineral or organic base. 9. Composition according to any one of the preceding claims, characterized in that the polymer has a number average molecular weight ranging from 1000 to 20 000 000 g / mol. <Desc / Clms Page number 19>  10. Composition according to the preceding claim, characterized in that the number average molecular weight ranges from 20,000 to 5,000,000 g / mol. 11. Composition according to any one of the preceding claims, characterized in that the polymer is capable of being obtained from at least one ethylenically unsaturated monomer containing sulphonic group, in free form or partially or totally neutralized, and at least one hydrophobic monomer. 12. Composition according to the preceding claim, characterized in that the ethylenically unsaturated monomer containing sulfonic group is chosen from vinylsulfonic acid, styrene sulfonic acid, (meth) acrylamido (C1-C22) alkylsulphonic acids, N- (C1-C22) alkyl (meth) acrylamido (C1-C22) alkylsulfonic acids and their partially or completely neutralized forms, and mixtures thereof. 13. Composition according to the preceding claim, characterized in that the ethylenically unsaturated monomer containing sulfonic group is selected from acrylamido-methanesulfonic acid, acrylamido-ethanesulfonic acid, acrylamido-propane-sulfonic acid. , 2-acrylamido-2-methylpropanesulfonic acid, methacrylamido-2-methylpropanesulfonic acid, 2-acrylamido-n-butanesulfonic acid, 2-acrylamido-2,4,4-trimethylpentanesulfonic acid, 2-methacrylamido-dodecyl-sulfonic acid, 2-acrylamido-2,6-dimethyl-3-heptanesulfonic acid, as well as their partially or completely neutralized forms, and mixtures thereof. 14. A composition according to claim 12 or 13, characterized in that the ethylenically unsaturated monomer containing sulfonic group is 2acrylamido-2-methylpropanesulfonic acid (AMPS), and its partially or completely neutralized forms. 15. Composition according to the preceding claim, characterized in that the amphiphilic polymer is chosen from the statistical polymers of AMPS modified by reaction with a n-mono (C6-C22) alkylamine or a di-n- (C6-C22) alkylamine. 16. Composition according to the preceding claim, characterized in that the AMPS amphiphilic polymer additionally contains at least one ethylenically unsaturated monomer chosen from (meth) acrylic acids and their ss-substituted alkyl derivatives, and their esters obtained with monoalcohols or mono or polyalkylene glycols, or from (meth) acrylamides, vinylpyrrolidone, maleic anhydride, itaconic acid, maleic acid, cationic monomers, or mixtures thereof. 17. Composition according to any one of the preceding claims, characterized in that the amphiphilic polymer is chosen from amphiphilic copolymers of AMPS and at least one hydrophobic ethylenically unsaturated monomer comprising at least one hydrophobic part having from 6 to 30 carbon atoms. <Desc / Clms Page number 20> 18. Composition according to the preceding claim, characterized in that the hydrophobic portion comprises from 6 to 22 carbon atoms. 19. Composition according to Claim 17 or 18, characterized in that the hydrophobic monomer containing ethylenic unsaturation is chosen from the acrylates, alkyl acrylates, acrylamides or alkyl acrylamides of formula (I) below:

 in which R1 and R3, which may be identical or different, denote a hydrogen atom or a linear or branched C1-C6 alkyl radical; Y is O or NH; R2 is a hydrophobic hydrocarbon radical having at least 6 to 30 carbon atoms; x denotes a number of moles of alkylene oxide and ranges from 0 to 100. 20. Composition according to the preceding claim, characterized in that the hydrophobic radical R2 is chosen from linear, branched or cyclic C6-C18 alkyl radicals; C 6 -C 18 perfluorinated alkyl radicals; the cholesteryl radical or a cholesterol ester residue; polycyclic aromatic groups. 21. Composition according to claim 19 or 20, characterized in that the monomer of formula (I) comprises at least one alkylene oxide unit (x # 1). 22. Composition according to any one of claims 19 to 21, characterized in that the monomer of formula (1) comprises only ethylene oxide units. 23. Composition according to any one of claims 19 to 22, characterized in that the number of moles of alkylene oxide ranges from 3 to 100, preferably from 3 to 50. 24. Composition according to any one of claims 17 to 19, characterized in that the AMPS amphiphilic polymer is chosen from: - uncrosslinked copolymers, neutralized or not, comprising from 15 to 60% by weight of AMPS units and from 40 to 85% by weight of (C 8 -C 16) alkyl (meth) acrylamide units or (C 8 -C 16) alkyl (meth) acrylate units, based on the polymer; <Desc / Clms Page number 21>  terpolymers comprising from 10 to 90 mol% of acrylamide units, from 0.1 to 10 mol% of AMPS units and from 5 to 80 mol% of n- (C6-C18) alkylacrylamide units, relative to the polymer ; uncrosslinked copolymers of partially or totally neutralized AMPS and of n-dodecyl, n-hexadecyl and / or n-octadecyl methacrylate. uncrosslinked copolymers of partially or totally neutralized AMPS and n-dodecylmethacrylamide. 25. Composition according to claims 17 to 19, characterized in that the AMPS amphiphilic polymer is chosen from copolymers consisting of 2-acrylamido-2-methylpropanesulfonic acid (AMPS) units of formula (II) below:

 in which X + is a proton, an alkali metal cation, an alkaline earth cation or the ammonium ion, and units of the following formula (III):

 wherein x is an integer ranging from 3 to 100; R1 has the same meaning as that indicated above in formula (I) and R4 denotes a linear or branched C6-C22 alkyl. 26. Composition according to the preceding claim, characterized in that x = 8, R1 denotes the methyl radical and R4 is C16-18. 27. Composition according to any one of the preceding claims, characterized in that the amount of amphiphilic polymer (s) ranges from 0.01 to 1% by weight of active material and preferably from 0.051 to 0.7% by weight. % by weight of active material, relative to the total weight of the composition. 28. Composition according to any one of the preceding claims, characterized in that the amount of aqueous phase ranges from 20 to 60% by weight. <Desc / Clms Page number 22>  weight and preferably from 25 to 55% by weight relative to the total weight of the composition. 29. Composition according to the preceding claim, characterized in that the amount of oily phase ranges from 40 to 80% by weight and preferably from 45 to 75% by weight relative to the total weight of the composition. 30. Composition according to any one of the preceding claims, characterized in that the makeup removal oil is selected from hydrocarbon oils, fatty acid esters having at least 8 carbon atoms and mixtures thereof. 31. Composition according to any one of the preceding claims, characterized in that the makeup removal oil is chosen from paraffin oils, volatile or not, and their derivatives, petroleum jelly, polydecenes, hydrogenated polyisobutene such parleam oil, hydrogenated isoparaffin, isohexadecane, isododecane, esters obtained from straight or branched chain fatty acids having at least 9 carbon atoms and straight or branched chain alcohols having 1 to 17 carbon atoms; esters obtained from straight or branched chain acid having 1 to 17 carbon atoms and straight or branched chain fatty alcohol having at least 9 carbon atoms; esters obtained from benzoic acid and straight or branched chain fatty alcohol having at least 9 carbon atoms; and their mixtures. 32. Composition according to the preceding claim, characterized in that the cleansing oil is chosen from the group 2-ethylhexyl palmitate, isononyl isononanoate, isostearyl lactate, ethyl myristate and 2 hexyl, isopropyl palmitate, isopropyl myristate, di-isopropyl adipate, di-octyl adipate, 2-ethylhexyl hexanoate, ethyl laurate, myristate methyl, octyldodecyl octanoate, isodecyl neopentanoate, ethyl myristate, myristyl propionate, 2-ethylhexyl 2-hexanoate, 2-ethylhexyl octanoate, 2-ethylhexyl caprate / caprylate, methyl palmitate, butyl myristate, isobutyl myristate, ethyl palmitate, isohexyl laurate, hexyl laurate, isopropyl isostearate , the benzoic acid ester and C12-C15 alcohols, and mixtures thereof. 33. Composition according to any one of the preceding claims, characterized in that the oily phase further comprises at least one silicone oil. 34. Composition according to any one of the preceding claims, characterized in that the amount of cleansing oil (s) represents from 1 to 100% and better still from 5 to 80% of the total weight of the oily phase. 35. Composition according to any one of the preceding claims, characterized in that it additionally contains one or more adjuvants chosen from hydrophilic or lipophilic active agents, preservatives, antioxidants, <Desc / Clms Page number 23>  perfumes, solvents, fillers, fibers, sunscreens, colorants, polymers, basic or acidic agents, lipid vesicles, and mixtures thereof. 36. Cosmetic use of the composition according to any one of the preceding claims for removing makeup and / or cleaning the skin, lips and / or eyes. 37. A cosmetic process for removing makeup and / or cleaning the skin, lips and / or eyes, characterized in that a composition according to any one of the invention is applied to the skin, the lips and / or the eyes. Claims 1 to 35