FR2833874A1 - Electrode wire, for discharge machining, composed of a copper core and a diffused zinc and copper alloy coating with a thickness greater than 10% of the electrode wire diameter - Google Patents

Abstract

An electrode wire for discharge machining comprises an unalloyed copper core (16) with a diffused zinc and copper alloy coating (17) with a thickness (E) greater than 10% of the diameter (D) of the electrode wire. Independent claims are also included for: (a) a method for the production of this electrode wire; and (b) utilisation of this electrode wire for discharge machining of a piece. The coating layer is optionally plated with a thin zinc, copper, nickel, silver or gold surface contact film (21).

Description

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HIGH-SPEED ELECTROEROSION WIRE
The present invention relates to electrode wires used for machining by erosive sparking, enabling the cutting or finishing of electrically conductive parts.

 Erosive sparking makes it possible to machine an electrically conductive part, generating sparks between the workpiece and an electrically conductive wire. The electrically conductive wire travels in the vicinity of the part in the direction of the length of the wire, and it is moved progressively in the transverse direction relative to the part either by translation of the wire or by translation of the part.

 The sparks gradually erode the part and the wire.

The longitudinal scrolling of the wire makes it possible to permanently maintain a sufficient wire diameter to avoid breaking it in the sparking area. The relative movement of the wire and the part in the transverse direction makes it possible to cut the part or to treat its surface, if necessary.

 Wire EDM machines include means for holding and tensioning a section of wire in the vicinity of the workpiece in a sparking area filled with a dielectric such as water, means for passing the wire longitudinally through the sparking area, means for generating a spark current between the wire and the workpiece, and means for producing a relative displacement of the wire and the workpiece transversely with respect to the longitudinal direction of the wire.

 There are currently many types of wire for EDM, which fall into two main families.

 In the first family, the wires have a generally homogeneous transverse structure, consisting for example of copper, brass, tungsten, or molybdenum. The alloy chosen must meet the requirements of electrical conductivity and mechanical resistance. Conductivity is necessary for bringing energy into the sparking area. Mechanical resistance is necessary to avoid wire breakage in the spark area. If possible, the alloy is chosen so that the wire has a behavior favorable to erosion, i.e. so that the wire

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 allows rapid erosion. The maximum erosion speed of a wire is the speed limit beyond which the wire breaks when the spark energy is increased to accelerate erosion.

 In general, each wire structure provides machining speed, machining precision and a surface finish.

 Brass wires containing 35 to 37% of zinc have thus been proposed, which constitute an economically acceptable compromise, but obtained at the cost of a relatively low rate of erosion.

 The second family of wires for EDM comprises coated wires, that is to say made up of a metallic core coated with a generally homogeneous surface layer of metal or alloy. During machining by erosive sparking by wire, the electric arc formed between the surface of the wire and the surface of the part, through the dielectric such as water, does not reach the center of the wire, under penalty of rupture of the latter. The wear of the wire is done by its coating.

 The advantage of coated wires is that one can choose the core of the wire according to its electrical and mechanical properties, and choose the coating according to its erosive properties and its contact resistance.

 Thus, in document FR 2 418 699, it has been proposed to coat a copper or brass core with an alloy of zinc, cadmium, tin, lead, bismuth or antimony. The document teaches that the machining speed is improved by the coating.

The example is a copper core coated with a coating whose thickness is approximately 15 μm for a total diameter of 180 μm.

 However, it turns out that such an EDM wire does not make it possible to obtain an optimum machining speed, and a need exists to further increase this speed.

 The present invention is the result of research aimed at optimizing the structure of a wire for EDM, in order to obtain a high rate of erosion.

 For this, a first observation taught by the document EP 0 185 492 is that an increase in thickness of a coating of zinc alloy on a copper-plated steel core is

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 favorable to the speed of EDM, but not beyond a thickness of 15 μm for a total diameter of 200 μm.

 A second observation is that, on some EDM machines, the machining speed can sometimes be further increased if the metal of the surface layer is brass obtained by thermal diffusion of peripheral zinc with an underlying layer containing copper.

 Then, in the wires with a surface layer of copper and diffused zinc alloy, it has been found that an increase in the thickness of the surface layer on a brass core with 37% zinc tends to reduce the speed of machining. , which is contrary to the desired goal. Thus, tests to cut a 50 mm piece of steel were carried out on the one hand with a wire having a homogeneous structure in brass with 37% zinc, on the other hand with a wire having a brass core with 37% zinc covered with a surface layer of zinc alloy and copper diffused by heat treatment. The diameters of the wires and the machining conditions being identical, the machining speeds (in mm2 / min) were respectively in the proportions of 98 for the homogeneous wire and 67 for the wire with surface layer, showing the negative effect of the surface layer.

 Thus, the problem proposed by the present invention is to design a new electrode wire structure for machining by erosive sparking making it possible to significantly increase the speed of machining by electroerosion, for a given diameter, and under machining conditions data.

 The object of the invention is also to propose a method of manufacturing such an electrode wire, and to propose a machining method making it possible to increase the machining speed.

 To achieve these and other goals, the invention starts from the surprising observation that, when the core is made of unalloyed copper, an increase in the thickness of the surface layer of diffused brass produces a significant increase in speed. machining. Thus, the invention provides an electrode wire for machining by erosive sparking, comprising a metal core coated with a coating layer of diffused zinc alloy, in which:

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 - the core is made of unalloyed copper, - the coating layer is made of zinc alloy and diffused copper, - the thickness of the coating layer made of copper and zinc alloy is greater than 10% of the diameter electrode wire.

 Preferably, the thickness E of the coating layer is greater than 11% of the diameter of the electrode wire.

 The copper constituting the core is unalloyed copper, the purity of which is defined in standard NF A 51 050. The recommended unalloyed copper has an electrical conductivity of approximately 100% IACS, ie 58 Mega Siemens / meter. According to the invention, the use of a copper chosen from the following family of recommended coppers is recommended, designated by their references according to standard NF A 51050, indicating in brackets the corresponding ISO references: Cu-al (Cu-ETP ); Cu-a2 (Cu-FRHC); Cu-b2 (CuDLP); Cu-Cl (Cu-OF); Cu-c2 (Cu-OFE). The wire according to the invention has an electrical conductivity of at least 60% IACS (60% of the standardized conductivity of pure annealed copper). Otherwise, there is a gradual decrease in the speed of EDM.

 Good results can for example be obtained, for a diameter D of electrode wire of 0.25 mm, with a thickness E of coating layer greater than or equal to 28 microns; for a wire of diameter D 0.30 mm, the thickness E of the coating layer can advantageously be at least 33 microns; for a wire of diameter D 0.33 mm, the thickness E of the coating layer can advantageously be at least 36 microns; and for a wire 0.35 mm in diameter D, the thickness E of the coating layer can advantageously be greater than or equal to 39 microns.

d'électroérosion sont obtenues lorsque la couche d'enrobage est en alliage cuivre-zinc en phases a, ss ou p'. La teneur en zinc est alors comprise entre 35 % et 57 %, de préférence comprise entre 35 et 50 % en poids. Sur des fils testés, et donnant satisfaction, on a relevé des teneurs en zinc de 45,7 %, 41,5 % et 35,4 %, et une teneur en oxygène de 0,5 % sous forme d'oxydes de zinc ou de cuivre. Les phases présentes dans la couche superficielle étaient les phases a, P et ss'du diagramme cuivre-zinc. For a yarn defined above, better properties

EDMs are obtained when the coating layer is made of copper-zinc alloy in a, ss or p 'phases. The zinc content is then between 35% and 57%, preferably between 35 and 50% by weight. Zinc contents of 45.7%, 41.5% and 35.4%, and an oxygen content of 0.5% in the form of zinc oxides or of copper. The phases present in the surface layer were phases a, P and ss of the copper-zinc diagram.

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 The fabrication of an electrode wire as defined above may include the steps of: a. provide a non-alloy copper core wire with a diameter greater than the diameter of the wire to be produced, b. cover the core wire with pure zinc to an appropriate thickness, c. subjecting the covered core wire to a heat diffusion treatment, to make a coating layer, d. drawing to bring the wire to the final diameter, the coating layer then having a thickness greater than 10% of the final diameter of the wire.

 Preferably, during step b, the zinc is deposited on the copper core wire by electrolytic deposition.

 After the diffusion step (c) or after the drawing step (d), the wire can also be covered with a thin surface contact layer, for example made of zinc, copper, nickel, silver or gold.

 According to the invention, it is advantageously possible to use an electrode wire thus defined for a method of machining a part by electroerosion. In this case, in a machining machine with an electric generator producing electrical sparking energy, the generator is adjusted to produce the maximum sparking energy compatible with the machining capacity of the wire without breaking, thus allowing d '' increase the machining speed.

 Other objects, characteristics and advantages of the present invention will emerge from the following description of particular embodiments, made in relation to the attached figures, among which: - Figure 1 is a schematic front view of a machine wire EDM; - Figure 2 is a top view illustrating the process of EDM on the machine of Figure 1; - Figure 3 illustrates a top view of the machined part of Figures 1 and 2; and - Figure 4 is a schematic perspective view, on a large scale of an electrode wire according to an embodiment of the present invention.

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 We first consider Figures 1 to 3, which illustrate a machining process by erosive sparking using a wire. The EDM machine as illustrated in FIG. 1 essentially comprises a machining enclosure 1 containing a dielectric such as water, means such as pulleys 2 and 3 and wire guides 20 and 30 for holding a electrode wire 4 and tension it in a spark zone 5 inside the enclosure 1, a workpiece support 6 and means 7 for moving the workpiece support 6 with respect to the electrode wire 4 in the work area spark 5.

The workpiece 8, held by the workpiece support 6, is placed in the sparking area 5. The wire guides 20.30 are on either side of the workpiece 8, and guide the electrode wire 4 precisely. They have for this a position close to the workpiece 8, and their diameter is little greater than that of the electrode wire 4, for example a diameter of 254 μm for an electrode wire 4 of 250 μm. The electrode wire 4 runs longitudinally as indicated by the arrow 9 in the sparking area 5 facing the workpiece 8. An electric generator 10, electrically connected on the one hand to the electrode wire 4 by a line 18 and a contact 18a which touches the electrode wire 4 during its passage through the dielectric of the enclosure 1 between the pulley 2 and the wire guide 20, and on the other hand to the workpiece 8 by a line 19, generates in the area d 'spark 5 an electrical energy suitable for causing electric arcs to appear between the workpiece 8 and the electrode wire 4.

 The machine comprises control means for adapting the electrical energy, the running speed of the electrode wire 4, and the movement of the workpiece 8 according to the machining steps.

 As can be seen in FIG. 2, by displacement of the workpiece in a transverse direction according to arrow ll, the erosive sparking gradually produces the penetration of the electrode wire 4 into the mass of the workpiece 8 which is conductive electricity, and produces a slot 12. Then, by moving the workpiece 8 in the direction of arrow 13, a perpendicular cut is produced, to finally achieve a

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 part as illustrated in FIG. 3, with a first facet 14 and a second facet 15 machined.

 It is understood that a high electrical energy generated by the electric generator 10 allows rapid sparking and therefore allows faster movement of the workpiece relative to the electrode wire 4, for rapid machining. Indeed, the movement of the part must follow the erosion produced by the sparks, without excess. Too slow a speed reduces the machining speed. Too fast a speed produces contact of the wire and the workpiece, and the machine stops due to the short circuit.

 However, the electrical energy produces a heating of the wire in the machining area, and the increase of this energy simultaneously increases the risks of wire breakage. Thus, for a given structure of the electrode wire, the maximum machining speed is obtained for the electrical energy just lower than the energy causing the rupture of the electrode wire.

 Let us now consider again the tests which enabled the conception of the present invention.

 Electroerosion machining tests were carried out on a Charmilles Robofil 2020 brand machine, in E3 cutting regime, with a piece of steel 50 mm high.

 A first comparative test was made on the one hand with a brass wire with 37% zinc, on the other hand with a wire whose brass core with 37% zinc is covered with a layer of 8 microns d alloy of copper and zinc obtained by diffusion heat treatment. The two wires had the same final diameter of 0.25 mm. In relative machining speed, the brass wire allowed a machining speed of 98, while the brass core wire covered with zinc alloy and diffused copper only allowed a speed of 67.

 A second comparative test was carried out using on the one hand a wire whose core is an alloy of copper and zinc with 80% copper, with a coating layer of 20 microns of copper and zinc alloy diffused, and on the other hand with a wire whose core is made of copper covered with a layer of 14 microns of copper alloy and diffused zinc. The two wires allowed machining according to the relative speeds of 109 and 125 respectively. it

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 shows the advantage of a copper core, which works faster than the brass core even if the coating layer is thinner.

 A third test successively used three wires having a copper core, with coating layers of copper and zinc alloy diffused respectively of 11 microns, 14 microns and 28 microns, for a wire diameter of 0.25 mm. The relative speeds which have been obtained are respectively 115, 125 and 133. It can be seen that with identical sparking power, a greater thickness of the diffused layer accelerates the cutting, in the case of wires with a copper core.

 Taking advantage of these results, the invention makes it possible to obtain a better machining speed by using a particular electrode wire, as illustrated in FIG. 4 on a larger scale. The electrode wire according to the invention comprises a core 16 of copper, coated with a coating layer 17 of an alloy of copper and of diffused zinc whose thickness E is greater than 10% of the diameter D of the electrode wire.

 It may be advantageous to greatly increase the thickness E of the coating layer. However, there is a limit in the relative deformation capacities of the metals during the drawing process which makes it possible to size the wire: too great a thickness of coating layer risks leading to detachment of the coating layer relative to the core during drawing, which affects the production and use properties of the electrode wire. Wire drawing remains easily achievable when the relative thickness of the coating layer is less than about 15% of the final diameter D.

 The interface between the core and the coating layer is generally deformed by the drawing operation, which naturally removes its smoothness and gives it a slight irregularity. This irregularity is not a problem for the EDM process.

 It is advantageous to add to the wire a surface contact layer 21, for example of zinc, copper, nickel, silver or gold, improving the electrical conduction between the electrode wire 4 and the contact 18a, and improving the stability of the sparking.

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 The surface of the wire can be covered with an oxide layer, resulting from the manufacturing steps. It is not essential to remove this layer, although this is possible. This layer can be uniform or not.

 The surface of the wire can be cracked, without reducing the speed of machining.

 The wire obtained according to the invention is generally yellow-brown in color.

 The surface of the wire should be relatively clean, with few traces of drawing lubricants or other soiling.

 The manufacture of an electrode wire according to the invention can be carried out according to a process comprising the steps: a. provide an unalloyed copper core wire of diameter Dl greater than the diameter D of the wire to be produced, b. cover the core wire with pure zinc to an appropriate thickness, then making the final thickness; vs. subjecting the covered core wire to a heat diffusion treatment, producing a coating layer 17; d. drawing to bring the wire to the final diameter, the coating layer then having a thickness greater than 10% of the final diameter D.

 The present invention is not limited to the embodiments which have been explicitly described, but it includes the various variants and generalizations thereof contained in the field of claims below.

Claims (10)

1-electrode wire for machining by erosive sparking, comprising a metal core (16) coated with a coating layer (17) of diffused zinc alloy, characterized in that: - the core (16) is made of non-copper alloyed, - the coating layer (17) is made of zinc alloy and diffused copper, - the thickness (E) of the coating layer (17) made of copper and zinc alloy is greater than 10% of the diameter (D) of the electrode wire.  2-electrode wire according to claim 1, characterized in that the thickness (E) is greater than 11% of the diameter (D) of the electrode wire.  3-electrode wire according to one of claims 1 or 2, characterized in that the unalloyed copper constituting the core (16) is chosen from the family of recommended brass: Cu-al (Cu-

 AND P) ; Cu-a2 (Cu-FRHC); Cu-b2 (Cu-DLP); Cu-Cl (Cu-OF); Cu-c2 (Cu-OFE).  4-electrode wire according to any one of claims 1 to 3, characterized in that: - for a diameter (D) of electrode wire of 0.25 mm, the thickness (E) of the coating layer is greater or equal to 28 microns, - for a diameter (D) of electrode wire of 0.30 mm, the thickness (E) of the coating layer is greater than or equal to 33 microns, - for a diameter (D) of electrode wire of 0.33 mm, the thickness (E) of the coating layer is greater than or equal to 36 microns, - for a diameter (D) of electrode wire of 0.35 mm, the thickness (E) of the coating layer is greater than or equal to 39 microns.  5-electrode wire according to any one of claims 1 to 4, characterized in that the coating layer (17) is made of copper and zinc alloy in a, ss or ss' phases, the zinc content then being between 35% and 57%, preferably between 35% and 50%.  6-electrode wire according to any one of claims 1 to 5, characterized in that the coating layer (17) is coated with a thin surface layer (21) of contact in zinc, copper, nickel, in silver or gold. <Desc / Clms Page number 11>  7-A method of producing an electrode wire for erosive sparking according to any one of claims 1 to 6, characterized in that it comprises the steps: a. provide an unalloyed copper core wire of diameter (Dl) greater than the diameter (D) of the wire to be produced, b. cover the core wire with pure zinc to an appropriate thickness, c. subjecting the covered core wire to a diffusion heat treatment in order to produce a coating layer (17), d. drawing to bring the wire to the final diameter (D), the coating layer (17) then having a thickness (E) greater than 10% of the final diameter (D) of the wire.  8-A method according to claim 7, characterized in that, in step b, the zinc is deposited on the copper core wire by electrolytic deposition.  9-Method according to one of claims 7 or 8, characterized in that the wire is covered with a thin surface layer (21) of contact in zinc, copper, nickel, silver or gold, after the diffusion step (c) or after the drawing step (d).  10- Use of an electrode wire according to any one of claims 1 to 6 for a method of machining a part by electroerosion in a machining machine with electric generator producing electrical sparking energy, characterized in that the generator is set to produce the maximum sparking energy compatible with the machining capacity of the wire without breaking, thereby increasing the machining speed.