FR2830867B1 - POLYMER OF TRIS (HYDROXYMETHYL) ACRYLAMIDOMETHANE, REVERSE LATEX AND MICROLATEX BY CONTAINING THE SAME, USE OF SAID POLYMER, REVERSE LATEX AND REVERSE MICROLATEX - Google Patents

POLYMER OF TRIS (HYDROXYMETHYL) ACRYLAMIDOMETHANE, REVERSE LATEX AND MICROLATEX BY CONTAINING THE SAME, USE OF SAID POLYMER, REVERSE LATEX AND REVERSE MICROLATEX

Info

Publication number
FR2830867B1
FR2830867B1 FR0113361A FR0113361A FR2830867B1 FR 2830867 B1 FR2830867 B1 FR 2830867B1 FR 0113361 A FR0113361 A FR 0113361A FR 0113361 A FR0113361 A FR 0113361A FR 2830867 B1 FR2830867 B1 FR 2830867B1
Authority
FR
France
Prior art keywords
monomers
polymer
microlatex
oil
reverse
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
FR0113361A
Other languages
French (fr)
Other versions
FR2830867A1 (en
Inventor
Paul Mallo
Guy Tabacchi
Olivier Braun
Bernard Pucci
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Societe dExploitation de Produits pour les Industries Chimiques SEPPIC SA
Original Assignee
Societe dExploitation de Produits pour les Industries Chimiques SEPPIC SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to FR0113361A priority Critical patent/FR2830867B1/en
Application filed by Societe dExploitation de Produits pour les Industries Chimiques SEPPIC SA filed Critical Societe dExploitation de Produits pour les Industries Chimiques SEPPIC SA
Priority to ES02793157T priority patent/ES2320109T3/en
Priority to PCT/FR2002/003394 priority patent/WO2003033553A1/en
Priority to EP02793157A priority patent/EP1448627B1/en
Priority to AT02793157T priority patent/ATE419284T1/en
Priority to EP08166824A priority patent/EP2011805A3/en
Priority to DE60230659T priority patent/DE60230659D1/en
Publication of FR2830867A1 publication Critical patent/FR2830867A1/en
Application granted granted Critical
Publication of FR2830867B1 publication Critical patent/FR2830867B1/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/52—Amides or imides
    • C08F20/54—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide
    • C08F20/58—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide containing oxygen in addition to the carbonamido oxygen, e.g. N-methylolacrylamide, N-acryloylmorpholine

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Cosmetics (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Detergent Compositions (AREA)
  • Polymerisation Methods In General (AREA)

Abstract

Polymers of N-tris(hydroxmethyl)methyl acrylamide, including copolymers with cationic, anionic or neutral comonomers, are new. Polymers obtainable by homopolymerization of N-tris(hydroxmethyl)methyl acrylamide (THAM) or by copolymerization of THAM with one or more cationic monomers, monomers with at least one strong or weak acid function (optionally partially or totally neutralized) or neutral monomers are new. Independent claims are also included for: (1) polymers as above crosslinked with a di- or polyethylenic crosslinking agent; (2) a composition comprising an oil phase, an aqueous phase, a water-in-oil emulsifier and an oil-in-water emulsifier, either in the form of an autoinvertible inverse latex comprising 20-70 wt.% of a polymer as above or in the form of an autoinvertible inverse microlatex comprising 10-50 wt.% of a polymer as above; (3) production of an inverse latex as above by emulsifying an aqueous solution containing the monomers and optional additives in an oil phase in the presence of a water-in-oil emulsifier, polymerizing the monomers after adding a radical initiator and optionally a coinitiator, and adding an oil-in-water emulsifier at a temperature below 50[deg]C; (4) production of an inverse microlatex as above by emulsifying an aqueous solution containing the monomers and optional additives in an oil phase in the presence of one or more emulsifiers to form a microemulsion, and polymerizing the monomers after adding a radical initiator and optionally a coinitiator.
FR0113361A 2001-10-17 2001-10-17 POLYMER OF TRIS (HYDROXYMETHYL) ACRYLAMIDOMETHANE, REVERSE LATEX AND MICROLATEX BY CONTAINING THE SAME, USE OF SAID POLYMER, REVERSE LATEX AND REVERSE MICROLATEX Expired - Fee Related FR2830867B1 (en)

Priority Applications (7)

Application Number Priority Date Filing Date Title
FR0113361A FR2830867B1 (en) 2001-10-17 2001-10-17 POLYMER OF TRIS (HYDROXYMETHYL) ACRYLAMIDOMETHANE, REVERSE LATEX AND MICROLATEX BY CONTAINING THE SAME, USE OF SAID POLYMER, REVERSE LATEX AND REVERSE MICROLATEX
PCT/FR2002/003394 WO2003033553A1 (en) 2001-10-17 2002-10-04 Tris(hydroxymethyl) acrylamidomethane polymer, inverse latex and microlatex containing same, use of said polymer, inverse latex and microlatex
EP02793157A EP1448627B1 (en) 2001-10-17 2002-10-04 Tris(hydroxymethyl) acrylamidomethane polymer, inverse latex and microlatex containing same, use of said polymer, inverse latex and microlatex
AT02793157T ATE419284T1 (en) 2001-10-17 2002-10-04 TRIS(HYDROXYMETHYL)ACRYLAMIDOMETHANE POLYMER, THIS CONTAINS INVERSE LATEX AND MICROLATEX, USE OF THE POLYMER, INVERSE LATEX AND MICROLATEX
ES02793157T ES2320109T3 (en) 2001-10-17 2002-10-04 TRI (HYDROXIMETHYL) POLYMER ACRYLAMIDOMETHANE, REVERSE LATEX AND MICRO-LATEX CONTAINING IT, USE OF SUCH POLYMERS, REVERSED LATEX AND REVERSED MICRO-LATEX.
EP08166824A EP2011805A3 (en) 2001-10-17 2002-10-04 Tris(hydroxymethyl) acrylamidomethane polymers, use thereof
DE60230659T DE60230659D1 (en) 2001-10-17 2002-10-04 TRIS (HYDROXYMETHYL) ACRYLAMIDOMETHANE POLYMER, THIS INTEGRATED INVERSE LATEX AND MICROLATEX, USE OF POLYMER, INVERSE LATEX AND MICROLATEX

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR0113361A FR2830867B1 (en) 2001-10-17 2001-10-17 POLYMER OF TRIS (HYDROXYMETHYL) ACRYLAMIDOMETHANE, REVERSE LATEX AND MICROLATEX BY CONTAINING THE SAME, USE OF SAID POLYMER, REVERSE LATEX AND REVERSE MICROLATEX

Publications (2)

Publication Number Publication Date
FR2830867A1 FR2830867A1 (en) 2003-04-18
FR2830867B1 true FR2830867B1 (en) 2006-12-22

Family

ID=8868380

Family Applications (1)

Application Number Title Priority Date Filing Date
FR0113361A Expired - Fee Related FR2830867B1 (en) 2001-10-17 2001-10-17 POLYMER OF TRIS (HYDROXYMETHYL) ACRYLAMIDOMETHANE, REVERSE LATEX AND MICROLATEX BY CONTAINING THE SAME, USE OF SAID POLYMER, REVERSE LATEX AND REVERSE MICROLATEX

Country Status (6)

Country Link
EP (2) EP2011805A3 (en)
AT (1) ATE419284T1 (en)
DE (1) DE60230659D1 (en)
ES (1) ES2320109T3 (en)
FR (1) FR2830867B1 (en)
WO (1) WO2003033553A1 (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2861397B1 (en) * 2003-10-22 2006-01-20 Soc Dexploitation De Produits Pour Les Industries Chimiques Seppic NEW CONCENTRATED REVERSE LATEX, PROCESS FOR PREPARATION AND USE IN INDUSTRY
EP2202250B1 (en) 2004-08-19 2013-10-09 Covidien LP Water-swellable copolymers and articles and coating made therefrom
US20090208443A1 (en) * 2008-02-19 2009-08-20 Conopco, Inc., D/B/A Unilever Cationic copolymer and starches formulated cosmetic compositions exhibiting radiance with soft focus
US9822297B2 (en) 2015-05-13 2017-11-21 Ecolab Usa Inc. Invertible water-in-oil latices and methods of use

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2482112B1 (en) * 1980-05-09 1985-06-07 Pharmindustrie NOVEL HYDROPHILIC COPOLYMERS BASED ON N- (TRIS (HYDROXYMETHYL) METHYL) ACRYLAMIDE, PROCESSES FOR THEIR PREPARATION, AQUEOUS GELS OF SAID COPOLYMERS AND THEIR USE AS ION EXCHANGERS
GB8713854D0 (en) * 1987-06-13 1987-07-15 Kozulic B Poly-n-acryloyl-tris(hydroxymethyl)aminomethane gels
EP0900786A1 (en) 1997-09-03 1999-03-10 Monsanto Europe S.A./N.V. New surface active compounds, method for their preparation, and their use
FR2781488B1 (en) 1998-07-07 2001-04-13 Snf Sa NOVEL ACRYLIC POLYMERS IN ESSENTIALLY AQUEOUS DISPERSIONS, THEIR PREPARATION PROCESS AND THEIR APPLICATIONS
FR2785801B1 (en) * 1998-11-06 2002-10-18 Seppic Sa NEW REVERSE LATEX AND USE IN COSMETICS

Also Published As

Publication number Publication date
EP1448627A1 (en) 2004-08-25
FR2830867A1 (en) 2003-04-18
EP2011805A2 (en) 2009-01-07
ATE419284T1 (en) 2009-01-15
EP1448627B1 (en) 2008-12-31
EP2011805A3 (en) 2009-01-21
ES2320109T3 (en) 2009-05-19
WO2003033553A1 (en) 2003-04-24
DE60230659D1 (en) 2009-02-12

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Effective date: 20160630