FR2822058A1 - SOLID COMPOSITION CONTAINING AT LEAST 75% BY WEIGHT OF SOLID PARTICLES AND AT LEAST ONE NON-VOLATILE LIQUID OIL - Google Patents

Abstract

The invention relates to a self-supported, compacted powder stick containing at least 75% by weight, in relation to the total weight of the stick, of solid particles and at least one non-volatile liquid oil, said stick being cosmetically and dermatologically acceptable. The stick is preferably a powder stick, in particular a make-up stick and, more specifically, an eye shadow or foundation stick, which can be easily applied and which leaves a natural-looking and homogeneous powdery deposit.

Description

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The present invention relates to a composition for caring for and / or treating and / or making up the skin, including the scalp, and / or the lips of human beings, said composition being solid, in the form of a stick, and containing at least 75%, by weight relative to the total weight of the composition, of solid particles, and at least one liquid non-volatile oil. This composition is stable over time and is in the form of a make-up stick and more particularly make-up for the complexion or eyeshadow, the application of which is easy and results in a powdery deposit, of natural appearance, and homogeneous.

son application jusqu'à épuisement total du produit, contrairement à un fond de teint classique que l'on applique à l'éponge. De plus, la surface du fond de teint reste lisse alors que la surface d'un produit compacté dans un boîtier se déforme sous la pression des prises successives. Enfin, il doit permettre l'obtention d'un maquillage homogène. De plus, les compositions de maquillage doivent présenter une bonne tenue dans le temps et en particulier de la couleur. Une mauvaise tenue se caractérise par une modification de la couleur (virage, palissement) ou une modification inhomogène du maquillage au cours du temps, généralement par suite d'une interaction avec le sébum et/ou la sueur sécrétés par la peau. En effet, une composition qui ne tient pas dans le temps oblige l'utilisateur à se maquiller très souvent. Or à ce jour, les utilisateurs souhaitent embellir leur visage et leur corps en y passant le moins de temps possible. The foundations currently sold are most often either in the form of a liquid packaged in a bottle, or in the form of a product compacted in a box. These foundations require the use of an applicator such as a sponge, which quickly becomes contaminated and must be cleaned very often, especially after each application. Also, users of foundations are increasingly looking for solid foundations in the form of sticks, in order to abstain from the sponge-type applicator. Such a foundation is easy to use, hygienic, allowing

its application until total exhaustion of the product, unlike a classic foundation that is applied with a sponge. In addition, the surface of the foundation remains smooth while the surface of a product compacted in a housing is deformed under the pressure of successive catches. Finally, it must allow obtaining a homogeneous makeup. In addition, the makeup compositions must exhibit good resistance over time and in particular color. Poor behavior is characterized by a change in color (toning, paling) or an inhomogeneous change in makeup over time, generally as a result of an interaction with the sebum and / or sweat secreted by the skin. Indeed, a composition that does not hold over time forces the user to wear makeup very often. However, to date, users want to beautify their face and body by spending as little time as possible.

There therefore remains the need for a composition which does not have the above drawbacks, leading to a deposit on the skin or the lips which is good over time and comfortable. In addition, this composition must be easy to manufacture, easy to apply, and give the deposit a feeling of comfort with a soft touch like peach skin, both during application and over time.

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The subject of the invention is precisely a composition for caring for and / or making up and / or treating the skin and / or the lips of the face and / or the integuments making it possible to remedy the drawbacks mentioned above and to have the properties mentioned above.

Surprisingly, the applicant has found that the combined use of solid particles and at least one non-volatile oil made it possible to obtain a composition in rigid stick form, the application of which to the skin or the lips led to a deposit with remarkable cosmetic properties. In particular, the deposit is flexible and comfortable, unlike the products of the prior art comprising solid particles in large quantities with volatile oil.

The composition according to the invention is a cosmetic care and / or makeup composition, and it applies more generally to skin makeup products, but also to skin care and / or treatment products, including scalp, and lips, facial or human body care products, personal care products and eye makeup products, as well as skin care and makeup products such as keratin fibers than hair, eyelashes and eyebrows. More specifically, the composition according to the invention is in the form of a complexion make-up, in particular a complexion powder, a concealer, an eyeshadow, a blush , a temporary tattoo product, a sun protection product for the skin, face and / or lips, a care product for the face and / or the human body, an eyeliner, an eye pencil, a mascara, or a care and / or makeup product for hair, eyelashes and eyebrows.

More specifically, the subject of the invention is a solid composition, in the form of a stick, containing at least 75%, by weight relative to the total weight of the composition, of solid particles and at least one non-volatile liquid oil, said composition forming a physiologically acceptable medium.

The composition of the invention is solid and is in particular in the form of a powder stick and preferably in the form of an anhydrous stick. This stick is by definition the packaging of the stiffened product in the form of a stick or stick. By abuse of language, we also speak of stick for the product itself. This stick when it is colored allows, after application, to obtain a uniform deposit in color, and of good behavior.

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environ 100 mm, et le rapport h/d est généralement strictement supérieur à 1, de préférence supérieur ou égal à 1, 2. La forme de la composition peut ainsi être généralement sensiblement cylindrique mais elle peut être différente selon l'application envisagée. Ainsi toute autre forme est envisageable dans le cadre de la présente invention. especially color over time. The stick can be a substantially cylindrical shape of height h and the section of which is inscribed in a circle of diameter d (see FIG. 2), preferably the section is substantially a circle of diameter d. h is generally from about 10 to about 100 mm, preferably from about 10 to about 50 mm, d is generally from about 10 to about 100 mm, preferably from about 10 to

about 100 mm, and the h / d ratio is generally strictly greater than 1, preferably greater than or equal to 1, 2. The shape of the composition can thus be generally substantially cylindrical but it can be different depending on the application envisaged. Thus any other form can be envisaged in the context of the present invention.

Advantageously, the composition of the invention is a composition for the skin and better still a composition for making up the complexion, for example complexion powder, concealer product or eyeshadow. The combined presence of solid particles at a certain rate and at least one non-volatile oil makes it possible to obtain, after compaction, a hard, rigid composition at room temperature (about 20 ° C.) and at atmospheric pressure (about 1.013. 105 Pa), does not break during repeated application to the skin or the lips.

According to the invention, the composition in the form of a stick can have a hardness greater than or equal to 0.8 N, measured, at ambient temperature (around 20 ° C.), using a texture analyzer of TA X T2i type, with the following parameters; - the mobile selected is a 1/2 stainless steel ball, - the pre-speed (outward speed before touching the surface of the stick): 0.1 mm / s, - the speed (of penetration): 0.1 mm / s , - post-speed (return speed): 0.1 mm / s, - displacement (depth of penetration): 0.3 mm.

The hardness of the composition according to the invention is such that the composition is advantageously self-supporting and can disintegrate easily to form a satisfactory deposit on the skin and / or the lips and / or the integuments. In addition, with this hardness, the composition of the invention resists impact well.

Solid particles

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 According to the invention, the composition contains at least 75%, by weight relative to the total weight of the composition, of solid particles. By "solid particles" is meant a particulate phase comprising in particular pigments and / or fillers, that is to say all materials in the form of solid particles, insoluble in the composition. We also speak of pulverulent materials or powders according to the invention.

By filler is meant a powder, of mineral origin or not, synthetic or not, colorless or white, constituting the base of the composition according to the invention. By binder is meant any material other than powders, such as a material chosen from liquid, lipophilic or hydrophilic bodies, gelling agents, dispersants, non-aqueous dispersed polymers (non-aqueous dispersion polymers or NAD).

By solid particles, it is also necessary to understand a set of particles of any shape (for example of platelet or lamellar shape, spherical, oblong, hexagonal or polygonal, or any approaching shape), whatever their crystallographic shape (for example of cubic type , hexagonal or orthorhombic). The solid particles can be coated at least partially, preferably completely, in particular with at least one silicone compound, such as polydimethylsiloxanes, and / or polymers, in particular polyethylenes, and / or at least one fluorinated compound and / or at least an amino acid. Preferably, according to the invention, the composition comprises, in addition to the optional fibers, at least one filler of platelet type, that is to say of which the shape of most, preferably all, of the particles is platelet , and / or at least one filler of non-platelet type, that is to say of which the shape of the major part, preferably all, of the particles is other than platelet.

The composition according to the invention therefore generally contains at least one filler of platelet type, generally in an amount from 45 to 98%, preferably from 55 to 95%, even more preferably from 60 to 90%, by weight relative to the total weight of the composition, and / or at least one filler of non-platelet type, generally in an amount from 0.5 to 33%, preferably from 1 to 25%, even more preferably from 4 to 20%, by weight relative to the total weight of the composition.

In particular, the platelet-type filler can be chosen from kaolin, boron nitride, bismuth oxychloride, clays, mica, talc, sericite, hydroxyapatite, or their mixtures, preferably from mica , talc, sericite. Even more preferably, said platelet-type filler is talc.

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En particulier la charge de type non plaquettaire peut être choisie parmi la silice, les poudres de poly-p-alanine, la lauroyl-lysine, l'amidon, les microsphères creuses synthétiques telles que l'Expancel (Nobel Industrie), les microéponges comme le Polytrap (Dow Corning), les microbilles de résine de méthylsilsesquioxane (Tospearls de la Société TOSHIBA, par exemple), le carbonate de calcium précipité, le carbonate et l'hydrocarbonate de magnésium, les microsphères de silice creuses (Silica Beads de la Société MAPRECOS), les microcapsules de verre et de céramique, la poudre de Nylon&commat; sphérique et leurs mélanges.

In particular, the filler of non-platelet type can be chosen from silica, poly-p-alanine powders, lauroyl-lysine, starch, synthetic hollow microspheres such as Expancel (Nobel Industry), micro-sponges such as Polytrap (Dow Corning), methylsilsesquioxane resin microbeads (Tospearls from TOSHIBA, for example), precipitated calcium carbonate, magnesium carbonate and hydrocarbon, hollow silica microspheres (Silica Beads from Company MAPRECOS), glass and ceramic microcapsules, nylon powder &commat; spherical and their mixtures.

According to the invention, the composition may contain, as solid particles, from 0.1 to 30%, preferably from 1 to 25%, even more preferably from 5 to 20%, by weight relative to the total weight of the composition, fiber. By “fiber” is meant any solid particle at ambient temperature and atmospheric pressure, of length greater than the apparent diameter, used alone or in combination, and which is insoluble in the various ingredients of the composition, even when these ingredients are brought to a temperature higher than room temperature and in particular their melting temperature. These fibers are most often and preferably chemically inert, that is to say that they do not react chemically with the various ingredients of the composition. Advantageously, the presence of these fibers makes it possible to improve the homogeneity of the deposit during the application of said product to the keratin fibers and in particular to the skin.

These fibers have melting temperatures at least above 170 C and better still above 200 cC. They may or may not be absorbent, that is to say capable in particular of absorbing the possible liquids of the composition as well as the biological substances secreted by the skin.

The fibers which can be used in the composition of the invention can be fibers of synthetic or natural, mineral or organic origin. They can be short or long, flat, cylindrical, lamellar, unitary or organized, for example braided, hollow or solid. Their shape can be arbitrary and in particular of elliptical or polygonal circular section (triangular, square, hexagonal or octagonal) according to the specific application envisaged. In particular, their ends are blunt and / or polished to avoid jogging.

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Their ends can be any, for example trilobed, pointed, rounded.

In particular, the fibers have a length L ranging from 0.10 mm to 5 mm, preferably from 0.10 mm to 1.5 mm and even more preferably from 0.15 μm to 0.6 mm. Their cross section can be included in a circle with a diameter D ranging from 10 μm to 100 μm, preferably ranging from 10 μm to 60 μm and even more preferably from 10 μm to 50 μm. The weight or title of the fibers is often given in denier or decitex (Dtex) and represents the weight in grams for 9 km of yarn. Preferably, the fibers which can be used in the composition according to the invention have a titer chosen from the range going from 0.10 to 30 denier and preferably from 0.18 to 18 denier.

Advantageously, said fibers have a length L and a diameter D such that UD is chosen from the range from 1 to 2,500, preferably from 1.5 to 500, even more preferably from 3 to 150.

The fibers may be those used in the manufacture of textiles and in particular silk, cotton, wool, linen fibers, cellulose fibers extracted in particular from wood, fruits, vegetables or algae, polyamide fibers ( Nylon &commat;), rayon, viscose, acetate, especially rayon acetate, cellulose, poly-p-phenylene terephthalate fibers, especially Keviare or aramid, acrylic fibers, especially polymethyl methacrylate (PMMA) or poly 2-hydroxyethyl methacrylate, of polyolefin and in particular of polyethylene or polypropylene, of glass, of silica, of carbon in particular in graphite form, of polytetrafluoroethylene (Teflon), of insoluble collagen, of polyesters, of polyvinyl chloride or of vinylidene, polyvinyl alcohol, polyacrylonitrile, chitosan, polyurethane, polyethylene phthalate, fibers formed from a mixture of polymers such as those mentioned above, such as s polyamide / polyester fibers, or polyamide-polyethylene terephthalate blend fibers, carbon fibers, and mixtures thereof.

One can also use the fibers used in surgery such as absorbable synthetic fibers prepared from glycolic acid and e-caprolactone (Monocryl from Johnson &Johnson); resorbable synthetic fibers of the lactic acid and glycolic acid copolymer type (Vicryl from Johnson &Johnson); polyester terephthalic fibers (Ethibond from Johnson & Johnson) and stainless steel wires (Steel from Johnson & Johnson).

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 Furthermore, the fibers may or may not be treated on the surface, coated or not, in particular in order to make them hydrophobic. As coated fibers which can be used in the invention, mention may be made of polyamide fibers coated with copper sulphide for an anti-static effect (for example R-STAT from Rhodia) or another polymer allowing a particular organization of the fibers (treatment specific surface) or surface treatment inducing color / hologram effects (Lurex fiber from Sildorex, for example).

It is also possible to use multilayer flat fibers having goniochromatic properties. Such fibers are in particular formed by alternating layers of polyamide and of polyester, in particular of polyester terephthalate.

Preferably, synthetic fibers are used and in particular organic fibers, such as those used in surgery.

The fibers which can be used in the composition according to the invention are preferably chosen from polyamide, cotton, polyester, cellulose, polyphenylene terephtamide (generally para and / or meta) fibers, and their mixtures. In particular, it is possible to use the polyamide fibers sold by Etablissements P. Bonte under the name Polyamide 0.9 Dtex 0.3 mm, having an average diameter of 6 μm, a weight of approximately (0.9 dtex) and a length ranging from 0.3mm to 1.5mm.

Polyphenylene terephtamide fibers with an average diameter of 12 μm and a length of approximately 1.5 mm can also be used, such as those sold under the name Kevlar Floc by the company Du Pont Fibers.

Preferably the composition according to the invention is a powder composition, that is to say that it comprises, in addition to the solid particles, a phase, liquid or solid, preferably liquid, as a binder. Said phase is generally but not necessarily fatty, and is intended to give the finished product a certain cohesion, to give a softness and an emollient property to the makeup product and to promote its adhesion to the skin. According to the invention, said phase, when it is liquid, comprises at least one non-volatile liquid oil which can serve as a binder in the case where the composition is a powder. The composition according to the invention can also comprise a hydrophilic phase, for example an aqueous phase, which gives them freshness properties on application.

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Preferably, the composition according to the invention can comprise, generally as a solid binder, in addition at least from 0.1 to 30%, preferably from 1 to 15%, by weight relative to the total weight of the composition, metallic soap derived from organic carboxylic acid generally having from 8 to 22 carbon atoms, preferably from 12 to
18 carbon atoms, per molecule, such as for example zinc, magnesium or lithium stearate, zinc laurate, magnesium myristate, and their mixtures.

 On the other hand, the composition according to the invention contains, generally as a liquid binder, at least one non-volatile oil and can also comprise at least one product which is liquid at room temperature such as a volatile oil and / or a solvent. volatile.

The composition according to the invention contains at least one non-volatile oil chosen in particular from hydrocarbon-based oils of mineral, vegetable or synthetic origin, synthetic esters or ethers, silicone oils and / or solvents, fluorinated oils, and their mixtures. The non-volatile oil is generally present in the composition in an amount of 1 to 30%, preferably from 2 to 25%, even more preferably from 5 to 20%, by weight relative to the total weight of the composition. By "non-volatile oil" is meant an oil remaining on the skin or the lips at room temperature and atmospheric pressure for at least one hour and having in particular a vapor pressure, at room temperature and atmospheric pressure, not zero, in particular less than 0 .01 mm Hg (1.33 Pa). In addition, non-volatile silicone oils generally have a viscosity greater than 5 cSt at room temperature and atmospheric pressure.

The presence of such a non-volatile liquid oil advantageously makes it possible to provide a feeling of comfort on application, and avoids the feeling of drying and tightness, which generally develops over the time following application when the composition applied to the skin or keratin fibers comprises at least one volatile liquid oil.

As non-volatile oils present in the composition according to the invention, there may be mentioned in particular: - hydrocarbon oils of animal origin such as perhydrosqualene; - vegetable hydrocarbon oils such as liquid triglycerides of fatty acids

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huiles de paraffine et leurs dérivés, la vaseline, les polydécènes, le polyisobutène hydrogéné tel que le parléam ; - les esters et les éthers de synthèse notamment d'acides gras comme les huiles de formule RiCOOR2 dans laquelle R, représente le reste d'un acide gras supérieur comportant de 1 à 40 atomes de carbone et R2 représente une chaîne hydrocarbonée contenant de 1 à 40 atomes de carbone avec R1 + R2 10 comme par exemple l'huile de Purcellin, l'isononanoate d'isononyle, le myristate d'isopropyle, le palmitat d'éthyl 2-

hexyle, le stéarate d'octyl 2-dodécyle, l'érucate d'octyl 2-dodécyle, l'isostéarate d'isostéaryle ; les esters hydroxylés comme le lactate d'isostéaryle, l'hydroxy stéarate d'octyle, l'hydroxy stéarate d'octyl dodécyle, le malate de di-isostéaryle, le citrate de triisocétyle, des heptanoates, octanoates, décanoates d'alcools gras ; des esters de polyol comme le di-octanoate de propylène glycol, le di-heptanoate de néopentyl glycol, le diisononanoate de di-éthylèneglycol ; et les esters du pent rythritol comme le tétraisostéarate de penta-érythrytyle ; - des alcools gras ayant de 12 à 26 atomes de carbone comme l'octyl dodécanol, le 2-

butyl octanol, le 2-hexyl décanol, le 2-undécylpenta décanol, l'alcool oléique ; - les huiles fluorées partiellement hydrocarbonées et/ou siliconées ; - les huiles siliconées comme les polydiméthylsiloxanes (PDMS) non volatiles, linéaires ou ramifiées ; les potydiméthyfsitoxanes comportant des groupements alkyle, alcoxy ou phényle, pendant ou en bout de chaîne siliconée, groupements ayant de 2 à 24 atomes de carbone ; les silicones phénylées comme les phenyl triméthicones, les phenyl diméthicones, les phényl triméthylsiloxy diphénylsiloxanes, les diphényl diméthicones, les diphényl méthyldiphényl trisiloxanes, les 2-phényléthyl triméthylsiloxysilicates ; - les acides gras ayant au de 12 à 22 atomes de carbone comme l'acide oléique, linolénique et linoléique ; et - leurs mélanges. from 4 to 24 carbon atoms like the triglycerides of heptanoic or octanoic acids, sunflower, corn, soybean, squash, grapeseed, sesame, rapeseed, hazelnut, apricot, macadamia oils , castor, avocado, triglycerides of caprylic / capric acids such as those sold by the company Stearineries Dubois or those sold under the names Miglyol 810,812 and 818 by the company Dynamit Nobel, jojoba oil, shea butter; - linear or branched hydrocarbons, of mineral or synthetic origin such as

paraffin oils and their derivatives, petrolatum, polydecenes, hydrogenated polyisobutene such as parlameam; - synthetic esters and ethers, in particular of fatty acids such as oils of formula RiCOOR2 in which R represents the remainder of a higher fatty acid containing from 1 to 40 carbon atoms and R2 represents a hydrocarbon chain containing from 1 to 40 carbon atoms with R1 + R2 10 such as, for example, Purcellin oil, isononyl isononanoate, isopropyl myristate, ethyl 2- palmitate

hexyl, octyl 2-dodecyl stearate, octyl 2-dodecyl erucate, isostearyl isostearate; hydroxylated esters such as isostearyl lactate, octyl hydroxy stearate, octyl dodecyl hydroxy stearate, di-isostearyl malate, triisocetyl citrate, heptanoates, octanoates, decanoates of fatty alcohols; polyol esters such as propylene glycol di-octanoate, neopentyl glycol di-heptanoate, di-ethylene glycol diisononanoate; and pent rythritol esters such as penta-erythrytyl tetraisostearate; - fatty alcohols having from 12 to 26 carbon atoms such as octyl dodecanol, 2-

butyl octanol, 2-hexyl decanol, 2-undecylpenta decanol, oleic alcohol; - partially hydrocarbon and / or silicone fluorinated oils; - non-volatile, linear or branched silicone oils such as polydimethylsiloxanes (PDMS); potydimethyfsitoxanes comprising alkyl, alkoxy or phenyl groups, during or at the end of the silicone chain, groups having from 2 to 24 carbon atoms; phenylated silicones such as phenyl trimethicones, phenyl dimethicones, phenyl trimethylsiloxy diphenylsiloxanes, diphenyl dimethicones, diphenyl methyldiphenyl trisiloxanes, 2-phenylethyl trimethylsiloxysilicates; - fatty acids having from 12 to 22 carbon atoms such as oleic, linolenic and linoleic acid; and - their mixtures.

Finally, said non-volatile liquid oil can also be a compound such as the combination of ester and silicone compound described in patent application EP-1,044. 677, or any other

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corps gras cité dans ladite demande, ou les composés particuliers cités dans les demandes de brevet EP-0. 923. 927 et EP-0. 792. 633 ou dans le brevet EP-0. 583. 460.

fatty substance cited in said application, or the specific compounds cited in patent applications EP-0. 923. 927 and EP-0. 792. 633 or in patent EP-0. 583. 460.

la composition à raison de 1 à 30%, de préférence de 2 à 25%, de manière encore plus préférée de 5 à 20%, en poids par rapport au poids total de la composition. In addition, the composition may contain, generally as co-binder for pulverulent materials or powders, at least one product which is liquid at room temperature, said product being chosen in particular from volatile oils and / or volatile hydrocarbon solvents of origin. mineral, vegetable or synthetic, volatile esters or volatile synthetic ethers, volatile oils and / or volatile silicone solvents, volatile oils and / or volatile fluorinated solvents, and mixtures thereof. Most often said liquid product is lipophilic, but it is also possible that said product is hydrophilic. Such a liquid, lipophilic or hydrophilic product, if it is present, is generally present in

the composition in an amount of 1 to 30%, preferably from 2 to 25%, even more preferably from 5 to 20%, by weight relative to the total weight of the composition.

The composition can therefore comprise a solvent or a volatile oil. By "solvent or volatile oil" is meant within the meaning of the invention any non-aqueous medium capable of evaporating on contact with the skin or the lips in less than an hour, at room temperature and atmospheric pressure. The volatile solvent and / or the volatile oil in the composition according to the invention are organic solvents and in particular volatile cosmetic oils, liquid at room temperature, having a non-zero vapor pressure, at room temperature and atmospheric pressure, ranging from in particular from 10-2 to 300mm Hg (1.33 to 40,000 Pa), preferably from 0.1 to 90mm Hg (13 to 12,000 Pa), even more preferably greater than 0.3mm Hg ( 40 Pa). In addition, volatile silicone oils generally have a viscosity of less than 5 cSt at room temperature and atmospheric pressure.

carbone. Comme huile de silicone volatile utilisable dans l'invention, on peut citer notamment l'octaméthyl cyclotétrasiloxane, le décaméthyl cyclopentasiloxane, le dodécaméthyl cyclohexasiloxane, l'heptaméthyl hexyltrisiloxane, l'heptaméthyloctyl trisiloxane, l'hexaméthyl disiloxane, l'octaméthyl trisiloxane, le décaméthyl tétrasiloxane, le dodécaméthyl pentasiloxane et leurs mélanges. As volatile solvent and / or volatile oil which can be used in the invention, mention may be made of linear or cyclic silicone oils having a viscosity at room temperature of less than 5 cSt and having in particular from 2 to 7 silicon atoms, these silicones optionally comprising alkyl or alkoxy groups having from 1 to 10 atoms

carbon. As volatile silicone oil which can be used in the invention, there may be mentioned in particular octamethyl cyclotetrasiloxane, decamethyl cyclopentasiloxane, dodecamethyl cyclohexasiloxane, heptamethyl hexyltrisiloxane, heptamethyloctyl trisiloxane, hexamethyl disiloxane, octamethyl trisil tetrasiloxane, dodecamethyl pentasiloxane and mixtures thereof.

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As other volatile solvent eVou volatile oil which can be used in the invention, there may be mentioned volatile hydrocarbon oils having from 8 to 16 carbon atoms and their mixtures and in particular branched alkanes of Cg-Cie such as iso-alkanes (also called isoparaffins) in Cs-Cie of petroleum origin, isododecane, isodecane, isohexadecane and for example the oils sold under the trade names of Isopars'ou or Peutyls, branched esters in Cg-Cie such as neopentanoate iso-hexyl and mixtures thereof. Preferably, the volatile solvent is chosen from volatile hydrocarbon oils having from 8 to 16 carbon atoms and their mixtures.

It is also possible to use volatile fluorinated solvents.

Preferably, isododecane (Permyls 99 A) is used, the Cg-Cie isoparaffins (Isopars L, E, H), their mixtures, optionally combined with decamethyl tetrasiloxane.

The compositions according to the invention can comprise a compound with an aqueous continuous phase, which generally functions as a co-binder, and which can represent up to 30%, preferably from 0.1 to 23%, and even more preferably from 3 to 20%, by weight relative to the total weight of the composition.

The aqueous phase of said co-binder according to the invention can comprise water or a floral water such as blueberry water.

Said aqueous phase can also comprise from 0% to 15% by weight, relative to the total weight of the aqueous phase, of a lower C2-C6 monoalcohol and / or of a polyol such as glycerol, butylene glycol, l isoprene glycol, propylene glycol.

acrylique/acrylate d'éthyle et les polymères carboxyvinyliques. Des exemples de tels polymères ou copolymères sont notamment les"carbomer" (CTFA) vendus par la société GOODRICH sous la dénomination Carbopol ou le polyglycérylméthacrylate vendu par la société GUARDIAN sous la dénomination Lubragel ou encore le polyglycérylacrylate vendu sous la dénomination Hispagel par la société HISPANO CHIMICA ou enfin le mélange polyacrylamide/C13-C14 Isoparaffin/Laureth7 vendu par la société SEPPIC sous la dénomination Sepigel. The aqueous phase can also comprise one or more gelling agents. Among these gelling agents, mention may be made of hydrophilic polymers such as acid copolymers

acrylic / ethyl acrylate and carboxyvinyl polymers. Examples of such polymers or copolymers are in particular the "carbomer" (CTFA) sold by the company GOODRICH under the name Carbopol or the polyglyceryl methacrylate sold by the company GUARDIAN under the name Lubragel or else the polyglyceryl acrylate sold under the name Hispagel by the company HISPANO CHIMICA or finally the polyacrylamide / C13-C14 Isoparaffin / Laureth7 mixture sold by the company SEPPIC under the name Sepigel.

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 As other gelling agents which can be used in the invention, mention may be made of: polysaccharide derivatives, such as cellulose derivatives such as carboxy-methylcellulose, hydroxymethylcellulose, hydroxypropylcellulose, microcrystalline cellulose; polymers of xanthan, gellan, rhamsan, alginates, maltodextrin, starch and its derivatives, hyaluronic acid and its salts, karoya gum, carob flour, guar derivatives, in particular hydropropylguar .

Polyethylene glycols (PEG) and their derivatives, polyvinylpyrrolidones and their derivatives can also be used as hydrophilic polymer.

In a preferred embodiment of the invention, the compound is an O / W emulsion stabilized by one or more organized systems. By organized systems is meant in the sense of the present invention reverse micelles or Iyotropic liquid crystal structures which are formed at room temperature by the mixture of several surfactants or the mixture of surfactants and polar solvents or the mixture of several solvents polar, the polar solvents being for example chosen from water, glycerol, panthenol, propylene glycol, butylene glycol and / or mixtures thereof. The liquid crystalline state is an intermediate state between the solid state and the liquid state. It is often called a mesomorphic state. Organized systems are thermodynamically stable. They are preferably chosen from Iyotropic liquid crystals. The Iyotropic liquid crystal state can be characterized by a person skilled in the art by known means such as transmission electron microscopy (after negative staining or cryofracture) or birefringence under polarized light and X-ray diffraction. Iyotropic liquid crystals can include reverse hexagonal liquid crystals, also known as hexagonal phase II or phase F, direct hexagonal liquid crystals, also known as hexagonal phase 1, cubic liquid crystals, also known as phase 12, and lamellar liquid crystals, also known as La phase and D phase.

The composition of the invention can, in addition, contain an aqueous phase containing water optionally thickened or gelled by a thickener or a gelling agent of aqueous phase and optionally compounds miscible with water. For an emulsion, for example of the water-in-oil or oil-in-water type, it is possible to use from 0.1 to 85%, preferably from 2 to 60% of water, by weight relative to the total weight of binder of composition. In the case of an emulsion; the composition according to the invention also advantageously comprises at least one surfactant chosen from hydrophilic surfactants,

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 HLB (English acronym for BHL = Lipophilic Hydrophilic Balance) generally greater than 8, suitable for the manufacture of stable water-in-oil emulsion and oil-in-water-in-oil or water-in-oil- emulsion in-water, and lipophilic surfactants, of HLB generally less than 6, suitable for the production of oil-in-water or water-in-oil-in-water emulsion. The surfactant can be monomeric or polymeric in nature.

antioxydants, les huiles essentielles, les conservateurs, les parfums, les cires, les produits pâteux à température ambiante, les neutralisants, les polymères liposolubles ou dispersibles dans le milieu, les gélifiants de phase grasse, les actifs cosmétiques ou dermatologiques comme par exemple des émollients, des hydratants, des vitamines, des acides gras essentiels, des filtres solaires, les dispersants et leurs mélanges. Ces additifs peuvent être présents dans la composition à raison de 0 à 20% (notamment de 0,01 à 20 %), de préférence de 0,01 à 10%, en poids par rapport au poids total de la composition (si présents). Additives The composition of the invention may also comprise at least one additive, usually used in the field concerned, and chosen in particular from

antioxidants, essential oils, preservatives, perfumes, waxes, pasty products at room temperature, neutralizers, liposoluble or dispersible polymers in the medium, fatty phase gelling agents, cosmetic or dermatological active ingredients such as emollients , moisturizers, vitamins, essential fatty acids, sunscreens, dispersants and their mixtures. These additives can be present in the composition at a rate of 0 to 20% (in particular from 0.01 to 20%), preferably from 0.01 to 10%, by weight relative to the total weight of the composition (if present) .

et/ou leur quantité de telle manière que les propriétés avantageuses de la composition selon l'invention ne soient pas ou substantiellement pas, altérées par l'adjonction envisagée. Of course the person skilled in the art will take care to choose any additional additives

and / or their quantity in such a way that the advantageous properties of the composition according to the invention are not or not substantially altered by the addition envisaged.

The composition according to the invention also contains at least one fatty compound which is pasty at room temperature. By “pasty fatty substance” within the meaning of the invention is meant fatty substances having a melting point ranging from 20 to 55 ° C., preferably 25 to 45 ° C., and / or a viscosity at 40 DC ranging from 0.1 at 40 Pa. s (1 to 400 poises), preferably 0.5 to 25 Pa. s, measured on Contraves TV or Rhéomat 80, equipped with a mobile rotating at 240 rpm (for revolutions per minute). Those skilled in the art can choose the mobile for measuring the viscosity, from the mobile MS-r3 and MS-r4, based on their general knowledge, so as to be able to measure the pasty compound tested.

According to the invention, one or more pasty fatty substances can be used. Preferably, these fatty substances are hydrocarbon compounds, optionally of the polymeric type; they

<Desc / Clms Page number 14>

 can also be chosen from silicone and / or fluorinated compounds; they can also be in the form of a mixture of hydrocarbon and / or silicone and / or fluorinated compounds. In the case of a mixture of different pasty fatty substances, use is preferably made of pasty hydrocarbon compounds (containing mainly carbon and hydrogen atoms and optionally ester groups), in the majority proportion.

acétylées ou les lanolines oxypropylènées ou le lanolate d'isopropyle, ayant une viscosité de 18 à 21 Pa. s, de préférence 19 à 20,5 Pa. s, et/ou un point de fusion de 30 à 55 C et leurs mélanges. On peut également utiliser des esters d'acides ou d'alcools gras, notamment ceux ayant 20 à 65 atomes de carbone (point de fusion de l'ordre de 20 à

35 C et/ou viscosité à 40'C allant de 0, 1 à 40 Pa. s) comme le citrate de tri-isostéaryle ou de cétyle ; le propionate d'arachidyle ; le polylaurate de vinyle ; les esters du cholestérol comme les triglycérides d'origine végétale tels que les huiles végétales hydrogénées, les polyesters visqueux comme l'acide poly (12-hydroxystéarique) et leurs mélanges. Comme triglycérides d'origine végétale, on peut utiliser les dérivés d'huile de ricin hydrogénée, tels que le"THIXINR"de Rhéox. Among the pasty compounds capable of being used in the composition according to the invention, mention may be made of lanolins and lanolin derivatives such as lanolines

acetylated or oxypropylenated lanolines or isopropyl lanolate, having a viscosity of 18 to 21 Pa. s, preferably 19 to 20.5 Pa. s, and / or a melting point of 30 to 55 C and their mixtures. It is also possible to use fatty acid or alcohol esters, in particular those having 20 to 65 carbon atoms (melting point of the order of 20 to

35 C and / or viscosity at 40 ° C ranging from 0.1 to 40 Pa. S) such as tri-isostearyl or cetyl citrate; arachidyl propionate; vinyl polylaurate; cholesterol esters such as triglycerides of plant origin such as hydrogenated vegetable oils, viscous polyesters such as poly (12-hydroxystearic acid) and their mixtures. As triglycerides of vegetable origin, it is possible to use derivatives of hydrogenated castor oil, such as "THIXINR" from Rheox.

Mention may also be made of silicone pasty fatty substances such as polydimethylsiloxanes (PDMS) having pendant chains of the alkyl or alkoxy type having from 8 to 24 carbon atoms, and a melting point of 20-55 C, such as stearyl dimethicones in particular those sold by the company Dow Corning under the trade names DC2503 and DC25514, cetyl dimethicones for example that sold by the company Goldschmidt under the trade name Abil Wax 9814 and their mixtures.

The composition according to the invention may be in the form of a dermatological tinted composition or for caring for keratin materials such as the skin, the lips and / or the integuments, in the form of a composition for sun protection or for personal hygiene. especially in the form of a deodorant product in the form of a stick. It can in particular be used as a care base for the skin, the integuments or the lips. According to the present invention, keratin materials are understood to mean the skin, the nails, the hair, the eyelashes and eyebrows, the mucous membranes (inside of the lower eyelids). ) and the semi-mucous membranes (lips), and any other skin area of the body and face.

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The composition of the invention can also be in the form of a colored product for making up the skin, in particular a make-up for the complexion, optionally having care or treatment properties, a blush, a blush or eyelids, concealer, eyeliner, body makeup; for making up the lips such as a lip powder, optionally having care or treatment properties; makeup makeup appendages such as nails, eyelashes in particular in the form of a bread mascara, eyebrows and hair in particular in the form of pencil.

Of course, the composition of the invention must be cosmetically or dermatologically acceptable, ie contain a physiologically acceptable medium which is non-toxic and capable of being applied to the skin, the integuments or the lips of human beings. By cosmetically acceptable is meant within the meaning of the invention a composition of pleasant appearance, odor and feel. The term “dermatologically acceptable” is intended to mean non-toxic and capable of being applied to the skin, the integuments or the lips of human beings.

Advantageously, the composition can contain at least one coloring material.

The coloring matter according to the invention can be chosen from lipophilic dyes, hydrophilic dyes, pigments and nacres usually used in cosmetic or dermatological compositions, and mixtures thereof. This coloring material is generally present in an amount of 0.01 to 30%, preferably from 2 to 30% and even more preferably from 3 to 20%, by weight relative to the total weight of the composition, if it is present .

Green 6, le ss-carotène, l'huile de soja, le D & C Yellow 11, le D & C Violet 2, le D & C orange 5, le jaune quinoléine, le rocou, et leurs mélanges. Les colorants hydrosolubles sont par exemple le jus de betterave, le bleu de méthylène, et leurs mélanges. The liposoluble dyes are for example Sudan red, D & C Red 17, D & C

Green 6, ss-carotene, soybean oil, D & C Yellow 11, D & C Violet 2, D & C orange 5, quinoline yellow, annatto, and their mixtures. The water-soluble dyes are, for example, beet juice, methylene blue, and their mixtures.

de fer et/ou de chrome, le violet de manganèse, le bleu outremer, l'hydrate de chrome, le bleu ferrique, et leurs mélanges. Parmi les pigments organiques, comprenant les laques, The pigments can be white or colored, mineral and / or organic, coated or not. Among the mineral pigments, mention may be made of titanium dioxide, optionally surface-treated, zirconium, zinc and / or cerium oxides, as well as oxides

of iron and / or chromium, manganese violet, ultramarine blue, chromium hydrate, ferric blue, and their mixtures. Among the organic pigments, including lacquers,

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 mention may be made of carbon black, pigments of the D & C type, and lakes based on barium, strontium, calcium, aluminum combined with at least one dye, for example cochineal carmine.

The pearlescent pigments can be chosen from white pearlescent pigments such as mica coated with titanium or bismuth oxychloride, colored pearlescent pigments such as titanium mica coated with at least one iron oxide, mica titanium coated especially with blue ferric and / or chromium oxide, titanium mica coated with at least one organic pigment of the aforementioned type, as well as pearlescent pigments based on bismuth oxychloride.

The composition according to the invention can be produced by a process comprising a step of mixing the various ingredients in powder form in a mixing device, the ingredients in liquid or semi-pasty form being added at the end of mixing, then a disagglomeration step in a grinding device, and finally a compacting step in a pressing or compacting device, said devices being devices known in the cosmetic or dermatological field. It can be manufactured by the process which consists in mixing the various ingredients, the binder being added at the end of the mixing, then in disaggregating the whole until a homogeneous mixture is obtained. The homogeneous mixture obtained can then be poured into an appropriate pressing or compacting device.

The compaction pressure of the mixture is generally between 200 and 700 kg / cm2. The homogeneous mixture is poured into a mold, of shape corresponding to the desired shape of the stick to be obtained, and the pressure is applied by means of a piston with evacuation of the air, until said stick is obtained.

The subject of the invention is also a cosmetic process for caring for, making up or treating keratin materials of human beings and in particular of the skin, lips and integuments, comprising ication on the keratin materials of the composition in particular cosmetic as defined above.

The examples which follow illustrate the implementation of the process of the invention and the products obtained. All the examples have been implemented by means of a compacting device as shown in the figures. Among these figures,

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'La figure 1 représente une coupe schématique dudit dispositif de compactage en coupe longitudinale 'La figure 2 représente de façon schématique le stick réalisé par le dispositif de compactage 'La figure 3 représente schématiquement le stick dans un conditionnement 9.

'Figure 1 shows a schematic section of said compacting device in longitudinal section' Figure 2 shows schematically the stick produced by the compacting device 'Figure 3 schematically shows the stick in a package 9.

The compacting device comprises an implementation cell 1 having a compression chamber 3 of cylindrical shape, into which is likely to penetrate a piston 2 linked to an upper press plate (not shown). Chamber 3 rests on a removable support 4 which seals it at the bottom, and is provided with a sinter 5 and a duct 6 for evacuating air.

The sticks 7 produced in the examples are of cylindrical shape such as the stick 7 shown in FIGS. 1 and 2, with a diameter d equal to 2 cm and a length h equal to 2.1 cm.

The stick 7 is placed in a conventional packaging 9, as shown in Figure 3, comprising a pusher 8 to allow the end of the stick to come out as it wears.

The invention is illustrated in more detail in the following examples. The quantities are given in percentage by mass.

Example sticks operating mode All of the pulverulent compounds (including the fibers) are first mixed in a turbine mixer (brand: Baker-Perkins) or ribbon mixer (Lödige brand), then deagglomerated in a mill pins ("Alpine" brand).

The mixture thus obtained is then transferred again to the turbine mixer and the liquid phase is added with gentle stirring, for 5 min.

8 to 10 grams of the mixture are then compacted in a press for 15 minutes under a compacting pressure of 500 kg / cm2. The product obtained is removed from the mold. A stick 7 of cylindrical shape is obtained as described in FIG. 2 and as packaged in FIG. 3.

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Example 1: Eyeshadow An eyeshadow of the following composition was prepared:. Talc 63, 4%. Polyamide fiber (0.3 mm long, 0.9 Dtex) 15%. Non-volatile silicone oil * 15%. Pigments (red and yellow iron oxides) 4%. 2.5% magnesium stearate. Preservative 0, 1% *: mixture 12. 3/19. 8 / 67.9 (in% by weight) of the non-volatile oils that are a poly methylketyl dimethylsiloxane (sold under the name Abil Wax 9801 by the company Goldschmidt), a mixture of trimethyl siloxysilicate resin and pols dimethyl siloxane (sold under the name DC 593 by the company Dow Corning, and a poly dimethyl siloxane (sold under the name DC 200 by the company Dow Corning).

EXAMPLE 2 Face Stick A make-up of the complexion was prepared, in the form of a powdered complexion stick, of the following composition:. Talc 70.9%. Cotton fiber (0.3 mm long) 7.5%. Nylon powder (Orgasol &commat;) 10%. Non-volatile silicone oil (the same as that of Example 1) 7.5%. Pigments (black, red and yellow iron oxides) 3%. Nanotitane 1%. Preservative 0.1% The compositions of Examples 1 and 2, in the form of a stick, are compositions with a smooth appearance, even after several applications, of good performance (progressive and homogeneous reduction over time in makeup).

Finally, these compositions were considered to be applied well, with a soft touch, called peach skin, of good comfort, giving a powdery and natural make-up. The

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 skin is unified and makeup is uniform. The presence of non-volatile silicone oil has also made it possible to improve their comfort properties.

Claims (45)

 1. Solid composition in the form of a stick (7), containing at least 75% of solid particles and at least one non-volatile liquid oil, said composition forming a physiologically acceptable medium. 2. Composition according to claim 1 such that the stick is anhydrous. 3. Composition according to one of claims 1 or 2 of substantially cylindrical shape. 4. Composition according to the preceding claim, such that the composition has the shape of a cylinder of height h between 10 and 100 mm, preferably between 10 and 50 mm, and whose section is part of a circle with a diameter between 10 and 100 mm, preferably between 10 and 50 mm. 5. Composition according to the preceding claim such that the ratio h / d is strictly greater than 1, preferably greater than or equal to 1.2. 6. Composition according to one of the preceding claims, such that the non-volatile oil is present in the composition in an amount of 1 to 30%, preferably from 2 to 25%, even more preferably from 5 to 20%, in weight relative to the total weight of the composition. 7. Composition according to one of the preceding claims, such that said non-volatile oil is chosen from: perhydrosqualene, triglycerides of heptanoic or octanoic acids, sunflower, corn, soybean, squash, grapeseed oils, sesame, rapeseed, hazelnut, apricot, macadamia, castor, avocado, triglycerides of caprylic / capric acids, jojoba oil, shea butter, paraffin oils and their derivatives, petrolatum, polydecenes,

 hydrogenated polyisobutene, Purcellin oil, isononyl isononanoate, isopropyl myristate, ethyl 2-hexyl palmitate, octyl 2-dodecyl stearate, octyl 2-dodecyl erucate , isostearyl isostearate, isostearyl lactate, octyl hydroxy stearate, octyl dodecyl hydroxy stearate, diisostearyl malate, triisocetyl citrate, heptanoates, octanoates, decanoates d fatty alcohols, propylene glycol di-octanoate, neopentyl di-heptanoate <Desc / Clms Page number 21>  methyldiphenyl trisiloxanes, 2-phenylethyl trimethylsiloxysilicates, oleic, linolenic and linoleic acid; and their mixtures.

 glycol, di-ethylene glycol di-isononanoate, pentaerythrytyl tetra-isostearate, octyl dodecanol, 2-butyl octanol, 2-hexyl decanol, 2-undecylpenta decanol, oleic alcohol partially hydrocarbon-based and / or silicone fluids, non-volatile, linear or branched polydimethylsiloxanes (PDMS); polydimethylsiloxanes comprising alkyl, alkoxy or phenyl groups, during or at the end of the silicone chain, groups having from 2 to 24 carbon atoms, phenyl trimethicones, phenyl dimethicones, phenyl trimethylsiloxy diphenylsiloxanes, diphenyl dimethicones, diphenyls

8. Composition according to one of the preceding claims, such that the solid particles are at least partially coated with at least one silicone compound and / or polymers and / or at least one fluorinated compound and / or at least one amino acid. 9. Composition according to one of the preceding claims comprising at least one charge of platelet type and / or at least one charge of non-platelet type. 10. Composition according to one of the preceding claims comprising at least one filler of platelet type, chosen from kaolin, boron nitride, oxychloride

 of bismuth, clays, mica, talc, sericite, hydroxyapatite, or their mixtures, preferably among mica, talc, sericite, even more preferably talc. 11. Composition according to the preceding claim such that said charge of platelet type is in an amount from 45 to 98%, preferably from 55 to 95%, even more preferably from 60 to 90%, by weight relative to the total weight of the composition. 12. Composition according to one of the preceding claims comprising at least one filler of non-platelet type, in an amount of 0.5 to 33%, preferably from 1 to 25%, even more preferably from 4 to 20%, by weight relative to the total weight of the composition. <Desc / Clms Page number 22>

 13. Composition according to the preceding claim such that the non-platelet filler is chosen from silica, powders of poty - atanine,) tauroyt-iysine, starch, synthetic hollow microspheres, micro sponges, microbeads of resin methylsilsesquioxane, precipitated calcium carbonate, carbonate and magnesium hydrocarbonate, hollow silica microspheres, glass and ceramic microcapsules, nylon powder &commat; spherical and their mixtures. 14. Composition according to one of the preceding claims as it comprises 0.1 to 30%, preferably 1 to 25%, even more preferably 5 to 20%, by weight relative to the total weight of the composition, of fibers. 15. Composition according to claim 14 such that the fibers are chosen from silk, cotton, wool, linen, cellulose fibers extracted in particular from wood, fruits, vegetables or algae, polyamide, rayon, viscose, acetate, especially rayon acetate, cellulose or silk, poly-p-phenylene terephtamide fibers, acrylic fibers, in particular polymethyl methacrylate or poly 2-hydroxyethyl methacrylate, polyolefin and especially polyethylene or of polypropylene, of glass, of silica, of aramid, of carbon in particular in graphite form, of polytetrafluoroethylene, of insoluble collagen, of polyesters, of polyvinyl chloride or of vinylidene, of polyvinyl alcohol, of polyacrylonitrile, of chitosan, polyurethane, polyethylene phthalate, fibers from polymer blends, carbon fibers, absorbable synthetic fibers prepared from glycolic acid and e-caprolactone; resorbable synthetic fibers of the lactic acid and glycolic acid copolymer type; polyester terephthalic fibers, stainless steel wire and their blends. 16. Composition according to one of claims 14 or 15 such that the fibers are chosen from multilayer flat fibers. 17. Composition according to the preceding claim, such that said fibers are polyamide and polyester fibers. 18. Composition according to one of claims 14 to 17 such that the fiber is treated or hydrophobic coated. <Desc / Clms Page number 23>  19. Composition according to one of claims 14 to 18 such that the fibers are chosen from polyamide, cotton, polyester, cellulose, polyphenylene terephtamide fibers, and their mixtures. 20 .. Composition according to one of claims 14 to 19 such that the fibers have a length L and a diameter D such that UD is chosen from the range from 1 to 2 500, preferably from 1.5 to 500, even more preferably from 3 to 150. 21. Composition according to one of claims 14 to 20 such that the fibers have a length L ranging from 0.10 mm to 5 mm, preferably from 0.10 mm to 1.5 mm and even more preferably from 0 , 15 µm to 0.6 mm. 22. Composition according to one of claims 14 to 21 such that the fibers have a section which can be included in a circle of diameter D ranging from 10 µm to 100 µm, preferably ranging from 10 µm to 60 µm and even more favorite of 10 µm to 50 µm. 23. Composition according to one of claims 14 to 22 such that the fibers have a denier titer chosen from the range going from 0.10 to 30 denier and preferably from 0.18 to 18 denier. 24. Composition according to one of the preceding claims, such that it has a hardness greater than or equal to 0.8 N, measured, at ambient temperature, using a texture analyzer of TA X T2i type, with the following parameters. ; - the mobile selected is a 1/2 stainless steel ball, - the pre-speed (outward speed before touching the surface of the stick): 0.1 mm / s, - the speed (of penetration): 0.1 mm / s , - post-speed (return speed): 0.1 mm / s, - displacement (depth of penetration): 0.3 mm. 25. Composition according to one of the preceding claims as it is in the form of a powder composition. 26. Composition according to the preceding claim such that said composition comprises, in addition to solid particles, a phase as a binder. <Desc / Clms Page number 24> 27. Composition according to one of the preceding claims as it contains at least 0.1 to 30%, preferably from 1 to 15%, by weight relative to the total weight of the composition, of metal soap derived from acid. organic carboxylic generally having from 8 to 22 carbon atoms, preferably from 12 to 18 carbon atoms, per molecule. 28. Composition according to the preceding claim such that said soap is chosen from zinc, magnesium or lithium stearate, zinc laurate, magnesium myristate, and mixtures thereof. 29. Composition according to one of the preceding claims as it contains at least one product which is liquid at room temperature such as a volatile oil and / or a volatile solvent, said product being chosen in particular from volatile oils and / or

 volatile hydrocarbon solvents of mineral, vegetable or synthetic origin, volatile esters or volatile synthetic ethers, volatile oils and / or volatile silicone solvents, volatile oils and / or volatile fluorinated solvents, and mixtures thereof. 30. Composition according to the preceding claim such that said liquid product is lipophilic or hydrophilic present in the composition in an amount of 1 to 30%, preferably from 2 to 25%, even more preferably from 5 to 20%, by weight per relative to the total weight of the composition. 31. Composition according to one of claims 29 or 30 such that said volatile solvent

 and / or said volatile oil is chosen from octamethyl cyclotetrasiloxane, decamethyl cyclopentasiloxane, dodecamethyl cyclohexasiloxane, heptamethyl hexyltrisiloxane, heptamethyloctyl trisiloxane, hexamethyl disiloxane, octamethyl trisilethylane pentamethylane pentamethylanetanesiloxane dexamethyletisiloxane pentamethylane isododecane, isodecane, isohexadecane, isohexyl neopentanoate, volatile fluorinated solvents, and mixtures thereof 32. Composition according to one of the preceding claims which also contains at least one compound with an aqueous continuous phase. <Desc / Clms Page number 25> 33. Composition according to the preceding claim such that said compound represents up to 30%, preferably from 0.1 to 23%, and even more preferably from 3 to 20%, by weight relative to the total weight of the composition. 34. Composition according to one of the preceding claims as it further comprises at least one additive chosen from antioxidants, essential oils, preservatives, perfumes, waxes, pasty products at room temperature,

 neutralizers, liposoluble or dispersible polymers in the medium, fatty phase gelling agents, emollients, moisturizers, vitamins, essential fatty acids, sunscreens, dispersants and their mixtures. 35. Composition according to the preceding claim such that said additive is present in an amount of 0.01 to 20%, preferably from 0.01 to 10%, by weight relative to the total weight of the composition. 36. Composition according to one of the preceding claims as it comprises at least one coloring material chosen from lipophilic dyes, hydrophilic dyes, pigments, nacres and their mixtures. 37. Composition according to the preceding claim, such that the coloring material is present in an amount of 0.01 to 30%, preferably from 2 to 30% and even more preferably from 3 to 20%, by weight relative to the total weight. of composition.

38. Composition according to one of claims 36 or 37 such that said coloring material is chosen from Sudan red, D & C Red 17, D & C Green 6, pcarotene, soybean oil, D & C Yellow 11, D & C Violet 2, D & C orange 5, quinoline yellow, annatto, beet juice, methylene blue, titanium dioxide, zirconium, zinc and / or oxides of cerium, iron and / or chromium oxides, manganese violet, ultramarine blue, chromium hydrate, ferric blue, carbon black, pigments of type D & C, lacquers based on barium, strontium, calcium, and / or aluminum combined with at least one dye, mica coated with titanium or bismuth oxychloride, mica titanium coated with at least one iron oxide, mica titanium coated with ferric blue and / or chromium oxide, titanium mica coated with at least one organic pigment, pearlescent pigments based on bismuth oxychloride, and mixtures thereof. <Desc / Clms Page number 26>  39. Composition according to one of the preceding claims as it also contains at least one fatty compound which is pasty at room temperature. 40. Composition according to the preceding claim such that said pasty body is chosen lanolins and lanolin derivatives, tri-isostearyl or cetyl citrate, arachidyl propionate, vinyl polylaurate, hydrogenated vegetable oils, poly (12-hydroxystearic) acid, hydrogenated castor oil derivatives, stearyl dimethicones, cetyl dimethicones and mixtures thereof. 41. Composition according to one of the preceding claims, in the form of a make-up for the complexion, a concealer product, an eyeshadow, a blush, a tattoo product. ephemeral, a sun protection product for the skin, face and / or lips, a care product for the face and / or the human body, an eyeliner, an eye pencil, a mascara, or a care and / or makeup product for hair, eyelashes and eyebrows. 42. Composition according to one of the preceding claims chosen from compositions of complexion powders, concealer products or eyeshadows. 43. A method of manufacturing a composition according to one of the preceding claims comprising a step of mixing the various ingredients in powder form in a mixing device, the ingredients in liquid or semi-pasty form being added at the end of mixing, then a deagglomeration step in a grinding device, and finally a compaction step in a pressing or compacting device. 44. Method according to the preceding claim such that the compaction pressure of the mixture is between 200 and 700 kg / cm2 45. Cosmetic method for caring for, making up or treating keratin materials of human beings, comprising the application to the keratin materials of the composition according to one of claims 1 to 42.