FR2820750A1 - Protective strip for surface zones of metal components such as turbine blades undergoing surface treatments is made from reticulated silicone elastomer with adhesive coating - Google Patents

Protective strip for surface zones of metal components such as turbine blades undergoing surface treatments is made from reticulated silicone elastomer with adhesive coating Download PDF

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Publication number
FR2820750A1
FR2820750A1 FR0101841A FR0101841A FR2820750A1 FR 2820750 A1 FR2820750 A1 FR 2820750A1 FR 0101841 A FR0101841 A FR 0101841A FR 0101841 A FR0101841 A FR 0101841A FR 2820750 A1 FR2820750 A1 FR 2820750A1
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FR
France
Prior art keywords
silicone
adhesive
tape
silicone elastomer
protective strip
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
FR0101841A
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French (fr)
Inventor
Michel Ozanne
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Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to FR0101841A priority Critical patent/FR2820750A1/en
Publication of FR2820750A1 publication Critical patent/FR2820750A1/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00Adhesives in the form of films or foils
    • C09J7/20Adhesives in the form of films or foils characterised by their carriers
    • C09J7/22Plastics; Metallised plastics
    • C09J7/25Plastics; Metallised plastics based on macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05BSPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B12/00Arrangements for controlling delivery; Arrangements for controlling the spray area
    • B05B12/16Arrangements for controlling delivery; Arrangements for controlling the spray area for controlling the spray area
    • B05B12/20Masking elements, i.e. elements defining uncoated areas on an object to be coated
    • B05B12/24Masking elements, i.e. elements defining uncoated areas on an object to be coated made at least partly of flexible material, e.g. sheets of paper or fabric
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2203/00Applications of adhesives in processes or use of adhesives in the form of films or foils
    • C09J2203/31Applications of adhesives in processes or use of adhesives in the form of films or foils as a masking tape for painting
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2483/00Presence of polysiloxane
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2483/00Presence of polysiloxane
    • C09J2483/006Presence of polysiloxane in the substrate

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Laminated Bodies (AREA)
  • Adhesive Tapes (AREA)

Abstract

A protective strip is made from an elastomer material with an adhesive layer applied by pressure to at least one of its free faces. The strip, in the form of a tape or panel a few microns thick, is of a Room Temperature Vulcanising material, and the adhesive layer has a detachable covering film for storage and handling, removed just before application.

Description

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La présente invention concerne une bande servant, pour des pièces, notamment métalliques, qui doivent subir un traitement de surface, à la protection de certaines zones desdites pièces pendant ledit traitement. Comme on le verra par la suite, cette bande peut se présenter sous la forme d'un ruban ou d'une plaque
A titre d'exemple de pièces métalliques subissant un traitement de surface, on peut citer des aubes de turbine qui comprennent des zones de surfaces sur lesquelles on fait des dépôts de céramique, en utilisant des dards de plasma dont la température peut atteindre 2200 C, et à côté, des zones adjacentes dont on doit protéger les surfaces afin de maintenir sous celles-ci une température de moins de 400 C.
The present invention relates to a strip used, for parts, in particular metal, which must undergo a surface treatment, to protect certain areas of said parts during said treatment. As will be seen later, this strip may be in the form of a ribbon or a plate
By way of example of metal parts undergoing a surface treatment, mention may be made of turbine blades which include areas of surfaces on which ceramic deposits are made, using plasma darts whose temperature can reach 2200 ° C., and next to it, adjacent areas whose surfaces must be protected in order to maintain a temperature below 400 C. below them.

On peut également citer des traitements d'anodisation de parties de pièces en aluminium dont les autres parties doivent être protégées.  Mention may also be made of anodizing treatments of parts of aluminum parts from which the other parts must be protected.

Pour protéger les surfaces appartenant à ces zones adjacentes, on les masque au moyen d'une couche thermiquement isolante. Par exemple, on a utilisé, à cet effet, des rubans adhésifs comprenant des trames de tissu composées de Téflon@, revêtues d'une matière superficielle adhésive. Pour assurer une bonne protection de surface, on utilise, au besoin, plusieurs couches de ruban, mais la pose en est plus longue et plus délicate. D'autre part, la métallisation adhère aux rubans protecteurs classiques, ce qui provoque par exemple une pollution du dépôt de céramique.  To protect the surfaces belonging to these adjacent zones, they are masked by means of a thermally insulating layer. For example, adhesive tape has been used for this purpose, comprising fabric wefts composed of Teflon®, coated with an adhesive surface material. To ensure good surface protection, several layers of tape are used, if necessary, but the installation is longer and more delicate. On the other hand, the metallization adheres to conventional protective tapes, which for example causes pollution of the ceramic deposit.

Dans l'état de la technique, on connaît aussi les qualités des élastomères silicones bi-composants (appelés par la suite silicones RTV) qui ont la propriété de réticuler à température ambiante par réaction de polyaddition, ce qui conduit en quelques minutes à une mousse, plus ou moins épaisse, à cellules fermées qui résiste au feu. Les silicones RTV sont très utilisés en isolation thermique et en isolation électrique.  In the prior art, the qualities of two-component silicone elastomers (hereinafter called RTV silicones) are also known, which have the property of crosslinking at room temperature by polyaddition reaction, which leads in a few minutes to a foam. , more or less thick, with closed cells which resists fire. RTV silicones are widely used in thermal insulation and electrical insulation.

Parmi les applications les plus connues, on citera les tresses et embouts de câbles isolants électriques, l'enrobage et le remplissage de moteurs. Ils sont aussi utilisés dans des cloisons qui protègent de coûteux équipements. Par ailleurs, on sait fabriquer, à partir de la mousse de silicone RTV, des rubans ou des plaques ou des bandes de faibles épaisseurs. Malheureusement, les silicones RTV, en particulier ces plaques, ne sont pas naturellement adhésifs. Il leur faut ajouter un adhésif compatible.  Among the most well-known applications are braids and ferrules for electrical insulating cables, the coating and filling of motors. They are also used in partitions that protect expensive equipment. Furthermore, it is known to manufacture, from RTV silicone foam, ribbons or plates or strips of small thicknesses. Unfortunately, RTV silicones, especially these plates, are not naturally adhesive. They need to add a compatible adhesive.

Dans l'état de la technique, on connaît, par ailleurs, des bandes de silicone adhésives sensibles à la pression (appelées par la suite silicones PSA). Le terme adhésifs sensibles à la pressions, tel qu'utilisé dans les présentes, se rapporte à des adhésifs qui peuvent adhérer à une surface et qui peuvent être enlevés ou éliminés de cette surface sans qu'il y ait transfert de plus d'une quantité infime d'adhésif sur la  In the state of the art, moreover, pressure-sensitive adhesive silicone bands are known (hereinafter called PSA silicones). The term pressure sensitive adhesives, as used herein, refers to adhesives which can adhere to a surface and which can be removed or removed from that surface without transfer of more than one amount tiny adhesive on the

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surface. Ces adhésifs sensibles à la pression peuvent ensuite être réutilisés pour adhérer à la même surface ou à une autre surface, car ils conservent toute ou partie de leur pégosité et de leur force d'adhésion.  area. These pressure-sensitive adhesives can then be reused to adhere to the same surface or to another surface, since they retain all or part of their tackiness and their adhesion strength.

Les silicones PSA sont utilisés, comme adhésifs, dans de nombreuses opérations industrielles à conditions chimiques sévères et à température élevée, telles que les bandes de masquage des plaques, des bandes de raccord à cisaillement élevé, la pulvérisation de plasma et de flammes, etc.  PSA silicones are used as adhesives in many industrial operations under severe chemical conditions and at high temperature, such as plate masking tapes, high shear connector tapes, plasma and flame spraying, etc.

Mais un inconvénient associé aux adhésifs sensibles à la pression de type silicone ou silicone PSA est le fait que ces adhésifs manquent de matières solides élevées et de bonne résistance en recouvrement associées à un pelage et à une pégosité élevés, en particulier à des températures élevées.  However, a drawback associated with pressure-sensitive adhesives of the silicone or PSA silicone type is the fact that these adhesives lack high solids and good covering resistance associated with high peeling and tackiness, in particular at high temperatures.

Toujours est-il qu'il n'y a aucun adhésif sensible à la pression de type silicone ou silicone PSA qui peut présenter de telles propriétés adhésives en l'absence de solvant.  The fact remains that there is no pressure-sensitive adhesive of the silicone or PSA silicone type which can exhibit such adhesive properties in the absence of solvent.

On a découvert, suivant la présente invention, qu'une bande en élastomère de silicone réticulée, par exemple du type RTV (Room Température Vulcaning), non adhésive au départ, pouvait être rendue adhésive en la revêtant d'une couche adhésive de silicone appliquée par pression telle que du silicone PSA, sans aucune interférence dommageable. Autrement dit, suivant l'invention, on a prévu de revêtir une bande (ou un ruban ou une plaque) de silicone RTV par une couche de silicone PSA, laquelle peut se présenter sous la forme d'un mince film de quelques microns.  It has been discovered, according to the present invention, that a crosslinked silicone elastomer strip, for example of the RTV (Room Temperature Vulcaning) type, initially non-adhesive, could be made adhesive by coating it with an adhesive layer of applied silicone. by pressure such as PSA silicone, without any harmful interference. In other words, according to the invention, provision has been made to coat a strip (or a ribbon or a plate) of RTV silicone with a layer of PSA silicone, which can be in the form of a thin film of a few microns.

On a pu remarquer que l'adhésion de la couche adhésive de silicone PSA était beaucoup plus importante avec la bande ou la plaque de silicone RTV qu'avec le métal qu'elle recouvre, et qu'ainsi les bandes (ou les plaques ou les rubans) de l'invention peuvent être facilement retirées des zones adjacentes après le traitement de surface des zones traitées, par exemple de dépôts de céramiques.  It has been observed that the adhesion of the adhesive layer of PSA silicone was much greater with the strip or plate of RTV silicone than with the metal which it covers, and thus the strips (or the plates or the ribbons) of the invention can be easily removed from the adjacent areas after the surface treatment of the treated areas, for example ceramic deposits.

On a pu également remarquer que les bandes de l'invention peuvent résister à des conditions très dures du milieu, notamment à des températures élevées telles que celles qui sont engendrées au voisinage de la pièce lors du dépôt par plasma de céramique ou à des attaques de produit d'anodisation.  It has also been noted that the strips of the invention can withstand very harsh conditions of the environment, in particular at high temperatures such as those which are generated in the vicinity of the part during the plasma deposition of ceramic or to attacks by anodizing product.

De préférence, la couche adhésive de silicone PSA est recouverte, côté surface libre, d'un film, avantageusement en mylar, pour en assurer la protection au cours du stockage ou de la manipulation, le film étant retiré juste avant l'utilisation. Preferably, the adhesive layer of PSA silicone is covered, on the free surface side, with a film, advantageously of mylar, to ensure protection during storage or handling, the film being removed just before use.

Claims (7)

REVENDICATIONS 1) Bande destinée à servir, pour des pièces, notamment métalliques, devant subir un traitement de surface, à la protection de certaines zones prédéterminées desdites pièces pendant ledit traitement, caractérisée en ce que la bande est constituée d'une matière en élastomère de silicone réticulée, ladite matière étant rendue adhésive en revêtant au moins une de ses surfaces libres d'une couche adhésive de silicone appliquée par pression, par exemple du type silicone PSA. 1) Tape intended to be used, for parts, in particular metallic, to undergo a surface treatment, for the protection of certain predetermined areas of said parts during said treatment, characterized in that the tape is made of a silicone elastomer material crosslinked, said material being made adhesive by coating at least one of its free surfaces with an adhesive layer of silicone applied by pressure, for example of the PSA silicone type. 2) Bande suivant la revendication 1, caractérisée en ce que ladite matière en élastomère est du type RTV (Room Température Vulcaning) 2) Strip according to claim 1, characterized in that said elastomeric material is of the RTV (Room Temperature Vulcaning) type 3) Bande suivant la revendication 1 ou 2, caractérisée en ce qu'elle se présente sous la forme d'un ruban. 3) Strip according to claim 1 or 2, characterized in that it is in the form of a ribbon. 4) Bande suivant la revendication 1 ou 2, caractérisée en ce qu'elle se présente sous la forme d'une plaque.  4) Strip according to claim 1 or 2, characterized in that it is in the form of a plate. 5) Bande suivant l'une des revendications 1 à 4, caractérisée en ce qu'elle se présente sous la forme d'un mince film de quelques microns.  5) Strip according to one of claims 1 to 4, characterized in that it is in the form of a thin film of a few microns. 6) Bande suivant l'une des revendications 1 à 5, caractérisée en ce que la couche adhésive de silicone est recouverte, côté surface libre, d'un film pour en assurer la protection au cours du stockage ou de la manipulation, le film étant retiré juste avant l'utilisation.  6) Tape according to one of claims 1 to 5, characterized in that the adhesive silicone layer is covered, on the free surface side, with a film to protect it during storage or handling, the film being removed just before use. 7) Bande suivant la revendication 6, caractérisée en ce que ledit film est en mylar. 7) Tape according to claim 6, characterized in that said film is made of mylar.
FR0101841A 2001-02-09 2001-02-09 Protective strip for surface zones of metal components such as turbine blades undergoing surface treatments is made from reticulated silicone elastomer with adhesive coating Pending FR2820750A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
FR0101841A FR2820750A1 (en) 2001-02-09 2001-02-09 Protective strip for surface zones of metal components such as turbine blades undergoing surface treatments is made from reticulated silicone elastomer with adhesive coating

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR0101841A FR2820750A1 (en) 2001-02-09 2001-02-09 Protective strip for surface zones of metal components such as turbine blades undergoing surface treatments is made from reticulated silicone elastomer with adhesive coating

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FR2820750A1 true FR2820750A1 (en) 2002-08-16

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1808506A1 (en) * 2006-01-17 2007-07-18 Siemens Aktiengesellschaft Method for treating a workpiece with a chemical

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1137596A (en) * 1954-10-07 1957-05-31 Dow Corning Tape
EP0529546A1 (en) * 1991-08-22 1993-03-03 Dow Corning Corporation Curable silicone pressure sensitive adhesive tape
US5631082A (en) * 1988-04-07 1997-05-20 Kanegafuchi Chemical Industry Co., Ltd. Pressure-sensitive adhesive material
US6036997A (en) * 1989-05-08 2000-03-14 Atd Corporation Pressure sensitive adhesive laminate

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1137596A (en) * 1954-10-07 1957-05-31 Dow Corning Tape
US5631082A (en) * 1988-04-07 1997-05-20 Kanegafuchi Chemical Industry Co., Ltd. Pressure-sensitive adhesive material
US6036997A (en) * 1989-05-08 2000-03-14 Atd Corporation Pressure sensitive adhesive laminate
EP0529546A1 (en) * 1991-08-22 1993-03-03 Dow Corning Corporation Curable silicone pressure sensitive adhesive tape

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1808506A1 (en) * 2006-01-17 2007-07-18 Siemens Aktiengesellschaft Method for treating a workpiece with a chemical

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