FR2751531A1 - Cosmetic nail varnish composition - Google Patents
Cosmetic nail varnish composition Download PDFInfo
- Publication number
- FR2751531A1 FR2751531A1 FR9609426A FR9609426A FR2751531A1 FR 2751531 A1 FR2751531 A1 FR 2751531A1 FR 9609426 A FR9609426 A FR 9609426A FR 9609426 A FR9609426 A FR 9609426A FR 2751531 A1 FR2751531 A1 FR 2751531A1
- Authority
- FR
- France
- Prior art keywords
- nail varnish
- cosmetic composition
- resin
- nail
- varnish according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 25
- 239000002966 varnish Substances 0.000 title claims abstract description 15
- 239000002537 cosmetic Substances 0.000 title claims abstract description 13
- 239000011347 resin Substances 0.000 claims abstract description 17
- 229920005989 resin Polymers 0.000 claims abstract description 17
- 239000004925 Acrylic resin Substances 0.000 claims abstract description 10
- 229920000178 Acrylic resin Polymers 0.000 claims abstract description 10
- 229920001169 thermoplastic Polymers 0.000 claims abstract description 10
- 239000004416 thermosoftening plastic Substances 0.000 claims abstract description 10
- 239000007788 liquid Substances 0.000 claims abstract description 4
- 238000001035 drying Methods 0.000 claims description 4
- 239000000975 dye Substances 0.000 claims description 4
- 239000003822 epoxy resin Substances 0.000 claims description 4
- 239000000049 pigment Substances 0.000 claims description 4
- 229920000647 polyepoxide Polymers 0.000 claims description 4
- LMYRWZFENFIFIT-UHFFFAOYSA-N toluene-4-sulfonamide Chemical compound CC1=CC=C(S(N)(=O)=O)C=C1 LMYRWZFENFIFIT-UHFFFAOYSA-N 0.000 claims description 4
- 239000000654 additive Substances 0.000 claims description 3
- 229920001577 copolymer Polymers 0.000 claims description 3
- 230000000996 additive effect Effects 0.000 claims description 2
- 239000002304 perfume Substances 0.000 claims description 2
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 7
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 6
- 230000000694 effects Effects 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- QZCLKYGREBVARF-UHFFFAOYSA-N Acetyl tributyl citrate Chemical compound CCCCOC(=O)CC(C(=O)OCCCC)(OC(C)=O)CC(=O)OCCCC QZCLKYGREBVARF-UHFFFAOYSA-N 0.000 description 3
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 3
- 239000000020 Nitrocellulose Substances 0.000 description 3
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 3
- 229920001220 nitrocellulos Polymers 0.000 description 3
- 239000004014 plasticizer Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 230000010494 opalescence Effects 0.000 description 2
- 229920001225 polyester resin Polymers 0.000 description 2
- 239000004645 polyester resin Substances 0.000 description 2
- IHZXTIBMKNSJCJ-UHFFFAOYSA-N 3-{[(4-{[4-(dimethylamino)phenyl](4-{ethyl[(3-sulfophenyl)methyl]amino}phenyl)methylidene}cyclohexa-2,5-dien-1-ylidene)(ethyl)azaniumyl]methyl}benzene-1-sulfonate Chemical compound C=1C=C(C(=C2C=CC(C=C2)=[N+](C)C)C=2C=CC(=CC=2)N(CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C=CC=1N(CC)CC1=CC=CC(S(O)(=O)=O)=C1 IHZXTIBMKNSJCJ-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 1
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 1
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 1
- 229940073609 bismuth oxychloride Drugs 0.000 description 1
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- BWOROQSFKKODDR-UHFFFAOYSA-N oxobismuth;hydrochloride Chemical compound Cl.[Bi]=O BWOROQSFKKODDR-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 125000002088 tosyl group Chemical group [H]C1=C([H])C(=C([H])C([H])=C1C([H])([H])[H])S(*)(=O)=O 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8152—Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/85—Polyesters
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q3/00—Manicure or pedicure preparations
- A61Q3/02—Nail coatings
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
- A61K2800/594—Mixtures of polymers
Abstract
Description
COMPOSITION COSMETIQUE A EFFET SPECIAL A APPLIQUER
SUR LES ONGLES
L'invention est relative à une composition cosmetique à usage pour les ongles.COSMETIC COMPOSITION WITH SPECIAL EFFECT TO APPLY
ON NAILS
The invention relates to a cosmetic composition for use for nails.
En géneral, les vernis à ongles sont des produits à base de solvants organiques ou à base de produits aqueux tels que des melanges à base de solution dans l'eau, ou des solutions dans des mélanges eau/alcool, ou des mélanges à base d'émulsion. In general, nail varnishes are products based on organic solvents or based on aqueous products such as mixtures based on solution in water, or solutions in water / alcohol mixtures, or mixtures based on 'emulsion.
De plus selon les exigences de la mode, il est nécessaire que les vernis à ongles offrent une palette de couleurs la plus variée possible. Pour obtenir cette palette de couleurs on ajoute des pigments et des colorants, mais on peut aussi ajouter des nacres artificielles ou naturelles, des particules d'oxychlorure de bismuth ou d'autres paillettes diverses pour obtenir des effets nacrés ou irisés. In addition, according to fashion requirements, it is necessary for nail polishes to offer the most varied palette of colors possible. To obtain this color palette, pigments and dyes are added, but it is also possible to add artificial or natural nacres, particles of bismuth oxychloride or other various flakes to obtain pearly or iridescent effects.
Généralement, les vernis à ongles sont brillants mais on peut aussi obtenir un film mat ou satine avec des silices ou différentes cires. Generally, nail polishes are shiny, but you can also obtain a matt or satin film with silica or different waxes.
Le but principal est d'obtenir des vernis à ongles offrant des qualités de durete, d'adhérence et de durabilité, ainsi que des propriétés mécaniques satisfaisantes, tout en offrant un aspect esthetique en harmonie avec les exigences de la mode. The main goal is to obtain nail varnishes offering qualities of hardness, adhesion and durability, as well as satisfactory mechanical properties, while offering an aesthetic appearance in harmony with the requirements of fashion.
La presente invention a pour but d'obtenir un vernis à ongles presentant un film ayant un aspect esthetique tries particulier opalescent ou laiteux tout en conservant un aspect brillant. The object of the present invention is to obtain a nail varnish having a film having an aesthetic appearance, particularly opalescent or milky, while retaining a shiny appearance.
La composition de la presente invention est obtenue par le melange de deux résines. Une telle composition n'est généralement pas utilisée pour les vernis à ongles car l'incompatibilité des résines fait qu'au séchage on obtient une perte de brillance. The composition of the present invention is obtained by the mixture of two resins. Such a composition is generally not used for nail varnishes because the incompatibility of the resins means that on drying a loss of gloss is obtained.
L'invention repose sur la découverte d'une composition contenant deux résines qui bien qu'incompatibles donnent au séchage un film opalescent et brillant. The invention is based on the discovery of a composition containing two resins which, although incompatible, give an opalescent and shiny film on drying.
L'invention a pour objet une composition cosmétique pour vernis à ongles caractérisée en ce qu'elle comprend au moins une premiere résine acrylique thermoplastique et une deuxieme résine incompatible avec la premiere, de telle sorte que la composition parfaitement limpide à l'état liquide donne un film opalescent et brillant au sechage. The subject of the invention is a cosmetic composition for nail varnish, characterized in that it comprises at least a first thermoplastic acrylic resin and a second resin incompatible with the first, so that the composition, perfectly clear in the liquid state, gives an opalescent and shiny film when dried.
La première résine acrylique thermoplastique a un poids moleculaire qui varie entre 20.000 et 100.000. The first thermoplastic acrylic resin has a molecular weight which varies between 20,000 and 100,000.
La deuxième resine est de préférence une resine tosyl amide/epoxy et/ou un copolymere anhydre phtalique/trimellitique-glycols. The second resin is preferably a tosyl amide / epoxy resin and / or a phthalic / trimellitic anhydrous copolymer-glycols.
Les resines sont utilisées dans un rapport allant de 1/10 à 10/1. The resins are used in a ratio ranging from 1/10 to 10/1.
La concentration globale des resines est comprise entre 5% et 95% en poids. The overall concentration of the resins is between 5% and 95% by weight.
Afin d'obtenir la palette de couleurs désirée on rajoute à la composition des pigments ou des colorants. In order to obtain the desired color palette, pigments or dyes are added to the composition.
La composition cosmetique pour ongles peut contenir des produits additifs de soin pour l'ongle ainsi que des filtres solaires. The cosmetic composition for nails can contain additive care products for the nail as well as sun filters.
L'invention sera mieux comprise grâce à la description qui va suivre à titre d'exemple non limitatif de plusieurs exemples de réalisation dans lesquels les pourcentages sont des pourcentages en masse de pro-duit. The invention will be better understood from the description which follows, by way of non-limiting example, of several exemplary embodiments in which the percentages are percentages by mass of product.
EXEMPLE 1
Acétate d'éthyle : 31
Methyl ethyl cétone . 30
Acetate de butyle : 10
Nitrocellulose 70% dans l'isopropanol :
Plastifiant acetyl tributyl citrate : 5
Résine acrylique thermoplastique : 9
Resine tosyl amide/epoxy : 8
Colorant DC Violet 2 : Trace
Dans cet exemple, la premiere résine acrylique thermoplastique est un copolymere butyl et méthyl methacrylate et la deuxieme resine est une resine tosylamide/epoxy. EXAMPLE 1
Ethyl acetate: 31
Methyl ethyl ketone. 30
Butyl acetate: 10
Nitrocellulose 70% in isopropanol:
Plasticizer acetyl tributyl citrate: 5
Thermoplastic acrylic resin: 9
Tosyl amide / epoxy resin: 8
Dye DC Violet 2: Trace
In this example, the first thermoplastic acrylic resin is a butyl and methyl methacrylate copolymer and the second resin is a tosylamide / epoxy resin.
Cette composition parfaitement transparente à l'état liquide donne, avec un séchage très rapide, un film d'un très bel aspect opalescent augmente d'un très beau brillant (le brillant etant supérieur à 90 au reflectometre 60 ). This perfectly transparent composition in the liquid state gives, with very rapid drying, a film of a very beautiful opalescent appearance increases with a very beautiful gloss (the gloss being greater than 90 at the reflectometer 60).
Il est à noter que les caracteristiques telles que dureté, adhérence sur l'ongle, durabilité et bonne tenue à l'eau sont tres satisfaisantes. It should be noted that characteristics such as hardness, adhesion to the nail, durability and good water resistance are very satisfactory.
On peut remarquer que dans ce cas là, la proportion des resines se trouve dans un rapport 50/50. It can be noted that in this case there, the proportion of resins is in a 50/50 ratio.
EXEMPLE 2
Acetate d'éthyle : 30
Acétate de butyle : 10
Méthyl isobutylcétone : 30
Nitrocellulose 70% dans l'isopropanol : 2
Plastifiant acetyl tributyl citrate : 3
Résine acrylique thermoplastique : 13
Résine tosyl amideJepoxy : 12
Dans cet exemple, le même couple de resines a été utilise dans un rapport 50/50, mais dans des proportions plus importantes et on a pu constater un effet opalescent plus fort, ce qui parait logique en raison des concentrations plus importantes.EXAMPLE 2
Ethyl acetate: 30
Butyl acetate: 10
Methyl isobutyl ketone: 30
Nitrocellulose 70% in isopropanol: 2
Plasticizer acetyl tributyl citrate: 3
Thermoplastic acrylic resin: 13
Tosyl amideJepoxy resin: 12
In this example, the same pair of resins was used in a 50/50 ratio, but in larger proportions and we could see a stronger opalescent effect, which seems logical due to the higher concentrations.
Le brillant obtenu reste très satisfaisant (superieur à 92) ainsi que les propriétés mecaniques, de résistance et de durabilite du vernis à ongles. The gloss obtained remains very satisfactory (greater than 92) as well as the mechanical, resistance and durability properties of the nail varnish.
EXEMPLE 3
Acetate d'éthyle : 41
Acetate de butyle : 32
Plastifiant acétyl tributyl citrate : 5
Nitrocellulose 70% dans l'isopropanol : 6
Résine acrylique thermoplastique : 10
Résine polyester: 6
Dans cet exemple, le couple de résines utilise est le couple résine acrylique thermoplastique/résine polyester et plus précisément copolymere anhydride phtalique/trimellitique-glycols,
On constate dans cet exemple un effet d'opalescence moins accentué mais le brillant du film reste très bon (superieur à 92).EXAMPLE 3
Ethyl acetate: 41
Butyl acetate: 32
Acetyl tributyl citrate plasticizer: 5
Nitrocellulose 70% in isopropanol: 6
Thermoplastic acrylic resin: 10
Polyester resin: 6
In this example, the pair of resins used is the pair of thermoplastic acrylic resin / polyester resin and more specifically phthalic anhydride / trimellitic-glycol copolymer,
In this example, there is a less pronounced opalescence effect but the gloss of the film remains very good (greater than 92).
A tous ces exemples on peut ajouter des pigments et tous colorants désirés afin d'obtenir une palette de couleurs la plus variée possible, ainsi que pour modifier la couleur de 1 'opalescence. Il est aussi possible de rajouter des additifs pour le soin des ongles ainsi que des parfums et des filtres solaires. To all these examples, pigments and any desired dyes can be added in order to obtain the most varied color palette possible, as well as to modify the color of the opalescence. It is also possible to add additives for nail care as well as perfumes and sun filters.
Claims (7)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR9609426A FR2751531B1 (en) | 1996-07-26 | 1996-07-26 | COSMETIC COMPOSITION WITH SPECIAL EFFECT TO APPLY ON NAILS |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR9609426A FR2751531B1 (en) | 1996-07-26 | 1996-07-26 | COSMETIC COMPOSITION WITH SPECIAL EFFECT TO APPLY ON NAILS |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| FR2751531A1 true FR2751531A1 (en) | 1998-01-30 |
| FR2751531B1 FR2751531B1 (en) | 1998-10-09 |
Family
ID=9494514
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FR9609426A Expired - Lifetime FR2751531B1 (en) | 1996-07-26 | 1996-07-26 | COSMETIC COMPOSITION WITH SPECIAL EFFECT TO APPLY ON NAILS |
Country Status (1)
| Country | Link |
|---|---|
| FR (1) | FR2751531B1 (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1990012829A1 (en) * | 1989-04-24 | 1990-11-01 | Mallavarapu Leo X | Novel epoxy sulfonamide-based resins, a process for their preparation and use of same |
| WO1991008731A1 (en) * | 1989-12-18 | 1991-06-27 | Amalia, Inc. | Quick-drying nail enamel compositions |
| FR2722404A1 (en) * | 1994-07-13 | 1996-01-19 | Oreal | Compsn. for care of nails |
| EP0714653A1 (en) * | 1994-12-02 | 1996-06-05 | L'oreal | Translucent nail composition |
-
1996
- 1996-07-26 FR FR9609426A patent/FR2751531B1/en not_active Expired - Lifetime
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1990012829A1 (en) * | 1989-04-24 | 1990-11-01 | Mallavarapu Leo X | Novel epoxy sulfonamide-based resins, a process for their preparation and use of same |
| WO1991008731A1 (en) * | 1989-12-18 | 1991-06-27 | Amalia, Inc. | Quick-drying nail enamel compositions |
| FR2722404A1 (en) * | 1994-07-13 | 1996-01-19 | Oreal | Compsn. for care of nails |
| EP0714653A1 (en) * | 1994-12-02 | 1996-06-05 | L'oreal | Translucent nail composition |
Also Published As
| Publication number | Publication date |
|---|---|
| FR2751531B1 (en) | 1998-10-09 |
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| Date | Code | Title | Description |
|---|---|---|---|
| PLFP | Fee payment |
Year of fee payment: 20 |