FR2750349B1 - USE OF PLATINUM COMPLEXES IN PARTICULAR AS HOMOGENEOUS AND THERMOACTIVABLE HYDROSILYLATION CATALYSTS - Google Patents

USE OF PLATINUM COMPLEXES IN PARTICULAR AS HOMOGENEOUS AND THERMOACTIVABLE HYDROSILYLATION CATALYSTS

Info

Publication number
FR2750349B1
FR2750349B1 FR9608302A FR9608302A FR2750349B1 FR 2750349 B1 FR2750349 B1 FR 2750349B1 FR 9608302 A FR9608302 A FR 9608302A FR 9608302 A FR9608302 A FR 9608302A FR 2750349 B1 FR2750349 B1 FR 2750349B1
Authority
FR
France
Prior art keywords
thermoactivable
homogeneous
platinum complexes
hydrosilylation catalysts
hydrosilylation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
FR9608302A
Other languages
French (fr)
Other versions
FR2750349A1 (en
Inventor
Gerard Mignani
John Osborn
Pascal Steffanut
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Rhodia Chimie SAS
Original Assignee
Rhone Poulenc Chimie SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rhone Poulenc Chimie SA filed Critical Rhone Poulenc Chimie SA
Priority to FR9608302A priority Critical patent/FR2750349B1/en
Priority to EP97930610A priority patent/EP0907685A1/en
Priority to PCT/FR1997/001157 priority patent/WO1998000463A1/en
Priority to JP10503882A priority patent/JP2000514849A/en
Priority to AU34495/97A priority patent/AU3449597A/en
Priority to CA002259255A priority patent/CA2259255A1/en
Publication of FR2750349A1 publication Critical patent/FR2750349A1/en
Application granted granted Critical
Publication of FR2750349B1 publication Critical patent/FR2750349B1/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/1608Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes the ligands containing silicon
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22Organic complexes
    • B01J31/2282Unsaturated compounds used as ligands
    • B01J31/2291Olefins
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22Organic complexes
    • B01J31/2282Unsaturated compounds used as ligands
    • B01J31/2295Cyclic compounds, e.g. cyclopentadienyls
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System
    • C07F15/0006Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System compounds of the platinum group
    • C07F15/0086Platinum compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/0091Complexes with metal-heteroatom-bonds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L83/00Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
    • C08L83/04Polysiloxanes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32Addition reactions to C=C or C-C triple bonds
    • B01J2231/323Hydrometalation, e.g. bor-, alumin-, silyl-, zirconation or analoguous reactions like carbometalation, hydrocarbation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82Metals of the platinum group
    • B01J2531/828Platinum
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04Polysiloxanes
    • C08G77/06Preparatory processes
    • C08G77/08Preparatory processes characterised by the catalysts used
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04Polysiloxanes
    • C08G77/12Polysiloxanes containing silicon bound to hydrogen
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04Polysiloxanes
    • C08G77/14Polysiloxanes containing silicon bound to oxygen-containing groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04Polysiloxanes
    • C08G77/14Polysiloxanes containing silicon bound to oxygen-containing groups
    • C08G77/16Polysiloxanes containing silicon bound to oxygen-containing groups to hydroxyl groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04Polysiloxanes
    • C08G77/14Polysiloxanes containing silicon bound to oxygen-containing groups
    • C08G77/18Polysiloxanes containing silicon bound to oxygen-containing groups to alkoxy or aryloxy groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04Polysiloxanes
    • C08G77/20Polysiloxanes containing silicon bound to unsaturated aliphatic groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04Polysiloxanes
    • C08G77/22Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen
    • C08G77/24Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen halogen-containing groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/70Siloxanes defined by use of the MDTQ nomenclature
FR9608302A 1996-06-28 1996-06-28 USE OF PLATINUM COMPLEXES IN PARTICULAR AS HOMOGENEOUS AND THERMOACTIVABLE HYDROSILYLATION CATALYSTS Expired - Fee Related FR2750349B1 (en)

Priority Applications (6)

Application Number Priority Date Filing Date Title
FR9608302A FR2750349B1 (en) 1996-06-28 1996-06-28 USE OF PLATINUM COMPLEXES IN PARTICULAR AS HOMOGENEOUS AND THERMOACTIVABLE HYDROSILYLATION CATALYSTS
EP97930610A EP0907685A1 (en) 1996-06-28 1997-06-27 Use of platinum complexes particularly as homogeneous and heat activable catalysts for hydrosilylation
PCT/FR1997/001157 WO1998000463A1 (en) 1996-06-28 1997-06-27 Use of platinum complexes particularly as homogeneous and heat activable catalysts for hydrosilylation
JP10503882A JP2000514849A (en) 1996-06-28 1997-06-27 Use of platinum complexes as thermally activatable homogeneous hydrosilylation catalysts.
AU34495/97A AU3449597A (en) 1996-06-28 1997-06-27 Use of platinum complexes particularly as homogeneous and heat activable catalysts for hydrosilylation
CA002259255A CA2259255A1 (en) 1996-06-28 1997-06-27 Use of platinum complexes particularly as homogeneous and heat activable catalysts for hydrosilylation

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR9608302A FR2750349B1 (en) 1996-06-28 1996-06-28 USE OF PLATINUM COMPLEXES IN PARTICULAR AS HOMOGENEOUS AND THERMOACTIVABLE HYDROSILYLATION CATALYSTS

Publications (2)

Publication Number Publication Date
FR2750349A1 FR2750349A1 (en) 1998-01-02
FR2750349B1 true FR2750349B1 (en) 1998-10-16

Family

ID=9493688

Family Applications (1)

Application Number Title Priority Date Filing Date
FR9608302A Expired - Fee Related FR2750349B1 (en) 1996-06-28 1996-06-28 USE OF PLATINUM COMPLEXES IN PARTICULAR AS HOMOGENEOUS AND THERMOACTIVABLE HYDROSILYLATION CATALYSTS

Country Status (6)

Country Link
EP (1) EP0907685A1 (en)
JP (1) JP2000514849A (en)
AU (1) AU3449597A (en)
CA (1) CA2259255A1 (en)
FR (1) FR2750349B1 (en)
WO (1) WO1998000463A1 (en)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19837855A1 (en) 1998-08-20 2000-02-24 Wacker Chemie Gmbh Curable organopolysiloxane compositions
FR2813081B1 (en) * 2000-08-17 2005-12-23 Rhodia Chimie Sa PROCESS FOR PREPARING SILICONE OILS BY HYDROSILYLATION OF SYNTHONS CONTAINING AT LEAST ONE HYDROCARBON CYCLE INCLUDING OXYGEN ATOM IN THE PRESENCE OF A CATALYTIC METAL COMPLEX
FR2825709B1 (en) * 2001-06-07 2005-07-01 Rhodia Chimie Sa HYDROSILYLATION ELASTOMER-CROSS-LINKABLE SILICONE COMPOSITION IN THE PRESENCE OF CARBENE-BASED METAL CATALYSTS AND CATALYSTS OF THIS TYPE
FR2831544B1 (en) 2001-10-30 2005-07-01 Rhodia Chimie Sa PROCESS FOR THE PREPARATION OF SILICON OILS CONTAINING AT LEAST ONE HYDROCARBON CYCLE INCLUDING AN OXYGEN ATOM
EP1520870B1 (en) * 2003-10-04 2006-01-25 Goldschmidt GmbH Process for manufacturing organic silicon compounds
FR2879612B1 (en) * 2004-12-21 2007-05-04 Rhodia Chimie Sa SILICONE ELASTOMER COMPOSITION, ADHESIVE, MONOCOMPONENT AND CROSS-LINKABLE BY POLYADDITION
DE102005039398A1 (en) 2005-08-20 2007-02-22 Goldschmidt Gmbh Process for the preparation of addition products of compounds containing SiH groups to olefin-containing reactants in aqueous media
DE102007013608A1 (en) 2007-03-21 2008-09-25 Wacker Chemie Ag Si-substituted quinones as co-catalysts in transition-metal-catalyzed hydrosilylation
DE102014213507A1 (en) 2014-07-11 2016-01-14 Evonik Degussa Gmbh Platinum-containing composition
EP3020749B1 (en) 2014-11-12 2020-09-30 Evonik Operations GmbH Method for the production of compositions containing platinum
CN105854945B (en) * 2016-03-03 2018-03-20 中科院广州化学有限公司南雄材料生产基地 A kind of storage-stable platiniferous hydrosilylation catalyst and preparation method thereof
EP3415547B1 (en) 2017-06-13 2020-03-25 Evonik Operations GmbH Method for producing sic-linked polyether siloxanes
EP3415548B1 (en) 2017-06-13 2020-03-25 Evonik Operations GmbH Method for producing sic-linked polyether siloxanes

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3775452A (en) * 1971-04-28 1973-11-27 Gen Electric Platinum complexes of unsaturated siloxanes and platinum containing organopolysiloxanes
JP2974692B2 (en) * 1989-08-31 1999-11-10 東レ・ダウコーニング・シリコーン株式会社 Platinum catalyst composition, method for producing the same, and curable organopolysiloxane composition containing the platinum catalyst composition
FR2717482B1 (en) * 1994-03-18 1996-06-21 Rhone Poulenc Chimie Organoplatinic complexes and photoactivatable catalytic hydrosilylation systems containing it.

Also Published As

Publication number Publication date
AU3449597A (en) 1998-01-21
CA2259255A1 (en) 1998-01-08
JP2000514849A (en) 2000-11-07
WO1998000463A1 (en) 1998-01-08
EP0907685A1 (en) 1999-04-14
FR2750349A1 (en) 1998-01-02

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