FR2738814B1 - REAGENT, COMPOUND AND PROCESS FOR THE PERFLUOROALC (O) YLATION OF NUCLEOPHILIC, AS WELL AS THE DERIVATIVES OBTAINED - Google Patents

REAGENT, COMPOUND AND PROCESS FOR THE PERFLUOROALC (O) YLATION OF NUCLEOPHILIC, AS WELL AS THE DERIVATIVES OBTAINED

Info

Publication number
FR2738814B1
FR2738814B1 FR9510937A FR9510937A FR2738814B1 FR 2738814 B1 FR2738814 B1 FR 2738814B1 FR 9510937 A FR9510937 A FR 9510937A FR 9510937 A FR9510937 A FR 9510937A FR 2738814 B1 FR2738814 B1 FR 2738814B1
Authority
FR
France
Prior art keywords
perfluoroalc
ylation
nucleophilic
reagent
compound
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
FR9510937A
Other languages
French (fr)
Other versions
FR2738814A1 (en
Inventor
Bernard Langlois
Nicolas Roques
Marc Tordeux
Claude Wakselman
Gerard Forat
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Rhodia Chimie SAS
Original Assignee
Rhone Poulenc Chimie SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to FR9510937A priority Critical patent/FR2738814B1/en
Application filed by Rhone Poulenc Chimie SA filed Critical Rhone Poulenc Chimie SA
Priority to DE69617401T priority patent/DE69617401T2/en
Priority to ES96904161T priority patent/ES2164868T3/en
Priority to HU9702299A priority patent/HUP9702299A3/en
Priority to CNA2004100284086A priority patent/CN1528722A/en
Priority to EP96904161A priority patent/EP0810993B1/en
Priority to JP8525447A priority patent/JPH11504619A/en
Priority to CNB961927275A priority patent/CN1160328C/en
Priority to AU48357/96A priority patent/AU4835796A/en
Priority to AT96904161T priority patent/ATE209631T1/en
Priority to PCT/FR1996/000264 priority patent/WO1996026185A1/en
Priority to US08/894,392 priority patent/US6156163A/en
Priority to IL11721596A priority patent/IL117215A0/en
Priority to TR96/00145A priority patent/TR199600145A2/en
Publication of FR2738814A1 publication Critical patent/FR2738814A1/en
Application granted granted Critical
Publication of FR2738814B1 publication Critical patent/FR2738814B1/en
Priority to US09/645,425 priority patent/US6506286B1/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C391/00—Compounds containing selenium
    • C07C391/02—Compounds containing selenium having selenium atoms bound to carbon atoms of six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B37/00—Reactions without formation or introduction of functional groups containing hetero atoms, involving either the formation of a carbon-to-carbon bond between two carbon atoms not directly linked already or the disconnection of two directly linked carbon atoms
    • C07B37/02—Addition
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/26—Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton
    • C07C17/272—Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton by addition reactions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/26—Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton
    • C07C17/32—Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton by introduction of halogenated alkyl groups into ring compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/35—Preparation of halogenated hydrocarbons by reactions not affecting the number of carbon or of halogen atoms in the reaction
    • C07C17/354—Preparation of halogenated hydrocarbons by reactions not affecting the number of carbon or of halogen atoms in the reaction by hydrogenation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C319/00—Preparation of thiols, sulfides, hydropolysulfides or polysulfides
    • C07C319/14—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of sulfides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C327/00—Thiocarboxylic acids
    • C07C327/20—Esters of monothiocarboxylic acids
    • C07C327/22—Esters of monothiocarboxylic acids having carbon atoms of esterified thiocarboxyl groups bound to hydrogen atoms or to acyclic carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C327/00—Thiocarboxylic acids
    • C07C327/20—Esters of monothiocarboxylic acids
    • C07C327/32—Esters of monothiocarboxylic acids having sulfur atoms of esterified thiocarboxyl groups bound to carbon atoms of hydrocarbon radicals substituted by carboxyl groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C327/00—Thiocarboxylic acids
    • C07C327/20—Esters of monothiocarboxylic acids
    • C07C327/32—Esters of monothiocarboxylic acids having sulfur atoms of esterified thiocarboxyl groups bound to carbon atoms of hydrocarbon radicals substituted by carboxyl groups
    • C07C327/34—Esters of monothiocarboxylic acids having sulfur atoms of esterified thiocarboxyl groups bound to carbon atoms of hydrocarbon radicals substituted by carboxyl groups with amino groups bound to the same hydrocarbon radicals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C381/00—Compounds containing carbon and sulfur and having functional groups not covered by groups C07C301/00 - C07C337/00
    • C07C381/04—Thiosulfonates
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/45—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by condensation
    • C07C45/455—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by condensation with carboxylic acids or their derivatives
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/28—Preparation of carboxylic acid esters by modifying the hydroxylic moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/293—Preparation of carboxylic acid esters by modifying the hydroxylic moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/333—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton
    • C07C67/343—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C07C67/347—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by addition to unsaturated carbon-to-carbon bonds
FR9510937A 1995-02-24 1995-09-15 REAGENT, COMPOUND AND PROCESS FOR THE PERFLUOROALC (O) YLATION OF NUCLEOPHILIC, AS WELL AS THE DERIVATIVES OBTAINED Expired - Fee Related FR2738814B1 (en)

Priority Applications (15)

Application Number Priority Date Filing Date Title
FR9510937A FR2738814B1 (en) 1995-09-15 1995-09-15 REAGENT, COMPOUND AND PROCESS FOR THE PERFLUOROALC (O) YLATION OF NUCLEOPHILIC, AS WELL AS THE DERIVATIVES OBTAINED
PCT/FR1996/000264 WO1996026185A1 (en) 1995-02-24 1996-02-19 Reagent, compound and method for nucleophile perfluoroalkylation, and resulting derivatives
HU9702299A HUP9702299A3 (en) 1995-02-24 1996-02-19 Reagent,and method for perfluoroalkylation,of nucleophile materials
CNA2004100284086A CN1528722A (en) 1995-02-24 1996-02-19 Perfluoro alkylated derivative
EP96904161A EP0810993B1 (en) 1995-02-24 1996-02-19 Reagent, compound and method for nucleophile perfluoroalkylation, and resulting derivatives
JP8525447A JPH11504619A (en) 1995-02-24 1996-02-19 Reactants, compounds and methods for perfluoroalkylation of nucleophiles and derivatives obtained
CNB961927275A CN1160328C (en) 1995-02-24 1996-02-19 Reagent, compound and method for nucleophile perfluoroalkylation, and resulting derivatives
AU48357/96A AU4835796A (en) 1995-02-24 1996-02-19 Reagent, compound and method for nucleophile perfluoroalkylation, and resulting derivatives
DE69617401T DE69617401T2 (en) 1995-02-24 1996-02-19 METHOD FOR PRODUCING PERHALOALKYLATED AND / OR PERHALOACYLATED COMPOUNDS AND PERHALOALKYLATING AGENTS AND / OR PERHALOACYLATING AGENTS
ES96904161T ES2164868T3 (en) 1995-02-24 1996-02-19 REAGENTS, COMPOUNDS AND PROCEDURE FOR THE PERFLUOROQUALATION OF NUCLEOFILOUS COMPOUNDS, AND DERIVATIVES OBTAINED.
US08/894,392 US6156163A (en) 1995-02-24 1996-02-19 Reactant, compound and process for the perfluoroalkylation of the nucleophile, and the derivatives obtained
AT96904161T ATE209631T1 (en) 1995-02-24 1996-02-19 METHOD FOR PRODUCING PERHALOAKYLATED AND/OR PERHALOACYLATED COMPOUNDS AND PERHALOAKYLATING AGENTS AND/OR PERHALOACYLATING AGENTS
IL11721596A IL117215A0 (en) 1995-02-24 1996-02-21 Reactant compound and process for perfluoroalk(o)ylation of a nucleophile and derivatives obtained thereby
TR96/00145A TR199600145A2 (en) 1995-02-24 1996-02-26 Reactive, compound and method and derivatives obtained for perfluoroalkylation of a nucleophile.
US09/645,425 US6506286B1 (en) 1995-02-24 2000-08-24 Reactant, compound and process for the perfluoroalkylation of a nucleophile, and the derivatives obtained

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR9510937A FR2738814B1 (en) 1995-09-15 1995-09-15 REAGENT, COMPOUND AND PROCESS FOR THE PERFLUOROALC (O) YLATION OF NUCLEOPHILIC, AS WELL AS THE DERIVATIVES OBTAINED

Publications (2)

Publication Number Publication Date
FR2738814A1 FR2738814A1 (en) 1997-03-21
FR2738814B1 true FR2738814B1 (en) 1997-11-14

Family

ID=9482672

Family Applications (1)

Application Number Title Priority Date Filing Date
FR9510937A Expired - Fee Related FR2738814B1 (en) 1995-02-24 1995-09-15 REAGENT, COMPOUND AND PROCESS FOR THE PERFLUOROALC (O) YLATION OF NUCLEOPHILIC, AS WELL AS THE DERIVATIVES OBTAINED

Country Status (1)

Country Link
FR (1) FR2738814B1 (en)

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4822904A (en) * 1985-12-12 1989-04-18 Ethyl Corporation Perfluoroalkylation process
FR2662439B1 (en) * 1990-05-23 1993-11-19 Rhone Poulenc Chimie REAGENT AND PROCESS FOR PERFLUOROALKYLATION OF NUCLEOPHILIC SUBSTRATES BY SODIUM PERFLUOROALCANESULFINATES IN OXIDIZING MEDIA.

Also Published As

Publication number Publication date
FR2738814A1 (en) 1997-03-21

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