FR2696662A1 - Prods made from heavy metal derivs, waste contg heavy metals, and light domestic and industrial waste - as containers, masonry and ceramics giving safe storage and transport of pollutants, and prods. for use in difficult conditions - Google Patents
Prods made from heavy metal derivs, waste contg heavy metals, and light domestic and industrial waste - as containers, masonry and ceramics giving safe storage and transport of pollutants, and prods. for use in difficult conditions Download PDFInfo
- Publication number
- FR2696662A1 FR2696662A1 FR9212452A FR9212452A FR2696662A1 FR 2696662 A1 FR2696662 A1 FR 2696662A1 FR 9212452 A FR9212452 A FR 9212452A FR 9212452 A FR9212452 A FR 9212452A FR 2696662 A1 FR2696662 A1 FR 2696662A1
- Authority
- FR
- France
- Prior art keywords
- waste
- prods
- industrial waste
- products according
- ceramics
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Revoked
Links
- 239000000919 ceramic Substances 0.000 title claims abstract description 15
- 239000010791 domestic waste Substances 0.000 title claims abstract description 15
- 229910001385 heavy metal Inorganic materials 0.000 title claims abstract description 12
- 239000002440 industrial waste Substances 0.000 title claims abstract description 12
- 239000002699 waste material Substances 0.000 title abstract description 12
- 239000003344 environmental pollutant Substances 0.000 title abstract 2
- 231100000719 pollutant Toxicity 0.000 title abstract 2
- 238000003860 storage Methods 0.000 title description 3
- 239000000463 material Substances 0.000 claims abstract description 15
- 229910052753 mercury Inorganic materials 0.000 claims abstract description 14
- 239000000126 substance Substances 0.000 claims abstract description 12
- 239000011230 binding agent Substances 0.000 claims abstract description 9
- 229910052793 cadmium Inorganic materials 0.000 claims abstract description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims abstract description 6
- 238000004381 surface treatment Methods 0.000 claims abstract description 6
- 238000004070 electrodeposition Methods 0.000 claims abstract description 4
- 239000010881 fly ash Substances 0.000 claims abstract description 4
- 230000002285 radioactive effect Effects 0.000 claims abstract description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 3
- 229910052785 arsenic Inorganic materials 0.000 claims abstract 2
- 238000006386 neutralization reaction Methods 0.000 claims abstract 2
- 239000011521 glass Substances 0.000 claims description 12
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 claims description 12
- -1 yttnum Chemical compound 0.000 claims description 12
- 230000005855 radiation Effects 0.000 claims description 10
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 8
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 8
- 238000004519 manufacturing process Methods 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 8
- 229910052718 tin Inorganic materials 0.000 claims description 8
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 7
- 239000002671 adjuvant Substances 0.000 claims description 7
- 150000004645 aluminates Chemical class 0.000 claims description 7
- 229910052796 boron Inorganic materials 0.000 claims description 7
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 claims description 7
- 150000004760 silicates Chemical class 0.000 claims description 7
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 6
- 229910052735 hafnium Inorganic materials 0.000 claims description 6
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 claims description 6
- 239000010802 sludge Substances 0.000 claims description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 5
- 229910052787 antimony Inorganic materials 0.000 claims description 5
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims description 5
- 230000000694 effects Effects 0.000 claims description 5
- 238000009713 electroplating Methods 0.000 claims description 5
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 5
- 239000011707 mineral Substances 0.000 claims description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 4
- 229920002367 Polyisobutene Polymers 0.000 claims description 4
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 4
- 239000002253 acid Substances 0.000 claims description 4
- 229910052768 actinide Inorganic materials 0.000 claims description 4
- 150000001255 actinides Chemical class 0.000 claims description 4
- 150000001642 boronic acid derivatives Chemical class 0.000 claims description 4
- 239000004568 cement Substances 0.000 claims description 4
- 150000001875 compounds Chemical class 0.000 claims description 4
- 229910052747 lanthanoid Inorganic materials 0.000 claims description 4
- 150000002602 lanthanoids Chemical class 0.000 claims description 4
- 229910052751 metal Inorganic materials 0.000 claims description 4
- 239000002184 metal Substances 0.000 claims description 4
- 229910052759 nickel Inorganic materials 0.000 claims description 4
- 230000035939 shock Effects 0.000 claims description 4
- 239000002904 solvent Substances 0.000 claims description 4
- 229910052725 zinc Inorganic materials 0.000 claims description 4
- 239000011701 zinc Substances 0.000 claims description 4
- 235000008733 Citrus aurantifolia Nutrition 0.000 claims description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 3
- 235000011941 Tilia x europaea Nutrition 0.000 claims description 3
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 3
- CNLWCVNCHLKFHK-UHFFFAOYSA-N aluminum;lithium;dioxido(oxo)silane Chemical compound [Li+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O CNLWCVNCHLKFHK-UHFFFAOYSA-N 0.000 claims description 3
- 230000003471 anti-radiation Effects 0.000 claims description 3
- 229910052797 bismuth Inorganic materials 0.000 claims description 3
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 claims description 3
- 150000001805 chlorine compounds Chemical class 0.000 claims description 3
- 238000000576 coating method Methods 0.000 claims description 3
- 229910052802 copper Inorganic materials 0.000 claims description 3
- 239000010949 copper Substances 0.000 claims description 3
- 229910000464 lead oxide Inorganic materials 0.000 claims description 3
- 239000004571 lime Substances 0.000 claims description 3
- 238000011084 recovery Methods 0.000 claims description 3
- 229920005989 resin Polymers 0.000 claims description 3
- 239000011347 resin Substances 0.000 claims description 3
- 239000000779 smoke Substances 0.000 claims description 3
- 229910052726 zirconium Inorganic materials 0.000 claims description 3
- DJHGAFSJWGLOIV-UHFFFAOYSA-K Arsenate3- Chemical class [O-][As]([O-])([O-])=O DJHGAFSJWGLOIV-UHFFFAOYSA-K 0.000 claims description 2
- 229910052684 Cerium Inorganic materials 0.000 claims description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 2
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 2
- 241001676573 Minium Species 0.000 claims description 2
- 229910019142 PO4 Inorganic materials 0.000 claims description 2
- 239000004952 Polyamide Substances 0.000 claims description 2
- 239000004698 Polyethylene Substances 0.000 claims description 2
- 239000004642 Polyimide Substances 0.000 claims description 2
- 239000004743 Polypropylene Substances 0.000 claims description 2
- 239000004793 Polystyrene Substances 0.000 claims description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 2
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 claims description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 2
- 150000001242 acetic acid derivatives Chemical class 0.000 claims description 2
- 150000007513 acids Chemical class 0.000 claims description 2
- 229910052782 aluminium Inorganic materials 0.000 claims description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 2
- 150000004649 carbonic acid derivatives Chemical class 0.000 claims description 2
- ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical compound [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 claims description 2
- 229910052878 cordierite Inorganic materials 0.000 claims description 2
- 150000001913 cyanates Chemical class 0.000 claims description 2
- 210000003298 dental enamel Anatomy 0.000 claims description 2
- JSKIRARMQDRGJZ-UHFFFAOYSA-N dimagnesium dioxido-bis[(1-oxido-3-oxo-2,4,6,8,9-pentaoxa-1,3-disila-5,7-dialuminabicyclo[3.3.1]nonan-7-yl)oxy]silane Chemical compound [Mg++].[Mg++].[O-][Si]([O-])(O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2)O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2 JSKIRARMQDRGJZ-UHFFFAOYSA-N 0.000 claims description 2
- 239000003822 epoxy resin Substances 0.000 claims description 2
- 150000002222 fluorine compounds Chemical class 0.000 claims description 2
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 claims description 2
- 239000008240 homogeneous mixture Substances 0.000 claims description 2
- 150000004677 hydrates Chemical class 0.000 claims description 2
- 229910052742 iron Inorganic materials 0.000 claims description 2
- 229910052746 lanthanum Inorganic materials 0.000 claims description 2
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 claims description 2
- 229910052744 lithium Inorganic materials 0.000 claims description 2
- 229910052749 magnesium Inorganic materials 0.000 claims description 2
- 239000011777 magnesium Substances 0.000 claims description 2
- 150000002823 nitrates Chemical class 0.000 claims description 2
- 239000003973 paint Substances 0.000 claims description 2
- 235000021317 phosphate Nutrition 0.000 claims description 2
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 claims description 2
- 150000003013 phosphoric acid derivatives Chemical class 0.000 claims description 2
- 229920002647 polyamide Polymers 0.000 claims description 2
- 229920000647 polyepoxide Polymers 0.000 claims description 2
- 229920000728 polyester Polymers 0.000 claims description 2
- 229920000573 polyethylene Polymers 0.000 claims description 2
- 229920001223 polyethylene glycol Polymers 0.000 claims description 2
- 229920001721 polyimide Polymers 0.000 claims description 2
- 229920001195 polyisoprene Polymers 0.000 claims description 2
- 229920005862 polyol Polymers 0.000 claims description 2
- 150000003077 polyols Chemical class 0.000 claims description 2
- 229920001155 polypropylene Polymers 0.000 claims description 2
- 229920001296 polysiloxane Polymers 0.000 claims description 2
- 229920002223 polystyrene Polymers 0.000 claims description 2
- 229920002635 polyurethane Polymers 0.000 claims description 2
- 239000004814 polyurethane Substances 0.000 claims description 2
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 2
- 229910052700 potassium Inorganic materials 0.000 claims description 2
- 239000011591 potassium Substances 0.000 claims description 2
- 229910052711 selenium Inorganic materials 0.000 claims description 2
- 239000011669 selenium Substances 0.000 claims description 2
- 229910052710 silicon Inorganic materials 0.000 claims description 2
- 239000010703 silicon Substances 0.000 claims description 2
- 239000000377 silicon dioxide Substances 0.000 claims description 2
- 229910052708 sodium Inorganic materials 0.000 claims description 2
- 239000011734 sodium Substances 0.000 claims description 2
- 229910052642 spodumene Inorganic materials 0.000 claims description 2
- 150000003467 sulfuric acid derivatives Chemical class 0.000 claims description 2
- 239000011135 tin Substances 0.000 claims description 2
- 229910052719 titanium Inorganic materials 0.000 claims description 2
- 239000010936 titanium Substances 0.000 claims description 2
- LSGOVYNHVSXFFJ-UHFFFAOYSA-N vanadate(3-) Chemical class [O-][V]([O-])([O-])=O LSGOVYNHVSXFFJ-UHFFFAOYSA-N 0.000 claims description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 2
- 229920002554 vinyl polymer Polymers 0.000 claims description 2
- 238000004056 waste incineration Methods 0.000 claims description 2
- 239000004033 plastic Substances 0.000 claims 2
- 229920003023 plastic Polymers 0.000 claims 2
- 239000011241 protective layer Substances 0.000 claims 2
- 229920006397 acrylic thermoplastic Polymers 0.000 claims 1
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 claims 1
- 239000002956 ash Substances 0.000 claims 1
- 150000001649 bromium compounds Chemical class 0.000 claims 1
- 239000002131 composite material Substances 0.000 claims 1
- 238000010411 cooking Methods 0.000 claims 1
- 229920001971 elastomer Polymers 0.000 claims 1
- 239000000806 elastomer Substances 0.000 claims 1
- 239000000835 fiber Substances 0.000 claims 1
- 150000004675 formic acid derivatives Chemical class 0.000 claims 1
- 150000004679 hydroxides Chemical class 0.000 claims 1
- 150000002739 metals Chemical class 0.000 claims 1
- 239000011120 plywood Substances 0.000 claims 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 claims 1
- 239000004800 polyvinyl chloride Substances 0.000 claims 1
- ISXSCDLOGDJUNJ-UHFFFAOYSA-N tert-butyl prop-2-enoate Chemical compound CC(C)(C)OC(=O)C=C ISXSCDLOGDJUNJ-UHFFFAOYSA-N 0.000 claims 1
- 231100000167 toxic agent Toxicity 0.000 claims 1
- 239000002023 wood Substances 0.000 claims 1
- 239000000654 additive Substances 0.000 abstract 1
- 239000003818 cinder Substances 0.000 abstract 1
- 239000003517 fume Substances 0.000 abstract 1
- 229910052745 lead Inorganic materials 0.000 abstract 1
- 231100000331 toxic Toxicity 0.000 abstract 1
- 230000002588 toxic effect Effects 0.000 abstract 1
- 239000010926 waste battery Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 description 4
- 239000002901 radioactive waste Substances 0.000 description 4
- 230000007797 corrosion Effects 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- 239000011449 brick Substances 0.000 description 2
- 150000003842 bromide salts Chemical class 0.000 description 2
- 229910052804 chromium Inorganic materials 0.000 description 2
- 239000011651 chromium Substances 0.000 description 2
- 239000004567 concrete Substances 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 229910052727 yttrium Inorganic materials 0.000 description 2
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 description 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- 206010028980 Neoplasm Diseases 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 229910052790 beryllium Inorganic materials 0.000 description 1
- ATBAMAFKBVZNFJ-UHFFFAOYSA-N beryllium atom Chemical compound [Be] ATBAMAFKBVZNFJ-UHFFFAOYSA-N 0.000 description 1
- 239000010882 bottom ash Substances 0.000 description 1
- 201000011510 cancer Diseases 0.000 description 1
- 230000001143 conditioned effect Effects 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- ZZUFCTLCJUWOSV-UHFFFAOYSA-N furosemide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC(C(O)=O)=C1NCC1=CC=CO1 ZZUFCTLCJUWOSV-UHFFFAOYSA-N 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 description 1
- 206010022000 influenza Diseases 0.000 description 1
- 230000035987 intoxication Effects 0.000 description 1
- 231100000566 intoxication Toxicity 0.000 description 1
- 150000004694 iodide salts Chemical class 0.000 description 1
- ILNKLXHFYKXPKY-UHFFFAOYSA-N iridium osmium Chemical compound [Os].[Ir] ILNKLXHFYKXPKY-UHFFFAOYSA-N 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 239000004570 mortar (masonry) Substances 0.000 description 1
- 229910052758 niobium Inorganic materials 0.000 description 1
- 239000010955 niobium Substances 0.000 description 1
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 239000012857 radioactive material Substances 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 229910052702 rhenium Inorganic materials 0.000 description 1
- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- 239000010948 rhodium Substances 0.000 description 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 229910052715 tantalum Inorganic materials 0.000 description 1
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B18/00—Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B18/04—Waste materials; Refuse
- C04B18/0463—Hazardous waste
- C04B18/0472—Waste material contaminated by heavy metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
- B09B—DISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
- B09B3/00—Destroying solid waste or transforming solid waste into something useful or harmless
- B09B3/20—Agglomeration, binding or encapsulation of solid waste
- B09B3/25—Agglomeration, binding or encapsulation of solid waste using mineral binders or matrix
- B09B3/29—Agglomeration, binding or encapsulation of solid waste using mineral binders or matrix involving a melting or softening step
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
- C04B28/10—Lime cements or magnesium oxide cements
-
- G—PHYSICS
- G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
- G21F—PROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULAR RADIATION OR PARTICLE BOMBARDMENT; TREATING RADIOACTIVELY CONTAMINATED MATERIAL; DECONTAMINATION ARRANGEMENTS THEREFOR
- G21F1/00—Shielding characterised by the composition of the materials
-
- G—PHYSICS
- G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
- G21F—PROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULAR RADIATION OR PARTICLE BOMBARDMENT; TREATING RADIOACTIVELY CONTAMINATED MATERIAL; DECONTAMINATION ARRANGEMENTS THEREFOR
- G21F1/00—Shielding characterised by the composition of the materials
- G21F1/02—Selection of uniform shielding materials
- G21F1/04—Concretes; Other hydraulic hardening materials
- G21F1/042—Concretes combined with other materials dispersed in the carrier
-
- G—PHYSICS
- G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
- G21F—PROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULAR RADIATION OR PARTICLE BOMBARDMENT; TREATING RADIOACTIVELY CONTAMINATED MATERIAL; DECONTAMINATION ARRANGEMENTS THEREFOR
- G21F1/00—Shielding characterised by the composition of the materials
- G21F1/02—Selection of uniform shielding materials
- G21F1/08—Metals; Alloys; Cermets, i.e. sintered mixtures of ceramics and metals
- G21F1/085—Heavy metals or alloys
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
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- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- High Energy & Nuclear Physics (AREA)
- General Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Environmental & Geological Engineering (AREA)
- Metallurgy (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Civil Engineering (AREA)
- Dispersion Chemistry (AREA)
- Processing Of Solid Wastes (AREA)
Abstract
Description
DES CRIPUON
La présente invention concerne des objets (récipients destinés à contenir des déchets radioactifs, éléments de maçonnerie, céramiques techniques et de laboratoires) obtenus par un procédé de fabrication qui utilise comme matériaux de base des liants/solidifiants, des adjuvants, et des déchets industriels ou ménagers, en particulier des résidus ultimes qui contiennent des proportions importantes de métaux lourds.CRIPUON
The present invention relates to objects (containers intended to contain radioactive waste, masonry elements, technical and laboratory ceramics) obtained by a manufacturing process which uses as base materials binders / solidifiers, adjuvants, and industrial waste or household, in particular ultimate residues which contain significant proportions of heavy metals.
Les métaux lourds (plomb, cadmium. mercure, chrome. nickel, étain, lanthanides, actinides, thalium, indium, bismuth, yttrium, zirconium, hafnium, or. argent, palladium, platine, zinc, cuivre, nickel, niobium, molybdène, rhodium. iridium osmium, rhénium. Heavy metals (lead, cadmium. Mercury, chromium. Nickel, tin, lanthanides, actinides, thalium, indium, bismuth, yttrium, zirconium, hafnium, gold. Silver, palladium, platinum, zinc, copper, nickel, niobium, molybdenum, rhodium, iridium osmium, rhenium.
tungstène, tantale entre autres) constituent une source de pollution et d'intoxication très importante. A tel point qu'il est envisagé de neutraliser, inerte recycler ou déposer en décharge de classe I les déchets industriels et urbains qui contiennent essentiellement des résidus de plomb, cadmium, mercure, zinc, chrome et qui sont appelés résidus ultimes.tungsten, tantalum among others) constitute a very important source of pollution and intoxication. So much so that it is planned to neutralize, inert to recycle or deposit in a Class I landfill industrial and urban waste which essentially contains residues of lead, cadmium, mercury, zinc, chromium and which are called ultimate residues.
Parmi ceux-ci figurent les résidus de traitement des fumées, les cendres volantes, les machefers des usines Wincinération d'ordures ménagères ; les piles usagées (piles boutons, au mercure, alcalines) ; les batteries ou accumulateurs à base de plomb, mercure, cadmium; les boues hydroxydes produites par les industries de la galvanoplastie, du traitement de surface et du dépot électrochimique; ; les boues du traitement des eaux ; les sables de fonderie. Among these are the residues from smoke treatment, fly ash, bottom ash from the factories Household waste incineration; used batteries (button, mercury, alkaline batteries); lead, mercury, cadmium based batteries or accumulators; hydroxide sludge produced by the electroplating, surface treatment and electrochemical deposition industries; ; water treatment sludge; foundry sands.
Parallèlement, les déchets radioactifs provenant des centrales nucléaires, des centres de recherche, ou des hôpitaux (radiologie, traitement des cancers...) posent des problèmes de transport et de stockage de plus en plus importants. At the same time, radioactive waste from nuclear power plants, research centers, or hospitals (radiology, cancer treatment, etc.) poses increasingly significant transport and storage problems.
Les objets selon l'invention sont des récipients (boites, futs. tonneaux. bidons, containers, citernes, bocaux, valises, bassins, caisses), des éléments de maçonnerie (blocs, parpaings, briques, bétons, mortiers, enduits, dalles et poutres préfabriquées, tuiles, conduits de cheminée, fosses septiques, panneaux prêts à monter) et des céramiques tecllniques et de laboratoires (carrelages, éviers, vaisselles et réacteurs chimiques. The objects according to the invention are containers (boxes, barrels. Barrels. Cans, containers, cisterns, jars, suitcases, basins, cases), masonry elements (blocks, concrete blocks, bricks, concretes, mortars, plasters, slabs and prefabricated beams, tiles, chimney flues, septic tanks, ready-to-assemble panels) and technical and laboratory ceramics (tiles, sinks, dishes and chemical reactors.
paillasses, pièces réfractaires utilisées dans les fours hautes et basses températures) fabriqués à partir des déchets précités (cendres volantes. résidus de fumées piles, batteries, machefers, sables de fonderie, boues hydro 'des) qui sont recyclés et revalorisés. benches, refractory parts used in high and low temperature ovens) made from the aforementioned waste (fly ash. smoke residues batteries, batteries, bottom flasks, foundry sands, hydro 's sludge) which are recycled and recovered.
Le matériau dont sont constitués ces objets fait écran à la radioactivité, par conséquents les objets selon l'invention protègent des effets de la radioactivité (rayonnements CL,, s y et
X) mais aussi de conditions physico-chimiques particulières (atmosphères et solutions corrosives, acides, basiques. oxydo-réductrices, ou des hautes et basses températures, résistance mécanique aux hautes pressions, aux chocs ou aux frottements). La protection antiradiation est causée par la présence en grande quantité dans le matériau des récipients.The material of which these objects are made shields the radioactivity, consequently the objects according to the invention protect from the effects of radioactivity (CL, sy, and
X) but also specific physicochemical conditions (corrosive, acidic, basic, oxidative-reducing atmospheres and solutions, or high and low temperatures, mechanical resistance to high pressures, shock or friction). Radiation protection is caused by the presence in large quantities in the material of the containers.
éléments de maçonnerie et céramiques techniques et de laboratoires, de métaux lourds qui absorbent ces rayonnements.elements of masonry and technical and laboratory ceramics, of heavy metals which absorb these radiations.
Les récipients contiendront des déchets nucléaires, chimiques, biologiques, biochimiques. Ils sers iront à les stocker et à les transporter sans dangers des lieux de leur production aux décharges de stockage classées ; ces récipients pourront également être entreposés dans les décharges de stockage de déchets nucléaires et même dans les décharges de classe I. Le fait d'être stockés dans des récipients en céramique, inaltérables au temps et à la corrosion, garantira une grandie sécurité vis à vis des déchets radioactifs. The containers will contain nuclear, chemical, biological, biochemical waste. They will be used to store and transport them without danger from the places of their production to classified landfills; these containers can also be stored in nuclear waste storage landfills and even in class I landfills. The fact of being stored in ceramic containers, unalterable in time and corrosion, will guarantee a great safety with regard to radioactive waste.
Les éléments de maçonnerie et les céramiques techniques et de laboratoires serviront à construire des bâtiments (abris antiatomiques, murs antiradiations dans les hôpitaux ou les centres de recherche, les cabinets de radiologie, les bâtiments où seront déposés des déchets nucléaires) et des laboratoires (de chimie ou de physique) qui seront donc protégés des effets des radiations nucléaires ou de conditions physico-chinriques particulières
Le procédé de fabrication des objets selon l'invention (récipients, éléments de maçonnerie et céramiques techniques et de laboratoires) permet de recycler et de revaloriser des déchets industriels et ménagers. De plus, ainsi conditionnés, les métaux lourds ne seront plus polluants.Ce procédé est composé de plusieurs étapes:
La première consiste, à sec, à produire un mélange homogène à partir des déchets industriels ou ménagers et d'un liantisolidifiant (ciment, chaux, résines minérales ou organique, sable, aluminates, zirconates, hafnates, silicates) ; des adjuvants pourront également être ajoutés. Le mélange obtenu est alors humidifié et maintenu sous agitation pour conserver une bonne homogénêité. Les déchets industriels et ménagers pourront pourront être débarrassés par lavage des chlorures, bromures. et iodures qu'ils sont susceptibles de contenir puis être séchés. Les pourcentages des constituants des melanges ainsi que leur nature sont ajustables en fonction des caractéristiques des objets que l'on voudra fabriquer. The masonry elements and technical ceramics and laboratories will be used to construct buildings (fallout shelters, radiation walls in hospitals or research centers, radiology offices, buildings where nuclear waste will be deposited) and laboratories (of chemistry or physics) which will therefore be protected from the effects of nuclear radiation or from specific physico-Chinese conditions
The method of manufacturing objects according to the invention (containers, masonry elements and technical and laboratory ceramics) makes it possible to recycle and recycle industrial and household waste. In addition, thus conditioned, heavy metals will no longer be polluting. This process consists of several stages:
The first consists, when dry, of producing a homogeneous mixture from industrial or household waste and a solidifying binder (cement, lime, mineral or organic resins, sand, aluminates, zirconates, hafnates, silicates); adjuvants may also be added. The mixture obtained is then moistened and kept stirring to maintain good homogeneity. Industrial and household waste can be removed by washing chlorides, bromides. and iodides that they are likely to contain and then be dried. The percentages of the constituents of the mixtures as well as their nature are adjustable according to the characteristics of the objects which one will want to manufacture.
La seconde étape consiste à transvaser le mélange obtenu dans un moule aux formes extèrieures et dimensions voulues de l'objet à fabriquer (un fut. un tonneau. une brique par exemple). Ensuite, un second moule (qui représente la forme intèrieure de l'objet à fabriquer) est disposé à l'intèrieur du moule externe et y est maintenu à haute pression (50 à 1000 bars) de manière à "mouler sous pression" le mélange contenu dans le moule externe. La quantité de produit (déchets et liants) déposée dans le moule externe a été calculée de manière à occuper l'espace laissé libre entre les moules internes et externes mis en place et à la pression d'utilisation. La quantité de liant est celle nécessaire à une bonne tenue mécanique et chimique du matériau final. The second step consists in transferring the mixture obtained into a mold with the external shapes and desired dimensions of the object to be manufactured (a barrel. A barrel. A brick for example). Then, a second mold (which represents the interior shape of the object to be manufactured) is placed inside the external mold and is maintained there at high pressure (50 to 1000 bars) so as to "mold under pressure" the mixture contained in the external mold. The quantity of product (waste and binders) deposited in the external mold was calculated so as to occupy the space left free between the internal and external molds put in place and at the pressure of use. The amount of binder is that necessary for good mechanical and chemical resistance of the final material.
Dans la dernière partie du procédé, Objet fabriqué est démoulé puis mis à sécher. Pour finir, diverses caractéristiques physico-chimiques du produit sont testées avant sa mise en vente. Il en est ainsi de l'étancheité (présence de fissures), de la résistance mécanique aux chocs, de la résistance chimique à la corrosion. aux solvants aux solutions acides. basiques et oxydo-réductrices, de la protection (effet d'écran) que le matériau assure contre les rayonnements radioactifs. In the last part of the process, the manufactured object is removed from the mold and allowed to dry. Finally, various physico-chemical characteristics of the product are tested before it goes on sale. This is the case for watertightness (presence of cracks), mechanical impact resistance, chemical resistance to corrosion. to solvents to acid solutions. basic and redox, protection (screen effect) that the material provides against radioactive radiation.
Selon des modes particuliers de réalisation:
--- La nature et la quantité du liant'solidifiant ajouté aux déchets contenant des métaux lourds varie selon les propriétés physico-chimiques du matériau que l'on désire fabriquer.According to particular embodiments:
--- The nature and the quantity of the solidifying binder added to the waste containing heavy metals varies according to the physico-chemical properties of the material which one wishes to manufacture.
Le ciment, de même que la chaux. des résines organiques ou minérales, des sables. des silicates, zirconates. hafnates, aluminates sont envisageables.Cement, as well as lime. organic or mineral resins, sands. silicates, zirconates. hafnates, aluminates are possible.
L'épaisseur des parois des récipients ou des éléments de maçonnerie sera adaptée à la résistance mécanique et au degré de radioprotection que nécessitent des produits radioactifs dangereux. The thickness of the walls of the containers or of the masonry elements will be adapted to the mechanical resistance and to the degree of radiation protection required by dangerous radioactive products.
Pour améliorer et renforcer les propriétés antiradiations (écran au rayonnement) ou physico-chimiques (résistances mécaniques aux hautes pressions, aux frottements, ou aux chocs, aux basses et hautes températures. aux atmosphères ou aux solutions acides. To improve and strengthen the anti-radiation (radiation shield) or physicochemical (mechanical resistance to high pressures, friction, or shock, low and high temperatures, atmospheres or acid solutions) properties.
basiques ou oxydo-réductrices), il sera possible d'ajouter divers ingrédients (adjuvants) au matériau de base (composé de déchets à base de résidus de métaux lourds) dont sont fabriqués les objets de la présente invention. Ces ingrédients ajoutés au matériau de base sont des dérivés du plomb, bore, lithium. béryllium, sodium. magnésium. potassium.basic or redox), it will be possible to add various ingredients (adjuvants) to the base material (composed of waste based on heavy metal residues) from which the objects of the present invention are manufactured. These ingredients added to the base material are derivatives of lead, boron, lithium. beryllium, sodium. magnesium. potassium.
aluminium. silicium, sélénium, étain, bismuth, fer. titane, zirconium, hafnium, nickel.aluminum. silicon, selenium, tin, bismuth, iron. titanium, zirconium, hafnium, nickel.
cuivre, zinc. étain, mercure, antimoine. yttrium. cérium. lanthane. Ces éléments sont apportés sous les formes chimiques de métal, oxydes, hydroxydesn hydrates. borates. copper, zinc. tin, mercury, antimony. yttrium. cerium. lanthanum. These elements are provided in the chemical forms of metal, oxides, hydroxydesn hydrates. borates.
sulfates, nitrates, phosphates, chlorures, fluorures, bromures, cromates, molybdates, vanadates, manganates aluminates, silicates. arséniates, carbonates. acétates. formiates hydroxycarbonates, phosphites, cyanates.sulfates, nitrates, phosphates, chlorides, fluorides, bromides, cromates, molybdates, vanadates, manganates aluminates, silicates. arsenates, carbonates. acetates. hydroxycarbonate formates, phosphites, cyanates.
- Les parois internes et externes des objets fabriqués (récipients articles de maçonnerie céramiques techniques et de laboratoires) pourront être recouvertes d'une couche de verre afin d'améliorer les propriétés de résistance chimique (à la corrosion, aux solvants. aux solutions et atmosphères acides, basiques, oxydo-réductrices aux hautes et basses températures, aux chocs, frottements et hautes pressions), d'étanchéité, et de résistance à l'effet des radiations. Le verre sera soit de récupération, soit un verre technique spécial (verre antiradiation au plomb etsou au bore) ou un verre réfractaire. - The internal and external walls of manufactured objects (receptacles for masonry, technical ceramics and laboratories) may be covered with a layer of glass in order to improve the chemical resistance properties (to corrosion, to solvents. To solutions and atmospheres acids, basic, redox at high and low temperatures, shock, friction and high pressure), sealing, and resistance to the effect of radiation. The glass will either be of recovery, or a special technical glass (lead and / or boron anti-radiation glass) or a refractory glass.
Pour recouvrir les parois des objets, il est également envisageable de faire appel à des céramiques techniques (en particulier zircone, hafnone, alumine, spodumène. cordiérite. To cover the walls of objects, it is also possible to use technical ceramics (in particular zirconia, hafnone, alumina, spodumene. Cordierite.
silice ou des composés à base d'oxydes de plomb, bore, cadmium, mercure, lanthanides, actinides, hafnium, étain, antimoine), des émaux, des boues hydroxydes produites par les industries de la galvanoplastie, du traitement de surface et du dépot electrochimique ou bien à des revêtements comme des enduits ou des peintures minérales ou organiques à base de silicates, aluminates, borates. oxydes de plomb (dont le minium), de silicones, de résines époxy, polyimides. polystyrènes, polyamides, polychiorures de vinyle, polyesters, polyéthylènes, polyéthylènes glycols polypropylènes, polyisobutènes, polyols, polyisobutylènes, polyisoprènes, polyuréthanes glycérophtaliques, vinyliques, acryliques, ou de céramiques techniques (entre particulier zircone. hafnone, alumine, spodumène, cordiérite, silice ou des composés à base d'oxydes de plomb, bore, cadmium, mercure, lanthanides, actinides, hafnium, étain, antimoine).Les verres et les céramiques pourront être préparés entièrement ou partiellement à partir de déchets industriels de récupération comme des boues hydroxydes produites par les industries de la galvanoplastie, du traitement de surface et du dépot électrochimique
--- Les objets selon l'invention pourront être démoulés, subir une première phase de séchage, puis être soumis à un processus de cuisson en four à haute température.silica or compounds based on lead oxides, boron, cadmium, mercury, lanthanides, actinides, hafnium, tin, antimony), enamels, hydroxide sludges produced by the industries of electroplating, surface treatment and deposit electrochemical or to coatings such as coatings or mineral or organic paints based on silicates, aluminates, borates. lead oxides (including minium), silicones, epoxy resins, polyimides. polystyrenes, polyamides, polyvinylchlorides, polyesters, polyethylenes, polyethylene glycols polypropylenes, polyisobutenes, polyols, polyisobutylenes, polyisoprenes, polyurethanes glycerophthalic, vinyl, acrylic, or of technical ceramics (especially zirconia. hafnone, cordurite, alumina, spodumene compounds based on oxides of lead, boron, cadmium, mercury, lanthanides, actinides, hafnium, tin, antimony). Glasses and ceramics can be prepared entirely or partially from industrial recovery waste such as hydroxide sludge produced by the electroplating, surface treatment and electrochemical deposit industries
--- The objects according to the invention can be removed from the mold, undergo a first drying phase, then be subjected to a baking process in an oven at high temperature.
Les industries du recyclage des déchets industriels et ménagers, celles du bâtiment et des travaux publics ; les centres de recherche, les centrales nucléaires, les hôpitaux, les cabinets de radiologie qui utilisent des matières radioactives pourront utiliser les récipients, les éléments de maçonnerie et les céramiques techniques et de laboratoires fabriqués par le procédé afin de revaloriser des résidus ultimes de déchets ménagers et industriels, de stocker et transporter en sécurité des déchets radioactifs, de construire des bâtiments. The recycling industries for industrial and household waste, the building and public works industries; research centers, nuclear power stations, hospitals, radiology offices that use radioactive materials may use the containers, masonry elements and technical and laboratory ceramics produced by the process in order to recycle final residues of household waste and industrialists, to safely store and transport radioactive waste, to construct buildings.
Claims (8)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR9212452A FR2696662A1 (en) | 1992-10-12 | 1992-10-12 | Prods made from heavy metal derivs, waste contg heavy metals, and light domestic and industrial waste - as containers, masonry and ceramics giving safe storage and transport of pollutants, and prods. for use in difficult conditions |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR9212452A FR2696662A1 (en) | 1992-10-12 | 1992-10-12 | Prods made from heavy metal derivs, waste contg heavy metals, and light domestic and industrial waste - as containers, masonry and ceramics giving safe storage and transport of pollutants, and prods. for use in difficult conditions |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| FR2696662A1 true FR2696662A1 (en) | 1994-04-15 |
Family
ID=9434640
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FR9212452A Revoked FR2696662A1 (en) | 1992-10-12 | 1992-10-12 | Prods made from heavy metal derivs, waste contg heavy metals, and light domestic and industrial waste - as containers, masonry and ceramics giving safe storage and transport of pollutants, and prods. for use in difficult conditions |
Country Status (1)
| Country | Link |
|---|---|
| FR (1) | FR2696662A1 (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0669626A2 (en) * | 1994-02-25 | 1995-08-30 | Scientific Ecology Group, Inc. | An article made out of radioactive or hazardous waste and a method of making the same |
| FR2763936A1 (en) * | 1997-05-27 | 1998-12-04 | Inertec | Aqueous binder for scrap battery consolidation and stabilisation |
| WO2019058086A1 (en) | 2017-09-25 | 2019-03-28 | Sarp Industries | Process for manufacturing a porous material from incineration clinkers |
| CN114566303A (en) * | 2022-03-01 | 2022-05-31 | 西南科技大学 | Preparation method of modified diopside glass solidified body containing radioactive waste containing molybdenum |
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| FR1188238A (en) * | 1957-11-20 | 1959-09-21 | Ceramic coatings for protection against ionizing radiation | |
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| FR2306952A1 (en) * | 1975-04-12 | 1976-11-05 | Philips Nv | Concrete or mortar for radiation-absorbing structures - contg hydraulic binder, filler and radiation-absorbing metal silicate or borate (BE121076) |
| EP0033810A1 (en) * | 1980-02-06 | 1981-08-19 | Francis Gagneraud | Method of manufacturing protection shields against radioactive materials |
| DE3630697C2 (en) * | 1985-09-10 | 1990-04-26 | Magindag Steirische Magnesit-Industrie Ag, Wien, At | |
| EP0402746A1 (en) * | 1989-06-10 | 1990-12-19 | ZWN ZIEGELWERK NEUNKIRCHEN GmbH | Process for the recycling of muddy or dusty accumulated special waste |
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| FR1188238A (en) * | 1957-11-20 | 1959-09-21 | Ceramic coatings for protection against ionizing radiation | |
| FR2279204A1 (en) * | 1974-07-18 | 1976-02-13 | Estienne Jean | Nuclear radiation shielding materials - contg linz-donawitz foundry slag and cements |
| FR2306952A1 (en) * | 1975-04-12 | 1976-11-05 | Philips Nv | Concrete or mortar for radiation-absorbing structures - contg hydraulic binder, filler and radiation-absorbing metal silicate or borate (BE121076) |
| EP0033810A1 (en) * | 1980-02-06 | 1981-08-19 | Francis Gagneraud | Method of manufacturing protection shields against radioactive materials |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0669626A2 (en) * | 1994-02-25 | 1995-08-30 | Scientific Ecology Group, Inc. | An article made out of radioactive or hazardous waste and a method of making the same |
| EP0669626A3 (en) * | 1994-02-25 | 1995-12-13 | Scient Ecology Group Inc | An article made out of radioactive or hazardous waste and a method of making the same. |
| FR2763936A1 (en) * | 1997-05-27 | 1998-12-04 | Inertec | Aqueous binder for scrap battery consolidation and stabilisation |
| WO2019058086A1 (en) | 2017-09-25 | 2019-03-28 | Sarp Industries | Process for manufacturing a porous material from incineration clinkers |
| FR3071494A1 (en) * | 2017-09-25 | 2019-03-29 | Sarp Industries | PROCESS FOR MANUFACTURING POROUS MATERIAL FROM INCINERATION MACHEFERS |
| CN114566303A (en) * | 2022-03-01 | 2022-05-31 | 西南科技大学 | Preparation method of modified diopside glass solidified body containing radioactive waste containing molybdenum |
| CN114566303B (en) * | 2022-03-01 | 2024-06-11 | 西南科技大学 | Preparation method of modified diopside glass solidified body containing molybdenum-containing radioactive waste |
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