FR2612931A1 - Process for the manufacture of plastic packaging and packaging obtained by making use of the process - Google Patents

Process for the manufacture of plastic packaging and packaging obtained by making use of the process Download PDF

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Publication number
FR2612931A1
FR2612931A1 FR8704525A FR8704525A FR2612931A1 FR 2612931 A1 FR2612931 A1 FR 2612931A1 FR 8704525 A FR8704525 A FR 8704525A FR 8704525 A FR8704525 A FR 8704525A FR 2612931 A1 FR2612931 A1 FR 2612931A1
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FR
France
Prior art keywords
packaging
masterbatch
degradable
polyethylene
under
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
FR8704525A
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French (fr)
Inventor
Abel Barbier
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BARBIER CIE EXTRUSION POLYETHY
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BARBIER CIE EXTRUSION POLYETHY
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BARBIER CIE EXTRUSION POLYETHY filed Critical BARBIER CIE EXTRUSION POLYETHY
Priority to FR8704525A priority Critical patent/FR2612931A1/en
Publication of FR2612931A1 publication Critical patent/FR2612931A1/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00Processes of treating or compounding macromolecular substances
    • C08J3/20Compounding polymers with additives, e.g. colouring
    • C08J3/22Compounding polymers with additives, e.g. colouring using masterbatch techniques
    • C08J3/226Compounding polymers with additives, e.g. colouring using masterbatch techniques using a polymer as a carrier
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/01Use of inorganic substances as compounding ingredients characterized by their specific function
    • C08K3/012Additives activating the degradation of the macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2325/00Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Derivatives of such polymers
    • C08J2325/02Homopolymers or copolymers of hydrocarbons
    • C08J2325/04Homopolymers or copolymers of styrene
    • C08J2325/06Polystyrene

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Extrusion Moulding Of Plastics Or The Like (AREA)

Abstract

The process is noteworthy in that a certain quantity of a master batch consisting of a product which has properties that are capable of making the packaging obtained degradable under the effect of an external atmospheric phenomenon is incorporated into the starting polymer before conversion.

Description

L'invention concerne un procédé de fabrication d'emballages en matière plastique et les emballages obtenus par la mise en oeuvre du procédé. The invention relates to a method of manufacturing plastic packaging and packaging obtained by the implementation of the method.

L'objet de l'invention se rattache au secteur technique de la transformation des matières plastiques. The object of the invention is related to the technical sector of plastics processing.

On sait que l'utilisation d'emballages, sous forme de films, sacs, sachets en matière plastique, notamment å base de polyéthylène, est de plus en plus importante. En effet, une grande partie des produits consommés sont emballés, regroupés et/ou transportés dans de tels emballages. Il a eté constaté que très souvent après leur utilisation et fonction première, ces différents types d'emballage sont laissés dans la nature, d'od une pollution importante. It is known that the use of packaging, in the form of films, bags, plastic bags, in particular based on polyethylene, is becoming increasingly important. Indeed, a large part of the consumed products are packaged, grouped and / or transported in such packaging. It has been found that very often after their use and primary function, these different types of packaging are left in the nature, of a significant pollution.

Le problème étant ainsi posé, l'invention s'est fixée pour but de remédier a ces inconvénients. d'une manière simple et efficace, en rendant ces différents emballages auto dégradabl es.  The problem being thus posed, the purpose of the invention is to remedy these drawbacks. in a simple and effective way, by making these different self-degradable packaging.

A cet égard, il a été conçu et mis au point un procédé spécifique de fabrication permettant de contrôler la dégradation des films polyéthylènes utilisés-pour l'emballage des denrées ou des biens de consommation les plus divers. In this respect, it has been designed and developed a specific manufacturing process to control the degradation of polyethylenes used for packaging foodstuffs or various consumer goods.

Pour atteindre ce résultat, on incorpore au polymère de départ, avant transformation, une certaine quantité d'un mé lange-ma-ltre consistant en un produit ayant des propriétés aptes à rendre dégradable les emballages obtenus, sous l'effet d'un phénomène atmosphérique extérieur. In order to achieve this result, a certain amount of a mixture-ma-lter consisting of a product having properties capable of rendering the packages obtained degradable under the effect of a phenomenon is incorporated into the starting polymer before transformation. outside atmosphere.

Le procédé selon l'invention s applique à tous les types d'emballages a base de polyéthylène tels que
- Films et gaines neutres ou imprimés. en rouleaux, utilisés en conditionnement automatique ou manuel,
- Films, gaines et housses rétractables utilisés pour le fardelage et le regroupage, - - Sacs a gueule ouverte,
- Sacs a bretelles,
- Sacs liassés,
- Sacs en rouleaux prédécoupés,
- Etc...
The process according to the invention is applicable to all types of polyethylene-based packaging such as
- Neutral or printed films and sleeves. in rolls, used in automatic or manual packaging,
- Films, sheaths and retractable covers used for bundling and bundling, - - Open mouth bags,
- Shoulder bags,
- Heaped bags,
- Bags in pre-cut rolls,
- Etc ...

L'invention est exposée ci-après plus en détail à l'aide des dessins annexés dans lesquels
- la figure l est une vue à caractère purement schéma- tique illustrant un exemple d'installation pour la mise en oeuvre du procédé,
- la figure 2 est un schéma fonctionnel des principales phases du procédé de fabrication.
The invention is described below in more detail with the aid of the accompanying drawings in which
FIG. 1 is a purely schematic view illustrating an example of an installation for carrying out the method,
- Figure 2 is a block diagram of the main phases of the manufacturing process.

Afin de rendre plus concret l'objet de l'invention, on le décrit maintenant d'une manière non limitative en se référant aux exemples de réalisation des figures des dessins. In order to make more concrete the object of the invention, it is now described in a non-limiting manner with reference to the embodiments of the figures of the drawings.

Les différents types d'emballage en polyéthylène sont obtenus, d'une manière parfaitement connue, par le procédé d'extrusion tubulaire. On rappelle, à cet effet, comme le montre schématiquement la figure 1, que le composé thermoplastique (P > est généralement présente en billettes ou en granulats dans une trémie (T) surmontant un caisson (C) chauffé pour maintenir la température nécessaire à l'état de viscosité satisfaisante du polymère. L'entraînement des granuls s'effectue au moyen d'une vis d'rchimEde (A) qui comporte successivement une zone d'alimentation, une zone de compression et une zone de dosage. L'extrématé de sortie comporte une filière de section appropriée à la forme souhaitée puis différents moyens et postes de travail compte-tenu du type d'emballage à obtenir. The various types of polyethylene packaging are obtained, in a perfectly known manner, by the tubular extrusion process. To this end, as is shown schematically in FIG. 1, the thermoplastic compound (P>) is generally present in billets or aggregates in a hopper (T) surmounting a box (C) heated to maintain the temperature required for satisfactory state of viscosity of the polymer The granules are driven by means of a cooling screw (A) which successively comprises a feed zone, a compression zone and a dosing zone. output comprises a die section appropriate to the desired shape and then different means and workstations given the type of packaging to obtain.

Selon une caractéristique à la base de l'invention, on incorpore au polymère de départ (mélange polybthylbne), une certaine quantité d'un mélange-maître (M > consistant en un produit apte à assurer l'auto-dégradabilité de l'emballage obtenu. According to a characteristic underlying the invention, is incorporated into the starting polymer (polybenthylbne mixture), a certain amount of a masterbatch (M> consisting of a product capable of ensuring the self-degradability of the packaging got.

Les quantites et proportions de ce mélange-maître peuvent être variables pour obtenir une dégradabilité contrôlé plus ou moins rapide. Ce melange maître est une matière concentrée intégrée à un certain pourcentage de l'ordre de 5 ; 6. The quantities and proportions of this masterbatch can be variable to obtain a more or less rapid controlled degradability. This masterbatch is a concentrated material integrated at a certain percentage of the order of 5; 6.

D'une manière préférée, ce mélange-maître consiste e un produit susceptible d'assurer la photo-dégrad=tion dé le.- ballage sous l'influence des rayons ultra-violets. fi titre d'exemple indicatif, le produit peut Btre dans ce cas un mélange à base de soufre et de fer. In a preferred manner, this masterbatch consists of a product capable of ensuring the photodegradation of the wrap under the influence of the ultraviolet rays. As an indicative example, the product can be in this case a mixture based on sulfur and iron.

Il est bien évident qu'on ne doit pas exclure d'autres agents de mélange aptes à assurer la biodégradabilité de l'emballage sous l'action, par exemple. de l'air, de l'eau et autres phénomènes atmosphériques extérieurs. It is obvious that other mixing agents capable of ensuring the biodegradability of the packaging under the action, for example, should not be excluded. air, water and other external atmospheric phenomena.

Le film polyéthyléne ainsi obtenu est ensuite tranf or- me sur des machines classiques d'impression et de soudure en fonction du type d'emballage désiré. Le procédé selon l'invention est donc caractérisé par les étapes essentielles suivantes:
- incorporation au polymère de départ (polyéthylène), d'une certaine quantité de mblange-maltre (étape 1),
- extrusion du mélange de polyéthylène additionné de mélange-maître (étape 2),
- transformation du film plastique obtenu en fonction du produit d'emballage final recherché (étape 3).
The polyethylene film thus obtained is then processed on conventional printing and welding machines depending on the type of packaging desired. The method according to the invention is therefore characterized by the following essential steps:
- incorporation into the starting polymer (polyethylene) of a certain amount of mblange-maltre (step 1),
extrusion of the mixture of polyethylene mixed with the masterbatch (step 2),
- Transformation of the plastic film obtained according to the desired final packaging product (step 3).

Par exemple, le mélange homogène obtenu est soufflé pour obtenir une gaine puis éventuellement impressionné. Cette gaine, imprimée ou non, est alors convenablement découpée et soudée pour la réalisation de sacs à bretelles, de sacs lissés, de sacs en roui eaux.  For example, the homogeneous mixture obtained is blown to obtain a sheath and then possibly impressed. This sheath, printed or not, is then properly cut and welded for the realization of shoulder bags, smooth bags, bags roui waters.

il en résulte donc, que les sacs ou autres types d'emballages obtenus selon l'invention, sont susceptibles d'tue automatiquement détruits s'ils sont laissés pendant un temps déterminé variable, allant de quelques jours à plusieurs mois, en contact avec les agents atmosphériques extérieurs.  it follows therefore that the bags or other types of packaging obtained according to the invention, are likely to kill automatically destroyed if they are left for a variable time variable, ranging from a few days to several months, in contact with the external atmospheric agents.

Claims (1)

REVENDICATIONS - i - Procédé de fabrication d'emballages en matière plastique notamment en polyéthylène, caractérisé en ce que l'on incorpore au polymère de départ avant transformation, une certaine quantité d'un mXlange-maltre consistant en un produit ayant des pro piétés aptes à rendre dégradable les emballages obtenus, sous l'effet d'un phénomène atmosphérique extérieur.- i - A process for manufacturing plastics packaging especially polyethylene, characterized in that is incorporated in the starting polymer before processing, a certain amount of a mxlange-maltre consisting of a product having pro pieties apt to to render the packaging obtained degradable, under the effect of an external atmospheric phenomenon. - 2 - Procédé selon la revendication l, caractérisé par le étapes essentielles suivantesThe process according to claim 1, characterized by the following essential steps - on incorpore au polymère de départ, à savoir le polyéthylène, une certaine quantité de mélange-maître  - is incorporated in the starting polymer, namely polyethylene, a certain amount of masterbatch - on extrude le mélange de polyéthylène additionné de mélange maître, the polyethylene mixture containing a masterbatch is extruded, - on transforme le film plastique obtenu en fonction du produit d'emballage recherché. the plastic film obtained is converted according to the desired packaging product. - 3 - Procédé selon la revendication i, caractérisé en ce que le mélange-maître concentré résulte d'un mélange conformé pour assurer la photo-dbgradation de l'emballage sous l'influence des rayons ultra-violets.- 3 - Process according to claim i, characterized in that the concentrated masterbatch results from a mixture shaped to ensure photo-degradation of the package under the influence of ultraviolet rays. - 4 - Procédé selon la revendication 1, caractérisé en ce que l'on incorpore le mElange-maltre en quantité variable en fonction du temps désiré pour que l'emballage devienne dégradable.- 4 - A method according to claim 1, characterized in that one incorporates the mix-maltre variable amount depending on the desired time for the packaging becomes degradable. - 5 - Emballage obtenu directement par la mise en oeuvre du pro cédé selon l'une quelconque des revendications l à 4! caractéri- sé en ce qu'il présente des caractéristiques chimiques aptes a le rendre dégradable, au bout d'un temps déterminé. sous l'effet de phénomènes atmosphériques extérieurs.- 5 - Packaging obtained directly by the implementation of the process according to any one of claims 1 to 4! characterized in that it has chemical characteristics capable of rendering it degradable after a given time. under the effect of external atmospheric phenomena. - t - Emballage selon la revendication 5, cara-tE e ce qu'il se présente sous forme de sacs. Packaging according to claim 5, because it is in the form of bags.
FR8704525A 1987-03-24 1987-03-24 Process for the manufacture of plastic packaging and packaging obtained by making use of the process Pending FR2612931A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
FR8704525A FR2612931A1 (en) 1987-03-24 1987-03-24 Process for the manufacture of plastic packaging and packaging obtained by making use of the process

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR8704525A FR2612931A1 (en) 1987-03-24 1987-03-24 Process for the manufacture of plastic packaging and packaging obtained by making use of the process

Publications (1)

Publication Number Publication Date
FR2612931A1 true FR2612931A1 (en) 1988-09-30

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FR8704525A Pending FR2612931A1 (en) 1987-03-24 1987-03-24 Process for the manufacture of plastic packaging and packaging obtained by making use of the process

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Country Link
FR (1) FR2612931A1 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5667574A (en) * 1996-11-06 1997-09-16 Chi May Co., Ltd. Starch-based composition for preparing an environment degradable α-olefinic polymer molding material

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2180946A1 (en) * 1972-04-18 1973-11-30 Akerlund & Rausing Ab

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2180946A1 (en) * 1972-04-18 1973-11-30 Akerlund & Rausing Ab

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5667574A (en) * 1996-11-06 1997-09-16 Chi May Co., Ltd. Starch-based composition for preparing an environment degradable α-olefinic polymer molding material

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