FR2552079B1 - IMPROVED PROCESS FOR THE SYNTHESIS OF BUTENE-1 BY DIMERIZATION OF ETHYLENE - Google Patents

IMPROVED PROCESS FOR THE SYNTHESIS OF BUTENE-1 BY DIMERIZATION OF ETHYLENE

Info

Publication number
FR2552079B1
FR2552079B1 FR8315040A FR8315040A FR2552079B1 FR 2552079 B1 FR2552079 B1 FR 2552079B1 FR 8315040 A FR8315040 A FR 8315040A FR 8315040 A FR8315040 A FR 8315040A FR 2552079 B1 FR2552079 B1 FR 2552079B1
Authority
FR
France
Prior art keywords
dimerization
butene
synthesis
ethylene
improved process
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
FR8315040A
Other languages
French (fr)
Other versions
FR2552079A1 (en
Inventor
Le Quan Nhuong
Daniel Cruypelinck
Dominique Commereur
Yves Chauvin
Gerard Leger
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IFP Energies Nouvelles IFPEN
Original Assignee
IFP Energies Nouvelles IFPEN
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IFP Energies Nouvelles IFPEN filed Critical IFP Energies Nouvelles IFPEN
Priority to FR8315040A priority Critical patent/FR2552079B1/en
Priority to DE8484401784T priority patent/DE3461173D1/en
Priority to EP84401784A priority patent/EP0135441B1/en
Priority to NO843713A priority patent/NO158575C/en
Priority to BR8404694A priority patent/BR8404694A/en
Priority to AU33288/84A priority patent/AU572191B2/en
Priority to NZ209604A priority patent/NZ209604A/en
Priority to US06/652,555 priority patent/US4532370A/en
Priority to JP59198390A priority patent/JPS6094923A/en
Priority to CA000463662A priority patent/CA1234383A/en
Publication of FR2552079A1 publication Critical patent/FR2552079A1/en
Priority to US06/728,901 priority patent/US4615998A/en
Application granted granted Critical
Publication of FR2552079B1 publication Critical patent/FR2552079B1/en
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/26—Catalytic processes with hydrides or organic compounds
    • C07C2/30—Catalytic processes with hydrides or organic compounds containing metal-to-carbon bond; Metal hydrides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/46—Titanium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/122—Metal aryl or alkyl compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • C07C2531/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
FR8315040A 1983-09-20 1983-09-20 IMPROVED PROCESS FOR THE SYNTHESIS OF BUTENE-1 BY DIMERIZATION OF ETHYLENE Expired FR2552079B1 (en)

Priority Applications (11)

Application Number Priority Date Filing Date Title
FR8315040A FR2552079B1 (en) 1983-09-20 1983-09-20 IMPROVED PROCESS FOR THE SYNTHESIS OF BUTENE-1 BY DIMERIZATION OF ETHYLENE
DE8484401784T DE3461173D1 (en) 1983-09-20 1984-09-11 Process for the synthesis of butene-1 by dimerisation of ethylene
EP84401784A EP0135441B1 (en) 1983-09-20 1984-09-11 Process for the synthesis of butene-1 by dimerisation of ethylene
NO843713A NO158575C (en) 1983-09-20 1984-09-18 PROCEDURE FOR THE CONVERSION OF THE ETHYLE TO BUTEN-I.
AU33288/84A AU572191B2 (en) 1983-09-20 1984-09-19 Synthesizing i-butene by dimerisation of ethylene
NZ209604A NZ209604A (en) 1983-09-20 1984-09-19 Catalytic production of 1-butene from ethylene
BR8404694A BR8404694A (en) 1983-09-20 1984-09-19 IMPROVED PROCESS FOR CONVERSION OF ETHYLENE TO BUTENE-1
US06/652,555 US4532370A (en) 1983-09-20 1984-09-20 Process for synthesizing 1-butene by dimerization of ethylene
JP59198390A JPS6094923A (en) 1983-09-20 1984-09-20 Improved synthesis of 1-butene by dimerization of ethylene
CA000463662A CA1234383A (en) 1983-09-20 1984-09-20 Improved catalyst and process for the synthesis of butene-1 by ethylene dimerization
US06/728,901 US4615998A (en) 1983-09-20 1985-04-30 Catalyst suitable for synthesizing 1-butene by dimerization of ethylene

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR8315040A FR2552079B1 (en) 1983-09-20 1983-09-20 IMPROVED PROCESS FOR THE SYNTHESIS OF BUTENE-1 BY DIMERIZATION OF ETHYLENE

Publications (2)

Publication Number Publication Date
FR2552079A1 FR2552079A1 (en) 1985-03-22
FR2552079B1 true FR2552079B1 (en) 1986-10-03

Family

ID=9292427

Family Applications (1)

Application Number Title Priority Date Filing Date
FR8315040A Expired FR2552079B1 (en) 1983-09-20 1983-09-20 IMPROVED PROCESS FOR THE SYNTHESIS OF BUTENE-1 BY DIMERIZATION OF ETHYLENE

Country Status (2)

Country Link
JP (1) JPS6094923A (en)
FR (1) FR2552079B1 (en)

Families Citing this family (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SU1662996A1 (en) * 1987-07-13 1991-07-15 Отделение Института химической физики АН СССР Method of producing butene-1
US5037997A (en) * 1988-02-23 1991-08-06 Institut Khimicheskoi Fiziki An Sssr Method of preparing 1-butene and/or hexenes
WO1992010451A1 (en) * 1990-12-07 1992-06-25 Okhtinskoe Nauchno-Proizvodstvennoe Obiedinenie 'plastopolimer' Method of obtaining butene-i
FR2879189B1 (en) 2004-12-13 2007-03-30 Inst Francais Du Petrole METHOD FOR TRANSPORTING SUSPENDED HYDRATES INTO PRODUCTION EFFLUENTS USING A NON-POLLUTANT ADDITIVE
FR2880018B1 (en) 2004-12-27 2007-02-23 Inst Francais Du Petrole PROPYLENE PRODUCTION USING DIMERIZATION OF ETHYLENE TO BUTENE-1, HYDRO-ISOMERISATION TO BUTENE-2 AND ETHYLENE METATHESIS
FR2960234B1 (en) * 2010-05-18 2013-11-01 Inst Francais Du Petrole A METHOD FOR DIMERIZING ETHYLENE TO BUTENE-1 USING A COMPOSITION COMPRISING A TITANIUM-BASED COMPLEX AND A HETEROATOMY-FUNCTIONALIZED ALCOXY LIGAND
FR2984311B1 (en) 2011-12-20 2015-01-30 IFP Energies Nouvelles PROCESS FOR THE PRODUCTION OF OCTENS USING THE DIMERISATION OF ETHYLENE TO BUTENES AND DIMERIZATION OF BUTENES IN OCTENES
FR2995893B1 (en) * 2012-09-21 2014-09-05 Axens PROCESS FOR THE PRODUCTION OF 1,3-BUTADIENE IMPLEMENTING THE ETHYLENE DIMERISATION AND THE DEHYDROGENATION OF THE BUTENES OBTAINED
FR3008697B1 (en) * 2013-07-19 2015-07-31 IFP Energies Nouvelles METHOD FOR SELECTIVELY DIMERIZING ETHYLENE TO BUTENE-1 USING A CATALYTIC COMPOSITION COMPRISING AN ADDITIVE TITANIUM COMPLEX IN ASSOCIATION WITH A HETERO-ATOMIC FUNCTIONALIZED ALCOXY LIGAND
FR3023183A1 (en) 2014-07-04 2016-01-08 IFP Energies Nouvelles CATALYTIC COMPOSITION AND METHOD FOR SELECTIVE DIMERIZATION OF ETHYLENE TO BUTENE-1
FR3023285B1 (en) 2014-07-04 2017-10-27 Ifp Energies Now IMPROVED METHOD FOR SELECTIVE DIMERIZATION OF ETHYLENE TO BUTENE-1
FR3068621B1 (en) 2017-07-10 2020-06-26 IFP Energies Nouvelles OLIGOMERIZATION PROCESS USING VORTEX
FR3068620B1 (en) 2017-07-10 2020-06-26 IFP Energies Nouvelles OLIGOMERIZATION PROCESS IMPLEMENTING A REACTIONAL DEVICE COMPRISING A MEANS OF DISPERSION
FR3083235B1 (en) 2018-06-29 2021-12-03 Ifp Energies Now CASCADE OLIGOMERIZATION PROCESS OF AGITATED LIQUID GAS REACTORS WITH STAGE INJECTION OF ETHYLENE
FR3086288A1 (en) 2018-09-21 2020-03-27 IFP Energies Nouvelles PROCESS FOR THE OLIGOMERIZATION OF ETHYLENE IN A COMPARTIMENT GAS / LIQUID REACTOR
FR3096587B1 (en) 2019-05-28 2021-06-11 Ifp Energies Now COMPARTMENTAL OLIGOMERIZATION REACTOR
FR3099476B1 (en) 2019-07-31 2021-07-30 Ifp Energies Now OLIGOMERIZATION PROCESS IMPLEMENTING A GAS SKY RECYCLE
FR3102685B1 (en) 2019-11-06 2021-10-29 Ifp Energies Now Olefin oligomerization process in an oligomerization reactor
FR3105018B1 (en) 2019-12-18 2021-12-10 Ifp Energies Now OLIGOMERIZATION GAS / LIQUID REACTOR INCLUDING TRANSVERSAL INTERNALS
FR3105019B1 (en) 2019-12-18 2022-07-22 Ifp Energies Now GAS/LIQUID OLIGOMERIZATION REACTOR WITH SUCCESSIVE ZONES OF VARIABLE DIAMETER
FR3108264B1 (en) 2020-03-19 2022-04-08 Ifp Energies Now Ethylene oligomerization plant to produce alpha-olefins
FR3112342A1 (en) 2020-07-09 2022-01-14 IFP Energies Nouvelles OLIGOMERIZATION PROCESS USING A GAS/LIQUID EXCHANGER
FR3112775B1 (en) 2020-07-24 2022-07-01 Ifp Energies Now Process of oligomerization implementing a recycling of the gaseous sky
FR3117891A1 (en) 2020-12-23 2022-06-24 IFP Energies Nouvelles GAS/LIQUID OLIGOMERIZATION REACTOR COMPRISING A CENTRAL PIPE
FR3117890B1 (en) 2020-12-23 2024-01-12 Ifp Energies Now GAS/LIQUID OLIGOMERISATION REACTOR INCLUDING A DOUBLE GAS/LIQUID DISTRIBUTOR
FR3121439B1 (en) 2021-03-30 2023-03-24 Ifp Energies Now OLIGOMERIZATION PROCESS COMPRISING A STEP FOR RECYCLING A PRECOOLED SOLVENT
FR3123354B1 (en) 2021-05-28 2023-05-26 Ifp Energies Now PROCESS FOR OLIGOMERIZATION IN A REACTOR WITH ZONES OF VARIABLE DIAMETERS COMPRISING A STEP FOR RECYCLING A PRECOOLED SOLVENT

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1235631A (en) * 1969-05-19 1971-06-16 Bp Chem Int Ltd Oligomerisation of ethylene
SU681032A1 (en) * 1976-02-23 1979-08-25 Грозненский филиал Охтинского научно-производственного объединения "Пластполимер" Process for the preparation of dimers and codimers of alpha-olefins
JPS57169430A (en) * 1981-04-14 1982-10-19 Mitsui Toatsu Chem Inc Dimerization of ethylene
JPS58146518A (en) * 1982-02-24 1983-09-01 Mitsubishi Petrochem Co Ltd Preparation of 1-butene

Also Published As

Publication number Publication date
JPS6094923A (en) 1985-05-28
FR2552079A1 (en) 1985-03-22
JPH0329767B2 (en) 1991-04-25

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