FR2460908A2 - Preparation de derives carbonyles par oxydation d'alcools par l'oxygene moleculaire - Google Patents
Preparation de derives carbonyles par oxydation d'alcools par l'oxygene moleculaire Download PDFInfo
- Publication number
- FR2460908A2 FR2460908A2 FR7918183A FR7918183A FR2460908A2 FR 2460908 A2 FR2460908 A2 FR 2460908A2 FR 7918183 A FR7918183 A FR 7918183A FR 7918183 A FR7918183 A FR 7918183A FR 2460908 A2 FR2460908 A2 FR 2460908A2
- Authority
- FR
- France
- Prior art keywords
- prodn
- oxidn
- catalyst
- complex
- aldehyde
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 150000001299 aldehydes Chemical class 0.000 title abstract description 3
- 150000002576 ketones Chemical class 0.000 title abstract description 3
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 title abstract 2
- 239000003054 catalyst Substances 0.000 title abstract 2
- 229910052802 copper Inorganic materials 0.000 title abstract 2
- 229910052707 ruthenium Inorganic materials 0.000 title abstract 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 title 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 title 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 title 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 title 1
- 239000010949 copper Substances 0.000 title 1
- 125000001153 fluoro group Chemical group F* 0.000 title 1
- 150000002505 iron Chemical class 0.000 title 1
- 229910052760 oxygen Inorganic materials 0.000 title 1
- 239000001301 oxygen Substances 0.000 title 1
- UGMIBZJOAVVFNP-UHFFFAOYSA-K ruthenium(3+);2,2,2-trifluoroacetate Chemical compound [Ru+3].[O-]C(=O)C(F)(F)F.[O-]C(=O)C(F)(F)F.[O-]C(=O)C(F)(F)F UGMIBZJOAVVFNP-UHFFFAOYSA-K 0.000 claims abstract description 5
- 150000003839 salts Chemical class 0.000 claims abstract description 4
- 238000000034 method Methods 0.000 claims abstract description 3
- HUMNYLRZRPPJDN-UHFFFAOYSA-N benzaldehyde Chemical compound O=CC1=CC=CC=C1 HUMNYLRZRPPJDN-UHFFFAOYSA-N 0.000 abstract 2
- 150000001298 alcohols Chemical class 0.000 abstract 1
- 150000001450 anions Chemical class 0.000 abstract 1
- 239000002917 insecticide Substances 0.000 abstract 1
- 239000000543 intermediate Substances 0.000 abstract 1
- 229910052742 iron Inorganic materials 0.000 abstract 1
- 229910052751 metal Chemical class 0.000 abstract 1
- 239000002184 metal Chemical class 0.000 abstract 1
- QNGNSVIICDLXHT-UHFFFAOYSA-N para-ethylbenzaldehyde Natural products CCC1=CC=C(C=O)C=C1 QNGNSVIICDLXHT-UHFFFAOYSA-N 0.000 abstract 1
- 239000002728 pyrethroid Substances 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
- WQRBJFZKPWPIJD-UHFFFAOYSA-N 1,1-dibutoxybutane Chemical compound CCCCOC(CCC)OCCCC WQRBJFZKPWPIJD-UHFFFAOYSA-N 0.000 description 2
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical compound CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- YBCAZPLXEGKKFM-UHFFFAOYSA-K ruthenium(iii) chloride Chemical compound [Cl-].[Cl-].[Cl-].[Ru+3] YBCAZPLXEGKKFM-UHFFFAOYSA-K 0.000 description 2
- ZTQSAGDEMFDKMZ-UHFFFAOYSA-N Butyraldehyde Chemical compound CCCC=O ZTQSAGDEMFDKMZ-UHFFFAOYSA-N 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 125000002524 organometallic group Chemical group 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 150000003138 primary alcohols Chemical class 0.000 description 1
- 150000003333 secondary alcohols Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
- C07C41/48—Preparation of compounds having groups
- C07C41/50—Preparation of compounds having groups by reactions producing groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
- C07C45/37—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of >C—O—functional groups to >C=O groups
- C07C45/38—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of >C—O—functional groups to >C=O groups being a primary hydroxyl group
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
- C07C45/37—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of >C—O—functional groups to >C=O groups
- C07C45/39—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of >C—O—functional groups to >C=O groups being a secondary hydroxyl group
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR7918183A FR2460908A2 (fr) | 1979-07-11 | 1979-07-11 | Preparation de derives carbonyles par oxydation d'alcools par l'oxygene moleculaire |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR7918183A FR2460908A2 (fr) | 1979-07-11 | 1979-07-11 | Preparation de derives carbonyles par oxydation d'alcools par l'oxygene moleculaire |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| FR2460908A2 true FR2460908A2 (fr) | 1981-01-30 |
| FR2460908B2 FR2460908B2 (cs) | 1983-02-04 |
Family
ID=9227832
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FR7918183A Granted FR2460908A2 (fr) | 1979-07-11 | 1979-07-11 | Preparation de derives carbonyles par oxydation d'alcools par l'oxygene moleculaire |
Country Status (1)
| Country | Link |
|---|---|
| FR (1) | FR2460908A2 (cs) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1987005289A1 (fr) * | 1986-03-06 | 1987-09-11 | Universite Du Maine (Le Mans) | Catalyseur de couplage biarylique au ruthenium; nouveaux steganolides |
| US4847471A (en) * | 1987-01-23 | 1989-07-11 | Pace, Incorporated | Heater for use as either primary or auxiliary heat source and improved circuitry for controlling the heater |
| WO2000053554A1 (en) * | 1999-03-09 | 2000-09-14 | Daicel Chemical Industries, Ltd. | Process for producing aldehydes |
-
1979
- 1979-07-11 FR FR7918183A patent/FR2460908A2/fr active Granted
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1987005289A1 (fr) * | 1986-03-06 | 1987-09-11 | Universite Du Maine (Le Mans) | Catalyseur de couplage biarylique au ruthenium; nouveaux steganolides |
| FR2595350A1 (fr) * | 1986-03-06 | 1987-09-11 | Maine Universite | Procede de couplage biarylique, catalyseur au ruthenium pour sa mise en oeuvre et nouveaux composes en resultant |
| US4847471A (en) * | 1987-01-23 | 1989-07-11 | Pace, Incorporated | Heater for use as either primary or auxiliary heat source and improved circuitry for controlling the heater |
| WO2000053554A1 (en) * | 1999-03-09 | 2000-09-14 | Daicel Chemical Industries, Ltd. | Process for producing aldehydes |
| US6506943B1 (en) | 1999-03-09 | 2003-01-14 | Daicel Chemical Industries, Ltd. | Process for producing aldehydes |
Also Published As
| Publication number | Publication date |
|---|---|
| FR2460908B2 (cs) | 1983-02-04 |
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