FR2457168A1 - PROCESS FOR PREVENTING THE FORMATION OF DEPOSITS DURING POLYMERIZATION IN AQUEOUS MEDIA OF ETHYLENICALLY UNSATURATED MONOMERS - Google Patents

PROCESS FOR PREVENTING THE FORMATION OF DEPOSITS DURING POLYMERIZATION IN AQUEOUS MEDIA OF ETHYLENICALLY UNSATURATED MONOMERS

Info

Publication number
FR2457168A1
FR2457168A1 FR8011206A FR8011206A FR2457168A1 FR 2457168 A1 FR2457168 A1 FR 2457168A1 FR 8011206 A FR8011206 A FR 8011206A FR 8011206 A FR8011206 A FR 8011206A FR 2457168 A1 FR2457168 A1 FR 2457168A1
Authority
FR
France
Prior art keywords
preventing
formation
ethylenically unsaturated
unsaturated monomers
aqueous media
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR8011206A
Other languages
French (fr)
Other versions
FR2457168B1 (en
Inventor
Hajime Kitamura
Toshihide Shimizu
Ichiro Kaneko
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shin Etsu Chemical Co Ltd
Original Assignee
Shin Etsu Chemical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shin Etsu Chemical Co Ltd filed Critical Shin Etsu Chemical Co Ltd
Publication of FR2457168A1 publication Critical patent/FR2457168A1/en
Application granted granted Critical
Publication of FR2457168B1 publication Critical patent/FR2457168B1/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/002—Scale prevention in a polymerisation reactor or its auxiliary parts
    • C08F2/004—Scale prevention in a polymerisation reactor or its auxiliary parts by a prior coating on the reactor walls

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polymerisation Methods In General (AREA)
  • Paints Or Removers (AREA)

Abstract

L'INVENTION EST RELATIVE A UN PROCEDE POUR PREVENIR LA FORMATION DE DEPOTS DE POLYMERE SUR LES PAROIS DU REACTEUR DANS LES PROCEDES DE POLYMERISATION DE MONOMERES ETHYLENIQUEMENT INSATURES DANS UN MILIEU AQUEUX, CARACTERISE EN CE QU'AVANT L'INTRODUCTION DU MONOMERE, DE L'EAU ET DES AUTRES INGREDIENTS NECESSAIRES POUR LA POLYMERISATION, ON APPLIQUE SUR LES SURFACES DES PAROIS DU REACTEUR DE POLYMERISATION UNE SOLUTION AQUEUSE CONTENANT: A.UN COLORANT ANIONIQUE HYDROSOLUBLE; B.UN COLORANT CATIONIQUE HYDROSOLUBLE; ET C.UNE ALKYLAMINE SECONDAIRE OU TERTIAIRE DANS LAQUELLE CHACUN DES GROUPES ALKYLE POSSEDE DE 1 A 6ATOMES DE CARBONE ET SECHE LA SURFACE AINSI REVETUE.THE INVENTION RELATES TO A PROCESS FOR PREVENTING THE FORMATION OF POLYMER DEPOSITS ON THE WALLS OF THE REACTOR IN PROCESSES FOR THE POLYMERIZATION OF ETHYLENICALLY UNSATURE MONOMERS IN AN AQUEOUS MEDIUM, CHARACTERIZED BY BEFORE THE INTRODUCTION OF THE MONOMER, OF ' WATER AND OTHER INGREDIENTS NECESSARY FOR THE POLYMERIZATION, AN AQUEOUS SOLUTION CONTAINING: A. A WATER-SOLUBLE ANIONIC COLORANT IS APPLIED TO THE SURFACES OF THE WALLS OF THE POLYMERIZATION REACTOR; B. A WATER-SOLUBLE CATIONIC DYE; AND C. A SECONDARY OR TERTIARY ALKYLAMINE IN WHICH EACH OF THE ALKYL GROUPS HAS 1 TO 6 ATOMS OF CARBON AND DRIES THE SURFACE THUS COATED.

FR8011206A 1979-05-21 1980-05-20 PROCESS FOR PREVENTING THE FORMATION OF DEPOSITS DURING POLYMERIZATION IN AQUEOUS MEDIA OF ETHYLENICALLY UNSATURATED MONOMERS Expired FR2457168B1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP6235079A JPS55155001A (en) 1979-05-21 1979-05-21 Polymerization of vinyl monomer

Publications (2)

Publication Number Publication Date
FR2457168A1 true FR2457168A1 (en) 1980-12-19
FR2457168B1 FR2457168B1 (en) 1986-05-16

Family

ID=13197577

Family Applications (1)

Application Number Title Priority Date Filing Date
FR8011206A Expired FR2457168B1 (en) 1979-05-21 1980-05-20 PROCESS FOR PREVENTING THE FORMATION OF DEPOSITS DURING POLYMERIZATION IN AQUEOUS MEDIA OF ETHYLENICALLY UNSATURATED MONOMERS

Country Status (4)

Country Link
JP (1) JPS55155001A (en)
DE (1) DE3019389A1 (en)
FR (1) FR2457168B1 (en)
GB (1) GB2049472B (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0096319A1 (en) * 1982-05-31 1983-12-21 Shin-Etsu Chemical Co., Ltd. Method for preventing scale deposition in the polymerization of ethylenically unsaturated monomers

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5978210A (en) * 1982-10-27 1984-05-07 Toyo Soda Mfg Co Ltd Nonaqueous polymerization of vinyl chloride
PH26338A (en) * 1988-08-10 1992-04-29 Shinetsu Chemical Co Method of preventing polymer scale formation
JPH0655769B2 (en) * 1988-08-19 1994-07-27 信越化学工業株式会社 Polymer scale adhesion prevention method
MX170464B (en) * 1988-08-19 1993-08-23 Shinetsu Chemical Co METHOD TO PREVENT THE FORMATION OF FLAKES
JP2678702B2 (en) * 1992-02-20 1997-11-17 信越化学工業株式会社 Polymer scale adhesion inhibitor and method for producing polymer using the same
US5654198A (en) * 1995-06-05 1997-08-05 National Starch And Chemical Investment Holding Corporation Detectable water-treatment polymers and methods for monitoring the concentration thereof

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE94210C (en) * 1970-05-07
JPS5223187A (en) * 1975-08-14 1977-02-21 Shin Etsu Chem Co Ltd Process for polymerizing vinyl monomers
JPS5941443B2 (en) * 1976-07-30 1984-10-06 信越化学工業株式会社 Polymer manufacturing method
DK303077A (en) * 1976-08-16 1978-02-17 Goodrich Co B F POLYMERIZATION REACTION CONTAINER AND PROCEDURE FOR PRACTICALLY ELIMINATING THE CONSTRUCTION OF POLYMERS ON ITS INTERIOR SURFACES
JPS548690A (en) * 1977-06-20 1979-01-23 Goodrich Co B F Method of preventing polymer from adhering on inner surface of polymerization reactor
US4105840A (en) * 1977-06-20 1978-08-08 The B. F. Goodrich Company Internally coated reaction vessel for use in olefinic polymerization

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0096319A1 (en) * 1982-05-31 1983-12-21 Shin-Etsu Chemical Co., Ltd. Method for preventing scale deposition in the polymerization of ethylenically unsaturated monomers

Also Published As

Publication number Publication date
FR2457168B1 (en) 1986-05-16
JPS55155001A (en) 1980-12-03
DE3019389C2 (en) 1988-11-17
GB2049472A (en) 1980-12-31
DE3019389A1 (en) 1980-12-04
GB2049472B (en) 1983-04-27

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Legal Events

Date Code Title Description
ER Errata listed in the french official journal (bopi)

Free format text: 51/80

ST Notification of lapse