FR2446815A1 - 1-Organo:thio-aldoxime cpd. prepn. from aldoxime - by halogenation and reaction with mercaptide in an aq. poly:hydric alcohol - Google Patents

1-Organo:thio-aldoxime cpd. prepn. from aldoxime - by halogenation and reaction with mercaptide in an aq. poly:hydric alcohol

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Publication number
FR2446815A1
FR2446815A1 FR7901259A FR7901259A FR2446815A1 FR 2446815 A1 FR2446815 A1 FR 2446815A1 FR 7901259 A FR7901259 A FR 7901259A FR 7901259 A FR7901259 A FR 7901259A FR 2446815 A1 FR2446815 A1 FR 2446815A1
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FR
France
Prior art keywords
aldoxime
reaction
mercaptide
halogenation
prepn
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
FR7901259A
Other languages
French (fr)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Union Carbide Corp
Original Assignee
Union Carbide Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Union Carbide Corp filed Critical Union Carbide Corp
Priority to FR7901259A priority Critical patent/FR2446815A1/en
Publication of FR2446815A1 publication Critical patent/FR2446815A1/en
Withdrawn legal-status Critical Current

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  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

A 1-organothio-aldoxime of formula R1-C(SR2)=NOH (I) is prepd. from an aldoxime of formula R1CH=NOH (II) by halogenation and reaction of the prod. with a mercaptide of formula R2SM. Reaction si in an aq. soln. contg. about 5-75 wt.% of ethyleneglycol, glycerol, sorbitol, erythritol or arabitol at -10 degrees to +15 dgrees C. In the formulae, R1 and R2 each is alkyl, cycloalkyl, phenyl or phenylalkyl, all of which are opt. substituted by alkyl, halo, alkoxy, cyano, nitro or dialkyl amino. R2SM is a mercaptide salt. Use of the above solvent results in a more effective process with increased yields. (I) are e.g. intermediates for insecticides, nematocides and miticides.
FR7901259A 1979-01-18 1979-01-18 1-Organo:thio-aldoxime cpd. prepn. from aldoxime - by halogenation and reaction with mercaptide in an aq. poly:hydric alcohol Withdrawn FR2446815A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
FR7901259A FR2446815A1 (en) 1979-01-18 1979-01-18 1-Organo:thio-aldoxime cpd. prepn. from aldoxime - by halogenation and reaction with mercaptide in an aq. poly:hydric alcohol

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR7901259A FR2446815A1 (en) 1979-01-18 1979-01-18 1-Organo:thio-aldoxime cpd. prepn. from aldoxime - by halogenation and reaction with mercaptide in an aq. poly:hydric alcohol

Publications (1)

Publication Number Publication Date
FR2446815A1 true FR2446815A1 (en) 1980-08-14

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ID=9220924

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7901259A Withdrawn FR2446815A1 (en) 1979-01-18 1979-01-18 1-Organo:thio-aldoxime cpd. prepn. from aldoxime - by halogenation and reaction with mercaptide in an aq. poly:hydric alcohol

Country Status (1)

Country Link
FR (1) FR2446815A1 (en)

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1559700A (en) * 1966-12-16 1969-03-14

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1559700A (en) * 1966-12-16 1969-03-14

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