FR2437417A1 - Modified ethylene terpolymers useful as lubricant additives - prepd. by metallation and reaction with N-substd. lactam - Google Patents

Modified ethylene terpolymers useful as lubricant additives - prepd. by metallation and reaction with N-substd. lactam

Info

Publication number
FR2437417A1
FR2437417A1 FR7827885A FR7827885A FR2437417A1 FR 2437417 A1 FR2437417 A1 FR 2437417A1 FR 7827885 A FR7827885 A FR 7827885A FR 7827885 A FR7827885 A FR 7827885A FR 2437417 A1 FR2437417 A1 FR 2437417A1
Authority
FR
France
Prior art keywords
substd
prepd
lactam
pref
metallation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7827885A
Other languages
French (fr)
Other versions
FR2437417B1 (en
Inventor
Daniel Brulet
Bernard Charvel
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Rhone Poulenc Industries SA
Original Assignee
Rhone Poulenc Industries SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rhone Poulenc Industries SA filed Critical Rhone Poulenc Industries SA
Priority to FR7827885A priority Critical patent/FR2437417A1/en
Publication of FR2437417A1 publication Critical patent/FR2437417A1/en
Application granted granted Critical
Publication of FR2437417B1 publication Critical patent/FR2437417B1/fr
Granted legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M143/00Lubricating compositions characterised by the additive being a macromolecular hydrocarbon or such hydrocarbon modified by oxidation
    • C10M143/14Lubricating compositions characterised by the additive being a macromolecular hydrocarbon or such hydrocarbon modified by oxidation containing non-conjugated diene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00Chemical modification by after-treatment
    • C08F8/30Introducing nitrogen atoms or nitrogen-containing groups
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/04Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/086Imides
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22Heterocyclic nitrogen compounds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22Heterocyclic nitrogen compounds
    • C10M2215/221Six-membered rings containing nitrogen and carbon only
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22Heterocyclic nitrogen compounds
    • C10M2215/225Heterocyclic nitrogen compounds the rings containing both nitrogen and oxygen
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22Heterocyclic nitrogen compounds
    • C10M2215/225Heterocyclic nitrogen compounds the rings containing both nitrogen and oxygen
    • C10M2215/226Morpholines
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/26Amines
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/28Amides; Imides
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/30Heterocyclic compounds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2227/00Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
    • C10M2227/08Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions having metal-to-carbon bonds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

New functionally modified termpolymers (I) are derived from terpolymers (II) having a Mn of 10,000-200,000 (pref. 20,000-100,000) and contg. 10-80 (pref. 40-60)wt.% ethylene units, 20-90 (pref. 35-60)wt.% of units derived from a 3-18C alpha-olefin, and 0.5-10 (pref. 1-5)wt.% of units derived from a 5-12C non-conjugated diene. (I) are prepd. by metallating (II) and reacting with a lactam of formula (III)x degree. In (III) (where Z is 1-20C alkyl, 2-10C alkenyl or phenyl opt. substd. by 1-10C alkyl. and n=2-11). (I) are useful as VI improves and dispersants for lubricants. They are cheaper to produce than the grafted terpolymers of US3879304.
FR7827885A 1978-09-29 1978-09-29 Modified ethylene terpolymers useful as lubricant additives - prepd. by metallation and reaction with N-substd. lactam Granted FR2437417A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
FR7827885A FR2437417A1 (en) 1978-09-29 1978-09-29 Modified ethylene terpolymers useful as lubricant additives - prepd. by metallation and reaction with N-substd. lactam

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR7827885A FR2437417A1 (en) 1978-09-29 1978-09-29 Modified ethylene terpolymers useful as lubricant additives - prepd. by metallation and reaction with N-substd. lactam

Publications (2)

Publication Number Publication Date
FR2437417A1 true FR2437417A1 (en) 1980-04-25
FR2437417B1 FR2437417B1 (en) 1983-02-11

Family

ID=9213164

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7827885A Granted FR2437417A1 (en) 1978-09-29 1978-09-29 Modified ethylene terpolymers useful as lubricant additives - prepd. by metallation and reaction with N-substd. lactam

Country Status (1)

Country Link
FR (1) FR2437417A1 (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0218298A2 (en) * 1985-10-09 1987-04-15 ENIRICERCHE S.p.A. Solid polymeric stabilizer compounds and process for their manufacturing
EP0244603A2 (en) * 1986-04-05 1987-11-11 BASF Aktiengesellschaft Polymers containing amino groups, their manufacture and their use
EP0529159A1 (en) * 1990-07-23 1993-03-03 Exxon Research And Engineering Company Cyclic carbonyl containing polymers
US5494976A (en) * 1992-08-25 1996-02-27 Basf Aktiengesellschaft Polymers based on conjugated dienes

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4402843A (en) 1981-10-23 1983-09-06 Phillips Petroleum Company Viscosity index improvers with dispersant properties prepared by reaction of lithiated hydrogenated copolymers with 4-substituted aminopyridines
US4402844A (en) 1981-10-23 1983-09-06 Phillips Petroleum Company Viscosity index improvers with dispersant properties prepared by reaction of lithiated hydrogenated copolymers with substituted aminolactams

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0218298A2 (en) * 1985-10-09 1987-04-15 ENIRICERCHE S.p.A. Solid polymeric stabilizer compounds and process for their manufacturing
EP0218298A3 (en) * 1985-10-09 1989-03-01 Eniricerche S.P.A. Solid polymeric stabilizer compounds and process for their manufacturing
EP0244603A2 (en) * 1986-04-05 1987-11-11 BASF Aktiengesellschaft Polymers containing amino groups, their manufacture and their use
EP0244603A3 (en) * 1986-04-05 1989-03-15 BASF Aktiengesellschaft Polymers containing amino groups, their manufacture and their use
EP0529159A1 (en) * 1990-07-23 1993-03-03 Exxon Research And Engineering Company Cyclic carbonyl containing polymers
US5494976A (en) * 1992-08-25 1996-02-27 Basf Aktiengesellschaft Polymers based on conjugated dienes

Also Published As

Publication number Publication date
FR2437417B1 (en) 1983-02-11

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