FR2424946A1 - Adhesive compsn. contg. ethylene copolymer or atactic polyolefin - grafted with unsatd. mono- or di:carboxylic acids or derivs., vinyl cpds., etc., and having improved heat resistance - Google Patents

Adhesive compsn. contg. ethylene copolymer or atactic polyolefin - grafted with unsatd. mono- or di:carboxylic acids or derivs., vinyl cpds., etc., and having improved heat resistance

Info

Publication number
FR2424946A1
FR2424946A1 FR7813043A FR7813043A FR2424946A1 FR 2424946 A1 FR2424946 A1 FR 2424946A1 FR 7813043 A FR7813043 A FR 7813043A FR 7813043 A FR7813043 A FR 7813043A FR 2424946 A1 FR2424946 A1 FR 2424946A1
Authority
FR
France
Prior art keywords
unsatd
mono
acids
grafted
cpds
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7813043A
Other languages
French (fr)
Other versions
FR2424946B1 (en
Inventor
Patrick Borg
Rudolf Hinterwaldner
Robert Laputte
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ATO Chimie SA
Original Assignee
ATO Chimie SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ATO Chimie SA filed Critical ATO Chimie SA
Priority to FR7813043A priority Critical patent/FR2424946A1/en
Priority to DE2917531A priority patent/DE2917531A1/en
Priority to NL7903419A priority patent/NL7903419A/en
Priority to JP5467379A priority patent/JPS54145738A/en
Priority to GB7915321A priority patent/GB2022597A/en
Priority to IT22322/79A priority patent/IT1113933B/en
Publication of FR2424946A1 publication Critical patent/FR2424946A1/en
Application granted granted Critical
Publication of FR2424946B1 publication Critical patent/FR2424946B1/fr
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J151/00—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
    • C09J151/003—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J151/00—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
    • C09J151/06—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

Adhesive compsn. comprises graft copolymers prepd. by free radical suspension graft polymerisation at 160-150 degrees C of an unsatd. cpd. (I)on a substrate comprising a copolymer of ethylene with a vinyl or acrylic ester or an atactic polyolefin. (I) comprises (a) unsatd. mono- or dicarboxylic acids, their anhydrides, amides or esters (the ester gp. being glycidyle or 1-18C amino- or hydroxylalkyl), vinyl esters of satd. 2-18C carboxylic acids, vinylpyridines, vinylpyrolidones or mixts. of thest opt. also with styrene cpds. and/or nitriles of above acids, and (b) mono- or dicarboxylic acid esters where the ester gp. is a 1-18C alkyl, mixts. of such esters opt. also with unsatd, mocarboxylic acids, their nitriles, anhydrides, amides, unsatd. mono-or dicarboxylic acid esters where the ester gp. is 1-18C aminoalkyl or hydroxyalkyl or glycidyl, styrene cpds., vinyl esters of 2-18C satd. acids, vinylpyridines, vinylpyrolidones, and opt. unsatd. dicarboxylic acids. The grafted copolymers comprise by wt. 0.05-75% grafted cpds. and 99.95-25% substrate polymer. The grafted copolymers are used in combination with such additives as tacky resins, waxes paraffins, bitumens, diluent polymers, fillers and/or pigments, and stabilisers as glues in dispersion or soln., as melt-adhesive, as pressure sensitive adhesives and as mastics. The grafted copolymers have good adhesion both to nonpretreated polar or non polar substrates, good mechanical strength and impact improved heat resistance to the adhesive compsns.
FR7813043A 1978-05-03 1978-05-03 Adhesive compsn. contg. ethylene copolymer or atactic polyolefin - grafted with unsatd. mono- or di:carboxylic acids or derivs., vinyl cpds., etc., and having improved heat resistance Granted FR2424946A1 (en)

Priority Applications (6)

Application Number Priority Date Filing Date Title
FR7813043A FR2424946A1 (en) 1978-05-03 1978-05-03 Adhesive compsn. contg. ethylene copolymer or atactic polyolefin - grafted with unsatd. mono- or di:carboxylic acids or derivs., vinyl cpds., etc., and having improved heat resistance
DE2917531A DE2917531A1 (en) 1978-05-03 1979-04-30 POLYMERIC ADHESIVES ON THE BASIS OF MODIFIED MIXED POLYMERISATES OF ETHYLENE AND VINYLESTERS OR ACRYLESTERS AND / OR MODIFIED ATACTICAL POLYOLEFINES AND ADHESIVE COMPOUNDS CONTAINING SUCH SUBSTANCES
NL7903419A NL7903419A (en) 1978-05-03 1979-05-01 ADHESIVE POLYMERS BASED ON MODIFIED COPOLYMERS OF ETHENE AND VINYL ESTERS OR ACRYLIC ESTERS AND / OR OF MODIFIED ATACTIC POLY-ALKINES AND ADHESIVE COMPOSITIONS CONTAINING SUCH POLYMERS.
JP5467379A JPS54145738A (en) 1978-05-03 1979-05-02 Adhesive polymer based on modified copolymer of ethylene and vinyl ester or acrylic ester and *or* modified atactic polyolefin* and adehesive composition containing asme
GB7915321A GB2022597A (en) 1978-05-03 1979-05-02 Adhesive graft polymers
IT22322/79A IT1113933B (en) 1978-05-03 1979-05-03 ADHESIVE POLYMERIC MATERIALS BASED ON MODIFIED ETHYLENE COPOLYMERS AND ACRYLIC VINYL ESTERS AND / OR MODIFIED ATACTIC POLYOLEFINS, AND ADHESIVE COMPOSITIONS CONTAINING SUCH MATERIALS

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR7813043A FR2424946A1 (en) 1978-05-03 1978-05-03 Adhesive compsn. contg. ethylene copolymer or atactic polyolefin - grafted with unsatd. mono- or di:carboxylic acids or derivs., vinyl cpds., etc., and having improved heat resistance

Publications (2)

Publication Number Publication Date
FR2424946A1 true FR2424946A1 (en) 1979-11-30
FR2424946B1 FR2424946B1 (en) 1981-01-23

Family

ID=9207850

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7813043A Granted FR2424946A1 (en) 1978-05-03 1978-05-03 Adhesive compsn. contg. ethylene copolymer or atactic polyolefin - grafted with unsatd. mono- or di:carboxylic acids or derivs., vinyl cpds., etc., and having improved heat resistance

Country Status (1)

Country Link
FR (1) FR2424946A1 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115181518A (en) * 2022-07-19 2022-10-14 广东汇齐新材料有限公司 Heat-resistant composite adhesive film for shoe sole and preparation method thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2179059A1 (en) * 1972-04-03 1973-11-16 Exxon Research Engineering Co
DE2530726A1 (en) * 1975-07-10 1977-01-20 Rudolf Hinterwaldner Polyolefins grafted with polar monomers as hot melt adhesives - for bonding polar or non polar surfaces

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2179059A1 (en) * 1972-04-03 1973-11-16 Exxon Research Engineering Co
DE2530726A1 (en) * 1975-07-10 1977-01-20 Rudolf Hinterwaldner Polyolefins grafted with polar monomers as hot melt adhesives - for bonding polar or non polar surfaces

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115181518A (en) * 2022-07-19 2022-10-14 广东汇齐新材料有限公司 Heat-resistant composite adhesive film for shoe sole and preparation method thereof
CN115181518B (en) * 2022-07-19 2023-11-07 广东汇齐新材料有限公司 Heat-resistant composite adhesive film for soles and preparation method thereof

Also Published As

Publication number Publication date
FR2424946B1 (en) 1981-01-23

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