FR2398089A1 - Light-stabilised polyolefin - contains a benzophenone or benzotriazole with a benzoate, partic. (N)-hexadecyl di-tert. butyl-3,5-hydroxy-4-benzoate - Google Patents

Light-stabilised polyolefin - contains a benzophenone or benzotriazole with a benzoate, partic. (N)-hexadecyl di-tert. butyl-3,5-hydroxy-4-benzoate

Info

Publication number
FR2398089A1
FR2398089A1 FR7821307A FR7821307A FR2398089A1 FR 2398089 A1 FR2398089 A1 FR 2398089A1 FR 7821307 A FR7821307 A FR 7821307A FR 7821307 A FR7821307 A FR 7821307A FR 2398089 A1 FR2398089 A1 FR 2398089A1
Authority
FR
France
Prior art keywords
hydroxy
benzoate
butyl
hexadecyl
benzotriazole
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
FR7821307A
Other languages
French (fr)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Wyeth Holdings LLC
Original Assignee
American Cyanamid Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by American Cyanamid Co filed Critical American Cyanamid Co
Publication of FR2398089A1 publication Critical patent/FR2398089A1/en
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/13—Phenols; Phenolates
    • C08K5/134—Phenols containing ester groups
    • C08K5/1345—Carboxylic esters of phenolcarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/13—Phenols; Phenolates
    • C08K5/132—Phenols containing keto groups, e.g. benzophenones
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/34—Heterocyclic compounds having nitrogen in the ring
    • C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
    • C08K5/3472—Five-membered rings
    • C08K5/3475—Five-membered rings condensed with carbocyclic rings

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The compsn. comprises 0.1-4, pref. 0.2-2 wt.% of each of (a) a hydroxy-2alkoxy-4 benzophenone or a (hydroxy-2'alkylphenyl-5')-2-benzotriazole, in which the alkoxy and alkyl substits. contain 1-12C; and (b) (where R1 is 1-20C, pref. 6-20C alkyl or alkenyl, R2 is 1-8C alkyl; and R3 is 3-8C alkyl joined by an alpha C atom, R2 and R3 being pref. t-butyl) incorporated in a polyolefin (including an ethylene/propylene copolymer). Pref. compsns. comprises polypropylene contg. (i) 0.25 wt.% hydroxy-2 n-octyloxy-4 benzophenone and 0.25 wt.% n-hexadecyl di-t-butyl-3,5-hydroxy-4-benzoate; and (ii) 0.25 wt.% (hydroxy-2't-octyl-phenyl-5')-2 benzotriazole and 0.25 wt.% n-hexadecyl di-t-butyl-3,5 hydroxy-4-benzoate. The additives efficiently stabilise polyolefin against light degradation caused by the sun or other UV sources. The prod. is partic. useful in film form, but may also be in fibre form.
FR7821307A 1977-07-18 1978-07-18 Light-stabilised polyolefin - contains a benzophenone or benzotriazole with a benzoate, partic. (N)-hexadecyl di-tert. butyl-3,5-hydroxy-4-benzoate Withdrawn FR2398089A1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US81662277A 1977-07-18 1977-07-18

Publications (1)

Publication Number Publication Date
FR2398089A1 true FR2398089A1 (en) 1979-02-16

Family

ID=25221162

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7821307A Withdrawn FR2398089A1 (en) 1977-07-18 1978-07-18 Light-stabilised polyolefin - contains a benzophenone or benzotriazole with a benzoate, partic. (N)-hexadecyl di-tert. butyl-3,5-hydroxy-4-benzoate

Country Status (11)

Country Link
JP (1) JPS5421450A (en)
AU (1) AU3642678A (en)
BE (1) BE869003A (en)
BR (1) BR7804592A (en)
CA (1) CA1087344A (en)
DE (1) DE2828363A1 (en)
FR (1) FR2398089A1 (en)
NL (1) NL7806493A (en)
PL (1) PL208485A1 (en)
SE (1) SE7807906L (en)
ZA (1) ZA782930B (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0048594A1 (en) * 1980-09-18 1982-03-31 Uniroyal, Inc. Combination of phenolic antioxidant and stabiliser for use in organic materials
EP0450683A1 (en) * 1990-03-26 1991-10-09 Akzo N.V. Stabilization of phenoxarsine microbiocides

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5959473U (en) * 1982-10-13 1984-04-18 本田技研工業株式会社 Automotive battery device
JP3987632B2 (en) * 1998-04-27 2007-10-10 株式会社Ａｄｅｋａ Automotive interior and exterior materials

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2078303A5 (en) * 1970-02-11 1971-11-05 Cincinnati Milacron Chem
FR2106095A5 (en) * 1970-08-26 1972-04-28 Ciba Geigy Ag
US3681431A (en) * 1970-02-06 1972-08-01 Ciba Geigy Corp N-OCTADECYL 3,5-DI-t-BUTYL-4-HYDROXYBENZOATE

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3681431A (en) * 1970-02-06 1972-08-01 Ciba Geigy Corp N-OCTADECYL 3,5-DI-t-BUTYL-4-HYDROXYBENZOATE
FR2078303A5 (en) * 1970-02-11 1971-11-05 Cincinnati Milacron Chem
FR2106095A5 (en) * 1970-08-26 1972-04-28 Ciba Geigy Ag

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0048594A1 (en) * 1980-09-18 1982-03-31 Uniroyal, Inc. Combination of phenolic antioxidant and stabiliser for use in organic materials
EP0450683A1 (en) * 1990-03-26 1991-10-09 Akzo N.V. Stabilization of phenoxarsine microbiocides

Also Published As

Publication number Publication date
JPS5421450A (en) 1979-02-17
CA1087344A (en) 1980-10-07
DE2828363A1 (en) 1979-02-08
PL208485A1 (en) 1979-03-26
ZA782930B (en) 1979-05-30
NL7806493A (en) 1979-01-22
SE7807906L (en) 1979-01-19
BE869003A (en) 1979-01-15
AU3642678A (en) 1979-11-29
BR7804592A (en) 1979-04-10

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