FR2397927A1 - METHYL POLYMETHACRYLATE COMPOSITE MATERIAL - Google Patents

METHYL POLYMETHACRYLATE COMPOSITE MATERIAL

Info

Publication number
FR2397927A1
FR2397927A1 FR7722044A FR7722044A FR2397927A1 FR 2397927 A1 FR2397927 A1 FR 2397927A1 FR 7722044 A FR7722044 A FR 7722044A FR 7722044 A FR7722044 A FR 7722044A FR 2397927 A1 FR2397927 A1 FR 2397927A1
Authority
FR
France
Prior art keywords
composite material
polymethyl methacrylate
methyl polymethacrylate
thickness
manufacturing process
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7722044A
Other languages
French (fr)
Other versions
FR2397927B1 (en
Inventor
Jean-Paul Ollivier
Albert Strassel
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Produits Chimiques Ugine Kuhlmann
Ugine Kuhlmann SA
Original Assignee
Produits Chimiques Ugine Kuhlmann
Ugine Kuhlmann SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Produits Chimiques Ugine Kuhlmann, Ugine Kuhlmann SA filed Critical Produits Chimiques Ugine Kuhlmann
Priority to FR7722044A priority Critical patent/FR2397927A1/en
Priority to IT68554/78A priority patent/IT1111418B/en
Priority to GB7829868A priority patent/GB2002287B/en
Priority to DE2831462A priority patent/DE2831462B2/en
Priority to BE190673A priority patent/BE870725A/en
Publication of FR2397927A1 publication Critical patent/FR2397927A1/en
Application granted granted Critical
Publication of FR2397927B1 publication Critical patent/FR2397927B1/fr
Granted legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/12—Bonding of a preformed macromolecular material to the same or other solid material such as metal, glass, leather, e.g. using adhesives
    • C08J5/124—Bonding of a preformed macromolecular material to the same or other solid material such as metal, glass, leather, e.g. using adhesives using adhesives based on a macromolecular component
    • C08J5/125—Adhesives in organic diluents
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/04—Coating
    • C08J7/0427—Coating with only one layer of a composition containing a polymer binder
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/04—Coating
    • C08J7/043—Improving the adhesiveness of the coatings per se, e.g. forming primers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2327/00—Polyvinylhalogenides
    • B32B2327/12—Polyvinylhalogenides containing fluorine
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2333/00—Polymers of unsaturated acids or derivatives thereof
    • B32B2333/04—Polymers of esters
    • B32B2333/12—Polymers of methacrylic acid esters, e.g. PMMA, i.e. polymethylmethacrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2333/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
    • C08J2333/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters
    • C08J2333/06—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters of esters containing only carbon, hydrogen, and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C08J2333/10—Homopolymers or copolymers of methacrylic acid esters
    • C08J2333/12—Homopolymers or copolymers of methyl methacrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2427/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2427/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2427/12—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Laminated Bodies (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

Cette invention concerne un matériau composite à base de polyméthacrylate de méthyle et son procédé de fabrication. Le matériau tout en conservant les propriétés du méthacrylate de méthyle possède une excellente résistance au vieillissement et particulièrement à la micro-fissuration. Ce matériau et son procédé de fabrication sont caractérisés en ce que l'on fixe sur une surface d'élément en polyméthacrylate de méthyle un revêtement de polyfluorure de vinylidène dont l'épaisseur maximum est dix fois moindre que l'épaisseur de l'élément en polyméthacrylate de méthyle sans toutefois que l'épaisseur du revêtement ne soit supérieure à 400 microns.This invention relates to a composite material based on polymethyl methacrylate and its manufacturing process. The material while retaining the properties of methyl methacrylate has excellent resistance to aging and particularly to micro-cracking. This material and its manufacturing process are characterized in that a polyvinylidene fluoride coating is fixed to a surface of a polymethyl methacrylate element, the maximum thickness of which is ten times less than the thickness of the element in polymethyl methacrylate without, however, the coating thickness being greater than 400 microns.

FR7722044A 1977-07-19 1977-07-19 METHYL POLYMETHACRYLATE COMPOSITE MATERIAL Granted FR2397927A1 (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
FR7722044A FR2397927A1 (en) 1977-07-19 1977-07-19 METHYL POLYMETHACRYLATE COMPOSITE MATERIAL
IT68554/78A IT1111418B (en) 1977-07-19 1978-06-30 COMPOSITE MATERIAL BASED ON METHYL POLYMETHACRYLATE WITH HIGH TRANSPARENCY AND STABILITY
GB7829868A GB2002287B (en) 1977-07-19 1978-07-14 Composite material based on polymethyl methacrylate
DE2831462A DE2831462B2 (en) 1977-07-19 1978-07-18 Composite material based on polymethyl methacrylate
BE190673A BE870725A (en) 1977-07-19 1978-09-25 METHYL POLYMETHACRYLATE COMPOSITE MATERIAL

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR7722044A FR2397927A1 (en) 1977-07-19 1977-07-19 METHYL POLYMETHACRYLATE COMPOSITE MATERIAL

Publications (2)

Publication Number Publication Date
FR2397927A1 true FR2397927A1 (en) 1979-02-16
FR2397927B1 FR2397927B1 (en) 1980-08-14

Family

ID=9193481

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7722044A Granted FR2397927A1 (en) 1977-07-19 1977-07-19 METHYL POLYMETHACRYLATE COMPOSITE MATERIAL

Country Status (5)

Country Link
BE (1) BE870725A (en)
DE (1) DE2831462B2 (en)
FR (1) FR2397927A1 (en)
GB (1) GB2002287B (en)
IT (1) IT1111418B (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0055802A2 (en) * 1980-12-29 1982-07-14 Swedlow, Inc. Plastic transparencies having improved resistance to cracking
EP0343491A2 (en) * 1988-05-21 1989-11-29 Renolit-Werke GmbH Multilayered surface film
EP0671746A1 (en) * 1994-03-10 1995-09-13 Elf Atochem S.A. Jacketed cables with improved flexibility method of manufacturing the same

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1085818A (en) * 1964-06-30 1967-10-04 Du Pont Adhesive composition
US3451876A (en) * 1964-05-28 1969-06-24 Ksh Inc Plastic light-transmitting panel
US3458391A (en) * 1965-02-15 1969-07-29 American Cyanamid Co Plastic laminates
US3505167A (en) * 1965-10-23 1970-04-07 Union Carbide Corp Fluorinated polyolefin laminates

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3447997A (en) * 1965-11-30 1969-06-03 Formica Corp Weatherable high impact resistant laminates

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3451876A (en) * 1964-05-28 1969-06-24 Ksh Inc Plastic light-transmitting panel
GB1085818A (en) * 1964-06-30 1967-10-04 Du Pont Adhesive composition
US3458391A (en) * 1965-02-15 1969-07-29 American Cyanamid Co Plastic laminates
US3505167A (en) * 1965-10-23 1970-04-07 Union Carbide Corp Fluorinated polyolefin laminates

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0055802A2 (en) * 1980-12-29 1982-07-14 Swedlow, Inc. Plastic transparencies having improved resistance to cracking
EP0055802A3 (en) * 1980-12-29 1982-08-04 Swedlow, Inc. Plastic transparencies having improved resistance to cracking
EP0343491A2 (en) * 1988-05-21 1989-11-29 Renolit-Werke GmbH Multilayered surface film
EP0343491A3 (en) * 1988-05-21 1990-08-29 Renolit-Werke Gesellschaft Mit Beschrankter Haftung Multilayered surface film
EP0671746A1 (en) * 1994-03-10 1995-09-13 Elf Atochem S.A. Jacketed cables with improved flexibility method of manufacturing the same

Also Published As

Publication number Publication date
GB2002287A (en) 1979-02-21
DE2831462A1 (en) 1979-01-25
BE870725A (en) 1979-03-26
FR2397927B1 (en) 1980-08-14
GB2002287B (en) 1982-01-20
IT7868554A0 (en) 1978-06-30
DE2831462B2 (en) 1980-06-19
IT1111418B (en) 1986-01-13

Similar Documents

Publication Publication Date Title
DE69001786D1 (en) COMPOSITE WITH CHANGEABLE CHARACTERISTICS BY PRE-IMPREGNATING AN ENDLESS FIBER.
FR2712307B1 (en) Articles made of super-alloy with high mechanical and cracking resistance and their manufacturing process.
DE68909441D1 (en) MODIFIED ANTIBODIES.
ES507552A0 (en) METHOD OF PRODUCING TUBULAR SYSTEMS RESISTANT TO GASEOUS DIFU-SION.
DE60222290D1 (en) OPTICAL COMPONENT WITH GRADIENT THICKNESS AND METHOD FOR THE PRODUCTION THEREOF
DE69606009D1 (en) Ceramic sleeve type component and method of manufacturing the same
FR2534902A1 (en) ASSEMBLY OF METAL AND CERAMIC
FR2397927A1 (en) METHYL POLYMETHACRYLATE COMPOSITE MATERIAL
IT9021865A0 (en) OIL-REPELLENT POLYMER COMPOSITIONS AND THEIR USE IN THE PREPARATION OF FORMED BODIES HAVING SURFACES WITH HIGH RESISTANCE TO SOLVENTS AND HIGH REPELLENCE TO DIRT
JPS61145509A (en) Optical coupler
ATE29787T1 (en) SIMPLE COLLECTING LENS WITH AN ASPHERIC SURFACE.
ES2056326T5 (en) MOLDED PIECE OF SYNTHETIC MATERIAL WITH GOFRADA SURFACE AND IMPROVED RASPED RESISTANCE.
FR2429484A1 (en) ELEMENT WITH A FERROMAGNETIC RESONANCE COMPOSITE STRUCTURE AND ITS MANUFACTURING METHOD
FR2393676A1 (en) COMPOSITE MATERIAL ACRYLONITRILE-BUTADIENE-STYRENE-VINYLIDENE POLYFLUORIDE RESIN
ATE294903T1 (en) CONSTRUCTION ELEMENT
DE68924703D1 (en) Composite material made of aluminum alloy reinforced with silicon carbide.
DE3580382D1 (en) MONOCLONAL ANTIBODIES AGAINST ALPHA-2 INTERFERON AND HYBRIDOMAS PRODUCING SUCH ANTIBODIES.
ATE306344T1 (en) A COMPOSITE MATERIAL COMPRISING A METAL OR ALLOY AND A SHAPE MEMORY ALLOY
JPS57193319A (en) Manufacture of superhigh molecular weight polyethylene sheet
EP1298469A3 (en) Tuneable filter comprising an optical fibre with a Bragg grating
Nakai et al. Analysis of closure behavior of small fatigue cracks
FR2451090A1 (en) RESISTANCE MATERIAL WITH POSITIVE TEMPERATURE COEFFICIENT AND RESISTANCE THEREFOR
Nengquan et al. An integral equation method applied to mode III crack problems
Laws et al. Microcracking in polycrystalline solids
FR2428858A1 (en) LEG OF GLASSES