FR2397229A1 - (Meth)acrolein prodn. process - by oxidn. of propylene or isobutylene using a catalyst contg. oxides of cobalt, iron, bismuth, molybdenum, potassium and opt. silicon - Google Patents

(Meth)acrolein prodn. process - by oxidn. of propylene or isobutylene using a catalyst contg. oxides of cobalt, iron, bismuth, molybdenum, potassium and opt. silicon

Info

Publication number
FR2397229A1
FR2397229A1 FR7721244A FR7721244A FR2397229A1 FR 2397229 A1 FR2397229 A1 FR 2397229A1 FR 7721244 A FR7721244 A FR 7721244A FR 7721244 A FR7721244 A FR 7721244A FR 2397229 A1 FR2397229 A1 FR 2397229A1
Authority
FR
France
Prior art keywords
oxidn
acrolein
propylene
prodn
isobutylene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7721244A
Other languages
French (fr)
Other versions
FR2397229B1 (en
Inventor
David Lee Childress
William Verne Hayes
Richard Lawrence Poppe
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dow Chemical Co
Original Assignee
Dow Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to AU26338/77A priority Critical patent/AU514315B2/en
Priority to DE19772729841 priority patent/DE2729841A1/en
Priority claimed from DE19772729841 external-priority patent/DE2729841A1/en
Application filed by Dow Chemical Co filed Critical Dow Chemical Co
Priority to FR7721244A priority patent/FR2397229A1/en
Publication of FR2397229A1 publication Critical patent/FR2397229A1/en
Application granted granted Critical
Publication of FR2397229B1 publication Critical patent/FR2397229B1/fr
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
    • C07C45/35—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in propene or isobutene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8876—Arsenic, antimony or bismuth
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

Oxidn. catalysts for oxidising 3-6C olefins to the corresp. unsatd. aldehydes, esp. for oxidising propylene and isobutylene to acrolein and methacrolein, contains oxides of Co, Fe, Bi, Mo and K in an atomic ratio Co4.5-7.0Fe1-2Bi1-2Mo15K0.05-0.2. The catalysts give very high (70-90%) conversion of the olefin with high selectivity (85-95%) to the prodn. of the desired unsatd. olefin. Use of the remaining oxidn. prods. (mainly (meth)acrylic acid, CO and CO2) in a recycle stream as a diluent for the oxygen improves the conversion of propylene to about 99% and the selectivity to acrolein to up to 97%.
FR7721244A 1977-06-22 1977-07-11 (Meth)acrolein prodn. process - by oxidn. of propylene or isobutylene using a catalyst contg. oxides of cobalt, iron, bismuth, molybdenum, potassium and opt. silicon Granted FR2397229A1 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
AU26338/77A AU514315B2 (en) 1977-06-22 1977-06-22 Catalyst and use thereof
DE19772729841 DE2729841A1 (en) 1977-06-22 1977-07-01 (Meth)acrolein prodn. process - by oxidn. of propylene or isobutylene using a catalyst contg. oxides of cobalt, iron, bismuth, molybdenum, potassium and opt. silicon
FR7721244A FR2397229A1 (en) 1977-07-01 1977-07-11 (Meth)acrolein prodn. process - by oxidn. of propylene or isobutylene using a catalyst contg. oxides of cobalt, iron, bismuth, molybdenum, potassium and opt. silicon

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19772729841 DE2729841A1 (en) 1977-06-22 1977-07-01 (Meth)acrolein prodn. process - by oxidn. of propylene or isobutylene using a catalyst contg. oxides of cobalt, iron, bismuth, molybdenum, potassium and opt. silicon
FR7721244A FR2397229A1 (en) 1977-07-01 1977-07-11 (Meth)acrolein prodn. process - by oxidn. of propylene or isobutylene using a catalyst contg. oxides of cobalt, iron, bismuth, molybdenum, potassium and opt. silicon

Publications (2)

Publication Number Publication Date
FR2397229A1 true FR2397229A1 (en) 1979-02-09
FR2397229B1 FR2397229B1 (en) 1981-11-20

Family

ID=25772253

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7721244A Granted FR2397229A1 (en) 1977-06-22 1977-07-11 (Meth)acrolein prodn. process - by oxidn. of propylene or isobutylene using a catalyst contg. oxides of cobalt, iron, bismuth, molybdenum, potassium and opt. silicon

Country Status (1)

Country Link
FR (1) FR2397229A1 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0501794A1 (en) * 1991-02-27 1992-09-02 MITSUI TOATSU CHEMICALS, Inc. Method for preparing methacrolein and method for preparing a catalyst for use in the preparation of methacrolein
US9492814B2 (en) 2013-04-08 2016-11-15 Saudi Basic Industries Corporation Catalyst for conversion of propylene to product comprising a carboxylic acid moiety

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0501794A1 (en) * 1991-02-27 1992-09-02 MITSUI TOATSU CHEMICALS, Inc. Method for preparing methacrolein and method for preparing a catalyst for use in the preparation of methacrolein
US5245083A (en) * 1991-02-27 1993-09-14 Mitsui Toatsu Chemicals, Inc. Method for preparing methacrolein and method for preparing a catalyst for use in the preparation of methacrolein
US9492814B2 (en) 2013-04-08 2016-11-15 Saudi Basic Industries Corporation Catalyst for conversion of propylene to product comprising a carboxylic acid moiety

Also Published As

Publication number Publication date
FR2397229B1 (en) 1981-11-20

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