FR2389661A1 - Polyurethane and engineering thermoplastics blend - contg. mono:alkenyl arene-conjugated diene! block copolymer as network interlocking mechanical or structural stabiliser - Google Patents

Polyurethane and engineering thermoplastics blend - contg. mono:alkenyl arene-conjugated diene! block copolymer as network interlocking mechanical or structural stabiliser

Info

Publication number
FR2389661A1
FR2389661A1 FR7813124A FR7813124A FR2389661A1 FR 2389661 A1 FR2389661 A1 FR 2389661A1 FR 7813124 A FR7813124 A FR 7813124A FR 7813124 A FR7813124 A FR 7813124A FR 2389661 A1 FR2389661 A1 FR 2389661A1
Authority
FR
France
Prior art keywords
block copolymer
structural
conjugated diene
iii
polyurethane
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7813124A
Other languages
French (fr)
Other versions
FR2389661B1 (en
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shell Internationale Research Maatschappij BV
Original Assignee
Shell Internationale Research Maatschappij BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US05/794,200 external-priority patent/US4088627A/en
Application filed by Shell Internationale Research Maatschappij BV filed Critical Shell Internationale Research Maatschappij BV
Publication of FR2389661A1 publication Critical patent/FR2389661A1/en
Application granted granted Critical
Publication of FR2389661B1 publication Critical patent/FR2389661B1/fr
Granted legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L75/00Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
    • C08L75/04Polyurethanes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L101/00Compositions of unspecified macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/18Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
    • C08L23/20Homopolymers or copolymers of hydrocarbons having four or more carbon atoms having four to nine carbon atoms
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/18Homopolymers or copolymers of nitriles
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L53/00Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L53/02Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
    • C08L53/025Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes modified
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L69/00Compositions of polycarbonates; Compositions of derivatives of polycarbonates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/04Polymer mixtures characterised by other features containing interpenetrating networks
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L59/00Compositions of polyacetals; Compositions of derivatives of polyacetals
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L71/00Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L75/00Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Polyurethanes Or Polyureas (AREA)

Abstract

A polymer blend comprises 4-40 pts. wt. of a block copolymer (I), 5-48 pts. wt. of >=1 dissimilar engineering thermoplastics (II) and a thermoplastic polyurethane (III) in a wt. ratio of (III) to (II) of >1:1. In the blend, >=2 of the polymers have at least partially continuous interlocked networks. (I) comprises >=2 monoalkenyl arene polymer end blocks of av. mol. wt. 5000-125000 and >=1 completely hydrogenated conjugated diene polymer mid block of av. mol. wt. 10000-300,000, the end blocks making up 8-55 wt.% of the block copolymer. (III) has a crystalline structure and m.pt. of >120 degrees C. (II) is selected from polyarylethers, polyarylsulphones, polycarbonates and acetal resins. (I) acts as a mechanical or structural stabilisers that interlocks the polymer networks and prevents separation of the polymers during processing and subsequent use. The blends are used in any application normally performed (II) e.g. metal replacements.
FR7813124A 1977-05-05 1978-05-03 Polyurethane and engineering thermoplastics blend - contg. mono:alkenyl arene-conjugated diene! block copolymer as network interlocking mechanical or structural stabiliser Granted FR2389661A1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US05/794,200 US4088627A (en) 1976-06-07 1977-05-05 Multicomponent polyurethane-block copolymer blends

Publications (2)

Publication Number Publication Date
FR2389661A1 true FR2389661A1 (en) 1978-12-01
FR2389661B1 FR2389661B1 (en) 1980-06-20

Family

ID=25161997

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7813124A Granted FR2389661A1 (en) 1977-05-05 1978-05-03 Polyurethane and engineering thermoplastics blend - contg. mono:alkenyl arene-conjugated diene! block copolymer as network interlocking mechanical or structural stabiliser

Country Status (11)

Country Link
JP (1) JPS53138460A (en)
AU (1) AU3570478A (en)
BE (1) BE866672A (en)
BR (1) BR7802767A (en)
CA (1) CA1098239A (en)
DE (1) DE2819492A1 (en)
ES (1) ES469413A1 (en)
FR (1) FR2389661A1 (en)
IT (1) IT1096271B (en)
NL (1) NL7804743A (en)
SE (1) SE7805152L (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0420016A2 (en) * 1989-09-28 1991-04-03 BASF Aktiengesellschaft Impact modified polyurethane-polyester moulding thermoplastics, process for their preparation and their use
EP2883898A1 (en) * 2013-12-11 2015-06-17 SK Innovation Co., Ltd. Aliphatic polycarbonate-polyurethane composition and aliphatic polycarbonate-polyurethane resin
TWI632172B (en) * 2013-12-11 2018-08-11 Sk新技術股份有限公司 Aliphatic polycarbonate-polyurethane composition and aliphatic polycarbonate-polyurethane resin

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3622825A1 (en) * 1986-07-08 1988-01-21 Bayer Ag POLY- (ALPHA) -ALKYL-OLEFIN- / POLYURETHANE-BLOCKCOPOLYMERS, METHOD FOR THEIR PRODUCTION AND THEIR USE
JPS6322852A (en) * 1987-06-08 1988-01-30 Asahi Chem Ind Co Ltd Block copolymer composition
JP3638752B2 (en) * 1996-03-21 2005-04-13 株式会社クラレ Resin composition and molded product thereof

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2354368A1 (en) * 1976-06-07 1978-01-06 Shell Int Research COMPOSITIONS CONTAINING HYDROGENIC SEQUENCE COPOLYMERS AND THERMOPLASTIC RESINS FOR MECHANICAL CONSTRUCTIONS

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2354368A1 (en) * 1976-06-07 1978-01-06 Shell Int Research COMPOSITIONS CONTAINING HYDROGENIC SEQUENCE COPOLYMERS AND THERMOPLASTIC RESINS FOR MECHANICAL CONSTRUCTIONS

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0420016A2 (en) * 1989-09-28 1991-04-03 BASF Aktiengesellschaft Impact modified polyurethane-polyester moulding thermoplastics, process for their preparation and their use
EP0420016A3 (en) * 1989-09-28 1991-05-15 Basf Aktiengesellschaft Impact modified polyurethane-polyester moulding thermoplastics, process for their preparation and their use
US5237000A (en) * 1989-09-28 1993-08-17 Basf Aktiengesellschaft Impact modified thermoplastic polyurethane-polyester molding materials and preparation thereof
EP2883898A1 (en) * 2013-12-11 2015-06-17 SK Innovation Co., Ltd. Aliphatic polycarbonate-polyurethane composition and aliphatic polycarbonate-polyurethane resin
US9718959B2 (en) 2013-12-11 2017-08-01 Sk Innovation Co., Ltd. Aliphatic polycarbonate-polyurethane composition and aliphatic polycarbonate-polyurethane resin
TWI632172B (en) * 2013-12-11 2018-08-11 Sk新技術股份有限公司 Aliphatic polycarbonate-polyurethane composition and aliphatic polycarbonate-polyurethane resin

Also Published As

Publication number Publication date
JPS53138460A (en) 1978-12-02
NL7804743A (en) 1978-11-07
ES469413A1 (en) 1979-10-01
CA1098239A (en) 1981-03-24
DE2819492A1 (en) 1978-11-09
SE7805152L (en) 1978-11-06
IT1096271B (en) 1985-08-26
BR7802767A (en) 1978-12-12
AU3570478A (en) 1979-11-08
BE866672A (en) 1978-11-03
FR2389661B1 (en) 1980-06-20
IT7822993A0 (en) 1978-05-03

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