FR2388011A1 - PROCESS FOR PREPARING MOLDING MATERIALS BASED ON POLYCARBONATES AND ABS COPOLYMERS, AND PRODUCTS OBTAINED BY THIS PROCESS - Google Patents
PROCESS FOR PREPARING MOLDING MATERIALS BASED ON POLYCARBONATES AND ABS COPOLYMERS, AND PRODUCTS OBTAINED BY THIS PROCESSInfo
- Publication number
- FR2388011A1 FR2388011A1 FR7811595A FR7811595A FR2388011A1 FR 2388011 A1 FR2388011 A1 FR 2388011A1 FR 7811595 A FR7811595 A FR 7811595A FR 7811595 A FR7811595 A FR 7811595A FR 2388011 A1 FR2388011 A1 FR 2388011A1
- Authority
- FR
- France
- Prior art keywords
- weight
- parts
- molding materials
- polycarbonate
- polycarbonates
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 229920000515 polycarbonate Polymers 0.000 title abstract 4
- 239000004417 polycarbonate Substances 0.000 title abstract 4
- 239000012778 molding material Substances 0.000 title abstract 3
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 abstract 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract 2
- -1 aromatic hydroxy compounds Chemical class 0.000 abstract 1
- 229920000578 graft copolymer Polymers 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 239000003960 organic solvent Substances 0.000 abstract 1
- 239000011343 solid material Substances 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- 239000000725 suspension Substances 0.000 abstract 1
- 238000009757 thermoplastic moulding Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Procédé perfectionné pour préparer des matières à mouler thermoplastiques consistant en 40 à 70 parties en poids d'un polycarbonate à base de composés aromatiques hydroxylés et 60 à 30 parties en poids d'un copolymère ABS consistant lui-même en un polymère greffé de 15 à 60 parties en poids d'un mélange de 95 à 50 % en poids de styrène et/ou de méthacrylate de méthyle et 50 à 5 % en poids d'acylonitrile et/ou de méthacrylate de méthyle polymérisé par greffage sur 85 à 40 parties en poids d'un caoutchouc. On dissout ou on met en suspension le polycarbonate et le copolymère ABS séparément dans un solvant organique, on mélange les solutions ou suspensions obtenues, on évapore dans un premier stade la plus grande partie du solvant et on fait passer la matière solide résiduelle dans une vis à évaporation. Le procédé selon l'invention permet de parvenir pour la première fois à des matières à mouler mélangées dans lesquelles la phase continue consiste en polycarbonate bien que celui-ci représente moins de 70 % du poids total.An improved process for preparing thermoplastic molding materials consisting of 40 to 70 parts by weight of a polycarbonate based on aromatic hydroxy compounds and 60 to 30 parts by weight of an ABS copolymer itself consisting of a graft polymer of 15 to 60 parts by weight of a mixture of 95 to 50% by weight of styrene and / or methyl methacrylate and 50 to 5% by weight of acylonitrile and / or methyl methacrylate polymerized by grafting on 85 to 40 parts in weight of a rubber. The polycarbonate and the ABS copolymer are dissolved or suspended separately in an organic solvent, the solutions or suspensions obtained are mixed, most of the solvent is evaporated off in a first stage and the residual solid material is passed through a screw. evaporative. The process according to the invention makes it possible for the first time to achieve mixed molding materials in which the continuous phase consists of polycarbonate although this represents less than 70% of the total weight.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19772717165 DE2717165A1 (en) | 1977-04-19 | 1977-04-19 | THERMOPLASTIC MOLDING COMPOUNDS MADE FROM POLYCARBONATE AND ABS POLYMERIZED |
Publications (1)
Publication Number | Publication Date |
---|---|
FR2388011A1 true FR2388011A1 (en) | 1978-11-17 |
Family
ID=6006601
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR7811595A Withdrawn FR2388011A1 (en) | 1977-04-19 | 1978-04-19 | PROCESS FOR PREPARING MOLDING MATERIALS BASED ON POLYCARBONATES AND ABS COPOLYMERS, AND PRODUCTS OBTAINED BY THIS PROCESS |
Country Status (6)
Country | Link |
---|---|
JP (1) | JPS53130749A (en) |
DE (1) | DE2717165A1 (en) |
FR (1) | FR2388011A1 (en) |
GB (1) | GB1586910A (en) |
IT (1) | IT7848917A0 (en) |
NL (1) | NL7804125A (en) |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0019127A1 (en) * | 1979-05-10 | 1980-11-26 | Bayer Ag | Flame resistant polycarbonate compositions with increased resistance against fissure by tension and against corrosion, their preparation and use |
DE3310757A1 (en) * | 1982-03-24 | 1983-09-29 | Montedison S.p.A., 20121 Milano | POLYMER MIXTURES WITH A CONTENT OF 1 OR MORE MODIFIED VINYLAROMATIC POLYMER (DE) |
FR2534265A1 (en) * | 1982-10-07 | 1984-04-13 | Sumitomo Naugatuck | THERMOPLASTIC RESIN COMPOSITION COMPRISING POLYCARBONATE RESIN AND ABS RESIN |
EP0163411A1 (en) * | 1984-04-23 | 1985-12-04 | UNIROYAL CHEMICAL COMPANY, Inc. | Polycarbonate compositions with improved low temperature impact strength |
EP0199846A1 (en) * | 1985-05-02 | 1986-11-05 | Rensselaer Polytechnic Institute | Fine particle dispersions of incompatible folymers in polymer matrices |
EP0460456A1 (en) * | 1990-06-04 | 1991-12-11 | General Electric Company | Polycarbonate/graft ABS/SAN copolymer blends having improved impact strength |
EP0570797A1 (en) * | 1992-05-21 | 1993-11-24 | Bayer Ag | Polycarbonate-ABS moulding compositions |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2853571A1 (en) * | 1978-12-12 | 1980-07-03 | Bayer Ag | THERMOPLASTIC-ELASTOMER POLYMER BLEND |
DE2853574A1 (en) * | 1978-12-12 | 1980-07-03 | Bayer Ag | HEAT-RESISTANT THERMOPLASTIC-ELASTOMER POLYMER BLEND |
DE3118861A1 (en) * | 1981-05-13 | 1982-12-02 | Bayer Ag, 5090 Leverkusen | "THERMOPLASTIC MOLDS MADE OF AROMATIC POLYCARBONATE AND GRAFT POLYMERISATE" |
JPH07102164A (en) * | 1993-09-30 | 1995-04-18 | Nippon G Ii Plast Kk | Thermoplastic resin composition |
DE60124758T2 (en) * | 2000-10-17 | 2007-10-11 | General Electric Co. | INDICATIVE AND TRANSPARENT THERMOPLASTIC POLYCARBONATE ALLOYS AND METHOD OF PREPARING THEM |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR1318121A (en) * | 1961-03-24 | 1963-02-15 | Borg Warner | Synthetic composition consisting of a mixture of polycarbonates with graft copolymers of polybutadiene, styrene and acrylonitrile |
DE1810993A1 (en) * | 1968-11-22 | 1970-06-18 | Borg Warner | Thermoplastic mixtures |
-
1977
- 1977-04-19 DE DE19772717165 patent/DE2717165A1/en not_active Withdrawn
-
1978
- 1978-04-17 IT IT7848917A patent/IT7848917A0/en unknown
- 1978-04-17 JP JP4432278A patent/JPS53130749A/en active Pending
- 1978-04-18 NL NL7804125A patent/NL7804125A/en not_active Application Discontinuation
- 1978-04-19 GB GB15424/78A patent/GB1586910A/en not_active Expired
- 1978-04-19 FR FR7811595A patent/FR2388011A1/en not_active Withdrawn
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR1318121A (en) * | 1961-03-24 | 1963-02-15 | Borg Warner | Synthetic composition consisting of a mixture of polycarbonates with graft copolymers of polybutadiene, styrene and acrylonitrile |
DE1170141B (en) * | 1961-03-24 | 1964-05-14 | Borg Warner | Polycarbonate injection molding compounds |
DE1810993A1 (en) * | 1968-11-22 | 1970-06-18 | Borg Warner | Thermoplastic mixtures |
FR1604656A (en) * | 1968-11-22 | 1972-01-03 |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0019127A1 (en) * | 1979-05-10 | 1980-11-26 | Bayer Ag | Flame resistant polycarbonate compositions with increased resistance against fissure by tension and against corrosion, their preparation and use |
DE3310757A1 (en) * | 1982-03-24 | 1983-09-29 | Montedison S.p.A., 20121 Milano | POLYMER MIXTURES WITH A CONTENT OF 1 OR MORE MODIFIED VINYLAROMATIC POLYMER (DE) |
FR2523988A1 (en) * | 1982-03-24 | 1983-09-30 | Montedison Spa | MIXTURE BASED ON VINYL-AROMATIC POLYMER |
FR2534265A1 (en) * | 1982-10-07 | 1984-04-13 | Sumitomo Naugatuck | THERMOPLASTIC RESIN COMPOSITION COMPRISING POLYCARBONATE RESIN AND ABS RESIN |
EP0163411A1 (en) * | 1984-04-23 | 1985-12-04 | UNIROYAL CHEMICAL COMPANY, Inc. | Polycarbonate compositions with improved low temperature impact strength |
EP0199846A1 (en) * | 1985-05-02 | 1986-11-05 | Rensselaer Polytechnic Institute | Fine particle dispersions of incompatible folymers in polymer matrices |
EP0460456A1 (en) * | 1990-06-04 | 1991-12-11 | General Electric Company | Polycarbonate/graft ABS/SAN copolymer blends having improved impact strength |
EP0570797A1 (en) * | 1992-05-21 | 1993-11-24 | Bayer Ag | Polycarbonate-ABS moulding compositions |
Also Published As
Publication number | Publication date |
---|---|
DE2717165A1 (en) | 1978-11-02 |
IT7848917A0 (en) | 1978-04-17 |
JPS53130749A (en) | 1978-11-15 |
NL7804125A (en) | 1978-10-23 |
GB1586910A (en) | 1981-03-25 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
RE | Withdrawal of published application |