FR2383904A1 - Substd. benzylidene camphor cpds. for cosmetic compsns. - used for protecting skin against irradiation esp. of sun - Google Patents

Substd. benzylidene camphor cpds. for cosmetic compsns. - used for protecting skin against irradiation esp. of sun

Info

Publication number
FR2383904A1
FR2383904A1 FR7707720A FR7707720A FR2383904A1 FR 2383904 A1 FR2383904 A1 FR 2383904A1 FR 7707720 A FR7707720 A FR 7707720A FR 7707720 A FR7707720 A FR 7707720A FR 2383904 A1 FR2383904 A1 FR 2383904A1
Authority
FR
France
Prior art keywords
alkyl
aryl
cpds
esp
substd
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7707720A
Other languages
French (fr)
Other versions
FR2383904B1 (en
Inventor
Claude Bouillon
Charles Vayssie
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
LOreal SA
Original Assignee
LOreal SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to FR7707720A priority Critical patent/FR2383904A1/en
Application filed by LOreal SA filed Critical LOreal SA
Priority to GB10103/78A priority patent/GB1575370A/en
Priority to DE19782811041 priority patent/DE2811041A1/en
Priority to CH279278A priority patent/CH630598A5/en
Priority to US05/886,560 priority patent/US4421739A/en
Priority to JP2917778A priority patent/JPS53116360A/en
Priority to IT67555/78A priority patent/IT1111618B/en
Priority to CA298,909A priority patent/CA1110654A/en
Priority to BE185907A priority patent/BE864862A/en
Priority to AU34152/78A priority patent/AU518876B2/en
Publication of FR2383904A1 publication Critical patent/FR2383904A1/en
Application granted granted Critical
Publication of FR2383904B1 publication Critical patent/FR2383904B1/fr
Priority to CA365,831A priority patent/CA1113480A/en
Granted legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
    • A61Q17/04—Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/35—Ketones, e.g. benzophenone
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/36—Carboxylic acids; Salts or anhydrides thereof
    • A61K8/368—Carboxylic acids; Salts or anhydrides thereof with carboxyl groups directly bound to carbon atoms of aromatic rings
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/37—Esters of carboxylic acids
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/41—Amines
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/42—Amides
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
    • A61K8/466—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfonic acid derivatives; Salts
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C309/00—Sulfonic acids; Halides, esters, or anhydrides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C323/00—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
    • C07C45/511—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition involving transformation of singly bound oxygen functional groups to >C = O groups
    • C07C45/515—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition involving transformation of singly bound oxygen functional groups to >C = O groups the singly bound functional group being an acetalised, ketalised hemi-acetalised, or hemi-ketalised hydroxyl group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/63—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by introduction of halogen; by substitution of halogen atoms by other halogen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/64—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by introduction of functional groups containing oxygen only in singly bound form
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
    • C07C45/68—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C07C45/70—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction with functional groups containing oxygen only in singly bound form
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
    • C07C45/68—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C07C45/70—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction with functional groups containing oxygen only in singly bound form
    • C07C45/71—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction with functional groups containing oxygen only in singly bound form being hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/587—Unsaturated compounds containing a keto groups being part of a ring
    • C07C49/687—Unsaturated compounds containing a keto groups being part of a ring containing halogen
    • C07C49/697—Unsaturated compounds containing a keto groups being part of a ring containing halogen containing six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/587—Unsaturated compounds containing a keto groups being part of a ring
    • C07C49/703—Unsaturated compounds containing a keto groups being part of a ring containing hydroxy groups
    • C07C49/747—Unsaturated compounds containing a keto groups being part of a ring containing hydroxy groups containing six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/587—Unsaturated compounds containing a keto groups being part of a ring
    • C07C49/753—Unsaturated compounds containing a keto groups being part of a ring containing ether groups, groups, groups, or groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/587—Unsaturated compounds containing a keto groups being part of a ring
    • C07C49/757—Unsaturated compounds containing a keto groups being part of a ring containing —CHO groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C59/00—Compounds having carboxyl groups bound to acyclic carbon atoms and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups
    • C07C59/40—Unsaturated compounds
    • C07C59/76—Unsaturated compounds containing keto groups
    • C07C59/90—Unsaturated compounds containing keto groups containing singly bound oxygen-containing groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C65/00—Compounds having carboxyl groups bound to carbon atoms of six—membered aromatic rings and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups
    • C07C65/32—Compounds having carboxyl groups bound to carbon atoms of six—membered aromatic rings and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups containing keto groups
    • C07C65/38—Compounds having carboxyl groups bound to carbon atoms of six—membered aromatic rings and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups containing keto groups having unsaturation outside the aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C65/00—Compounds having carboxyl groups bound to carbon atoms of six—membered aromatic rings and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups
    • C07C65/32—Compounds having carboxyl groups bound to carbon atoms of six—membered aromatic rings and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups containing keto groups
    • C07C65/40—Compounds having carboxyl groups bound to carbon atoms of six—membered aromatic rings and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups containing keto groups containing singly bound oxygen-containing groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D295/00—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
    • C07D295/04—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms
    • C07D295/10—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by doubly bound oxygen or sulphur atoms
    • C07D295/112—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by doubly bound oxygen or sulphur atoms with the ring nitrogen atoms and the doubly bound oxygen or sulfur atoms separated by carbocyclic rings or by carbon chains interrupted by carbocyclic rings
    • C07D295/116—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by doubly bound oxygen or sulphur atoms with the ring nitrogen atoms and the doubly bound oxygen or sulfur atoms separated by carbocyclic rings or by carbon chains interrupted by carbocyclic rings with the doubly bound oxygen or sulfur atoms directly attached to a carbocyclic ring

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Veterinary Medicine (AREA)
  • Public Health (AREA)
  • Animal Behavior & Ethology (AREA)
  • Epidemiology (AREA)
  • Birds (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Emergency Medicine (AREA)
  • Dermatology (AREA)
  • Cosmetics (AREA)

Abstract

Benzylidene camphor cpds. of formula (I) and their salts with (in)organic acids are new. In the formula Y is H or SO3H; Z is -CH2BR or -CH(Br) (Br); or CH2R where R is I, -NR1R2, -NR1R2R3, OR4, -OC-OR5, -SR6, CN, COOR", or -SSO3Na; or -CH(R1)(R1), -CHO- or -COOR"; R1 and R2 ae H, 1-18C alkyl or hydroxyalkyl or form together a heterocycle such as morpholine, piperidine, pyrrolidine, piperazine, N-phenyl-piperazine; R3 is 1-4C alkyl, hydroxyalkyl or sulphopropyl; R4 is H, alkyl, polyethylenoxy, opt. substd. aryl, menthyl or dialkylaminoalkyl; R5 is alkyl, alkenyl, aryl or a 5 or 6 membered heterocycle; R6 is H, alkyl, carboxyalkyl, aminoalky, hydroxyalkyl, aryl or alaryl-3; R1 is -OR14 or -SR16 where R14 and R16 are as R4 and R6 except H, polyethylenoxy, hydroxyalky, alaryl-3 and aryl; R" is H or alkyl; provided that when R is NR1R2 the cpd. may form an acid addn. salt, and when R is N+R1R2R3 with R1R2=H, the ionic equilibrium is maintained when R3 is sulphopropyl by an ion X- (where is SO4 alkyl, SO3 aryl, SO3 alkyl or halo). (I) are used in cosmetic compsns. for protection against actinic rays, esp. from the sun. The cpds. are good fibres, have good solubility and also good compatability esp. in multi-phase compsns.
FR7707720A 1977-03-15 1977-03-15 Substd. benzylidene camphor cpds. for cosmetic compsns. - used for protecting skin against irradiation esp. of sun Granted FR2383904A1 (en)

Priority Applications (11)

Application Number Priority Date Filing Date Title
FR7707720A FR2383904A1 (en) 1977-03-15 1977-03-15 Substd. benzylidene camphor cpds. for cosmetic compsns. - used for protecting skin against irradiation esp. of sun
BE185907A BE864862A (en) 1977-03-15 1978-03-14 NEW BENZYLIDENE CAMPHERS, THEIR PREPARATION PROCESS AND COSMETIC COMPOSITIONS CONTAINING THEM
CH279278A CH630598A5 (en) 1977-03-15 1978-03-14 NOVEL BENZYLIDENE CAMPHERS, PROCESS FOR THEIR PREPARATION AND COSMETIC COMPOSITION CONTAINING THEM.
US05/886,560 US4421739A (en) 1977-03-15 1978-03-14 Benzylidene-camphors, processes for their preparation and cosmetic compositions containing them
JP2917778A JPS53116360A (en) 1977-03-15 1978-03-14 Novel benzylidene camphor process for preparing same and cosmetic composition containig sae
IT67555/78A IT1111618B (en) 1977-03-15 1978-03-14 CAMPHOR DERIVATIVES AND THEIR USE IN THE COSMETIC FIELD
GB10103/78A GB1575370A (en) 1977-03-15 1978-03-14 Benzylidene-camphors processes for their preparation and cosmetic compositions containing them
DE19782811041 DE2811041A1 (en) 1977-03-15 1978-03-14 NEW BENZYLIDENE CAMPHERO COMPOUNDS, PROCESS FOR THEIR PRODUCTION AND COSMETIC AGENTS CONTAINING THEM
CA298,909A CA1110654A (en) 1977-03-15 1978-03-14 Camphor-treated benzylidenes; process for their preparation and cosmetic substances holding same
AU34152/78A AU518876B2 (en) 1977-03-15 1978-03-15 Benzyl i dene-camphors
CA365,831A CA1113480A (en) 1977-03-15 1980-11-28 Benzylidenecamphors, production and cosmetic compositions thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR7707720A FR2383904A1 (en) 1977-03-15 1977-03-15 Substd. benzylidene camphor cpds. for cosmetic compsns. - used for protecting skin against irradiation esp. of sun

Publications (2)

Publication Number Publication Date
FR2383904A1 true FR2383904A1 (en) 1978-10-13
FR2383904B1 FR2383904B1 (en) 1980-04-18

Family

ID=9188115

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7707720A Granted FR2383904A1 (en) 1977-03-15 1977-03-15 Substd. benzylidene camphor cpds. for cosmetic compsns. - used for protecting skin against irradiation esp. of sun

Country Status (2)

Country Link
BE (1) BE864862A (en)
FR (1) FR2383904A1 (en)

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3321679A1 (en) * 1982-06-15 1983-12-15 Oreal 3-BENZYLIDE-CAMPHER COMPOUNDS, METHOD FOR THE PRODUCTION THEREOF AND THE USE THEREOF FOR PROTECTION AGAINST UV RADIATION, AND MEANS THAT CONTAIN THEM
GB2133984A (en) * 1983-01-26 1984-08-08 Oreal Compositions containing natural essences
GB2133985A (en) * 1983-01-26 1984-08-08 Oreal Compositions containing natural essences
DE3443647A1 (en) * 1983-12-01 1985-06-13 Oreal ANTI-ACNE AGENT THAT CONTAINS BENZOYL PEROXYDE AND AT LEAST ONE SUN FILTER
DE3445365A1 (en) * 1983-12-14 1985-06-27 L'oreal, Paris NEW 3-BENZYLIDES COMBAT DERIVATIVES, METHOD FOR THE PRODUCTION AND USE THEREOF AS A MEANS FOR PROTECTION AGAINST UV RAYS AND AS A MEDICINAL PRODUCT
EP0251398A2 (en) * 1986-06-27 1988-01-07 The Procter & Gamble Company Novel chromophores, sunscreen compositions and methods for preventing sunburn
EP0255157A2 (en) * 1986-06-27 1988-02-03 The Procter & Gamble Company Novel sunscreen agents, sunscreen compositions and methods for preventing sunburn
US4793990A (en) * 1980-04-02 1988-12-27 L'oreal Use of coffee bean oil as a sun filter
US4814162A (en) * 1981-05-20 1989-03-21 L'oreal Cosmetic compositions containing hydroxyl derivatives of dibenzoylmethane and their use in protecting the skin against ultraviolet rays and derivatives for use therein
FR2639347A1 (en) * 1988-11-22 1990-05-25 Oreal POLYVALENT METAL SALTS OF BENZYLIDENE-CAMPHRE SULFONATED DERIVATIVES AND THEIR USE FOR SKIN PROTECTION AGAINST ULTRAVIOLET RADIATION
US4937370A (en) * 1987-06-02 1990-06-26 The Procter & Gamble Company Novel chromophores, sunscreen compositions and methods for preventing sunburn
US4994263A (en) * 1984-06-27 1991-02-19 L'oreal Medicinal combination used in photochemotherapy
FR2959125A1 (en) * 2010-04-22 2011-10-28 Oreal Method for treating keratin fibers, preferably human hair, comprises applying, on the keratin fibers, an oil-in-water emulsion containing one or more water-soluble benzylidenecamphor UV filters in a medium

Cited By (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4793990A (en) * 1980-04-02 1988-12-27 L'oreal Use of coffee bean oil as a sun filter
US4814162A (en) * 1981-05-20 1989-03-21 L'oreal Cosmetic compositions containing hydroxyl derivatives of dibenzoylmethane and their use in protecting the skin against ultraviolet rays and derivatives for use therein
US4585597A (en) * 1982-06-15 1986-04-29 L'oreal 3-benzylidene-camphors, process for their preparation and their use in protection against UV rays
DE3321679A1 (en) * 1982-06-15 1983-12-15 Oreal 3-BENZYLIDE-CAMPHER COMPOUNDS, METHOD FOR THE PRODUCTION THEREOF AND THE USE THEREOF FOR PROTECTION AGAINST UV RADIATION, AND MEANS THAT CONTAIN THEM
GB2133984A (en) * 1983-01-26 1984-08-08 Oreal Compositions containing natural essences
GB2133985A (en) * 1983-01-26 1984-08-08 Oreal Compositions containing natural essences
US4950478A (en) * 1983-01-26 1990-08-21 L'oreal Cosmetic compositions containing natural essences and benzylidenecamphor derivatives
US4731200A (en) * 1983-01-26 1988-03-15 L'oreal Alcoholic or aqueous-alcoholic compositions containing natural essences and benzylidene-camphor derivatives
DE3443647A1 (en) * 1983-12-01 1985-06-13 Oreal ANTI-ACNE AGENT THAT CONTAINS BENZOYL PEROXYDE AND AT LEAST ONE SUN FILTER
DE3445365A1 (en) * 1983-12-14 1985-06-27 L'oreal, Paris NEW 3-BENZYLIDES COMBAT DERIVATIVES, METHOD FOR THE PRODUCTION AND USE THEREOF AS A MEANS FOR PROTECTION AGAINST UV RAYS AND AS A MEDICINAL PRODUCT
US4710584A (en) * 1983-12-14 1987-12-01 L'oreal Derivatives of 3-benzylidene camphor, process for their preparation and their use as protective agents against UV rays and as medicaments
US4994263A (en) * 1984-06-27 1991-02-19 L'oreal Medicinal combination used in photochemotherapy
EP0251398A3 (en) * 1986-06-27 1988-06-15 The Procter & Gamble Company Novel chromophores, sunscreen compositions and methods for preventing sunburn
EP0255157A3 (en) * 1986-06-27 1988-06-15 The Procter & Gamble Company Novel sunscreen agents, sunscreen compositions and methods for preventing sunburn
EP0255157A2 (en) * 1986-06-27 1988-02-03 The Procter & Gamble Company Novel sunscreen agents, sunscreen compositions and methods for preventing sunburn
EP0251398A2 (en) * 1986-06-27 1988-01-07 The Procter & Gamble Company Novel chromophores, sunscreen compositions and methods for preventing sunburn
US4999186A (en) * 1986-06-27 1991-03-12 The Procter & Gamble Company Novel sunscreen agents, sunscreen compositions and methods for preventing sunburn
US4937370A (en) * 1987-06-02 1990-06-26 The Procter & Gamble Company Novel chromophores, sunscreen compositions and methods for preventing sunburn
FR2639347A1 (en) * 1988-11-22 1990-05-25 Oreal POLYVALENT METAL SALTS OF BENZYLIDENE-CAMPHRE SULFONATED DERIVATIVES AND THEIR USE FOR SKIN PROTECTION AGAINST ULTRAVIOLET RADIATION
EP0370867A1 (en) * 1988-11-22 1990-05-30 L'oreal Polyvalent metal salts of sulfonated derivatives of benzylidene-camphor and their use in the protection of the skin against ultra-violet radiation
BE1002272A3 (en) * 1988-11-22 1990-11-13 Oreal SALTS OF VERSATILE METALS OF SULPHONATED BENZYLIDENE-CAMPHOR DERIVATIVES AND THEIR USE FOR PROTECTING THE SKIN AGAINST ULTRAVIOLET RADIATION.
US5064641A (en) * 1988-11-22 1991-11-12 L'oreal Polyvalent metal salts of sulphonted derivatives of benzylidenecamphor and their use for protecting the skin against ultraviolet radiation
FR2959125A1 (en) * 2010-04-22 2011-10-28 Oreal Method for treating keratin fibers, preferably human hair, comprises applying, on the keratin fibers, an oil-in-water emulsion containing one or more water-soluble benzylidenecamphor UV filters in a medium

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BE864862A (en) 1978-09-14

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