FR2376074A1 - Silico-aluminate(s) esp. for use in washing powders - with higher cation exchange power and less incrustation - Google Patents

Silico-aluminate(s) esp. for use in washing powders - with higher cation exchange power and less incrustation

Info

Publication number
FR2376074A1
FR2376074A1 FR7639527A FR7639527A FR2376074A1 FR 2376074 A1 FR2376074 A1 FR 2376074A1 FR 7639527 A FR7639527 A FR 7639527A FR 7639527 A FR7639527 A FR 7639527A FR 2376074 A1 FR2376074 A1 FR 2376074A1
Authority
FR
France
Prior art keywords
aluminate
esp
cation exchange
silico
exchange power
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7639527A
Other languages
French (fr)
Other versions
FR2376074B1 (en
Inventor
Max Michel
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Rhone Poulenc Industries SA
Original Assignee
Rhone Poulenc Industries SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rhone Poulenc Industries SA filed Critical Rhone Poulenc Industries SA
Priority to FR7639527A priority Critical patent/FR2376074A1/en
Priority to MX10081077U priority patent/MX5230E/en
Priority to LU78780A priority patent/LU78780A1/xx
Priority to NO774491A priority patent/NO152746C/en
Priority to FI773942A priority patent/FI66130C/en
Priority to NLAANVRAGE7714535,A priority patent/NL188402C/en
Priority to PT67480A priority patent/PT67480B/en
Priority to JP52158700A priority patent/JPS5857367B2/en
Priority to CH1619777A priority patent/CH628004A5/en
Priority to GB54158/77A priority patent/GB1563467A/en
Priority to CA294,125A priority patent/CA1132526A/en
Priority to BE183968A priority patent/BE862470A/en
Priority to BR7708747A priority patent/BR7708747A/en
Priority to IE2643/77A priority patent/IE46054B1/en
Priority to ES465558A priority patent/ES465558A1/en
Priority to DK583877A priority patent/DK154415C/en
Priority to AT0944677A priority patent/AT367721B/en
Priority to IT31465/77A priority patent/IT1090149B/en
Priority to DE2759110A priority patent/DE2759110C3/en
Publication of FR2376074A1 publication Critical patent/FR2376074A1/en
Application granted granted Critical
Publication of FR2376074B1 publication Critical patent/FR2376074B1/fr
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/12—Water-insoluble compounds
    • C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
    • C11D3/1246—Silicates, e.g. diatomaceous earth
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00—Silicon; Compounds thereof
    • C01B33/20—Silicates
    • C01B33/26—Aluminium-containing silicates, i.e. silico-aluminates
    • C01B33/28—Base exchange silicates, e.g. zeolites
    • C01B33/2807—Zeolitic silicoaluminates with a tridimensional crystalline structure possessing molecular sieve properties; Isomorphous compounds wherein a part of the aluminium ore of the silicon present may be replaced by other elements such as gallium, germanium, phosphorus; Preparation of zeolitic molecular sieves from molecular sieves of another type or from preformed reacting mixtures
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00—Silicon; Compounds thereof
    • C01B33/20—Silicates
    • C01B33/26—Aluminium-containing silicates, i.e. silico-aluminates
    • C01B33/28—Base exchange silicates, e.g. zeolites
    • C01B33/2807—Zeolitic silicoaluminates with a tridimensional crystalline structure possessing molecular sieve properties; Isomorphous compounds wherein a part of the aluminium ore of the silicon present may be replaced by other elements such as gallium, germanium, phosphorus; Preparation of zeolitic molecular sieves from molecular sieves of another type or from preformed reacting mixtures
    • C01B33/2815—Zeolitic silicoaluminates with a tridimensional crystalline structure possessing molecular sieve properties; Isomorphous compounds wherein a part of the aluminium ore of the silicon present may be replaced by other elements such as gallium, germanium, phosphorus; Preparation of zeolitic molecular sieves from molecular sieves of another type or from preformed reacting mixtures of type A (UNION CARBIDE trade name; corresponds to GRACE's types Z-12 or Z-12L)
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/12—Water-insoluble compounds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Detergent Compositions (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)

Abstract

New crystalline silico-aluminate is of formula: xSiO2, yAl2o3, zNa2O, wH2O(I). In the formula, for y=1, x is 1.5-6 (pref. 1.85), w is 0-5 (pref. 4-5) and z is 1. (I) has a granulometry of 0.2-8 mu and a BET surface value of 0.5-10 m2/gm. (I) are prepd. by adding an alkali metal silicate solution to an alkali metal aluminate solution; ripening at high temp., then sepg. off the crystals obtd. The reaction mass formed from the solns. is gelled in a highly conc. homogeneous medium. (I) are used as detergent auxiliary in detergent compositions, esp. in washing powders to replace Na tripolyphosphate. They have a high and fast cation exchange power and are non-incrusting on clothes.
FR7639527A 1976-12-30 1976-12-30 Silico-aluminate(s) esp. for use in washing powders - with higher cation exchange power and less incrustation Granted FR2376074A1 (en)

Priority Applications (19)

Application Number Priority Date Filing Date Title
FR7639527A FR2376074A1 (en) 1976-12-30 1976-12-30 Silico-aluminate(s) esp. for use in washing powders - with higher cation exchange power and less incrustation
MX10081077U MX5230E (en) 1976-12-30 1977-12-15 IMPROVED PROCEDURE FOR THE MANUFACTURE OF A CRYSTAL ALUMINUM SILICO
NO774491A NO152746C (en) 1976-12-30 1977-12-28 SYNTHETIC CRYSTALLINIC ALUMINUM SILICATE AND USE THEREOF IN DETERGENT MIXTURES
FI773942A FI66130C (en) 1976-12-30 1977-12-28 SYNTHETIC FINISHED CRYSTALS SILICONE ALUMINUM FOUNDARY FOAR DESS FRAMSTAELLNING SAMT DESS ANVAENDNING
LU78780A LU78780A1 (en) 1976-12-30 1977-12-28
ES465558A ES465558A1 (en) 1976-12-30 1977-12-29 Production of alkali metal silicoaluminates
JP52158700A JPS5857367B2 (en) 1976-12-30 1977-12-29 Method for producing synthetic crystalline aluminosilicate
CH1619777A CH628004A5 (en) 1976-12-30 1977-12-29 Process for the manufacture of a crystalline silicoaluminate
GB54158/77A GB1563467A (en) 1976-12-30 1977-12-29 Production of alkali metal silicoaluminates
CA294,125A CA1132526A (en) 1976-12-30 1977-12-29 Process for making a synthetic crystaline silico-aluminate through addition of an alkaline silicate solution to an alkaline aluminate solution
NLAANVRAGE7714535,A NL188402C (en) 1976-12-30 1977-12-29 METHOD FOR PREPARING A SYNTHETIC CRYSTALLINE ALUMINOSILICATE OF THE TYPE ZEOLITE 4A, AND METHOD FOR PREPARING A DETERGENT PREPARATION.
BR7708747A BR7708747A (en) 1976-12-30 1977-12-29 MANUFACTURING PROCESS OF SYNTHETIC CRYSTALLINE SILICOALUMINATE AND CRYSTALLINE SILICO-ALUMINATE OBTAINED BY THE SAME
IE2643/77A IE46054B1 (en) 1976-12-30 1977-12-29 Production of alkali metal silicoaluminates
PT67480A PT67480B (en) 1976-12-30 1977-12-29 PROCESS FOR THE PREPARATION OF NEW SYNTHETIC CRYSTALLINE SILICO ALUMINATES APPLICABLE IN DETERGENCE
DK583877A DK154415C (en) 1976-12-30 1977-12-29 PROCEDURE FOR THE PREPARATION OF A CRYSTALLINIC SILICO ALUMINATE AND USE OF THIS
BE183968A BE862470A (en) 1976-12-30 1977-12-29 NEW FINELY DIVIDED SYNTHETIC CRYSTALLINE SILICO-ALUMINATE
AT0944677A AT367721B (en) 1976-12-30 1977-12-30 METHOD FOR PRODUCING A CRYSTALINE ZEOLITH 4A
IT31465/77A IT1090149B (en) 1976-12-30 1977-12-30 SYNTHETIC SILICON-ALUMINATE, ITS PREPARATION AND APPLICATION
DE2759110A DE2759110C3 (en) 1976-12-30 1977-12-30 Process for the preparation of a synthetic crystalline zeolite 4A

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR7639527A FR2376074A1 (en) 1976-12-30 1976-12-30 Silico-aluminate(s) esp. for use in washing powders - with higher cation exchange power and less incrustation

Publications (2)

Publication Number Publication Date
FR2376074A1 true FR2376074A1 (en) 1978-07-28
FR2376074B1 FR2376074B1 (en) 1979-04-20

Family

ID=9181710

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7639527A Granted FR2376074A1 (en) 1976-12-30 1976-12-30 Silico-aluminate(s) esp. for use in washing powders - with higher cation exchange power and less incrustation

Country Status (3)

Country Link
AT (1) AT367721B (en)
BE (1) BE862470A (en)
FR (1) FR2376074A1 (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2474014A1 (en) * 1980-01-18 1981-07-24 Rhone Poulenc Ind NOVEL PROCESS FOR OBTAINING A TYPE A CRYSTALLINE SILICO-ALUMINATE WITH HIGH WATER RETENTION, AND IN PARTICULAR TYPE 4A, AND PRODUCT SO OBTAINED
FR2517291A1 (en) * 1981-11-27 1983-06-03 Rhone Poulenc Spec Chim Zeolite Y prepn. - from aluminium cpd. and sodium silicate aq. solutions
EP0123753A1 (en) * 1983-04-28 1984-11-07 Rhone-Poulenc Specialites Chimiques Process for the manufacture of Y-type zeolite

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
NEANT *

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2474014A1 (en) * 1980-01-18 1981-07-24 Rhone Poulenc Ind NOVEL PROCESS FOR OBTAINING A TYPE A CRYSTALLINE SILICO-ALUMINATE WITH HIGH WATER RETENTION, AND IN PARTICULAR TYPE 4A, AND PRODUCT SO OBTAINED
EP0032854A1 (en) * 1980-01-18 1981-07-29 Rhone-Poulenc Chimie Process for obtaining a type A crystalline silicoaluminate with high water regain, and especially of type 4A, and product so obtained
FR2517291A1 (en) * 1981-11-27 1983-06-03 Rhone Poulenc Spec Chim Zeolite Y prepn. - from aluminium cpd. and sodium silicate aq. solutions
EP0123753A1 (en) * 1983-04-28 1984-11-07 Rhone-Poulenc Specialites Chimiques Process for the manufacture of Y-type zeolite

Also Published As

Publication number Publication date
AT367721B (en) 1982-07-26
FR2376074B1 (en) 1979-04-20
BE862470A (en) 1978-06-29
ATA944677A (en) 1980-12-15

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ST Notification of lapse