FR2375271A1 - Polycarbonates with (meth)acrylic end-gps. - and their conversion to transparent films, esp. as lacquers for paper - Google Patents
Polycarbonates with (meth)acrylic end-gps. - and their conversion to transparent films, esp. as lacquers for paperInfo
- Publication number
- FR2375271A1 FR2375271A1 FR7638822A FR7638822A FR2375271A1 FR 2375271 A1 FR2375271 A1 FR 2375271A1 FR 7638822 A FR7638822 A FR 7638822A FR 7638822 A FR7638822 A FR 7638822A FR 2375271 A1 FR2375271 A1 FR 2375271A1
- Authority
- FR
- France
- Prior art keywords
- polycarbonates
- lacquers
- esp
- meth
- gps
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G64/00—Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule
- C08G64/02—Aliphatic polycarbonates
- C08G64/0291—Aliphatic polycarbonates unsaturated
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F290/00—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups
- C08F290/02—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups on to polymers modified by introduction of unsaturated end groups
- C08F290/06—Polymers provided for in subclass C08G
- C08F290/061—Polyesters; Polycarbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/64—Polyesters containing both carboxylic ester groups and carbonate groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/66—Polyesters containing oxygen in the form of ether groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/13—Phenols; Phenolates
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
- Polyesters Or Polycarbonates (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
New (cyclo)aliphatic polycarbonates of mol. wt. =3000 include hydrocarbon radicals of is not 4C and may contain (thio)ether bridges; they also have two (methy)acrylic end-gps. Polycarbonates are susceptible to self-polymerisation on heating or under u.v. radiation to give transparent films with many end-uses, but esp. as lacquers for papers for use as playing cards, wrappers, etc. A hydroxytelechelic aliphatic or cycloaliphatic polycarbonate is a esterified with a slight excess of (meth)acrylic acid in presence of an inert aromatic solvent that forms an azeotrope with water, in presence of a polymerisation inhibitor and an acid catalyst. Reaction takes place under reflux with regular removal of the azeotrope. Polycarbonates easy to apply since many of them are liq. Also they are chemically neutral and therefore can be applied to most natural or synthetic supports.
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR7638822A FR2375271A1 (en) | 1976-12-23 | 1976-12-23 | Polycarbonates with (meth)acrylic end-gps. - and their conversion to transparent films, esp. as lacquers for paper |
DE19772757086 DE2757086A1 (en) | 1976-12-23 | 1977-12-21 | POLYCARBONATE WITH ACRYLATE OR METHACRYLATE END GROUPS, THEIR PRODUCTION AND USE |
BE183807A BE862279A (en) | 1976-12-23 | 1977-12-23 | NEW POLYCARBONATES WITH ACRYLIC OR METHACRYLIC TERMINATIONS AND THEIR APPLICATIONS TO PHOTO CROSSING |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR7638822A FR2375271A1 (en) | 1976-12-23 | 1976-12-23 | Polycarbonates with (meth)acrylic end-gps. - and their conversion to transparent films, esp. as lacquers for paper |
Publications (2)
Publication Number | Publication Date |
---|---|
FR2375271A1 true FR2375271A1 (en) | 1978-07-21 |
FR2375271B1 FR2375271B1 (en) | 1979-07-13 |
Family
ID=9181441
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR7638822A Granted FR2375271A1 (en) | 1976-12-23 | 1976-12-23 | Polycarbonates with (meth)acrylic end-gps. - and their conversion to transparent films, esp. as lacquers for paper |
Country Status (3)
Country | Link |
---|---|
BE (1) | BE862279A (en) |
DE (1) | DE2757086A1 (en) |
FR (1) | FR2375271A1 (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0207688A2 (en) * | 1985-06-19 | 1987-01-07 | Nippon Kayaku Kabushiki Kaisha | Resin composition for coating optical glass fibers |
EP0273144A2 (en) * | 1986-12-15 | 1988-07-06 | General Electric Company | Cross-linked branched polycarbonate composition |
EP0424219A2 (en) * | 1989-10-11 | 1991-04-24 | Daicel Chemical Industries, Ltd. | Polycarbonate-polyol composition and polycarbonate (meth) acrylate compositions and urethane (meth) acrylate compositions prepared therefrom |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2829256A1 (en) * | 1978-07-04 | 1980-01-17 | Bayer Ag | POLYCARBONATE WITH END GROUPS CONTAINING UV LIGHT CROSSLINKABLE DOUBLE BINDINGS |
DE2842004A1 (en) * | 1978-09-27 | 1980-04-10 | Bayer Ag | METHOD FOR PRODUCING MODIFIED POLYCARBONATE MOLDS |
IT1151545B (en) * | 1982-04-15 | 1986-12-24 | Anic Spa | COMPOSITION BASED ON ALIPHATIC POLYCARBONATES WITH ACRYLIC OR METACRYLIC TERMINATIONS RETICULABLE IN THE PRESENCE OF ROOTIC INITIATORS |
US4423205A (en) | 1982-05-24 | 1983-12-27 | Ethyl Corporation | Cationic polymerization of cyclic carbonates |
US4456745A (en) * | 1982-05-24 | 1984-06-26 | Ethyl Corporation | Polyurethanes prepared from polycarbonates |
US5198527A (en) * | 1990-12-24 | 1993-03-30 | The Dow Chemical Company | Arylcyclobutene terminated carbonate polymer |
US5171824A (en) * | 1990-12-24 | 1992-12-15 | The Dow Chemical Company | Process for the preparation of arylcyclobutene terminated condensation polymers |
-
1976
- 1976-12-23 FR FR7638822A patent/FR2375271A1/en active Granted
-
1977
- 1977-12-21 DE DE19772757086 patent/DE2757086A1/en active Pending
- 1977-12-23 BE BE183807A patent/BE862279A/en unknown
Non-Patent Citations (1)
Title |
---|
NEANT * |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0207688A2 (en) * | 1985-06-19 | 1987-01-07 | Nippon Kayaku Kabushiki Kaisha | Resin composition for coating optical glass fibers |
EP0207688A3 (en) * | 1985-06-19 | 1988-06-08 | Nippon Kayaku Kabushiki Kaisha | Resin composition for coating optical glass fibers |
US4783544A (en) * | 1985-06-19 | 1988-11-08 | Nippon Kayaku Kabushiki Kaisha | Di-(meth)acrylic acid ester, resin composition comprising the same and coating agent comprising the same |
US5021467A (en) * | 1985-06-19 | 1991-06-04 | Nippon Kayaku Kabushiki Kaisha | Photocurable di-(meth)acrylic acid ester resin coating composition |
EP0273144A2 (en) * | 1986-12-15 | 1988-07-06 | General Electric Company | Cross-linked branched polycarbonate composition |
EP0273144A3 (en) * | 1986-12-15 | 1990-03-21 | General Electric Company | Cross-linked branched polycarbonate composition |
EP0424219A2 (en) * | 1989-10-11 | 1991-04-24 | Daicel Chemical Industries, Ltd. | Polycarbonate-polyol composition and polycarbonate (meth) acrylate compositions and urethane (meth) acrylate compositions prepared therefrom |
EP0424219A3 (en) * | 1989-10-11 | 1992-02-26 | Daicel Chemical Industries, Ltd. | Polycarbonate-polyol composition and polycarbonate (meth) acrylate compositions and urethane (meth) acrylate compositions prepared therefrom |
Also Published As
Publication number | Publication date |
---|---|
BE862279A (en) | 1978-06-23 |
DE2757086A1 (en) | 1978-06-29 |
FR2375271B1 (en) | 1979-07-13 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
ST | Notification of lapse |