FR2362151A1 - Tert.-pentanoyl-vinyl thio-phosphonate and phosphate ester(s) - useful as insecticides, acaricides and nematocides - Google Patents
Tert.-pentanoyl-vinyl thio-phosphonate and phosphate ester(s) - useful as insecticides, acaricides and nematocidesInfo
- Publication number
- FR2362151A1 FR2362151A1 FR7724937A FR7724937A FR2362151A1 FR 2362151 A1 FR2362151 A1 FR 2362151A1 FR 7724937 A FR7724937 A FR 7724937A FR 7724937 A FR7724937 A FR 7724937A FR 2362151 A1 FR2362151 A1 FR 2362151A1
- Authority
- FR
- France
- Prior art keywords
- tert
- useful
- nematocides
- pentanoyl
- acaricides
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 230000000895 acaricidal effect Effects 0.000 title abstract 2
- 230000001069 nematicidal effect Effects 0.000 title abstract 2
- -1 phosphate ester Chemical class 0.000 title abstract 2
- 229910019142 PO4 Inorganic materials 0.000 title 1
- 239000000642 acaricide Substances 0.000 title 1
- 239000002917 insecticide Substances 0.000 title 1
- 239000005645 nematicide Substances 0.000 title 1
- 239000010452 phosphate Substances 0.000 title 1
- 229920002554 vinyl polymer Polymers 0.000 title 1
- 125000000217 alkyl group Chemical group 0.000 abstract 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 abstract 1
- 241001465754 Metazoa Species 0.000 abstract 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 abstract 1
- 125000003545 alkoxy group Chemical group 0.000 abstract 1
- 125000004414 alkyl thio group Chemical group 0.000 abstract 1
- 230000000749 insecticidal effect Effects 0.000 abstract 1
- 231100000053 low toxicity Toxicity 0.000 abstract 1
- GJYXGIIWJFZCLN-UHFFFAOYSA-N octane-2,4-dione Chemical compound CCCCC(=O)CC(C)=O GJYXGIIWJFZCLN-UHFFFAOYSA-N 0.000 abstract 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 1
- 229910052698 phosphorus Inorganic materials 0.000 abstract 1
- 239000011574 phosphorus Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/16—Esters of thiophosphoric acids or thiophosphorous acids
- C07F9/165—Esters of thiophosphoric acids
- C07F9/173—Esters of thiophosphoric acids with unsaturated acyclic alcohols
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/10—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds
- A01N57/12—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds containing acyclic or cycloaliphatic radicals
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/08—Esters of oxyacids of phosphorus
- C07F9/09—Esters of phosphoric acids
- C07F9/113—Esters of phosphoric acids with unsaturated acyclic alcohols
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/40—Esters thereof
- C07F9/4071—Esters thereof the ester moiety containing a substituent or a structure which is considered as characteristic
- C07F9/4078—Esters with unsaturated acyclic alcohols
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Biochemistry (AREA)
- Molecular Biology (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Phosphorus cpds. of formula (I) are new: (where R is alkyl, R1 is alkyl, alkoxy, alkylthio or phenyl, X is O or S). They are prepd. by reacting RO(R1)P(X)Hal with tert. pentanoylacetone (II). (I) have insecticidal, acaricidal and nematocidal activities and are more effective than known cpds. of similar structure. They have low toxicity towards plants and warm-blooded animals, and are useful in agriculture, for protecting stored goods and in hygienic applications. In an example, reaction of (II) and O,O-diethyl-thionophosphonyl chloride gave O,O-diethyl-O-(1-methyl-2-tert. pentanoylvinyl)thionophosphate.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19762636785 DE2636785A1 (en) | 1976-08-16 | 1976-08-16 | 2-TERT.-PENTYRYL-VINYL (THIONO) (THIOL) -PHOSPHOR- (PHOSPHON) ACID ESTER, METHOD FOR THE PRODUCTION THEREOF AND THEIR USE AS INSECTICIDES, ACARICIDES AND NEMATICIDES |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| FR2362151A1 true FR2362151A1 (en) | 1978-03-17 |
Family
ID=5985538
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FR7724937A Withdrawn FR2362151A1 (en) | 1976-08-16 | 1977-08-12 | Tert.-pentanoyl-vinyl thio-phosphonate and phosphate ester(s) - useful as insecticides, acaricides and nematocides |
Country Status (9)
| Country | Link |
|---|---|
| JP (1) | JPS5323932A (en) |
| BE (1) | BE857813A (en) |
| BR (1) | BR7705379A (en) |
| DE (1) | DE2636785A1 (en) |
| DK (1) | DK362077A (en) |
| FR (1) | FR2362151A1 (en) |
| IL (1) | IL52716A0 (en) |
| NL (1) | NL7709040A (en) |
| ZA (1) | ZA774918B (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5834592U (en) * | 1981-08-27 | 1983-03-07 | 新神戸電機株式会社 | Inverter device |
-
1976
- 1976-08-16 DE DE19762636785 patent/DE2636785A1/en active Pending
-
1977
- 1977-08-12 IL IL52716A patent/IL52716A0/en unknown
- 1977-08-12 FR FR7724937A patent/FR2362151A1/en not_active Withdrawn
- 1977-08-15 ZA ZA00774918A patent/ZA774918B/en unknown
- 1977-08-15 BR BR7705379A patent/BR7705379A/en unknown
- 1977-08-15 DK DK362077A patent/DK362077A/en unknown
- 1977-08-15 JP JP9708877A patent/JPS5323932A/en active Pending
- 1977-08-16 NL NL7709040A patent/NL7709040A/en not_active Application Discontinuation
- 1977-08-16 BE BE180193A patent/BE857813A/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| NL7709040A (en) | 1978-02-20 |
| DK362077A (en) | 1978-02-17 |
| DE2636785A1 (en) | 1978-02-23 |
| BR7705379A (en) | 1978-05-30 |
| IL52716A0 (en) | 1977-10-31 |
| BE857813A (en) | 1978-02-16 |
| ZA774918B (en) | 1978-06-28 |
| JPS5323932A (en) | 1978-03-06 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| ST | Notification of lapse |