FR2360620A1 - IRRADIATION CURING COATING COMPOSITION - Google Patents

IRRADIATION CURING COATING COMPOSITION

Info

Publication number
FR2360620A1
FR2360620A1 FR7723611A FR7723611A FR2360620A1 FR 2360620 A1 FR2360620 A1 FR 2360620A1 FR 7723611 A FR7723611 A FR 7723611A FR 7723611 A FR7723611 A FR 7723611A FR 2360620 A1 FR2360620 A1 FR 2360620A1
Authority
FR
France
Prior art keywords
isocyanate
glycol
group
active hydrogen
addition polymerizable
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
FR7723611A
Other languages
French (fr)
Inventor
Dennis D Howard
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Lord Corp
Original Assignee
Lord Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US05/710,776 external-priority patent/US4112017A/en
Application filed by Lord Corp filed Critical Lord Corp
Publication of FR2360620A1 publication Critical patent/FR2360620A1/en
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4205—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups
    • C08G18/4208—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing aromatic groups
    • C08G18/4211—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing aromatic groups derived from aromatic dicarboxylic acids and dialcohols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/67—Unsaturated compounds having active hydrogen
    • C08G18/671—Unsaturated compounds having only one group containing active hydrogen

Abstract

L'invention a pour objet des résines uréthanes polymérisables par addition. Les résines uréthanes se caractérisent en ce qu'elles présentent au moins un groupe terminal ayant la structure CH2 = C < et en ce qu'elles contiennent le produit de la réaction d'au moins un composé isocyanate organique ayant au moins deux groupes isocyanate; d'au moins un polyol polyester ayant au moins deux groupes hydroxy et contenant le produit de la réaction d'au moins un glycol choisi dans le groupe comprenant le butylène 1,3 glycol et le néopentyl glycol; d'acide adipique; d'acide isophtalique et de 0 à 50 moles pour cent d'au moins un polyol aliphatique ayant au moins trois groupes hydroxyles, les moles % étant basées sur le total des moles de glycol et de polyol aliphatique; la quantité d'acide isophtalique étant de l'ordre d'environ 1 à environ 50 moles % basées sur le total des moles d'acide adipique et d'acide isophtalique; et au moins un composé monomère insaturé polymérisable par addition ayant un groupe hydrogène actif unique réagissant avec l'isocyanate; le composé isocyanate étant en excès par rapport aux groupes hydroxyles du polyol polyester, le composé monomère insaturé polymérisable par addition ayant un groupe hydrogène actif unique réagissant avec l'isocyanate, étant présent en quantité suffisante pour fournir au moins un équivalent molaire d'un groupe hydrogène actif en ce qui concerne la réactivité avec l'isocyanate. Application à la réalisation de composition de revêtement.The subject of the invention is addition polymerizable urethane resins. Urethane resins are characterized in that they have at least one end group having the structure CH2 = C <and in that they contain the reaction product of at least one organic isocyanate compound having at least two isocyanate groups; at least one polyester polyol having at least two hydroxy groups and containing the product of the reaction of at least one glycol selected from the group comprising butylene 1,3 glycol and neopentyl glycol; adipic acid; isophthalic acid and from 0 to 50 mole percent of at least one aliphatic polyol having at least three hydroxyl groups, the mole% being based on the total of the moles of glycol and aliphatic polyol; the amount of isophthalic acid being on the order of about 1 to about 50 mole% based on the total of the moles of adipic acid and isophthalic acid; and at least one addition polymerizable unsaturated monomeric compound having a single active hydrogen group reacting with isocyanate; the isocyanate compound being in excess of the hydroxyl groups of the polyester polyol, the addition polymerizable unsaturated monomeric compound having a single active hydrogen group reacting with the isocyanate, being present in an amount sufficient to provide at least one molar equivalent of a group active hydrogen with respect to reactivity with isocyanate. Application to the production of a coating composition.

FR7723611A 1976-08-02 1977-08-01 IRRADIATION CURING COATING COMPOSITION Withdrawn FR2360620A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US71077576A 1976-08-02 1976-08-02
US05/710,776 US4112017A (en) 1976-07-23 1976-08-02 Radiation curable coating compositions

Publications (1)

Publication Number Publication Date
FR2360620A1 true FR2360620A1 (en) 1978-03-03

Family

ID=27108521

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7723611A Withdrawn FR2360620A1 (en) 1976-08-02 1977-08-01 IRRADIATION CURING COATING COMPOSITION

Country Status (7)

Country Link
JP (1) JPS5317694A (en)
AU (1) AU516173B2 (en)
CA (1) CA1127345A (en)
DE (1) DE2734237A1 (en)
FR (1) FR2360620A1 (en)
GB (1) GB1590412A (en)
SE (1) SE7708525L (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2425094A1 (en) * 1978-05-01 1979-11-30 Minnesota Mining & Mfg PHOTOPOLYMERISABLE COMPOSITIONS
EP0102312A1 (en) * 1982-07-28 1984-03-07 The Goodyear Tire & Rubber Company Unsaturated polyurethanes

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2150938B (en) * 1983-12-05 1987-04-23 Tyndale Plains Hunter Limited Hydrophilic polyurethane acrylate compositions
JPS60235822A (en) * 1984-05-10 1985-11-22 Toagosei Chem Ind Co Ltd Curable resin composition
US4771078A (en) * 1985-11-12 1988-09-13 The Goodyear Tire & Rubber Company Method of producing a foam from a radiation-curable composition
GB8621835D0 (en) * 1986-09-10 1986-10-15 Courtaulds Plc Urethane polymer films

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2284622A1 (en) * 1974-09-13 1976-04-09 Basf Ag PHOTOCURLABLE LIQUID MOLDING MATERIAL FOR THE MAKING OF RELIEF PRINTING PLATES

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2284622A1 (en) * 1974-09-13 1976-04-09 Basf Ag PHOTOCURLABLE LIQUID MOLDING MATERIAL FOR THE MAKING OF RELIEF PRINTING PLATES

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2425094A1 (en) * 1978-05-01 1979-11-30 Minnesota Mining & Mfg PHOTOPOLYMERISABLE COMPOSITIONS
EP0102312A1 (en) * 1982-07-28 1984-03-07 The Goodyear Tire & Rubber Company Unsaturated polyurethanes

Also Published As

Publication number Publication date
JPS5317694A (en) 1978-02-17
CA1127345A (en) 1982-07-06
GB1590412A (en) 1981-06-03
AU516173B2 (en) 1981-05-21
SE7708525L (en) 1978-02-03
AU2736177A (en) 1979-02-01
DE2734237A1 (en) 1978-02-09

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Legal Events

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ST Notification of lapse