FR2359156A1 - PROCESS FOR THE PREPARATION OF HOMOPOLYMERS AND COPOLYMERS OF A-MONO-OLEFINS - Google Patents

PROCESS FOR THE PREPARATION OF HOMOPOLYMERS AND COPOLYMERS OF A-MONO-OLEFINS

Info

Publication number
FR2359156A1
FR2359156A1 FR7722687A FR7722687A FR2359156A1 FR 2359156 A1 FR2359156 A1 FR 2359156A1 FR 7722687 A FR7722687 A FR 7722687A FR 7722687 A FR7722687 A FR 7722687A FR 2359156 A1 FR2359156 A1 FR 2359156A1
Authority
FR
France
Prior art keywords
degrees
olefins
copolymers
mono
preparation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7722687A
Other languages
French (fr)
Other versions
FR2359156B1 (en
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Publication of FR2359156A1 publication Critical patent/FR2359156A1/en
Application granted granted Critical
Publication of FR2359156B1 publication Critical patent/FR2359156B1/fr
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond

Abstract

Procédé de préparation d'homo- et de copolymères d' alpha -mono-oléfines au moyen d'un système catalytique de Ziegler comprenant : contenant du vanadium; 1 degrés Un composant contenant du vanadium; 2 degrés Un composé métallique MeAm-n X n , (Me - Al, Mg ou Zn, A est un reste hydrocarboné, m - valence de Me et n < m, et éventuellement 3 degrés Un hydrocarbure halogéné. Le composant 1 est obtenu en mettant en contact une substance de type oxyde, de formule QiO2 . aAl2 O3 (O =< a =< 2) avec un composé d'aluminium de formule Al B3-p Y p (B est un reste hydrocarboné. Y = H, Cl, Br ou OR, avec R = reste hydrocarboné et p est compris entre 0 et 3), puis en mélangeant le produit solide obtenu avec un alcool saturé et un halogénure vanadeux de manière à obtenir une dispersion qui après évaporation à siccité donne le composant 1.A process for the preparation of homo- and copolymers of alpha-mono-olefins using a Ziegler catalyst system comprising: containing vanadium; 1 degrees A component containing vanadium; 2 degrees A metallic compound MeAm-n X n, (Me - Al, Mg or Zn, A is a hydrocarbon residue, m - valency of Me and n <m, and optionally 3 degrees A halogenated hydrocarbon. Component 1 is obtained by contacting an oxide-type substance of formula QiO2. aAl2 O3 (O = <a = <2) with an aluminum compound of formula Al B3-p Y p (B is a hydrocarbon residue. Y = H, Cl , Br or OR, with R = hydrocarbon residue and p is between 0 and 3), then by mixing the solid product obtained with a saturated alcohol and a vanadous halide so as to obtain a dispersion which after evaporation to dryness gives component 1 .

FR7722687A 1976-07-23 1977-07-22 PROCESS FOR THE PREPARATION OF HOMOPOLYMERS AND COPOLYMERS OF A-MONO-OLEFINS Granted FR2359156A1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19762633109 DE2633109A1 (en) 1976-07-23 1976-07-23 PROCESS FOR PRODUCING HOMOPOLYMERIZED AND COPOLYMERIZED ALPHA-MONOOLEFINS

Publications (2)

Publication Number Publication Date
FR2359156A1 true FR2359156A1 (en) 1978-02-17
FR2359156B1 FR2359156B1 (en) 1981-04-30

Family

ID=5983726

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7722687A Granted FR2359156A1 (en) 1976-07-23 1977-07-22 PROCESS FOR THE PREPARATION OF HOMOPOLYMERS AND COPOLYMERS OF A-MONO-OLEFINS

Country Status (8)

Country Link
JP (1) JPS5313690A (en)
AT (1) AT354726B (en)
BE (1) BE857100A (en)
DE (1) DE2633109A1 (en)
ES (1) ES460960A1 (en)
FR (1) FR2359156A1 (en)
GB (1) GB1582287A (en)
IT (1) IT1076790B (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0064637A1 (en) * 1981-05-02 1982-11-17 BASF Aktiengesellschaft Process for producing homo and copolymers of monoolefins by polymerization of the respective monomers with the aid of a Ziegler-type catalyst comprising a vanadium-containing compound

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4378304A (en) * 1981-06-03 1983-03-29 Chemplex Company Catalyst and methods
DE3144311A1 (en) * 1981-11-07 1983-05-19 Basf Ag, 6700 Ludwigshafen METHOD FOR PRODUCING A VANADIUM-CONTAINING CATALYST COMPONENT FOR ZIEGLER CATALYST SYSTEMS
DE3242149A1 (en) * 1982-11-13 1984-05-17 Basf Ag, 6700 Ludwigshafen METHOD FOR PRODUCING HOMO AND COPOLYMERISATS FROM (ALPHA) MONOOLEFINES BY MEANS OF A ZIEGLER CATALYST SYSTEM
DE3242150A1 (en) * 1982-11-13 1984-05-17 Basf Ag, 6700 Ludwigshafen METHOD FOR PRODUCING HOMO AND COPOLYMERISATS FROM (ALPHA) MONOOLEFINES BY MEANS OF A ZIEGLER CATALYST SYSTEM
DE3417238A1 (en) * 1984-05-10 1985-11-14 Basf Ag, 6700 Ludwigshafen METHOD FOR PRODUCING HOMOPOLYMERISATES OF ETHEN AND COPOLYMERISATES OF ETHEN WITH HIGHER MONOOLEFINES BY MEANS OF A ZIEGLER CATALYST SYSTEM
US5030605A (en) * 1989-12-29 1991-07-09 Union Carbide Chemicals And Plastics Technology Corporation Catalyst for regulating the molecular weight distribution of ethylene polymers
US5374597A (en) * 1993-02-12 1994-12-20 Quantum Chemical Corporation Vanadium based olefin polymerization catalyst
US5405817A (en) * 1993-02-12 1995-04-11 Quantum Chemical Corporation V/TI multi-site olefin polymerization catalyst
US5670439A (en) * 1995-03-29 1997-09-23 Quantum Chemical Corporation Vanadium-containing catalyst system

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1417195A (en) * 1963-09-11 1965-11-12 Hercules Powder Co Ltd Olefin polymerization improvements
FR2058778A5 (en) * 1969-09-25 1971-05-28 Naphtachimie Sa

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2082153A5 (en) * 1970-03-05 1971-12-10 Solvay ADVANCED CATALYSTS AND PROCESS FOR THE POLYMERIZATION AND COPOLYMERIZATION OF OLEFINS

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1417195A (en) * 1963-09-11 1965-11-12 Hercules Powder Co Ltd Olefin polymerization improvements
FR2058778A5 (en) * 1969-09-25 1971-05-28 Naphtachimie Sa

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0064637A1 (en) * 1981-05-02 1982-11-17 BASF Aktiengesellschaft Process for producing homo and copolymers of monoolefins by polymerization of the respective monomers with the aid of a Ziegler-type catalyst comprising a vanadium-containing compound

Also Published As

Publication number Publication date
JPS5313690A (en) 1978-02-07
FR2359156B1 (en) 1981-04-30
ES460960A1 (en) 1978-05-16
ATA535377A (en) 1979-06-15
BE857100A (en) 1978-01-25
DE2633109A1 (en) 1978-02-02
DE2633109C2 (en) 1987-12-03
GB1582287A (en) 1981-01-07
IT1076790B (en) 1985-04-27
AT354726B (en) 1979-01-25

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