FR2356639A1 - Preparation de cyano-pyridines a partir de piperidines - Google Patents
Preparation de cyano-pyridines a partir de piperidinesInfo
- Publication number
- FR2356639A1 FR2356639A1 FR7719938A FR7719938A FR2356639A1 FR 2356639 A1 FR2356639 A1 FR 2356639A1 FR 7719938 A FR7719938 A FR 7719938A FR 7719938 A FR7719938 A FR 7719938A FR 2356639 A1 FR2356639 A1 FR 2356639A1
- Authority
- FR
- France
- Prior art keywords
- piperidines
- support
- nicotinonitrile
- catalyst
- vanadium oxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 150000003053 piperidines Chemical class 0.000 title abstract 2
- GZPHSAQLYPIAIN-UHFFFAOYSA-N 3-pyridinecarbonitrile Chemical compound N#CC1=CC=CN=C1 GZPHSAQLYPIAIN-UHFFFAOYSA-N 0.000 abstract 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 abstract 2
- PVNIIMVLHYAWGP-UHFFFAOYSA-N Niacin Chemical class OC(=O)C1=CC=CN=C1 PVNIIMVLHYAWGP-UHFFFAOYSA-N 0.000 abstract 2
- DFPAKSUCGFBDDF-UHFFFAOYSA-N Nicotinamide Chemical compound NC(=O)C1=CC=CN=C1 DFPAKSUCGFBDDF-UHFFFAOYSA-N 0.000 abstract 2
- NQRYJNQNLNOLGT-UHFFFAOYSA-N Piperidine Chemical compound C1CCNCC1 NQRYJNQNLNOLGT-UHFFFAOYSA-N 0.000 abstract 2
- XHCLAFWTIXFWPH-UHFFFAOYSA-N [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] XHCLAFWTIXFWPH-UHFFFAOYSA-N 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- 229910001935 vanadium oxide Inorganic materials 0.000 abstract 2
- FFNVQNRYTPFDDP-UHFFFAOYSA-N 2-cyanopyridine Chemical class N#CC1=CC=CC=N1 FFNVQNRYTPFDDP-UHFFFAOYSA-N 0.000 abstract 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 229910021529 ammonia Inorganic materials 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 229910001882 dioxygen Inorganic materials 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 230000003647 oxidation Effects 0.000 abstract 1
- 238000007254 oxidation reaction Methods 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 239000011148 porous material Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D213/78—Carbon atoms having three bonds to hetero atoms, with at the most one bond to halogen, e.g. ester or nitrile radicals
- C07D213/84—Nitriles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/20—Vanadium, niobium or tantalum
- B01J23/22—Vanadium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/613—10-100 m2/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/63—Pore volume
- B01J35/633—Pore volume less than 0.5 ml/g
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Pyridine Compounds (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US05/701,694 US4057552A (en) | 1976-07-01 | 1976-07-01 | Production of cyanopyridines from piperidines |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| FR2356639A1 true FR2356639A1 (fr) | 1978-01-27 |
| FR2356639B1 FR2356639B1 (enExample) | 1982-09-17 |
Family
ID=24818308
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FR7719938A Granted FR2356639A1 (fr) | 1976-07-01 | 1977-06-29 | Preparation de cyano-pyridines a partir de piperidines |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US4057552A (enExample) |
| JP (1) | JPS5822115B2 (enExample) |
| BE (1) | BE856303A (enExample) |
| BR (1) | BR7704283A (enExample) |
| CA (1) | CA1063609A (enExample) |
| CH (1) | CH634054A5 (enExample) |
| DE (1) | DE2729009A1 (enExample) |
| FR (1) | FR2356639A1 (enExample) |
| GB (1) | GB1573683A (enExample) |
| IT (1) | IT1083075B (enExample) |
| NL (1) | NL179054C (enExample) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4721789A (en) * | 1984-12-05 | 1988-01-26 | The Standard Oil Company | Oxidative cyclization of 2-methylglutaronitrile to 3-cyanopyridine |
| JP2615819B2 (ja) * | 1988-04-28 | 1997-06-04 | 三菱瓦斯化学株式会社 | シアノピリジンの製造法 |
| TW577876B (en) * | 1997-01-29 | 2004-03-01 | Reilly Ind Inc | Processes for producing 3-cyanopyridine from 2-methyl-1,5-pentanediamine |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3555021A (en) * | 1967-02-21 | 1971-01-12 | Merck & Co Inc | Process for the preparation of heterocyclic nitriles |
| US3925447A (en) * | 1971-05-26 | 1975-12-09 | Lummus Co | Production of nitriles |
| FR2291194A1 (fr) * | 1973-11-15 | 1976-06-11 | Lummus Co | Procede de preparation de nicotinitrile |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2592123A (en) * | 1948-09-28 | 1952-04-08 | Socony Vacuum Oil Co Inc | Production of pyridine nitriles |
| US3544617A (en) * | 1967-12-27 | 1970-12-01 | Showa Denko Kk | Process for the manufacture of aromatic nitriles |
-
1976
- 1976-07-01 US US05/701,694 patent/US4057552A/en not_active Expired - Lifetime
-
1977
- 1977-06-27 GB GB26880/77A patent/GB1573683A/en not_active Expired
- 1977-06-28 JP JP52077723A patent/JPS5822115B2/ja not_active Expired
- 1977-06-28 DE DE19772729009 patent/DE2729009A1/de not_active Withdrawn
- 1977-06-29 FR FR7719938A patent/FR2356639A1/fr active Granted
- 1977-06-29 NL NLAANVRAGE7707231,A patent/NL179054C/xx not_active IP Right Cessation
- 1977-06-30 BE BE178940A patent/BE856303A/xx not_active IP Right Cessation
- 1977-06-30 BR BR7704283A patent/BR7704283A/pt unknown
- 1977-06-30 CH CH807277A patent/CH634054A5/de not_active IP Right Cessation
- 1977-06-30 CA CA281,848A patent/CA1063609A/en not_active Expired
- 1977-06-30 IT IT68518/77A patent/IT1083075B/it active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3555021A (en) * | 1967-02-21 | 1971-01-12 | Merck & Co Inc | Process for the preparation of heterocyclic nitriles |
| US3925447A (en) * | 1971-05-26 | 1975-12-09 | Lummus Co | Production of nitriles |
| FR2291194A1 (fr) * | 1973-11-15 | 1976-06-11 | Lummus Co | Procede de preparation de nicotinitrile |
Also Published As
| Publication number | Publication date |
|---|---|
| NL179054C (nl) | 1986-07-01 |
| GB1573683A (en) | 1980-08-28 |
| IT1083075B (it) | 1985-05-21 |
| BE856303A (fr) | 1977-10-17 |
| DE2729009A1 (de) | 1978-01-12 |
| BR7704283A (pt) | 1978-03-28 |
| US4057552A (en) | 1977-11-08 |
| NL7707231A (nl) | 1978-01-03 |
| CA1063609A (en) | 1979-10-02 |
| CH634054A5 (de) | 1983-01-14 |
| JPS5822115B2 (ja) | 1983-05-06 |
| JPS535173A (en) | 1978-01-18 |
| FR2356639B1 (enExample) | 1982-09-17 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| TP | Transmission of property | ||
| ST | Notification of lapse |