FR2336489A1 - Recuperation du rhodium a partir des residus de distillation d'hydroformylation et rhodium ainsi recupere - Google Patents

Recuperation du rhodium a partir des residus de distillation d'hydroformylation et rhodium ainsi recupere

Info

Publication number
FR2336489A1
FR2336489A1 FR7633424A FR7633424A FR2336489A1 FR 2336489 A1 FR2336489 A1 FR 2336489A1 FR 7633424 A FR7633424 A FR 7633424A FR 7633424 A FR7633424 A FR 7633424A FR 2336489 A1 FR2336489 A1 FR 2336489A1
Authority
FR
France
Prior art keywords
rhodium
hydroformylation
recovered
recovery
distillation residues
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7633424A
Other languages
English (en)
French (fr)
Other versions
FR2336489B1 (OSRAM
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
EIDP Inc
Original Assignee
EI Du Pont de Nemours and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by EI Du Pont de Nemours and Co filed Critical EI Du Pont de Nemours and Co
Publication of FR2336489A1 publication Critical patent/FR2336489A1/fr
Application granted granted Critical
Publication of FR2336489B1 publication Critical patent/FR2336489B1/fr
Granted legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/185—Phosphites ((RO)3P), their isomeric phosphonates (R(RO)2P=O) and RO-substitution derivatives thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B01J31/4015—Regeneration or reactivation of catalysts containing metals
    • B01J31/4023—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper
    • B01J31/4038—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals
    • B01J31/4046—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals containing rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F9/00—Making metallic powder or suspensions thereof
    • B22F9/16—Making metallic powder or suspensions thereof using chemical processes
    • B22F9/30—Making metallic powder or suspensions thereof using chemical processes with decomposition of metal compounds, e.g. by pyrolysis
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G55/00—Compounds of ruthenium, rhodium, palladium, osmium, iridium, or platinum
    • C01G55/001—Preparation involving a liquid-liquid extraction, an adsorption or an ion-exchange
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/56—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds from heterocyclic compounds
    • C07C45/57—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds from heterocyclic compounds with oxygen as the only heteroatom
    • C07C45/59—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds from heterocyclic compounds with oxygen as the only heteroatom in five-membered rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/56—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds from heterocyclic compounds
    • C07C45/57—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds from heterocyclic compounds with oxygen as the only heteroatom
    • C07C45/60—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds from heterocyclic compounds with oxygen as the only heteroatom in six-membered rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D319/00—Heterocyclic compounds containing six-membered rings having two oxygen atoms as the only ring hetero atoms
    • C07D319/04—1,3-Dioxanes; Hydrogenated 1,3-dioxanes
    • C07D319/06—1,3-Dioxanes; Hydrogenated 1,3-dioxanes not condensed with other rings
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B11/00—Obtaining noble metals
    • C22B11/04—Obtaining noble metals by wet processes
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
    • C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
    • C22B3/262—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds using alcohols or phenols
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46—Ruthenium, rhodium, osmium or iridium
    • B01J23/464—Rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00—Technologies related to metal processing
    • Y02P10/20—Recycling
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Mechanical Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Environmental & Geological Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geology (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Manufacture And Refinement Of Metals (AREA)
  • Manufacture Of Metal Powder And Suspensions Thereof (AREA)
FR7633424A 1975-12-23 1976-11-05 Recuperation du rhodium a partir des residus de distillation d'hydroformylation et rhodium ainsi recupere Granted FR2336489A1 (fr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US05/643,913 US3998622A (en) 1975-12-23 1975-12-23 Rhodium from hydroformylation still heels

Publications (2)

Publication Number Publication Date
FR2336489A1 true FR2336489A1 (fr) 1977-07-22
FR2336489B1 FR2336489B1 (OSRAM) 1981-01-23

Family

ID=24582682

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7633424A Granted FR2336489A1 (fr) 1975-12-23 1976-11-05 Recuperation du rhodium a partir des residus de distillation d'hydroformylation et rhodium ainsi recupere

Country Status (8)

Country Link
US (1) US3998622A (OSRAM)
JP (1) JPS5280217A (OSRAM)
BE (1) BE847854A (OSRAM)
CA (1) CA1083855A (OSRAM)
DE (1) DE2651000A1 (OSRAM)
FR (1) FR2336489A1 (OSRAM)
GB (1) GB1516569A (OSRAM)
NL (1) NL7612379A (OSRAM)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2516546A1 (fr) * 1981-11-16 1983-05-20 Halcon Sd Group Inc Procede de recuperation de metaux nobles a partir de residus d'une reaction catalytique de carbonylation
RU2198947C2 (ru) * 2000-09-12 2003-02-20 Антонов Андрей Александрович Способ извлечения благородных металлов

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4135911A (en) * 1977-07-28 1979-01-23 E. I. Du Pont De Nemours And Company Rhodium recovery from hydroformylation still heel with triaryl phosphite ligand
JPS5645436A (en) * 1979-09-21 1981-04-25 Mitsubishi Chem Ind Ltd Hydroformylation of olefin
DE3320630A1 (de) * 1983-06-08 1985-02-21 Hoechst Ag, 6230 Frankfurt Verfahren zur rueckgewinnung von edelmetallen der gruppe viii des periodensystems der elemente aus der bei der carbonylierung von methylacetat und/oder dimethylether anfallenden verunreinigten katalysatorloesung
US4979985A (en) * 1990-02-06 1990-12-25 E. I. Du Pont De Nemours And Company Process for making finely divided particles of silver metal
US5208194A (en) * 1992-02-25 1993-05-04 Arco Chemical Technology, L.P. Recovery of group VIII transition metals from organic solutions using acidic ion-exchange resins
US5773665A (en) * 1996-07-01 1998-06-30 Elf Atochem North America, Inc. Hydroformylation process with separation and recycle of active rhodium catalyst
US6946114B2 (en) * 2000-09-05 2005-09-20 Conocophillips Company Lanthanide-promoted rhodium catalysts and process for producing synthesis gas
CN102373335B (zh) * 2010-08-27 2013-08-14 中国石油化工股份有限公司 一种从失活铑膦络合催化剂中回收铑的方法
CN102019427A (zh) * 2010-12-20 2011-04-20 吴浩 一种高效吸波粒子、吸波材料及其应用、制备方法
CN113618076A (zh) * 2021-07-21 2021-11-09 无锡威孚环保催化剂有限公司 一种海绵铑粉及其制备方法

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1249168A (fr) * 1959-03-04 1960-12-23 Engelhard Ind Inc Récupération du rhodium dans les produits de fission
US3547964A (en) * 1968-07-24 1970-12-15 Union Oil Co Group viii noble metal catalyst recovery

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1518305A (fr) * 1966-04-14 1968-03-22 Ajinomoto Kk Procédé de récupération du rhodium à partir d'un mélange provenant d'une réaction catalysée par le rhodium

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1249168A (fr) * 1959-03-04 1960-12-23 Engelhard Ind Inc Récupération du rhodium dans les produits de fission
US3547964A (en) * 1968-07-24 1970-12-15 Union Oil Co Group viii noble metal catalyst recovery

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2516546A1 (fr) * 1981-11-16 1983-05-20 Halcon Sd Group Inc Procede de recuperation de metaux nobles a partir de residus d'une reaction catalytique de carbonylation
RU2198947C2 (ru) * 2000-09-12 2003-02-20 Антонов Андрей Александрович Способ извлечения благородных металлов

Also Published As

Publication number Publication date
FR2336489B1 (OSRAM) 1981-01-23
US3998622A (en) 1976-12-21
JPS5280217A (en) 1977-07-05
NL7612379A (nl) 1977-06-27
DE2651000A1 (de) 1977-07-07
GB1516569A (en) 1978-07-05
BE847854A (fr) 1977-04-29
CA1083855A (en) 1980-08-19

Similar Documents

Publication Publication Date Title
BR7608395A (pt) Processo de obtencao de tereftalato de dimetila a partir de residuos de poliester
FR2336489A1 (fr) Recuperation du rhodium a partir des residus de distillation d'hydroformylation et rhodium ainsi recupere
BE892365A (fr) Recuperation de rhodium de residus de carbonylation
IT1083954B (it) Dispositivo per rivelare l'azionamento di interruttori relativi a tasti
RO69967A (ro) Compozitie catalitica folosita la obtinerea acizilor nesaturati
BE846190A (fr) Melanges de polyols et polyurethannes prepares a partir de ces melanges
IT1158653B (it) Ricupero di adiponitrile e suoi precursori da un residuo di processo dell'preparazione di adiponitrile
OA05414A (fr) Procédé pour préconcentrer des minerais nickélifères oxydés d'origine latérique.
BE892367A (fr) Recuperation de rhodium de residus de carbonylation
BE843964A (fr) Perfectionnements relatifs a l'extraction de la gelatine
FR2314938A1 (fr) Procede d'elimination des cendres et de cokefaction du charbon
BR7607100A (pt) Dispositif de separation des constituants d'un melange gaze ux
FR2346317A1 (fr) Recuperation de la glycine et de l'acide iminodiacetique
BE828643A (fr) Recuperation de l'argent et de l'acide terephalique de pellicules photosensibles
BE846054A (fr) Recuperation d'alkylene-glycols
BE880940A (fr) Recuperation de l'acetone produite lors d'une carbonylation
FR2324340A1 (fr) Traitement d'emulsions huileuses en vue de la recuperation des huiles
FR2301852A1 (fr) Dispositif applicateur d'une matiere de separation
FR2333664A1 (fr) Structure d'un siege de vehicule
AT350542B (de) Verfahren zur trennung von auf technischem weg zugaenglichen dinitroanthrachinon-gemischen
BE870256A (fr) Procede de recuperation ou de purification du rhodium
BR7606605A (pt) Conjunto de orgaos de conducao e de corte de fios de trama num tear
BE824850A (fr) Procedes de recuperation de metaux a partir de residus metalliferes
BE853150A (fr) Recuperation du zinc des solutions residuelles de l'electrodeposition
BE850911A (fr) Nouveaux esters d'indan-5-yle d'acide n-methylcarbamique

Legal Events

Date Code Title Description
ST Notification of lapse