FR2303786A1 - OPTICALLY ACTIVE CYCLOHEXANE DERIVATIVES AND THEIR PREPARATION PROCESS - Google Patents

OPTICALLY ACTIVE CYCLOHEXANE DERIVATIVES AND THEIR PREPARATION PROCESS

Info

Publication number
FR2303786A1
FR2303786A1 FR7616821A FR7616821A FR2303786A1 FR 2303786 A1 FR2303786 A1 FR 2303786A1 FR 7616821 A FR7616821 A FR 7616821A FR 7616821 A FR7616821 A FR 7616821A FR 2303786 A1 FR2303786 A1 FR 2303786A1
Authority
FR
France
Prior art keywords
preparation process
optically active
cyclohexane derivatives
active cyclohexane
derivatives
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7616821A
Other languages
French (fr)
Other versions
FR2303786B1 (en
Inventor
Walter Boguth
Hans Georg Wilhelm Leuenberger
Hans Johann Mayer
Erich Widmer
Reinhard Zell
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
F Hoffmann La Roche AG
Original Assignee
F Hoffmann La Roche AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from CH1143474A external-priority patent/CH605533A5/xx
Application filed by F Hoffmann La Roche AG filed Critical F Hoffmann La Roche AG
Publication of FR2303786A1 publication Critical patent/FR2303786A1/en
Application granted granted Critical
Publication of FR2303786B1 publication Critical patent/FR2303786B1/fr
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C403/00—Derivatives of cyclohexane or of a cyclohexene or of cyclohexadiene, having a side-chain containing an acyclic unsaturated part of at least four carbon atoms, this part being directly attached to the cyclohexane or cyclohexene or cyclohexadiene rings, e.g. vitamin A, beta-carotene, beta-ionone
    • C07C403/24—Derivatives of cyclohexane or of a cyclohexene or of cyclohexadiene, having a side-chain containing an acyclic unsaturated part of at least four carbon atoms, this part being directly attached to the cyclohexane or cyclohexene or cyclohexadiene rings, e.g. vitamin A, beta-carotene, beta-ionone having side-chains substituted by six-membered non-aromatic rings, e.g. beta-carotene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C403/00—Derivatives of cyclohexane or of a cyclohexene or of cyclohexadiene, having a side-chain containing an acyclic unsaturated part of at least four carbon atoms, this part being directly attached to the cyclohexane or cyclohexene or cyclohexadiene rings, e.g. vitamin A, beta-carotene, beta-ionone
    • C07C403/02—Derivatives of cyclohexane or of a cyclohexene or of cyclohexadiene, having a side-chain containing an acyclic unsaturated part of at least four carbon atoms, this part being directly attached to the cyclohexane or cyclohexene or cyclohexadiene rings, e.g. vitamin A, beta-carotene, beta-ionone having side-chains containing only carbon and hydrogen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C403/00—Derivatives of cyclohexane or of a cyclohexene or of cyclohexadiene, having a side-chain containing an acyclic unsaturated part of at least four carbon atoms, this part being directly attached to the cyclohexane or cyclohexene or cyclohexadiene rings, e.g. vitamin A, beta-carotene, beta-ionone
    • C07C403/06—Derivatives of cyclohexane or of a cyclohexene or of cyclohexadiene, having a side-chain containing an acyclic unsaturated part of at least four carbon atoms, this part being directly attached to the cyclohexane or cyclohexene or cyclohexadiene rings, e.g. vitamin A, beta-carotene, beta-ionone having side-chains substituted by singly-bound oxygen atoms
    • C07C403/08—Derivatives of cyclohexane or of a cyclohexene or of cyclohexadiene, having a side-chain containing an acyclic unsaturated part of at least four carbon atoms, this part being directly attached to the cyclohexane or cyclohexene or cyclohexadiene rings, e.g. vitamin A, beta-carotene, beta-ionone having side-chains substituted by singly-bound oxygen atoms by hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C403/00—Derivatives of cyclohexane or of a cyclohexene or of cyclohexadiene, having a side-chain containing an acyclic unsaturated part of at least four carbon atoms, this part being directly attached to the cyclohexane or cyclohexene or cyclohexadiene rings, e.g. vitamin A, beta-carotene, beta-ionone
    • C07C403/06—Derivatives of cyclohexane or of a cyclohexene or of cyclohexadiene, having a side-chain containing an acyclic unsaturated part of at least four carbon atoms, this part being directly attached to the cyclohexane or cyclohexene or cyclohexadiene rings, e.g. vitamin A, beta-carotene, beta-ionone having side-chains substituted by singly-bound oxygen atoms
    • C07C403/12—Derivatives of cyclohexane or of a cyclohexene or of cyclohexadiene, having a side-chain containing an acyclic unsaturated part of at least four carbon atoms, this part being directly attached to the cyclohexane or cyclohexene or cyclohexadiene rings, e.g. vitamin A, beta-carotene, beta-ionone having side-chains substituted by singly-bound oxygen atoms by esterified hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C403/00—Derivatives of cyclohexane or of a cyclohexene or of cyclohexadiene, having a side-chain containing an acyclic unsaturated part of at least four carbon atoms, this part being directly attached to the cyclohexane or cyclohexene or cyclohexadiene rings, e.g. vitamin A, beta-carotene, beta-ionone
    • C07C403/14—Derivatives of cyclohexane or of a cyclohexene or of cyclohexadiene, having a side-chain containing an acyclic unsaturated part of at least four carbon atoms, this part being directly attached to the cyclohexane or cyclohexene or cyclohexadiene rings, e.g. vitamin A, beta-carotene, beta-ionone having side-chains substituted by doubly-bound oxygen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C403/00—Derivatives of cyclohexane or of a cyclohexene or of cyclohexadiene, having a side-chain containing an acyclic unsaturated part of at least four carbon atoms, this part being directly attached to the cyclohexane or cyclohexene or cyclohexadiene rings, e.g. vitamin A, beta-carotene, beta-ionone
    • C07C403/14—Derivatives of cyclohexane or of a cyclohexene or of cyclohexadiene, having a side-chain containing an acyclic unsaturated part of at least four carbon atoms, this part being directly attached to the cyclohexane or cyclohexene or cyclohexadiene rings, e.g. vitamin A, beta-carotene, beta-ionone having side-chains substituted by doubly-bound oxygen atoms
    • C07C403/16—Derivatives of cyclohexane or of a cyclohexene or of cyclohexadiene, having a side-chain containing an acyclic unsaturated part of at least four carbon atoms, this part being directly attached to the cyclohexane or cyclohexene or cyclohexadiene rings, e.g. vitamin A, beta-carotene, beta-ionone having side-chains substituted by doubly-bound oxygen atoms not being part of —CHO groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/64—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by introduction of functional groups containing oxygen only in singly bound form
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/385—Saturated compounds containing a keto group being part of a ring
    • C07C49/403—Saturated compounds containing a keto group being part of a ring of a six-membered ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/54—Quaternary phosphonium compounds
    • C07F9/5428—Acyclic unsaturated phosphonium compounds
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P7/00—Preparation of oxygen-containing organic compounds
    • C12P7/24—Preparation of oxygen-containing organic compounds containing a carbonyl group
    • C12P7/26—Ketones
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B2200/00—Indexing scheme relating to specific properties of organic compounds
    • C07B2200/07—Optical isomers
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/16—Systems containing only non-condensed rings with a six-membered ring the ring being unsaturated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • General Health & Medical Sciences (AREA)
  • Biochemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Microbiology (AREA)
  • Biotechnology (AREA)
  • Molecular Biology (AREA)
  • Bioinformatics & Cheminformatics (AREA)
  • General Engineering & Computer Science (AREA)
  • Genetics & Genomics (AREA)
  • Preparation Of Compounds By Using Micro-Organisms (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
FR7616821A 1974-08-21 1976-06-03 OPTICALLY ACTIVE CYCLOHEXANE DERIVATIVES AND THEIR PREPARATION PROCESS Granted FR2303786A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CH1143474A CH605533A5 (en) 1974-08-21 1974-08-21
CH1467474 1974-11-01

Publications (2)

Publication Number Publication Date
FR2303786A1 true FR2303786A1 (en) 1976-10-08
FR2303786B1 FR2303786B1 (en) 1980-05-30

Family

ID=25708324

Family Applications (3)

Application Number Title Priority Date Filing Date
FR7525631A Granted FR2303797A1 (en) 1974-08-21 1975-08-19 PROCESS FOR THE PREPARATION OF OPTICALLY ACTIVE CYCLOHEXANE DERIVATIVES
FR7616822A Granted FR2303798A1 (en) 1974-08-21 1976-06-03 PROCESS FOR THE PREPARATION OF (3R, 3'R) -ZEAXANTHENE
FR7616821A Granted FR2303786A1 (en) 1974-08-21 1976-06-03 OPTICALLY ACTIVE CYCLOHEXANE DERIVATIVES AND THEIR PREPARATION PROCESS

Family Applications Before (2)

Application Number Title Priority Date Filing Date
FR7525631A Granted FR2303797A1 (en) 1974-08-21 1975-08-19 PROCESS FOR THE PREPARATION OF OPTICALLY ACTIVE CYCLOHEXANE DERIVATIVES
FR7616822A Granted FR2303798A1 (en) 1974-08-21 1976-06-03 PROCESS FOR THE PREPARATION OF (3R, 3'R) -ZEAXANTHENE

Country Status (7)

Country Link
JP (1) JPS587277B2 (en)
AT (1) AT347422B (en)
DE (1) DE2537060C3 (en)
FR (3) FR2303797A1 (en)
GB (1) GB1508195A (en)
IT (1) IT1041904B (en)
NL (1) NL169195C (en)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4000198A (en) * 1975-06-09 1976-12-28 Hoffmann-La Roche Inc. Hydroxy-acetylene-substituted cyclohexenone
JPS61105975U (en) * 1984-12-14 1986-07-05
DE19543619A1 (en) * 1995-11-23 1997-05-28 Basf Ag Process for the pure preparation of trans- and cis-4-hydroxy-2,2,6-trimethyl-cyclohexan-l-one from isomer mixtures
DE19723480A1 (en) * 1997-06-04 1998-12-10 Basf Ag Process for the preparation of zeaxanthin, intermediates for this process and process for its preparation
ATE318925T1 (en) * 1998-08-19 2006-03-15 Dsm Ip Assets Bv MICROBIAL PRODUCTION OF ACTINOL
DE10145223A1 (en) 2001-09-13 2003-04-03 Basf Ag Process for the preparation of meso-zeaxanthin
ES2670671T3 (en) 2014-06-18 2018-05-31 Allied Biotech Corporation Procedures for preparing lycopene from Wittig C-15 salts and procedures for the purification of Wittig C-15 salts with all-E content and high 6Z

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1167712A (en) * 1955-07-22 1958-11-28 Hoffmann La Roche Process for the preparation of carotenoids
FR1210619A (en) * 1955-08-31 1960-03-09 Hoffmann La Roche Process for the preparation of carotenoids
FR1165058A (en) * 1955-10-11 1958-10-17 Hoffmann La Roche Process for the preparation of cyclic ketones

Also Published As

Publication number Publication date
IT1041904B (en) 1980-01-10
FR2303797B1 (en) 1980-07-25
DE2537060A1 (en) 1976-03-04
FR2303798B1 (en) 1982-10-29
FR2303798A1 (en) 1976-10-08
FR2303786B1 (en) 1980-05-30
JPS5182789A (en) 1976-07-20
FR2303797A1 (en) 1976-10-08
JPS587277B2 (en) 1983-02-09
AT347422B (en) 1978-12-27
DE2537060C3 (en) 1980-01-17
GB1508195A (en) 1978-04-19
DE2537060B2 (en) 1979-05-23
NL169195B (en) 1982-01-18
NL169195C (en) 1982-06-16
NL7509925A (en) 1976-02-24
ATA645575A (en) 1978-05-15

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Legal Events

Date Code Title Description
TP Transmission of property
ST Notification of lapse