FR2263228A1 - Tetraphenyl diaminodimethyl ether - prepd. from formaldehyde and diphenylamine and use as anti-oxidant pref. in rubber - Google Patents
Tetraphenyl diaminodimethyl ether - prepd. from formaldehyde and diphenylamine and use as anti-oxidant pref. in rubberInfo
- Publication number
- FR2263228A1 FR2263228A1 FR7506670A FR7506670A FR2263228A1 FR 2263228 A1 FR2263228 A1 FR 2263228A1 FR 7506670 A FR7506670 A FR 7506670A FR 7506670 A FR7506670 A FR 7506670A FR 2263228 A1 FR2263228 A1 FR 2263228A1
- Authority
- FR
- France
- Prior art keywords
- rubber
- diaminodimethyl
- prepd
- pref
- oxidant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/17—Amines; Quaternary ammonium compounds
- C08K5/18—Amines; Quaternary ammonium compounds with aromatically bound amino groups
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Anti-Oxidant Or Stabilizer Compositions (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Novel tretraphenyl diaminodimethyl ether of formula Ph2N-CH2-O-CH2-NPh2 (I) is prepd. by reacting HCHO and HNPh2 in pref. HCHO:HNPh2 mol. ratios 0.85-1.5 (1-1.2):1, at 1-150 (90-110) degrees C, esp. at 45 degrees C and partic. at room temp., advantageously in the absence of solvents. The cpd. is an anti-oxidant for organic materials, e.g. fats, oils, but esp. polymers, e.g. polyolefins, other polymers of ethylenically unsatd. cpds., and natural or synthetic rubber. Rubber vulcanisates contg. (I) resist heat ageing and tearing on bending.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB982274 | 1974-03-05 |
Publications (2)
Publication Number | Publication Date |
---|---|
FR2263228A1 true FR2263228A1 (en) | 1975-10-03 |
FR2263228B3 FR2263228B3 (en) | 1977-11-10 |
Family
ID=9879448
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR7506670A Granted FR2263228A1 (en) | 1974-03-05 | 1975-03-04 | Tetraphenyl diaminodimethyl ether - prepd. from formaldehyde and diphenylamine and use as anti-oxidant pref. in rubber |
Country Status (2)
Country | Link |
---|---|
DE (1) | DE2508602A1 (en) |
FR (1) | FR2263228A1 (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6583246B2 (en) * | 2000-11-09 | 2003-06-24 | Bayer Aktiengesellschaft | Modifiers for anionic polymerization |
-
1975
- 1975-02-27 DE DE19752508602 patent/DE2508602A1/en active Pending
- 1975-03-04 FR FR7506670A patent/FR2263228A1/en active Granted
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6583246B2 (en) * | 2000-11-09 | 2003-06-24 | Bayer Aktiengesellschaft | Modifiers for anionic polymerization |
Also Published As
Publication number | Publication date |
---|---|
DE2508602A1 (en) | 1975-09-11 |
FR2263228B3 (en) | 1977-11-10 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
ST | Notification of lapse |