FR2259839A1 - Highly active catalyst for polymerising cyclo-olefines - contg carbonyl deriv of molybdenum or tungsten, aaa ,nn, and titanium tetrachloride - Google Patents

Highly active catalyst for polymerising cyclo-olefines - contg carbonyl deriv of molybdenum or tungsten, aaa ,nn, and titanium tetrachloride

Info

Publication number
FR2259839A1
FR2259839A1 FR7403715A FR7403715A FR2259839A1 FR 2259839 A1 FR2259839 A1 FR 2259839A1 FR 7403715 A FR7403715 A FR 7403715A FR 7403715 A FR7403715 A FR 7403715A FR 2259839 A1 FR2259839 A1 FR 2259839A1
Authority
FR
France
Prior art keywords
carbonyl
cyclo
deriv
olefines
polymerising
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7403715A
Other languages
French (fr)
Other versions
FR2259839B1 (en
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IFP Energies Nouvelles IFPEN
Original Assignee
IFP Energies Nouvelles IFPEN
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IFP Energies Nouvelles IFPEN filed Critical IFP Energies Nouvelles IFPEN
Priority to FR7403715A priority Critical patent/FR2259839A1/en
Priority to IT19789/75A priority patent/IT1031321B/en
Priority to DE19752503943 priority patent/DE2503943A1/en
Priority to NL7501268A priority patent/NL7501268A/en
Priority to US05/547,032 priority patent/US4005047A/en
Priority to JP50015218A priority patent/JPS50129492A/ja
Priority to GB4737/75A priority patent/GB1502014A/en
Publication of FR2259839A1 publication Critical patent/FR2259839A1/en
Application granted granted Critical
Publication of FR2259839B1 publication Critical patent/FR2259839B1/fr
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/02—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes
    • C08G61/04—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms
    • C08G61/06—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds
    • C08G61/08—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds of carbocyclic compounds containing one or more carbon-to-carbon double bonds in the ring

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

A catalyst for polymn. of olefins, esp. cyclo-olefins, consists of (a) carbonyl or carbonyl-metal-carbene cpd. of Mo or W, and (b) TiCl4. The catalyst has high activity. (a) the carbonyl pref. has formula M(CO)yLz or Lx(CO)5-x MC(R)R', where L is an amine, ether, nitrile, ketone, pyridine, phosphine, arsine, stibine or a trihalide of P, As or Sb, M is Mo or W, R and R' and R1, OR3, SR1, NHR1 or NR1R2, where R1 and R2 are H or a hydrocarbon residue, R3 is H, a hydrocarbon residue or a quat. ammonium gp., z=0-5, y=6-zN, N is the number of polar gps. in L, and x=0 or 1. Pref., R is XR4, where X is O, S or N, R4 is an alkyl or aryl residue or a quat. ammonium gp., R' is a 1-12C alkyl or aryl residue, and L is an amine, phosphine, arsine or stibine.
FR7403715A 1974-02-04 1974-02-04 Highly active catalyst for polymerising cyclo-olefines - contg carbonyl deriv of molybdenum or tungsten, aaa ,nn, and titanium tetrachloride Granted FR2259839A1 (en)

Priority Applications (7)

Application Number Priority Date Filing Date Title
FR7403715A FR2259839A1 (en) 1974-02-04 1974-02-04 Highly active catalyst for polymerising cyclo-olefines - contg carbonyl deriv of molybdenum or tungsten, aaa ,nn, and titanium tetrachloride
IT19789/75A IT1031321B (en) 1974-02-04 1975-01-31 CATALYTIC COMPOSITION AND ITS UTI LIZATION FOR THE POLYM ERUPTION OF CYCLOOSEFINS
DE19752503943 DE2503943A1 (en) 1974-02-04 1975-01-31 NEW CATALYTIC COMPOSITION AND ITS USE FOR THE POLYMERIZATION OF CYCLOOLEFINS
NL7501268A NL7501268A (en) 1974-02-04 1975-02-03 PROCEDURE FOR PREPARING A NEW CATALY COMPOSITION AND ITS APPLICATION POLYMERIZATION OF CYCLIC ALKENES.
US05/547,032 US4005047A (en) 1974-02-04 1975-02-04 Catalytic composition and its use for polymerizing cycloolefins
JP50015218A JPS50129492A (en) 1974-02-04 1975-02-04
GB4737/75A GB1502014A (en) 1974-02-04 1975-02-04 Cyclo-olefin polymerization catalysts and their use

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR7403715A FR2259839A1 (en) 1974-02-04 1974-02-04 Highly active catalyst for polymerising cyclo-olefines - contg carbonyl deriv of molybdenum or tungsten, aaa ,nn, and titanium tetrachloride

Publications (2)

Publication Number Publication Date
FR2259839A1 true FR2259839A1 (en) 1975-08-29
FR2259839B1 FR2259839B1 (en) 1977-06-10

Family

ID=9134460

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7403715A Granted FR2259839A1 (en) 1974-02-04 1974-02-04 Highly active catalyst for polymerising cyclo-olefines - contg carbonyl deriv of molybdenum or tungsten, aaa ,nn, and titanium tetrachloride

Country Status (1)

Country Link
FR (1) FR2259839A1 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0364661A2 (en) * 1988-10-17 1990-04-25 Hercules Incorporated Improved metathesis catalyst system for the polymerization of dicyclopentadiene

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0364661A2 (en) * 1988-10-17 1990-04-25 Hercules Incorporated Improved metathesis catalyst system for the polymerization of dicyclopentadiene
EP0364661A3 (en) * 1988-10-17 1990-12-05 Hercules Incorporated Improved metathesis catalyst system for the polymerization of dicyclopentadiene

Also Published As

Publication number Publication date
FR2259839B1 (en) 1977-06-10

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