FR2248309A1 - Rubbers made adhesive with phenolic resins - e.g. phenol-diene-phenol, poly-(phenol-diene) phenol diene-olefine and phenol-terpene resins - Google Patents

Rubbers made adhesive with phenolic resins - e.g. phenol-diene-phenol, poly-(phenol-diene) phenol diene-olefine and phenol-terpene resins

Info

Publication number
FR2248309A1
FR2248309A1 FR7435378A FR7435378A FR2248309A1 FR 2248309 A1 FR2248309 A1 FR 2248309A1 FR 7435378 A FR7435378 A FR 7435378A FR 7435378 A FR7435378 A FR 7435378A FR 2248309 A1 FR2248309 A1 FR 2248309A1
Authority
FR
France
Prior art keywords
phenol
mol
diene
reacting
prepd
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7435378A
Other languages
French (fr)
Other versions
FR2248309B1 (en
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
3M Co
Original Assignee
Minnesota Mining and Manufacturing Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US05/408,592 external-priority patent/US4032486A/en
Priority claimed from US05/408,591 external-priority patent/US3976606A/en
Priority claimed from US408590A external-priority patent/US3927239A/en
Priority claimed from US05/408,584 external-priority patent/US3944523A/en
Application filed by Minnesota Mining and Manufacturing Co filed Critical Minnesota Mining and Manufacturing Co
Publication of FR2248309A1 publication Critical patent/FR2248309A1/en
Application granted granted Critical
Publication of FR2248309B1 publication Critical patent/FR2248309B1/fr
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/02—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J109/00—Adhesives based on homopolymers or copolymers of conjugated diene hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
    • C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
    • C08L2666/14—Macromolecular compounds according to C08L59/00 - C08L87/00; Derivatives thereof

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)
  • Polyurethanes Or Polyureas (AREA)

Abstract

Adhesive compsns. which readily adhere to surfaces on application of very little or no pressure contain a non-adhesive rubber and a phenoplast adhesive consisting of: (I) pheno-diene-phenol adduct having mol.wt. >=400, prepd. by reacting 1 mol non-conjugated diene with 2 mole phenolic cpd. having only one ring-C capable of alkylation; (II) poly-(phenol-diene)-resin, having alternating diene and phenol units, vitreous transition temp. 100-220 degrees C, no.av.mol. wt. 600-5000, prepd. by reacting 1 mol non-conjugated diene with 1.75 mol phenolic cpd. having >=2 ring-C capable of alkylation; (III) phenol-diene-olefine resin having no.av. mol. wt. 600-6000 and prepd. by first reacting 2 mol phenol with 1 mol non-conjugated diene and reacting prod. with 1-4 mol olefin; and (IV) terpene-phenolic resin having av.no.mol.wt. 400-3500, and prepd. by reacting 2-4 mol terpene with 1 mol cpd. contg. >=2 phenolic gps., each of which has at least 1 free ortho- or para-position for alkylation by terpene. Reactions are carried out in an inert atmos. in presence of a Friedel-Crafts catalyst, at 20-130 degrees C. Compsns. are useful as pressure-sensitive adhesives applied to articles having several surfaces requiring bonding; adhesive strips; non-slip safety sheets for floors, stairs and/or bathroom floors or bath-tubs.
FR7435378A 1973-10-23 1974-10-22 Rubbers made adhesive with phenolic resins - e.g. phenol-diene-phenol, poly-(phenol-diene) phenol diene-olefine and phenol-terpene resins Granted FR2248309A1 (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US05/408,592 US4032486A (en) 1973-10-23 1973-10-23 Adhesives tackified with phenol-diene-olefin adducts having number average molecular weight between about 600 to 6000
US05/408,591 US3976606A (en) 1973-10-23 1973-10-23 Adhesives tackified with low molecular weight terpene-phenolic resins
US408590A US3927239A (en) 1973-10-23 1973-10-23 Flexible strip coated with a pressure-sensitive adhesive composition tackified with phenol-diene-phenol resin adduct
US05/408,584 US3944523A (en) 1973-10-23 1973-10-23 Poly(phenol/diene) resin and rubber adhesive compositions tackified therewith

Publications (2)

Publication Number Publication Date
FR2248309A1 true FR2248309A1 (en) 1975-05-16
FR2248309B1 FR2248309B1 (en) 1978-08-11

Family

ID=27503555

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7435378A Granted FR2248309A1 (en) 1973-10-23 1974-10-22 Rubbers made adhesive with phenolic resins - e.g. phenol-diene-phenol, poly-(phenol-diene) phenol diene-olefine and phenol-terpene resins

Country Status (5)

Country Link
JP (1) JPS5073926A (en)
DE (1) DE2450590A1 (en)
FR (1) FR2248309A1 (en)
IT (1) IT1021886B (en)
SE (1) SE7412816L (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2350374A1 (en) * 1976-05-04 1977-12-02 Neville Chemical Co ANTIOXIDANTS FOR RUBBER MIXTURES, BASED ON PHENOLIC COMPOUNDS AND DICYCLOPENTADIENE, AND THEIR PREPARATION METHODS
EP0075771A1 (en) * 1981-09-25 1983-04-06 Bayer Ag Phenols, process for their production and their use as stabilizers for polymers
EP0209956A1 (en) * 1985-07-26 1987-01-28 Dsm Resins B.V. Hydrogenated hydrocarbon resins and their use in adhesives and coatings
EP0240762A1 (en) * 1986-03-13 1987-10-14 Hercules Incorporated Vinyl aromatic/terpene/phenol/terpolymers
EP0444275A1 (en) * 1990-02-27 1991-09-04 Bayer Ag Use of certain phenolic resins for the reinforcement of rubber vulcanisates
WO2002048221A1 (en) * 2000-12-11 2002-06-20 Eastman Chemical Resins, Inc. Thermally polymerized copolymers made from styrene and dicyclopentadiene monomers

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3842344A1 (en) * 1988-12-16 1990-06-21 Beiersdorf Ag Aqueous contact adhesive dispersion
JP7317807B2 (en) * 2018-04-24 2023-07-31 Ｅｎｅｏｓ株式会社 Rubber additive, uncrosslinked rubber composition, crosslinked rubber and tire
EP3862376A1 (en) 2020-02-07 2021-08-11 Rain Carbon Germany GmbH Tackifier for elastomer compounds

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2350374A1 (en) * 1976-05-04 1977-12-02 Neville Chemical Co ANTIOXIDANTS FOR RUBBER MIXTURES, BASED ON PHENOLIC COMPOUNDS AND DICYCLOPENTADIENE, AND THEIR PREPARATION METHODS
EP0075771A1 (en) * 1981-09-25 1983-04-06 Bayer Ag Phenols, process for their production and their use as stabilizers for polymers
EP0209956A1 (en) * 1985-07-26 1987-01-28 Dsm Resins B.V. Hydrogenated hydrocarbon resins and their use in adhesives and coatings
EP0240762A1 (en) * 1986-03-13 1987-10-14 Hercules Incorporated Vinyl aromatic/terpene/phenol/terpolymers
EP0444275A1 (en) * 1990-02-27 1991-09-04 Bayer Ag Use of certain phenolic resins for the reinforcement of rubber vulcanisates
US5214100A (en) * 1990-02-27 1993-05-25 Bayer Aktiengesellschaft Use of certain phenolic resins for reinforcing rubber vulcanizates
WO2002048221A1 (en) * 2000-12-11 2002-06-20 Eastman Chemical Resins, Inc. Thermally polymerized copolymers made from styrene and dicyclopentadiene monomers
EP2251364A1 (en) * 2000-12-11 2010-11-17 Eastman Chemical Resins, Inc. Process for producing copolymers made from styrene and dicyclopentadiene monomers

Also Published As

Publication number Publication date
FR2248309B1 (en) 1978-08-11
JPS5073926A (en) 1975-06-18
IT1021886B (en) 1978-02-20
DE2450590A1 (en) 1975-04-30
SE7412816L (en) 1975-04-24

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Legal Events

Date Code Title Description
ST Notification of lapse