FR2213928A1 - 2-Aryloxypropanal perfume chemicals and inters - by rhodium-catalysed hydroformylation of aryl vinyl ethers - Google Patents

2-Aryloxypropanal perfume chemicals and inters - by rhodium-catalysed hydroformylation of aryl vinyl ethers

Info

Publication number
FR2213928A1
FR2213928A1 FR7400802A FR7400802A FR2213928A1 FR 2213928 A1 FR2213928 A1 FR 2213928A1 FR 7400802 A FR7400802 A FR 7400802A FR 7400802 A FR7400802 A FR 7400802A FR 2213928 A1 FR2213928 A1 FR 2213928A1
Authority
FR
France
Prior art keywords
aryloxypropanal
inters
rhodium
vinyl ethers
aryl vinyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
FR7400802A
Other languages
French (fr)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Publication of FR2213928A1 publication Critical patent/FR2213928A1/en
Withdrawn legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22Organic complexes
    • B01J31/2282Unsaturated compounds used as ligands
    • B01J31/2295Cyclic compounds, e.g. cyclopentadienyls
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/20Carbonyls
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C47/00Compounds having —CHO groups
    • C07C47/20Unsaturated compounds having —CHO groups bound to acyclic carbon atoms
    • C07C47/277Unsaturated compounds having —CHO groups bound to acyclic carbon atoms containing ether groups, groups, groups, or groups
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D307/00Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/77Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom ortho- or peri-condensed with carbocyclic rings or ring systems
    • C07D307/91Dibenzofurans; Hydrogenated dibenzofurans
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32Addition reactions to C=C or C-C triple bonds
    • B01J2231/321Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82Metals of the platinum group
    • B01J2531/822Rhodium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Furan Compounds (AREA)
  • Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)

Abstract

Title cpds of formula AOCH(CH3)CHO (I) (where A is aryl, pref. Ph opt. substd by 1-3 alkyl of 1-4C, 1-4C alkoxy cyclohexyl, Cl, 7-10C aralkyl Ph, are prepd by heating AOCH=CH2 with a large excess of CO/H2 at 50-150 degrees and 20-1500 atmos, in the presence of 0.001 ppm -0.5% Rh in the form of a carbonyl complex (pref. formed in situ). Cpds (I) and the derived alcohols and esters are perfumery chemicals the derived amines are analgesics, spasmolytics, anti-inflammatories, diuretics and hypotensives. (I) also have fungicidal props.
FR7400802A 1973-01-16 1974-01-10 2-Aryloxypropanal perfume chemicals and inters - by rhodium-catalysed hydroformylation of aryl vinyl ethers Withdrawn FR2213928A1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19732301940 DE2301940A1 (en) 1973-01-16 1973-01-16 2-ARYLOXYPROPANALE- (1) AND A PROCESS FOR THEIR PRODUCTION

Publications (1)

Publication Number Publication Date
FR2213928A1 true FR2213928A1 (en) 1974-08-09

Family

ID=5869094

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7400802A Withdrawn FR2213928A1 (en) 1973-01-16 1974-01-10 2-Aryloxypropanal perfume chemicals and inters - by rhodium-catalysed hydroformylation of aryl vinyl ethers

Country Status (5)

Country Link
JP (1) JPS49108033A (en)
BE (1) BE809718A (en)
DE (1) DE2301940A1 (en)
FR (1) FR2213928A1 (en)
NL (1) NL7400584A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1288186A2 (en) * 2001-08-30 2003-03-05 Daicel Chemical Industries, Ltd. Vinyl ether compounds and preparation process thereof

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1288186A2 (en) * 2001-08-30 2003-03-05 Daicel Chemical Industries, Ltd. Vinyl ether compounds and preparation process thereof
EP1288186A3 (en) * 2001-08-30 2003-09-17 Daicel Chemical Industries, Ltd. Vinyl ether compounds and preparation process thereof
US7074970B2 (en) 2001-08-30 2006-07-11 Daicel Chemical Industries, Ltd. Process for producing vinyl ether compounds
EP1826196A2 (en) * 2001-08-30 2007-08-29 Daicel Chemical Industries, Ltd. Vinyl ether compounds
US7271297B2 (en) 2001-08-30 2007-09-18 Daicel Chemical Industries, Ltd. Process for producing vinyl ether compounds
EP1826196A3 (en) * 2001-08-30 2007-11-14 Daicel Chemical Industries, Ltd. Vinyl ether compounds

Also Published As

Publication number Publication date
NL7400584A (en) 1974-07-18
JPS49108033A (en) 1974-10-14
BE809718A (en) 1974-07-15
DE2301940A1 (en) 1974-08-01

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Legal Events

Date Code Title Description
RE Withdrawal of published application