FR2213928A1 - 2-Aryloxypropanal perfume chemicals and inters - by rhodium-catalysed hydroformylation of aryl vinyl ethers - Google Patents
2-Aryloxypropanal perfume chemicals and inters - by rhodium-catalysed hydroformylation of aryl vinyl ethersInfo
- Publication number
- FR2213928A1 FR2213928A1 FR7400802A FR7400802A FR2213928A1 FR 2213928 A1 FR2213928 A1 FR 2213928A1 FR 7400802 A FR7400802 A FR 7400802A FR 7400802 A FR7400802 A FR 7400802A FR 2213928 A1 FR2213928 A1 FR 2213928A1
- Authority
- FR
- France
- Prior art keywords
- aryloxypropanal
- inters
- rhodium
- vinyl ethers
- aryl vinyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2282—Unsaturated compounds used as ligands
- B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/20—Carbonyls
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C47/00—Compounds having —CHO groups
- C07C47/20—Unsaturated compounds having —CHO groups bound to acyclic carbon atoms
- C07C47/277—Unsaturated compounds having —CHO groups bound to acyclic carbon atoms containing ether groups, groups, groups, or groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
- C07D307/77—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom ortho- or peri-condensed with carbocyclic rings or ring systems
- C07D307/91—Dibenzofurans; Hydrogenated dibenzofurans
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
- B01J2231/32—Addition reactions to C=C or C-C triple bonds
- B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/822—Rhodium
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Furan Compounds (AREA)
- Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
Abstract
Title cpds of formula AOCH(CH3)CHO (I) (where A is aryl, pref. Ph opt. substd by 1-3 alkyl of 1-4C, 1-4C alkoxy cyclohexyl, Cl, 7-10C aralkyl Ph, are prepd by heating AOCH=CH2 with a large excess of CO/H2 at 50-150 degrees and 20-1500 atmos, in the presence of 0.001 ppm -0.5% Rh in the form of a carbonyl complex (pref. formed in situ). Cpds (I) and the derived alcohols and esters are perfumery chemicals the derived amines are analgesics, spasmolytics, anti-inflammatories, diuretics and hypotensives. (I) also have fungicidal props.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19732301940 DE2301940A1 (en) | 1973-01-16 | 1973-01-16 | 2-ARYLOXYPROPANALE- (1) AND A PROCESS FOR THEIR PRODUCTION |
Publications (1)
Publication Number | Publication Date |
---|---|
FR2213928A1 true FR2213928A1 (en) | 1974-08-09 |
Family
ID=5869094
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR7400802A Withdrawn FR2213928A1 (en) | 1973-01-16 | 1974-01-10 | 2-Aryloxypropanal perfume chemicals and inters - by rhodium-catalysed hydroformylation of aryl vinyl ethers |
Country Status (5)
Country | Link |
---|---|
JP (1) | JPS49108033A (en) |
BE (1) | BE809718A (en) |
DE (1) | DE2301940A1 (en) |
FR (1) | FR2213928A1 (en) |
NL (1) | NL7400584A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1288186A2 (en) * | 2001-08-30 | 2003-03-05 | Daicel Chemical Industries, Ltd. | Vinyl ether compounds and preparation process thereof |
-
1973
- 1973-01-16 DE DE19732301940 patent/DE2301940A1/en active Pending
-
1974
- 1974-01-10 FR FR7400802A patent/FR2213928A1/en not_active Withdrawn
- 1974-01-14 BE BE139786A patent/BE809718A/en unknown
- 1974-01-16 NL NL7400584A patent/NL7400584A/xx unknown
- 1974-01-16 JP JP49007174A patent/JPS49108033A/ja active Pending
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1288186A2 (en) * | 2001-08-30 | 2003-03-05 | Daicel Chemical Industries, Ltd. | Vinyl ether compounds and preparation process thereof |
EP1288186A3 (en) * | 2001-08-30 | 2003-09-17 | Daicel Chemical Industries, Ltd. | Vinyl ether compounds and preparation process thereof |
US7074970B2 (en) | 2001-08-30 | 2006-07-11 | Daicel Chemical Industries, Ltd. | Process for producing vinyl ether compounds |
EP1826196A2 (en) * | 2001-08-30 | 2007-08-29 | Daicel Chemical Industries, Ltd. | Vinyl ether compounds |
US7271297B2 (en) | 2001-08-30 | 2007-09-18 | Daicel Chemical Industries, Ltd. | Process for producing vinyl ether compounds |
EP1826196A3 (en) * | 2001-08-30 | 2007-11-14 | Daicel Chemical Industries, Ltd. | Vinyl ether compounds |
Also Published As
Publication number | Publication date |
---|---|
NL7400584A (en) | 1974-07-18 |
JPS49108033A (en) | 1974-10-14 |
BE809718A (en) | 1974-07-15 |
DE2301940A1 (en) | 1974-08-01 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
RE | Withdrawal of published application |