FR2185638A1 - Scale prevention in polyvinyl halide reactors - by adding oxyacids of P,N or S, or their salts - Google Patents
Scale prevention in polyvinyl halide reactors - by adding oxyacids of P,N or S, or their saltsInfo
- Publication number
- FR2185638A1 FR2185638A1 FR7318867A FR7318867A FR2185638A1 FR 2185638 A1 FR2185638 A1 FR 2185638A1 FR 7318867 A FR7318867 A FR 7318867A FR 7318867 A FR7318867 A FR 7318867A FR 2185638 A1 FR2185638 A1 FR 2185638A1
- Authority
- FR
- France
- Prior art keywords
- pref
- reactors
- salts
- scale prevention
- polyvinyl halide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F14/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F14/02—Monomers containing chlorine
- C08F14/04—Monomers containing two carbon atoms
- C08F14/06—Vinyl chloride
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
The polymers are prepd. by aq. suspension polymsn. with oil sol. catalysts (0.001-1 wt.%, pref. 0.05-5 wt.% of alpha-acyl peroxides and/or dialkyl peroxydicarbonates), dispersants e.g., cellulose ether etc., in presence of 1-2,000 ppm. (2-2,000) pref. 10-300 ppm. of water-sol. reducing agents based on water. The reactor surface has a depth of irregularities of is not >10 mu m, pref. 1 mu m and flow speed at the surface of >=0.1 m/sec., pref. 17/sec. pH is 3-8, pref. 3.5-7.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE2225236A DE2225236C3 (en) | 1972-05-24 | 1972-05-24 | Process for the polymerization of vinyl chloride |
DE19722248607 DE2248607A1 (en) | 1972-10-04 | 1972-10-04 | METHOD FOR PRODUCING POLYVINYL HALOGENIDES |
Publications (2)
Publication Number | Publication Date |
---|---|
FR2185638A1 true FR2185638A1 (en) | 1974-01-04 |
FR2185638B1 FR2185638B1 (en) | 1976-05-07 |
Family
ID=25763309
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR7318867A Granted FR2185638A1 (en) | 1972-05-24 | 1973-05-24 | Scale prevention in polyvinyl halide reactors - by adding oxyacids of P,N or S, or their salts |
FR7413362A Expired FR2230660B1 (en) | 1972-05-24 | 1974-04-17 |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR7413362A Expired FR2230660B1 (en) | 1972-05-24 | 1974-04-17 |
Country Status (5)
Country | Link |
---|---|
CH (1) | CH576491A5 (en) |
DD (1) | DD106851A5 (en) |
ES (1) | ES415009A1 (en) |
FR (2) | FR2185638A1 (en) |
IT (1) | IT985114B (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2400041A1 (en) * | 1977-08-09 | 1979-03-09 | Sumitomo Chemical Co | EQUIPMENT FOR POLYMERIZATION OF VINYL CHLORIDE MONOMERS, AND POLYMERIZATION PROCESS USING THEM |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5589315A (en) * | 1978-12-27 | 1980-07-05 | Kureha Chem Ind Co Ltd | Production of graft polymer |
ATE165845T1 (en) * | 1992-02-13 | 1998-05-15 | Europ Vinyls Corp Technology A | POLYMERIZATION PROCESS |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2062531A5 (en) * | 1969-09-24 | 1971-06-25 | Wacker Chemie Gmbh | |
FR2086635A5 (en) * | 1970-04-03 | 1971-12-31 | Pechiney Saint Gobain | Vinyl chloride polymers - by aqs emulsion polymerisation in reaction medium contg an emulsifier, org peroxide and reducing age |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
SE324767B (en) * | 1968-11-14 | 1970-06-15 | Fosfatbolaget Ab |
-
1973
- 1973-05-02 DD DD17057873A patent/DD106851A5/xx unknown
- 1973-05-22 ES ES415009A patent/ES415009A1/en not_active Expired
- 1973-05-22 IT IT5011373A patent/IT985114B/en active
- 1973-05-23 CH CH737073A patent/CH576491A5/xx not_active IP Right Cessation
- 1973-05-24 FR FR7318867A patent/FR2185638A1/en active Granted
-
1974
- 1974-04-17 FR FR7413362A patent/FR2230660B1/fr not_active Expired
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2062531A5 (en) * | 1969-09-24 | 1971-06-25 | Wacker Chemie Gmbh | |
FR2086635A5 (en) * | 1970-04-03 | 1971-12-31 | Pechiney Saint Gobain | Vinyl chloride polymers - by aqs emulsion polymerisation in reaction medium contg an emulsifier, org peroxide and reducing age |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2400041A1 (en) * | 1977-08-09 | 1979-03-09 | Sumitomo Chemical Co | EQUIPMENT FOR POLYMERIZATION OF VINYL CHLORIDE MONOMERS, AND POLYMERIZATION PROCESS USING THEM |
Also Published As
Publication number | Publication date |
---|---|
FR2185638B1 (en) | 1976-05-07 |
IT985114B (en) | 1974-11-30 |
DD106851A5 (en) | 1974-07-05 |
ES415009A1 (en) | 1976-02-16 |
CH576491A5 (en) | 1976-06-15 |
FR2230660A1 (en) | 1974-12-20 |
FR2230660B1 (en) | 1977-07-15 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
ST | Notification of lapse |