FR2180152A6 - 1,5-dimethyl-1,5-hexadienylidene sulphone derivs - - intermediates for terpenes - Google Patents

1,5-dimethyl-1,5-hexadienylidene sulphone derivs - - intermediates for terpenes

Info

Publication number
FR2180152A6
FR2180152A6 FR7212477A FR7212477A FR2180152A6 FR 2180152 A6 FR2180152 A6 FR 2180152A6 FR 7212477 A FR7212477 A FR 7212477A FR 7212477 A FR7212477 A FR 7212477A FR 2180152 A6 FR2180152 A6 FR 2180152A6
Authority
FR
France
Prior art keywords
opt
substd
gps
alkyl
functional
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
FR7212477A
Other languages
French (fr)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Rhone Poulenc SA
Original Assignee
Rhone Poulenc SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to BE794872D priority Critical patent/BE794872A/en
Application filed by Rhone Poulenc SA filed Critical Rhone Poulenc SA
Priority to FR7212477A priority patent/FR2180152A6/en
Priority to IT34006/72A priority patent/IT982381B/en
Priority to NL737301103A priority patent/NL152530B/en
Priority to JP1279073A priority patent/JPS5323827B2/ja
Priority to CH9675A priority patent/CH570977A5/xx
Priority to CA162,696A priority patent/CA994796A/en
Priority to US05/328,537 priority patent/US4331814A/en
Priority to DE2305267A priority patent/DE2305267C3/en
Priority to DD168635A priority patent/DD107447A5/xx
Priority to DD178212*A priority patent/DD112991A5/xx
Priority to GB536773A priority patent/GB1396622A/en
Application granted granted Critical
Publication of FR2180152A6 publication Critical patent/FR2180152A6/en
Priority to SU1998403A priority patent/SU506291A3/en
Priority to US06/345,927 priority patent/US4474983A/en
Priority to US06/345,748 priority patent/US4433171A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C403/00—Derivatives of cyclohexane or of a cyclohexene or of cyclohexadiene, having a side-chain containing an acyclic unsaturated part of at least four carbon atoms, this part being directly attached to the cyclohexane or cyclohexene or cyclohexadiene rings, e.g. vitamin A, beta-carotene, beta-ionone
    • C07C403/24—Derivatives of cyclohexane or of a cyclohexene or of cyclohexadiene, having a side-chain containing an acyclic unsaturated part of at least four carbon atoms, this part being directly attached to the cyclohexane or cyclohexene or cyclohexadiene rings, e.g. vitamin A, beta-carotene, beta-ionone having side-chains substituted by six-membered non-aromatic rings, e.g. beta-carotene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C317/00—Sulfones; Sulfoxides
    • C07C317/14—Sulfones; Sulfoxides having sulfone or sulfoxide groups bound to carbon atoms of six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C317/00—Sulfones; Sulfoxides
    • C07C317/16—Sulfones; Sulfoxides having sulfone or sulfoxide groups and singly-bound oxygen atoms bound to the same carbon skeleton
    • C07C317/18—Sulfones; Sulfoxides having sulfone or sulfoxide groups and singly-bound oxygen atoms bound to the same carbon skeleton with sulfone or sulfoxide groups bound to acyclic carbon atoms of the carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C317/00—Sulfones; Sulfoxides
    • C07C317/44—Sulfones; Sulfoxides having sulfone or sulfoxide groups and carboxyl groups bound to the same carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C403/00—Derivatives of cyclohexane or of a cyclohexene or of cyclohexadiene, having a side-chain containing an acyclic unsaturated part of at least four carbon atoms, this part being directly attached to the cyclohexane or cyclohexene or cyclohexadiene rings, e.g. vitamin A, beta-carotene, beta-ionone
    • C07C403/06—Derivatives of cyclohexane or of a cyclohexene or of cyclohexadiene, having a side-chain containing an acyclic unsaturated part of at least four carbon atoms, this part being directly attached to the cyclohexane or cyclohexene or cyclohexadiene rings, e.g. vitamin A, beta-carotene, beta-ionone having side-chains substituted by singly-bound oxygen atoms
    • C07C403/08—Derivatives of cyclohexane or of a cyclohexene or of cyclohexadiene, having a side-chain containing an acyclic unsaturated part of at least four carbon atoms, this part being directly attached to the cyclohexane or cyclohexene or cyclohexadiene rings, e.g. vitamin A, beta-carotene, beta-ionone having side-chains substituted by singly-bound oxygen atoms by hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C403/00—Derivatives of cyclohexane or of a cyclohexene or of cyclohexadiene, having a side-chain containing an acyclic unsaturated part of at least four carbon atoms, this part being directly attached to the cyclohexane or cyclohexene or cyclohexadiene rings, e.g. vitamin A, beta-carotene, beta-ionone
    • C07C403/06—Derivatives of cyclohexane or of a cyclohexene or of cyclohexadiene, having a side-chain containing an acyclic unsaturated part of at least four carbon atoms, this part being directly attached to the cyclohexane or cyclohexene or cyclohexadiene rings, e.g. vitamin A, beta-carotene, beta-ionone having side-chains substituted by singly-bound oxygen atoms
    • C07C403/12—Derivatives of cyclohexane or of a cyclohexene or of cyclohexadiene, having a side-chain containing an acyclic unsaturated part of at least four carbon atoms, this part being directly attached to the cyclohexane or cyclohexene or cyclohexadiene rings, e.g. vitamin A, beta-carotene, beta-ionone having side-chains substituted by singly-bound oxygen atoms by esterified hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C403/00—Derivatives of cyclohexane or of a cyclohexene or of cyclohexadiene, having a side-chain containing an acyclic unsaturated part of at least four carbon atoms, this part being directly attached to the cyclohexane or cyclohexene or cyclohexadiene rings, e.g. vitamin A, beta-carotene, beta-ionone
    • C07C403/22—Derivatives of cyclohexane or of a cyclohexene or of cyclohexadiene, having a side-chain containing an acyclic unsaturated part of at least four carbon atoms, this part being directly attached to the cyclohexane or cyclohexene or cyclohexadiene rings, e.g. vitamin A, beta-carotene, beta-ionone having side-chains substituted by sulfur atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/16—Systems containing only non-condensed rings with a six-membered ring the ring being unsaturated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Title cpds. of the formula: (where -SO2R is situated on one of the two secondary C atoms, R = alkyl, alkenyl, aralkyl, alkaryl or aryl all opt. substd by electron attracting or donating gps, A = (5n+1) C hydrocarbon opt. ethylenically or acetylenically unsatd or polyunsatd and opt. conjugated and opt. substd by functional gps. or by alkyl gps. n = 1 to 5, and when n >=2. A may be cyclic and also opt. substd by alkyl or by functional gps such opt protected =O or -OH or A may be a functional gp. as for Q, opt. different, Q = methyl opt. substd by halogen, -SR', -CH2OH and its ethers or esters, opt. protected aldehyde, carboxy or its acid chloride, esters or nitrile to hydrocarbyl as for A, R'=R (the same or different).
FR7212477A 1972-02-02 1972-04-10 1,5-dimethyl-1,5-hexadienylidene sulphone derivs - - intermediates for terpenes Expired FR2180152A6 (en)

Priority Applications (15)

Application Number Priority Date Filing Date Title
BE794872D BE794872A (en) 1972-02-02 NEW SULPHONES DERIVED FROM DIMETHYL-1,5 HEXADIENE-1,5 YLENE
FR7212477A FR2180152A6 (en) 1972-04-10 1972-04-10 1,5-dimethyl-1,5-hexadienylidene sulphone derivs - - intermediates for terpenes
IT34006/72A IT982381B (en) 1972-02-02 1972-12-29 SULPHONES DERIVED FROM DIMETHYL I 5 HEXADIEN I 5 ILENE
NL737301103A NL152530B (en) 1972-02-02 1973-01-25 PROCESS FOR THE PREPARATION OF POLYENE COMPOUNDS.
JP1279073A JPS5323827B2 (en) 1972-02-02 1973-01-31
CA162,696A CA994796A (en) 1972-02-02 1973-02-01 Dimethyl-1,5 hexadiene-1,5 ylene sulfone derivatives
CH9675A CH570977A5 (en) 1972-04-10 1973-02-01
US05/328,537 US4331814A (en) 1972-02-02 1973-02-01 Sulphones having a 1,5-dimethyl-hexa-1,5-dienylene group
DE2305267A DE2305267C3 (en) 1972-02-02 1973-02-02 Polyenic sulfones and process for their preparation
DD168635A DD107447A5 (en) 1972-02-02 1973-02-02
DD178212*A DD112991A5 (en) 1972-04-10 1973-02-02
GB536773A GB1396622A (en) 1972-02-02 1973-02-02 Sulphones having a 1,5-dimethyl-hexa-1,5-dienylene group
SU1998403A SU506291A3 (en) 1972-04-10 1974-02-19 The method of producing sulfones
US06/345,927 US4474983A (en) 1972-02-02 1982-02-04 Process for preparing compounds having a 1,5-dimethyl-hexa-1,5-dienylene group by desulphonylation of a corresponding sulphone
US06/345,748 US4433171A (en) 1972-02-02 1982-02-04 Sulphones having a 1,5-dimethyl-hexa-1,5-dienylene group

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR7212477A FR2180152A6 (en) 1972-04-10 1972-04-10 1,5-dimethyl-1,5-hexadienylidene sulphone derivs - - intermediates for terpenes

Publications (1)

Publication Number Publication Date
FR2180152A6 true FR2180152A6 (en) 1973-11-23

Family

ID=9096582

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7212477A Expired FR2180152A6 (en) 1972-02-02 1972-04-10 1,5-dimethyl-1,5-hexadienylidene sulphone derivs - - intermediates for terpenes

Country Status (4)

Country Link
CH (1) CH570977A5 (en)
DD (1) DD112991A5 (en)
FR (1) FR2180152A6 (en)
SU (1) SU506291A3 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2573074A1 (en) * 1984-11-13 1986-05-16 Rhone Poulenc Sante Process for the preparation of retinonitrile

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2573074A1 (en) * 1984-11-13 1986-05-16 Rhone Poulenc Sante Process for the preparation of retinonitrile

Also Published As

Publication number Publication date
DD112991A5 (en) 1975-05-12
SU506291A3 (en) 1976-03-05
CH570977A5 (en) 1975-12-31

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