FR2137320A1 - Hydrocarbon conversion catalyst contg germanium - and a platinum-group metal - uniformly distributed in a support - Google Patents

Hydrocarbon conversion catalyst contg germanium - and a platinum-group metal - uniformly distributed in a support

Info

Publication number
FR2137320A1
FR2137320A1 FR7118011A FR7118011A FR2137320A1 FR 2137320 A1 FR2137320 A1 FR 2137320A1 FR 7118011 A FR7118011 A FR 7118011A FR 7118011 A FR7118011 A FR 7118011A FR 2137320 A1 FR2137320 A1 FR 2137320A1
Authority
FR
France
Prior art keywords
soln
pref
group metal
hydrocarbon conversion
support
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7118011A
Other languages
French (fr)
Other versions
FR2137320B1 (en
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Universal Oil Products Co
Original Assignee
Universal Oil Products Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Universal Oil Products Co filed Critical Universal Oil Products Co
Priority to FR7118011A priority Critical patent/FR2137320A1/en
Publication of FR2137320A1 publication Critical patent/FR2137320A1/en
Application granted granted Critical
Publication of FR2137320B1 publication Critical patent/FR2137320B1/fr
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G35/00—Reforming naphtha
    • C10G35/04—Catalytic reforming
    • C10G35/06—Catalytic reforming characterised by the catalyst used
    • C10G35/085—Catalytic reforming characterised by the catalyst used containing platinum group metals or compounds thereof
    • C10G35/09—Bimetallic catalysts in which at least one of the metals is a platinum group metal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/62—Platinum group metals with gallium, indium, thallium, germanium, tin or lead
    • B01J23/622—Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

A composite catalyst, esp. for hydrocarbon conversion, contg. at Pt-group constit. and a Ge constit. uniformly dispersed in a support, is produced by (a) dissolving GeCl4 in an anhydrous alcohol, pref. EtOH or iProH; (b) treating the soln. to establish an equilibrium state, pref. by ageing for 1-4 days at ambient temp. or for 1-5 hrs. at 70 degrees C; (c) mixing the soln. with an aq. soln. of a decomposable, water soluble Pt-group metal cpd., pref H2PtCl6 in aqs. HCl, to form a soln. free from ppte; (d) impregnating a porous support material with a high specific surface, pref Al2O3, with soln.; and (e) drying and calcining; and opt. (f) reducing with dry H2 at 427-593 degrees C and sulphurising to introduce 0.05-0.5 wt.%S. The catalyst pref. contains 0.01-5 wt.% Ge 0.01-2 wt.% Pt and 0.5 - 4% Cl. The ageing treatment avoids the pptn. GeO2.
FR7118011A 1971-05-18 1971-05-18 Hydrocarbon conversion catalyst contg germanium - and a platinum-group metal - uniformly distributed in a support Granted FR2137320A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
FR7118011A FR2137320A1 (en) 1971-05-18 1971-05-18 Hydrocarbon conversion catalyst contg germanium - and a platinum-group metal - uniformly distributed in a support

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR7118011A FR2137320A1 (en) 1971-05-18 1971-05-18 Hydrocarbon conversion catalyst contg germanium - and a platinum-group metal - uniformly distributed in a support

Publications (2)

Publication Number Publication Date
FR2137320A1 true FR2137320A1 (en) 1972-12-29
FR2137320B1 FR2137320B1 (en) 1973-05-11

Family

ID=9077251

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7118011A Granted FR2137320A1 (en) 1971-05-18 1971-05-18 Hydrocarbon conversion catalyst contg germanium - and a platinum-group metal - uniformly distributed in a support

Country Status (1)

Country Link
FR (1) FR2137320A1 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2670132A1 (en) * 1990-12-10 1992-06-12 Inst Francais Du Petrole CATALYST BASED ON CHLORINATED ALUMINA AND ITS USE IN ISOMERIZATION OF NORMAL C4-C6 PARAFFINS

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2670132A1 (en) * 1990-12-10 1992-06-12 Inst Francais Du Petrole CATALYST BASED ON CHLORINATED ALUMINA AND ITS USE IN ISOMERIZATION OF NORMAL C4-C6 PARAFFINS
WO1992010289A1 (en) * 1990-12-10 1992-06-25 Institut Français Du Petrole Chlorinated alumina-based catalyst and its use in normal c4-c6 paraffins
US5446230A (en) * 1990-12-10 1995-08-29 Institut Francais Du Petrole Chlorinated, alumina-based, bimetallic catalyst and its use in the isomerization of C4 -C6 paraffins

Also Published As

Publication number Publication date
FR2137320B1 (en) 1973-05-11

Similar Documents

Publication Publication Date Title
AT248011B (en) Process for producing gas mixtures, catalyst for carrying out this process and process for producing the catalyst
ES431446A1 (en) Expanding tobacco
NO141594C (en) USE OF LARGE SURFACE CATALYSTS AND EXISTING ACTIVE AL203 AND YTTRIUM, LANTAN OR LANTANOID COMPOUNDS FOR THE CLAUS REACTION TREATMENT
CH413247A (en) Process and device for the production of flat glass, as well as flat gas produced according to the process
ZA718019B (en) Process for the preparation of catalysts and/or acceptors
GB1488154A (en) Platinum reforming catalysts
CH544126A (en) Dry, extrudable mixture and use thereof for the production of moldings
NL179024C (en) COMPOSITION OF BEDPAN AND SUPPORT.
IT962171B (en) PROCESS AND PLANT FOR THE IMPREGNATION OF TIMBER
NL160207C (en) ISOTHERM TANK INCLUDED IN THE CARRYING CONSTRUCTION OF A SHIP.
FR2137320A1 (en) Hydrocarbon conversion catalyst contg germanium - and a platinum-group metal - uniformly distributed in a support
AT354403B (en) METHOD FOR PRODUCING STABILIZED, BROMIC-CONTAINING AQUEOUS SOLUTIONS AND MEANS FOR IMPLEMENTING THE METHOD
NL7508219A (en) PROCEDURE FOR WINNING HYDROGEN AND OXYGEN BY SPLITTING WATER.
AU3454771A (en) Catalytic treatment of exhaust gases
BR7202024D0 (en) DEPROPORTING PROCESS OF UNSATURATED CATALYST COMPOUNDS USED IN THE PROCESS
AT309944B (en) Aqueous solutions for the chemical surface treatment of metals and solid mixtures for the production of these solutions
IT7822868A0 (en) CATALYST AND PROCESS FOR THE ISOMERIZATION OF NORMAL-PARAFFINS AND HYDROCARBONS SUBJECTED TO THE SAID PROCESS.
IT1003177B (en) PROCEDURE FOR THE CATALYTIC HYDROGENATION OF UNSATURATED COMPOUNDS AND CATALYST THAT CAN BE USED IN THE SAID PROCEDURE
ES435551A1 (en) Carrier-supported catalyst
NL7512869A (en) IMPROVEMENTS IN AND RELATING TO THE EXTRACTION OF CARBON WITH HYDROGEN.
AR218204A1 (en) METHOD FOR THE PURGE OF CATALYTIC AGENT
FR2202146A2 (en) Washing platinum, germanium, rhenium, alumina catalysts - with water to regulate their chlorine content and increase their hydrocarbon conversion activity
AT305219B (en) Process for the production of metal-containing support materials, in particular supported catalysts
IT1017882B (en) PROCESS OF CATALYTIC HYDROCRACKING AND CATALYST TO BE USED IN THE PROCESS
BR7107800D0 (en) PROCESS TO EXTEND THE LIFE OF CATALYSTS USED IN GAS OR STEAM OXIDATION PROCESSES

Legal Events

Date Code Title Description
ST Notification of lapse