FR2108766A1 - Bulk (co)polymerisation of propylene - in presence of a three-component catalyst - Google Patents
Bulk (co)polymerisation of propylene - in presence of a three-component catalystInfo
- Publication number
- FR2108766A1 FR2108766A1 FR7035660A FR7035660A FR2108766A1 FR 2108766 A1 FR2108766 A1 FR 2108766A1 FR 7035660 A FR7035660 A FR 7035660A FR 7035660 A FR7035660 A FR 7035660A FR 2108766 A1 FR2108766 A1 FR 2108766A1
- Authority
- FR
- France
- Prior art keywords
- propylene
- component catalyst
- polymerisation
- bulk
- alkyls
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/04—Monomers containing three or four carbon atoms
- C08F10/06—Propene
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
Propylene is (co)polymerised, at 80 degrees C., in presence of a three-component catalyst system comprising TiCl3 or TiCl3.1/3Al.Cl3; and a trialkyl-Al or dialkyl-cpd. (alkyls have 1-4C, halogen is Br or Cl); and a polyethylene glycoldialkyl ether or polyethylene thioglycol dialkylthioether (ether has 2-5 ethylene units, alkyls have 1-4C). No solvent is present. The product has high bulk density. No costs arising from solvent loss or recovery. Catalyst easily removed. Any atactic polymer present does not impair mech. or physical props. of the atactic polymer.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR7035660A FR2108766A1 (en) | 1970-10-02 | 1970-10-02 | Bulk (co)polymerisation of propylene - in presence of a three-component catalyst |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR7035660A FR2108766A1 (en) | 1970-10-02 | 1970-10-02 | Bulk (co)polymerisation of propylene - in presence of a three-component catalyst |
Publications (2)
Publication Number | Publication Date |
---|---|
FR2108766A1 true FR2108766A1 (en) | 1972-05-26 |
FR2108766B1 FR2108766B1 (en) | 1973-07-13 |
Family
ID=9062186
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR7035660A Granted FR2108766A1 (en) | 1970-10-02 | 1970-10-02 | Bulk (co)polymerisation of propylene - in presence of a three-component catalyst |
Country Status (1)
Country | Link |
---|---|
FR (1) | FR2108766A1 (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0006130A1 (en) * | 1978-06-21 | 1980-01-09 | Ato Chimie | Process for the catalytic preparation of polymers or copolymers of alpha-olefins having a high isotacticity index, and composition based on titanium chloride suitable as component of the catalytic systems used in this process |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR1363459A (en) * | 1962-05-11 | 1964-06-12 | Basf Ag | Process and device for the polymerization of monoolefins |
-
1970
- 1970-10-02 FR FR7035660A patent/FR2108766A1/en active Granted
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR1363459A (en) * | 1962-05-11 | 1964-06-12 | Basf Ag | Process and device for the polymerization of monoolefins |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0006130A1 (en) * | 1978-06-21 | 1980-01-09 | Ato Chimie | Process for the catalytic preparation of polymers or copolymers of alpha-olefins having a high isotacticity index, and composition based on titanium chloride suitable as component of the catalytic systems used in this process |
Also Published As
Publication number | Publication date |
---|---|
FR2108766B1 (en) | 1973-07-13 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
ST | Notification of lapse |