FR2045229A5 - (co) polymersion of vinyl monomer using - hydrosoluble catalyst - Google Patents
(co) polymersion of vinyl monomer using - hydrosoluble catalystInfo
- Publication number
- FR2045229A5 FR2045229A5 FR6921207A FR6921207A FR2045229A5 FR 2045229 A5 FR2045229 A5 FR 2045229A5 FR 6921207 A FR6921207 A FR 6921207A FR 6921207 A FR6921207 A FR 6921207A FR 2045229 A5 FR2045229 A5 FR 2045229A5
- Authority
- FR
- France
- Prior art keywords
- catalyst
- polymer
- support
- polymersion
- hydrosoluble
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/34—Polymerisation in gaseous state
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/02—Polymerisation in bulk
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Catalysts (AREA)
Abstract
Bulk or gas phase polymerisation of vinyl monomers is carried out with the catalyst in an aqueous solution whose water content is sufficiently low that the polymer can absorb it and maintain a consistency ranging from a dry powder to a wet cake. The catalytic element comprises a support which has been impregnated with the catalyst solution, and the weight ratio water: support is between 0.02:1 and 1.5:1, particularly between 0.05:1 and 1.1:1. Pref. monomers are vinyl chloride, styrene, acrylonitrile and alkyl (meth) acrylates. Typical catalysts are alkali or ammonium persulphates or perborates and typical supports are silica, glass fibres or CaCO3. Unlike solution or emulsion polymerisations, the polymer is obtained as a powder and without the inclusion of emulsifiers etc.
Priority Applications (12)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR6921207A FR2045229A5 (en) | 1969-06-24 | 1969-06-24 | (co) polymersion of vinyl monomer using - hydrosoluble catalyst |
BE751136D BE751136A (en) | 1969-06-24 | 1970-05-29 | PROCESS FOR THE POLYMERIZATION OR COPOLYMERIZATION OF VINYL MONOMERS AND THE RESIN COMPOSITIONS OBTAINED BY THIS PROCESS |
DE19702027736 DE2027736A1 (en) | 1969-06-24 | 1970-06-05 | Process for the polymerization or copolymerization of vinyl monomers and the plastic products of this process |
ES380486A ES380486A1 (en) | 1969-06-24 | 1970-06-06 | Process for the polymerization and copolymerization of vinyl monomers and the resin compositions obtained thereby |
US48184A US3676413A (en) | 1969-06-24 | 1970-06-22 | Process for the polymerization and copolymerization of vinyl monomers and the resin compositions obtained thereby |
ZA704262A ZA704262B (en) | 1969-06-24 | 1970-06-22 | Polymerisation of vinyl monomers |
GB3045970A GB1310955A (en) | 1969-06-24 | 1970-06-23 | Polymerisation of vinyl monomers |
AT565470A AT307037B (en) | 1969-06-24 | 1970-06-23 | Process for the polymerization or copolymerization of vinyl monomers |
AU16757/70A AU1675770A (en) | 1969-06-24 | 1970-06-24 | Polymerisation of vinyl monomers |
NL7009282A NL7009282A (en) | 1969-06-24 | 1970-06-24 | |
BR219947/70A BR7019947D0 (en) | 1969-06-24 | 1970-06-24 | POLYMERIZATION OR COPOLIMERIZATION PROCESS OF VINYL MONOMERS AS WELL AS RESIDENT COMPOSITIONS OBTAINED BY THIS PROCESS |
JP45054449A JPS4812433B1 (en) | 1969-06-24 | 1970-06-24 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR6921207A FR2045229A5 (en) | 1969-06-24 | 1969-06-24 | (co) polymersion of vinyl monomer using - hydrosoluble catalyst |
Publications (1)
Publication Number | Publication Date |
---|---|
FR2045229A5 true FR2045229A5 (en) | 1971-02-26 |
Family
ID=9036314
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR6921207A Expired FR2045229A5 (en) | 1969-06-24 | 1969-06-24 | (co) polymersion of vinyl monomer using - hydrosoluble catalyst |
Country Status (3)
Country | Link |
---|---|
BR (1) | BR7019947D0 (en) |
FR (1) | FR2045229A5 (en) |
ZA (1) | ZA704262B (en) |
-
1969
- 1969-06-24 FR FR6921207A patent/FR2045229A5/en not_active Expired
-
1970
- 1970-06-22 ZA ZA704262A patent/ZA704262B/en unknown
- 1970-06-24 BR BR219947/70A patent/BR7019947D0/en unknown
Also Published As
Publication number | Publication date |
---|---|
BR7019947D0 (en) | 1973-01-02 |
ZA704262B (en) | 1971-03-31 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
ST | Notification of lapse |