FR1108154A - Manufacture of alkyl nitrates - Google Patents

Manufacture of alkyl nitrates

Info

Publication number
FR1108154A
FR1108154A FR1108154DA FR1108154A FR 1108154 A FR1108154 A FR 1108154A FR 1108154D A FR1108154D A FR 1108154DA FR 1108154 A FR1108154 A FR 1108154A
Authority
FR
France
Prior art keywords
urea
acid
nitric
ester
mineral acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
Other languages
French (fr)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Imperial Chemical Industries Ltd
Original Assignee
Imperial Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Imperial Chemical Industries Ltd filed Critical Imperial Chemical Industries Ltd
Application granted granted Critical
Publication of FR1108154A publication Critical patent/FR1108154A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C203/00—Esters of nitric or nitrous acid
    • C07C203/02—Esters of nitric acid
    • C07C203/04—Esters of nitric acid having nitrate groups bound to acyclic carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C201/00—Preparation of esters of nitric or nitrous acid or of compounds containing nitro or nitroso groups bound to a carbon skeleton
    • C07C201/02—Preparation of esters of nitric acid

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Volatile liquid nitric esters of monohydric aliphatic alcohols are purified substantially from nitrous ester by washing the nitric ester with an excess of an aqueous solution containing urea and a mineral acid in a concetration to cause evolution of gas in the presence of the urea only as long as the nitrous ester is present, and thereafter freeing the nitric ester substantially from said acid and excess urea. The washing with urea and mineral acid is preferably conducted at about 40 DEG C. and is preferably preceded by a washing with water. The mineral acid is preferably nitric acid and the concentration of the aqueous solution in contact with the alkyl nitrate is preferably between 1 and 3 Normal. The urea and mineral acid are preferably employed in the form of the urea salt of the acid, e.g. urea nitrate, a saturated solution thereof being employed. The examples describe the purification of ethyl, isopropyl and secondary butyl nitrate.
FR1108154D 1953-07-10 1954-07-01 Manufacture of alkyl nitrates Expired FR1108154A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB326537X 1953-07-10

Publications (1)

Publication Number Publication Date
FR1108154A true FR1108154A (en) 1956-01-10

Family

ID=10341982

Family Applications (1)

Application Number Title Priority Date Filing Date
FR1108154D Expired FR1108154A (en) 1953-07-10 1954-07-01 Manufacture of alkyl nitrates

Country Status (6)

Country Link
BE (1) BE530298A (en)
CH (1) CH326537A (en)
DE (1) DE1050325B (en)
FR (1) FR1108154A (en)
GB (1) GB743141A (en)
NL (1) NL88445C (en)

Also Published As

Publication number Publication date
CH326537A (en) 1957-12-31
GB743141A (en) 1956-01-11
BE530298A (en)
NL88445C (en)
DE1050325B (en) 1959-02-12

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