ES8605653A1 - Method for replacing PCB-containing coolants in electrical induction apparatus with substantially PCB-free dielectric coolants. - Google Patents

Method for replacing PCB-containing coolants in electrical induction apparatus with substantially PCB-free dielectric coolants.

Info

Publication number
ES8605653A1
ES8605653A1 ES539090A ES539090A ES8605653A1 ES 8605653 A1 ES8605653 A1 ES 8605653A1 ES 539090 A ES539090 A ES 539090A ES 539090 A ES539090 A ES 539090A ES 8605653 A1 ES8605653 A1 ES 8605653A1
Authority
ES
Spain
Prior art keywords
pcb
coolant
electrical
tank
cooling liquid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES539090A
Other languages
Spanish (es)
Other versions
ES539090A0 (en
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Union Carbide Corp
Original Assignee
Union Carbide Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Union Carbide Corp filed Critical Union Carbide Corp
Publication of ES8605653A1 publication Critical patent/ES8605653A1/en
Publication of ES539090A0 publication Critical patent/ES539090A0/en
Expired legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01FMAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
    • H01F27/00Details of transformers or inductances, in general
    • H01F27/08Cooling; Ventilating
    • H01F27/10Liquid cooling
    • H01F27/12Oil cooling
    • H01F27/14Expansion chambers; Oil conservators; Gas cushions; Arrangements for purifying, drying, or filling
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B08CLEANING
    • B08BCLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
    • B08B3/00Cleaning by methods involving the use or presence of liquid or steam
    • B08B3/04Cleaning involving contact with liquid
    • B08B3/08Cleaning involving contact with liquid the liquid having chemical or dissolving effect
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G21/00Refining of hydrocarbon oils, in the absence of hydrogen, by extraction with selective solvents
    • C10G21/006Refining of hydrocarbon oils, in the absence of hydrogen, by extraction with selective solvents of waste oils, e.g. PCB's containing oils

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Power Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Organic Insulating Materials (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • General Induction Heating (AREA)
  • Processing Of Solid Wastes (AREA)
  • Transformer Cooling (AREA)
  • Lubricants (AREA)
  • Insulating Of Coils (AREA)

Abstract

Method for replacing a coolant containing PCB in electrical induction having a tank containing the PCB-containing coolant and an electrical winding and porous solid cellulosic electrical insulation immersed in the PCB-containing coolant with a substantially PCB-free permanent coolant to convert said electrical apparatus into one in which the rate of elution of PCB into the PCB-free coolant is below the maximum allowable rate of elution into the coolant of an electrical apparatus rated as non-PCB, the porous electrical insulation being impregnated with said PCB-containing coolant. The method comprises the steps of: (a) draining the PCB-containing coolant from said tank to remove a major portion of the PCB-containing coolant contained by it (b) filling the tank with an interim dielectric cooling liquid that is (i) miscible with PCB, (ii) sufficiently low in viscosity to circulate within said tank and penetrate the interstices of the porous solid electrical insulation, and (iii) capable of being readily separated from said PCB (c) electrically operating the electrical induction apparatus for a period sufficient to elute PCB contained in the PCB-containing coolant impregnated in the porous insulation therefrom into the interim dielectric cooling liquid (d) thereafter draining the interim dielectric cooling liquid containing the eluted PCB from the tank (e) repeating the cycle of steps (b), (c) and (d), when the rate of elution of PCB into the interim dielectric cooling liquid exceeds 0.55 ppm of PCB per day based on the weight of the permanent dielectric coolant, a sufficient number of times until the rate of elution of PCB into the interim dielectric cooling liquid does not exceed the rate of 50 ppm PCB based on the weight of the permanent coolant after 90 days of electrical operation and (f) filling the tank with a substantially PCB-free permanent coolant selected from the group consisting of high boiling, high viscosity, silicone oils, synthetic ester fluids, poly-alpha-olefin oils and hydrocarbon oils.
ES539090A 1983-12-28 1984-12-27 Method for replacing PCB-containing coolants in electrical induction apparatus with substantially PCB-free dielectric coolants. Expired ES8605653A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US56630683A 1983-12-28 1983-12-28
US67527884A 1984-11-27 1984-11-27

Publications (2)

Publication Number Publication Date
ES8605653A1 true ES8605653A1 (en) 1986-03-16
ES539090A0 ES539090A0 (en) 1986-03-16

Family

ID=27074146

Family Applications (1)

Application Number Title Priority Date Filing Date
ES539090A Expired ES8605653A1 (en) 1983-12-28 1984-12-27 Method for replacing PCB-containing coolants in electrical induction apparatus with substantially PCB-free dielectric coolants.

Country Status (20)

Country Link
EP (1) EP0147860B1 (en)
JP (1) JPH0644534B2 (en)
KR (1) KR900005687B1 (en)
AR (1) AR244461A1 (en)
AU (1) AU570294B2 (en)
BR (1) BR8407245A (en)
CA (1) CA1262606A (en)
DE (1) DE3462640D1 (en)
ES (1) ES8605653A1 (en)
FI (1) FI78367C (en)
GR (1) GR82586B (en)
HK (1) HK56389A (en)
IL (1) IL73971A (en)
IN (1) IN163604B (en)
MX (1) MX168456B (en)
NZ (1) NZ210768A (en)
PH (1) PH23329A (en)
PT (1) PT79758A (en)
SG (1) SG22889G (en)
WO (1) WO1985002937A1 (en)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4790337A (en) * 1984-07-18 1988-12-13 Quadrex Hps Inc. Apparatus for removing PCB's from electrical apparatus
US4738780A (en) * 1984-11-27 1988-04-19 Union Carbide Corporation Method for replacing PCB-containing coolants in electrical induction apparatus with substantially PCB-free dielectric coolants
GB2182925B (en) * 1985-11-13 1990-07-18 Quadrex Hps Inc Process for removing pcb's from electrical apparatus
EP0290098B1 (en) * 1987-05-07 1990-11-14 Micafil Ag Process and apparatus for extracting oil or polychlorinated biphenyls from impregnated electrical components by means of a solvating agent, and distillation of the solvent
US4950837A (en) * 1989-07-18 1990-08-21 General Electric Company Method for reclassifying PCB transformers
US6380454B1 (en) 1991-03-15 2002-04-30 Luciano A. Gonzalez Destruction of polychlorinated biphenyls
JPH0555054A (en) * 1991-08-26 1993-03-05 Mitsubishi Electric Corp Medium filling method for electrical machinery
FR2705140B1 (en) * 1993-05-11 1995-07-28 Elf Antar France Method of replacing the lubrication product for the conversion of existing refrigeration systems to refrigerants without action on atmospheric ozone.

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BR7703653A (en) * 1976-06-08 1978-04-04 Rhone Poulenc Ind NEW DIELETRIC LIQUIDS
US4124834A (en) * 1977-10-05 1978-11-07 Westinghouse Electric Corp. Electrical inductive apparatus
US4357175A (en) * 1980-04-10 1982-11-02 Stauffer Chemical Company Process for cleaning the interiors of vessels
US4299704A (en) * 1980-05-19 1981-11-10 General Electric Company Method for removing polychlorinated biphenyls from contaminated transformer dielectric liquid
US4379746A (en) * 1980-08-18 1983-04-12 Sun-Ohio, Inc. Method of destruction of polychlorinated biphenyls
US4396436A (en) * 1981-07-20 1983-08-02 Aluminum Company Of America Method and flushing for removing hydraulic fluid from hydraulic systems

Also Published As

Publication number Publication date
FI853299L (en) 1985-08-28
AU570294B2 (en) 1988-03-10
KR850700178A (en) 1985-10-25
EP0147860B1 (en) 1987-03-11
JPH0644534B2 (en) 1994-06-08
IN163604B (en) 1988-10-15
HK56389A (en) 1989-07-21
EP0147860A2 (en) 1985-07-10
JPS61500880A (en) 1986-05-01
WO1985002937A1 (en) 1985-07-04
DE3462640D1 (en) 1987-04-16
PH23329A (en) 1989-07-14
MX168456B (en) 1993-05-25
FI853299A0 (en) 1985-08-28
IL73971A (en) 1988-12-30
CA1262606A (en) 1989-11-07
AU3783285A (en) 1985-07-12
PT79758A (en) 1985-01-01
FI78367B (en) 1989-03-31
BR8407245A (en) 1985-11-26
KR900005687B1 (en) 1990-08-06
EP0147860A3 (en) 1985-08-07
ES539090A0 (en) 1986-03-16
GR82586B (en) 1985-04-30
FI78367C (en) 1989-07-10
SG22889G (en) 1990-07-06
AR244461A1 (en) 1993-10-29
NZ210768A (en) 1988-07-28

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Legal Events

Date Code Title Description
FD1A Patent lapsed

Effective date: 19970612